CN110317037A - The tiger fur spot tortoise shell glaze ceramics and its manufacture craft of glazing - Google Patents

The tiger fur spot tortoise shell glaze ceramics and its manufacture craft of glazing Download PDF

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Publication number
CN110317037A
CN110317037A CN201910572753.2A CN201910572753A CN110317037A CN 110317037 A CN110317037 A CN 110317037A CN 201910572753 A CN201910572753 A CN 201910572753A CN 110317037 A CN110317037 A CN 110317037A
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Prior art keywords
parts
tortoise shell
tiger fur
spot
fur spot
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CN201910572753.2A
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CN110317037B (en
Inventor
郑泽洽
郑鹏飞
郑衍彬
郑晟亮
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DEHUA SHUNERMEI CRAFTS Co Ltd
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DEHUA SHUNERMEI CRAFTS Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/04Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
    • B28B11/044Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243Setting, e.g. drying, dehydrating or firing ceramic articles
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The present invention relates to ceramic fabrication technique fields, are specifically related to the tiger fur spot tortoise shell glaze ceramics and its manufacture craft of an a kind of glazing.The tiger fur spot tortoise shell glaze ceramics of a glazing of this kind, including ceramic body and tiger fur spot tortoise shell glaze, the iron-content of the ceramic body is 7.8-8.3%, and the tiger fur spot tortoise shell glaze raw material includes potassium feldspar, quartz, white clouds soil, sodium pyroborate, calcium carbonate, ZnOw, yellow ferric oxide.The tiger fur spot tortoise shell glaze ceramics of a glazing provided by the invention, the tiger fur spot tortoise shell glaze ceramics being fired into have the background color of dark brown, the golden yellow color lump of large area is showed on the background color of dark brown, and the dark brown lines formed in golden yellow speckle with ZnOw, form the effect of tiger fur spot;Tiger fur spot tortoise shell glaze ceramics of the invention provide a kind of completely new ceramic decoration method, and firing can be completed in a glazing, with positive meaning and have positive economic benefit to the development of promotion ceramic product.

Description

The tiger fur spot tortoise shell glaze ceramics and its manufacture craft of glazing
Technical field
The present invention relates to ceramic fabrication technique fields, are specifically related to the tiger fur spot tortoise shell glaze ceramics and its system of a glazing Make technique.
Background technique
Tortoise shell glaze is that a kind of glaze is black, the colors such as yellow interweave mixing, the moist glaze of tone.Tortoise shell glaze is Song dynasty's period Jiangxi Chien ware create burning, a kind of black glaze is first imposed on base face, then with the mixing of the glass glaze containing lime and iron (Fe) element Glaze is arbitrarily write freely and easily, and irregular speckle is formed, the element of this iron content (Fe), after roasting that colour generation is yellowish-brown, is contrasted with black matrix And mutually blend, such as hawksbill turtle, have very special beauty.
Although the oxidizing roasting that the yellowish-brown in tortoise shell glaze is known as iron (Fe) element is made, colouration mechanism has compared clearly Chu, but discovery is tested, the glaze body surface face yellowish-brown area that addition iron oxide is fired into glaze merely is small, and hawksbill turtle style is special Levy unobvious, the appreciative of porcelain appearance is poor.
To solve the above problems, application No. is the applications for a patent for invention of CN201711237439.6 to disclose a kind of hawksbill turtle flower Glaze and its method for cooking, this kind of hawksbill turtle fancy glaze is by the way that di-iron trioxide modification, modified di-iron trioxide is for matching Bottom set glaze, only needs once-firing, can burn out and mix with the colors such as natural black, Huang intertexture, the surface pattern of this kind of tortoise shell glaze For decorative pattern, there are also very big gaps with the effect of traditional tiger fur spot hawksbill turtle glaze;In addition, needing two when this kind of hawksbill turtle fancy glaze manufacture Secondary glazing, manufacturing process are complicated.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of tiger fur spot tortoise shell glaze ceramics of a glazing and its Manufacture craft.
To achieve the above object, The technical solution adopted by the invention is as follows: the tiger fur spot tortoise shell glaze of a glazing is ceramic, Be characterized in that: including ceramic body and tiger fur spot tortoise shell glaze, the iron-content of the ceramic body is 7.8-8.3%, the tiger fur Spot tortoise shell glaze raw material weight component is as follows: 30-40 parts of potassium feldspar, 20-30 parts of quartz, 10-15 parts of white clouds soil, sodium pyroborate 1-5 parts, 5-10 parts of calcium carbonate, 5-10 parts of ZnOw, 5-10 parts of yellow ferric oxide.
Optimization, the raw material components of ceramic body are as follows: soil 50-60 parts of Jianyang, 10-15 parts of smolmitza, yellow mud 15- 20, volcanic ash 10-15 parts.
Optimization, the raw material components of ceramic body are as follows: Jianyang soil 56 parts, 14 parts of smolmitza, yellow mud 16, volcanic ash 14 Part, the iron-content of the green body is 7.9%.
Optimization, tiger fur spot tortoise shell glaze raw material weight component is as follows: 38 parts of potassium feldspar, 25 parts of quartz, 13 parts of white clouds soil, coke 4 parts of Boratex, 6 parts of calcium carbonate, 8 parts of ZnOw, 6 parts of yellow ferric oxide.
Optimization, the raw material components of ceramic body are as follows: Jianyang soil 56 parts, 14 parts of smolmitza, yellow mud 16, volcanic ash 14 Part, the iron-content of the green body is 8.1%.
Optimization, tiger fur spot tortoise shell glaze raw material weight component is as follows: 32 parts of potassium feldspar, 28 parts of quartz, 12 parts of white clouds soil, coke 4 parts of Boratex, 6 parts of calcium carbonate, 10 parts of ZnOw, 8 parts of yellow ferric oxide.
A kind of manufacture craft of the tiger fur spot tortoise shell glaze ceramics of a glazing, makes the tiger fur spot turtle of an above-mentioned glazing Hawksbill turtle glaze ceramics, the specific steps are as follows:
Step 1, base prepares green body, and the green body repaired biscuit made is formed;
Step 2, enamel frit makeing prepares tiger fur spot tortoise shell glaze according to tiger fur spot tortoise shell glaze raw material components;
Step 3, billet surface moisture content is waited to apply tiger fur spot tortoise shell glaze in billet surface when 3-5%;
Step 4, glaze green body will be contained after waiting body drying to be put into kiln, formed by a firing, firing temperature 1200- 1210℃。
Further, tiger fur spot tortoise shell glaze is put into ball mill by material in step 2: ball: water=1.0:1.8-2.1: The ratio ball milling of 1-1.2, Ball-milling Time are 1-3 hours.
Further, the glazed thickness that tiger fur spot tortoise shell glaze is applied in step 3 is 0.6-1.2mm.
Further, the firing control in step 4 is as follows:
Low-temperature zone: in oxidizing atmosphere in kiln, 500 DEG C were risen to by room temperature through 5-6 hours;
Warming-up section: turning reducing atmosphere in kiln, pine is put into kiln, was warming up to firing temperature by 6-8 hours, And 3-4 hours are kept the temperature under firing temperature state;
Cooling section: 60-30 DEG C is cooled in kiln, 8-10 hours cooling time.
The tiger fur spot tortoise shell glaze ceramics of a glazing provided by the invention, pass through the iron-content and tiger fur to ceramic body Spot tortoise shell glaze raw material components are controlled, and the tiger fur spot tortoise shell glaze ceramics being fired into have the background color of dark brown, in dark brown The golden yellow color lump of large area, and the dark brown colo(u)r streak formed in golden yellow speckle with ZnOw are showed on background color Item forms the effect of tiger fur spot;Tiger fur spot tortoise shell glaze ceramics of the invention provide a kind of completely new ceramic decoration method, once Firing can be completed in glazing, with positive meaning and has positive economic benefit to the development of promotion ceramic product.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
A kind of tiger fur spot tortoise shell glaze ceramics of a glazing, including ceramic body and tiger fur spot tortoise shell glaze, the ceramic blank The iron-content of body is 7.8-8.3%, and the tiger fur spot tortoise shell glaze raw material weight component is as follows: 30-40 parts of potassium feldspar, quartz 20-30 parts, 10-15 parts of white clouds soil, 1-5 parts of sodium pyroborate, 5-10 parts of calcium carbonate, 5-10 parts of ZnOw, yellow oxidation 5-10 parts of iron;Wherein the raw material components of ceramic body are as follows: soil 50-60 parts of Jianyang, 10-15 parts of smolmitza, yellow mud 15- 20, volcanic ash 10-15 parts.
The manufacture craft of the tiger fur spot tortoise shell glaze ceramics of glazing, makes the tiger fur spot tortoise shell glaze of an above-mentioned glazing Ceramics, the specific steps are as follows:
Step 1, base prepares green body, and the green body repaired biscuit made is formed;
Step 2, tiger fur spot tortoise shell glaze is put into ball mill by material by enamel frit makeing according to tiger fur spot tortoise shell glaze raw material components: Ball: water=1.0:1.8-2.1:1-1.2 ratio ball milling, Ball-milling Time are 1-3 hours, prepare tiger fur spot tortoise shell glaze;
Step 3, wait billet surface moisture content to apply tiger fur spot tortoise shell glaze in billet surface when 3-5%, glazed thickness is 0.6-1.2mm;
Step 4, glaze green body will be contained after waiting body drying to be put into kiln, formed by a firing, firing temperature 1200- 1210 DEG C, firing control is as follows:
Low-temperature zone: in oxidizing atmosphere in kiln, 500 DEG C were risen to by room temperature through 5-6 hours;
Warming-up section: turning reducing atmosphere in kiln, pine is put into kiln, was warming up to firing temperature by 6-8 hours, And 3-4 hours are kept the temperature under firing temperature state;
Cooling section: 60-30 DEG C is cooled in kiln, 8-10 hours cooling time.
Specific embodiment one:
A kind of tiger fur spot tortoise shell glaze ceramics of a glazing, including ceramic body and tiger fur spot tortoise shell glaze, the ceramic blank The iron-content of body is 7.9%, and the tiger fur spot tortoise shell glaze raw material weight component is as follows: 38 parts of potassium feldspar, 25 parts of quartz, white clouds soil 13 parts, 4 parts of sodium pyroborate, 6 parts of calcium carbonate, 8 parts of ZnOw, 6 parts of yellow ferric oxide;Wherein the raw material components of ceramic body are such as Under: Jianyang soil 56 parts, 14 parts of smolmitza, yellow mud 16,14 parts of volcanic ash.
The manufacture craft of the tiger fur spot tortoise shell glaze ceramics of glazing, makes the tiger fur spot tortoise shell glaze of an above-mentioned glazing Ceramics, the specific steps are as follows:
Step 1, base prepares green body, and the green body repaired biscuit made is formed;
Step 2, tiger fur spot tortoise shell glaze is put into ball mill by material by enamel frit makeing according to tiger fur spot tortoise shell glaze raw material components: Ball: water=1:1.9:1 ratio ball milling, Ball-milling Time are 2 hours, prepare tiger fur spot tortoise shell glaze;
Step 3, tiger fur spot tortoise shell glaze is applied in billet surface when waiting billet surface moisture content is 3.5%, glazed thickness is 0.8mm;
Step 4, glaze green body will be contained after waiting body drying to be put into kiln, formed by a firing, firing temperature is 1205 DEG C, is burnt It is as follows at controlling:
Low-temperature zone: in oxidizing atmosphere in kiln, 500 DEG C were risen to by room temperature through 5 hours;
Warming-up section: turning reducing atmosphere in kiln, pine is put into kiln, by being warming up within 7 hours firing temperature, and 3 hours are kept the temperature under firing temperature state;
Cooling section: 50 DEG C are cooled in kiln, 9 hours cooling times.
Specific embodiment two:
A kind of tiger fur spot tortoise shell glaze ceramics of a glazing, including ceramic body and tiger fur spot tortoise shell glaze, the ceramic blank The iron-content of body is 8.1%, and the tiger fur spot tortoise shell glaze raw material weight component is as follows: 32 parts of potassium feldspar, 28 parts of quartz, white clouds soil 12 parts, 4 parts of sodium pyroborate, 6 parts of calcium carbonate, 10 parts of ZnOw, 8 parts of yellow ferric oxide;The wherein raw material components of ceramic body It is as follows: Jianyang soil 56 parts, 14 parts of smolmitza, yellow mud 16,14 parts of volcanic ash.
The manufacture craft of the tiger fur spot tortoise shell glaze ceramics of glazing, makes the tiger fur spot tortoise shell glaze of an above-mentioned glazing Ceramics, the specific steps are as follows:
Step 1, base prepares green body, and the green body repaired biscuit made is formed;
Step 2, tiger fur spot tortoise shell glaze is put into ball mill by material by enamel frit makeing according to tiger fur spot tortoise shell glaze raw material components: Ball: water=1:2:1.1 ratio ball milling, Ball-milling Time are 3 hours, prepare tiger fur spot tortoise shell glaze;
Step 3, tiger fur spot tortoise shell glaze is applied in billet surface when waiting billet surface moisture content is 5%, glazed thickness is 1.1mm;
Step 4, glaze green body will be contained after waiting body drying to be put into kiln, formed by a firing, firing temperature is 1210 DEG C, is burnt It is as follows at controlling:
Low-temperature zone: in oxidizing atmosphere in kiln, 500 DEG C were risen to by room temperature through 6 hours;
Warming-up section: turning reducing atmosphere in kiln, pine is put into kiln, by being warming up within 7 hours firing temperature, and 4 hours are kept the temperature under firing temperature state;
Cooling section: 30 DEG C are cooled in kiln, 10 hours cooling times.
The tiger fur spot tortoise shell glaze ceramics of a glazing provided by the invention, pass through the iron-content and tiger fur to ceramic body Spot tortoise shell glaze raw material components are controlled, and the tiger fur spot tortoise shell glaze ceramics being fired into have the background color of dark brown, in dark brown The golden yellow color lump of large area, and the dark brown colo(u)r streak formed in golden yellow speckle with ZnOw are showed on background color Item forms the effect of tiger fur spot;Tiger fur spot tortoise shell glaze ceramics of the invention provide a kind of completely new ceramic decoration method, once Firing can be completed in glazing, is fired in sintering procedure by change and is divided into and puts into pine, makes tiger fur by redox reaction Spot tortoise shell glaze ceramics form the background color of dark brown, with positive meaning and have actively to the development of promotion ceramic product Economic benefit.
It above are only the specific embodiment of the present invention, but the design concept of the present invention is not limited to this, all benefits It is made a non-material change to the present invention, should all be belonged to behavior that violates the scope of protection of the present invention with this design.

Claims (10)

1. the tiger fur spot tortoise shell glaze ceramics of a glazing, it is characterised in that: including ceramic body and tiger fur spot tortoise shell glaze, the pottery The iron-content of porcelain billet body is 7.8-8.3%, and the tiger fur spot tortoise shell glaze raw material weight component is as follows: 30-40 parts of potassium feldspar, stone 20-30 parts of English, 10-15 parts of white clouds soil, 1-5 parts of sodium pyroborate, 5-10 parts of calcium carbonate, 5-10 parts of ZnOw, yellow oxygen Change iron 5-10 parts.
2. the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 1, it is characterised in that: the ceramic body Raw material components are as follows: soil 50-60 parts of Jianyang, 10-15 parts of smolmitza, yellow mud 15-20,10-15 parts of volcanic ash.
3. the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 2, it is characterised in that: the ceramic body Raw material components are as follows: Jianyang soil 56 parts, 14 parts of smolmitza, yellow mud 16,14 parts of volcanic ash, the iron-content of the green body are 7.9%.
4. the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 1 or 3, it is characterised in that: the tiger fur spot Tortoise shell glaze raw material weight component is as follows: 38 parts of potassium feldspar, quartz 25 parts, white clouds soil 13 parts, 4 parts of sodium pyroborate, 6 parts of calcium carbonate, 8 parts of ZnOw, 6 parts of yellow ferric oxide.
5. the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 2, it is characterised in that: the ceramic body Raw material components are as follows: Jianyang soil 56 parts, 14 parts of smolmitza, yellow mud 16,14 parts of volcanic ash, the iron-content of the green body are 8.1%.
6. the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 1 or 5, it is characterised in that: the tiger fur spot Tortoise shell glaze raw material weight component is as follows: 32 parts of potassium feldspar, quartz 28 parts, white clouds soil 12 parts, 4 parts of sodium pyroborate, 6 parts of calcium carbonate, 10 parts of ZnOw, 8 parts of yellow ferric oxide.
7. the manufacture craft of the tiger fur spot tortoise shell glaze ceramics of a glazing, production requires a glazing described in 1-6 any one Tiger fur spot tortoise shell glaze ceramics, the specific steps are as follows:
Step 1, base prepares green body, and the green body repaired biscuit made is formed;
Step 2, enamel frit makeing prepares tiger fur spot tortoise shell glaze according to tiger fur spot tortoise shell glaze raw material components;
Step 3, billet surface moisture content is waited to apply tiger fur spot tortoise shell glaze in billet surface when 3-5%;
Step 4, glaze green body will be contained after waiting body drying to be put into kiln, formed by a firing, firing temperature is 1200-1210 DEG C.
8. the manufacture craft of the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 7, it is characterised in that: described Tiger fur spot tortoise shell glaze is put into ball mill in material in step 2: ball: water=1.0:1.8-2.1:1-1.2 ratio ball milling, ball Time consuming is 1-3 hours.
9. the manufacture craft of the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 7, it is characterised in that: described The glazed thickness that tiger fur spot tortoise shell glaze is applied in step 3 is 0.6-1.2mm.
10. the manufacture craft of the tiger fur spot tortoise shell glaze ceramics of a glazing according to claim 7, which is characterized in that step Firing control in rapid 4 is as follows:
Low-temperature zone: in oxidizing atmosphere in kiln, 500 DEG C were risen to by room temperature through 5-6 hours;
Warming-up section: turning reducing atmosphere in kiln, pine is put into kiln, by being warming up within 6-8 hours firing temperature, and 3-4 hours are kept the temperature under firing temperature state;
Cooling section: 60-30 DEG C is cooled in kiln, 8-10 hours cooling time.
CN201910572753.2A 2019-06-28 2019-06-28 One-time glazed shell hawksbill carapace glaze ceramic and manufacturing process thereof Active CN110317037B (en)

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* Cited by examiner, † Cited by third party
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CN113003937A (en) * 2021-05-07 2021-06-22 武汉遇知音文化发展有限公司 Hawksbill turtle stain transmutation glaze porcelain and preparation method thereof
CN113003937B (en) * 2021-05-07 2024-01-16 武汉遇知音文化发展有限公司 Hawksbill-shaped colored-spot transmutation glaze porcelain and preparation method thereof
CN113480175A (en) * 2021-08-20 2021-10-08 德化县顺尔美工艺品有限公司 Lichen mottled glaze ceramic and preparation method thereof
CN113480175B (en) * 2021-08-20 2022-10-14 德化县顺尔美工艺品有限公司 Lichen mottled glaze ceramic and preparation method thereof

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