CN107417102A - Low temperature transmutation plum blossom glaze porcelain and its preparation technology - Google Patents
Low temperature transmutation plum blossom glaze porcelain and its preparation technology Download PDFInfo
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- CN107417102A CN107417102A CN201710352272.1A CN201710352272A CN107417102A CN 107417102 A CN107417102 A CN 107417102A CN 201710352272 A CN201710352272 A CN 201710352272A CN 107417102 A CN107417102 A CN 107417102A
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
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- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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Abstract
The invention belongs to ceramic field, more particularly to a kind of low temperature transmutation plum blossom glaze porcelain and preparation technology.This kind of low temperature transmutation plum blossom glaze porcelain, including ceramic body, in addition to base substrate and the ground glaze layer and cover coat that are arranged at ceramic body surface.This kind of low temperature transmutation plum blossom glaze porcelain and preparation method thereof, the porcelain burnt out has the background color of brown, dark reddish brown, pink, pink spot is distributed on the ground-coat enamel of dark color, formed on every piece of spot substantially in the scarce glaze pore of plum blossom-shaped arrangement, it appears coarse dry and astringent, water can fill up scarce glaze pore rapidly after meeting water, make glaze paint one integrated mass, naturally it is just glittering and translucent, just like " Yuhuatai colorful pebble " water breakthrough with regard to bright speciality, there is unique artistic effect.The ceramic body of this kind of low temperature transmutation plum blossom glaze porcelain, ground-coat enamel, cover-coat enamel raw material in largely used feldspar mine tailing powder that there is the significant value of environmental protection as raw material, while effectively reduce the production cost of raw material, increase economic efficiency and the market competitiveness.
Description
Technical field
The invention belongs to ceramic field, more particularly to a kind of low temperature transmutation plum blossom glaze porcelain and preparation technology.
Background technology
For ceramic in China using widely, the technology for preparing ceramics is also highly developed.Traditional ceramic surface
Trailing is that in ceramic surface glazing, glaze layer is smooth, brightness is high, can both make ceramic outward appearance more beautiful, and can increase again
Add its tolerance level.It is oxidized or go back original work due to containing a variety of pigmentation elements in kiln when furnace transmutation glaze is that implements are burnt till in kiln
With unexpected glaze colours effect is presented after kiln discharge.Traditional furnace transmutation glaze burns till for high temperature, firing temperature 1200 DEG C with
On, firing time is mostly at 12 more than hour, and its firing temperature is high, time length, and energy loss is big, and cost is high and not environmentally.
To solve the above problems, application publication number be the A of CN 105152684 application for a patent for invention to disclose lightweight porcelain low temperature transmutation red
Mottled enamels material formula, method of preparation and use, the glazing effect that this kind of lightweight porcelain low temperature transmutation erythema glaze is burnt out have red
Or the background color of copper red color, irregular black splotch, the respectively size of black splotch and density are uniformly distributed on background color
Changed according to ceramic type and glazing thickness, there is unique artistic effect.
With the continuous improvement of people's living standards, aesthetic requirement is also constantly changing, it is special to be aided with glaze paint
Texture decorated.It can not only expire so if can develop and be different from the porcelain of existing low temperature furnace transmutation glaze glazing effect
The aesthetic needs of sufficient consumer, moreover it is possible to a kind of brand-new ceramic is provided, had actively to the development for promoting ceramic product
Meaning.
The content of the invention
In order to solve the above problems, the present invention provides a kind of low temperature transmutation plum blossom glaze porcelain and its preparation technology.
To achieve the above object, low temperature transmutation plum blossom glaze porcelain provided by the invention, including ceramic body, its feature exist
In：It is also as follows including base substrate and the ground glaze layer and cover coat that are arranged at ceramic body surface, the ceramic body, its parts by weight：
Feldspar mine tailing powder 25-35, kiln slag 15-20 parts, calcination of talc 15-20 parts, bauxite clay 10-15 parts, attaclay 5-10, silicon
Limestone flour 5-10 parts, kaolin 1-5 parts, barium sulphide 1-5 parts, lithium feldspar 1-5 parts；The ground glaze layer, its parts by weight are as follows：It is black viscous
Native 20-30 parts, calcining barium carbonate 15-20 parts, sericite 15-20 parts, feldspar mine tailing powder 10-15 parts, potassium feldspar 10-15 parts,
Chromium oxide 5-15 parts, kaolin 2-10 parts；The cover coat, its parts by weight are as follows：Potassium feldspar 20-30 parts, quartzy 20-30 parts,
Kaolin 10-15 parts, tin frit 5-10 parts, glass 5-10 parts, glutinous rice flour 1-5, cupric oxalate 1-5 parts, zinc oxide 1-5 parts, oxidation
Sodium 1-5 parts, bamboo charcoal 1-5 parts, feldspar mine tailing powder 1-5 parts.
Optimization, the parts by weight of ceramic body are as follows：Feldspar mine tailing powder 28,19 parts of kiln slag, 16 parts of calcination of talc, aluminum
13 parts of clay, attaclay 7,6 parts of wollastonite in powder, 3 parts of kaolin, 4 parts of barium sulphide, 4 parts of lithium feldspar.
Optimize, ground glaze layer, its parts by weight is as follows：26 parts of smolmitza, 17 parts of barium carbonate of calcining, 16 parts of sericite, feldspar
13 parts of mine tailing powder, 14 parts of potassium feldspar, 6 parts of chromium oxide, 8 parts of kaolin.
Optimize, cover coat, its parts by weight is as follows：26 parts of potassium feldspar, quartz 24 parts, 14 parts of kaolin, 9 parts of tin frit,
8 parts of glass, glutinous rice flour 4,3 parts of cupric oxalate, 4 parts of zinc oxide, 3 parts of sodium oxide molybdena, 2 parts of bamboo charcoal, feldspar mine tailing powder 3.
Optimization, the thickness of cover coat is 0.1-0.2mm, and the thickness of the ground glaze layer is 0.3-0.5mm.
The preparation technology of low temperature transmutation plum blossom glaze porcelain, it is characterised in that prepare the low temperature kiln described in above-mentioned any one
Become plum blossom glaze porcelain, comprise the following steps that：
Step 1, carry out proportioning by ceramic body composition of raw materials to weigh, ceramic body glaze slip be made,；
Step 2, carry out proportioning by ground glaze layer composition of raw materials to weigh, ground-coat enamel, material are made respectively after adding water for ball milling：Ball：Water
Mass ratio is 3：1-2：1-3 carries out wet ball grinding 1h~3h, and the mesh sieve of 80 mesh -100 is crossed after ball milling；
Step 3, carry out proportioning by cover-coat enamel composition of raw materials to weigh, cover-coat enamel, material are made respectively after adding water for ball milling：Ball：The matter of water
Amount is than being 2：1：2-3, wet ball grinding 5h~8h is carried out, the mesh sieve of 200 mesh -300 is crossed after ball milling；
Step 4, after waiting ceramic body to be completely dried, ground-coat enamel is applied on ceramic body surface；
Step 5, ceramic body is made using glaze slip, after waiting ceramic body to be completely dried, one is applied on ceramic body surface
Layer ground-coat enamel, after waiting cover-coat enamel to dry, to ground-coat enamel surface spraying cover-coat enamel；
Step 6, the ceramic body for applying cracking ground glaze layer and cover coat is put into kiln and once formed by a firing, burn till temperature
Spend for 1220-1260 DEG C, after kiln reaches firing temperature, be at the uniform velocity cooled to natural cooling.
Further, the feldspar mine tailing used in step 1, step 2 in ceramic body raw material and ground-coat enamel, successively through crushing,
After magnetic separation, 1080 degrees Celsius are calcined.
Further, the B concentration of ground-coat enamel is 50-60 degree during glazing, and the B concentration of cover-coat enamel is 30- during glazing
40 degree.
Further, the moisture content after step 4 body drying is 1-2%.
Further, when being burnt till in step 6, in step 6 the firing temperature control of kiln be divided into five sections, it is specific as follows：
A：Under oxidizing atmosphere, kiln is at the uniform velocity warming up to 500 DEG C through 30-40 minutes；
B：Kiln continues to heat up, and is warming up to 800 DEG C through 1.5-2 hours, is incubated 20-30 minutes；
C：Turn reducing atmosphere, through 3-5 minutes, furnace heating-up to firing temperature, be incubated 2-3 hours；
D：Kiln is cooled to 1000 DEG C with 100 DEG C/h-120 DEG C/h rate of temperature fall under reducing atmosphere；
E：Turn oxidizing atmosphere, fast cooling is cooled to 600 DEG C by 1000 DEG C of degree through 10-30 minutes, is being naturally cooling to out
Kiln.
Low temperature transmutation plum blossom glaze porcelain provided by the invention and preparation method thereof, use the composition of raw materials and low temperature kiln of uniqueness
Become burning process, the porcelain burnt out has the background color of brown, dark reddish brown, is distributed on the ground-coat enamel of dark color pink, pink
Spot, formed on every piece of spot substantially in the scarce glaze pore of plum blossom-shaped arrangement, it appears coarse dry and astringent, water can fill up rapidly after meeting water
Glaze pore is lacked, makes glaze paint one integrated mass, it is naturally just glittering and translucent, just like " Yuhuatai colorful pebble " water breakthrough with regard to bright speciality, there is uniqueness
Artistic effect.The ceramic body of this kind of low temperature transmutation plum blossom glaze porcelain, ground-coat enamel, cover-coat enamel raw material in largely used feldspar mine tailing
Powder has the significant value of environmental protection as raw material, while effectively reduces the production cost of raw material, increases economic efficiency and market
Competitiveness.
Embodiment
Below by way of embodiment, the invention will be further described.
Low temperature transmutation plum blossom glaze porcelain, including ceramic body, it is characterised in that：Also include base substrate and be arranged at ceramic body
The ground glaze layer and cover coat on surface,
The ceramic body, its parts by weight are as follows：Feldspar mine tailing powder 25-35, kiln slag 15-20 parts, calcination of talc 15-20
Part, bauxite clay 10-15 parts, attaclay 5-10, wollastonite in powder 5-10 parts, kaolin 1-5 parts, barium sulphide 1-5 parts, lithium feldspar
1-5 parts；
The ground glaze layer, its parts by weight are as follows：Smolmitza 20-30 parts, calcining barium carbonate 15-20 parts, sericite 15-20
Part, feldspar mine tailing powder 10-15 parts, potassium feldspar 10-15 parts, chromium oxide 5-15 parts, kaolin 2-10 parts；
The cover coat, its parts by weight are as follows：Potassium feldspar 20-30 parts, quartzy 20-30 parts, kaolin 10-15 parts, tin are brilliant
Expect 5-10 parts, glass 5-10 parts, glutinous rice flour 1-5, cupric oxalate 1-5 parts, zinc oxide 1-5 parts, sodium oxide molybdena 1-5 parts, bamboo charcoal 1-5 parts,
Feldspar mine tailing powder 1-5 parts.
Specific embodiment one：
Low temperature transmutation plum blossom glaze porcelain, including ceramic body, in addition to base substrate and the ground-coat enamel for being arranged at ceramic body surface
Layer and cover coat, the thickness of cover coat is 0.1-0.2mm, and the thickness of the ground glaze layer is 0.3-0.5mm；
The parts by weight of ceramic body are as follows：Feldspar mine tailing powder 28,19 parts of kiln slag, 16 parts of calcination of talc, bauxite clay 13
Part, attaclay 7,6 parts of wollastonite in powder, 3 parts of kaolin, 4 parts of barium sulphide, 4 parts of lithium feldspar；
Ground glaze layer, its parts by weight are as follows：26 parts of smolmitza, 17 parts of barium carbonate of calcining, 16 parts of sericite, feldspar mine tailing powder
13 parts, 14 parts of potassium feldspar, 6 parts of chromium oxide, 8 parts of kaolin；
Cover coat, its parts by weight are as follows：26 parts of potassium feldspar, quartz 24 parts, 14 parts of kaolin, 9 parts of tin frit, 8 parts of glass,
Glutinous rice flour 4,3 parts of cupric oxalate, 4 parts of zinc oxide, 3 parts of sodium oxide molybdena, 2 parts of bamboo charcoal, feldspar mine tailing powder 3.
The porcelain burnt out has the background color of brown, is distributed pink spot on the ground-coat enamel of dark color, on every piece of spot
Formed substantially in the scarce glaze pore of plum blossom-shaped arrangement, can send out after being fired due to the organic material introduced in cover-coat enamel and be formed on spot
Substantially in the scarce glaze pore of plum blossom-shaped arrangement.
Specific embodiment two：
Low temperature transmutation plum blossom glaze porcelain, including ceramic body, it is characterised in that：Also include base substrate and be arranged at ceramic body
The ground glaze layer and cover coat on surface,
The ceramic body, its parts by weight are as follows：Feldspar mine tailing powder 32,16 parts of kiln slag, 18 parts of calcination of talc, aluminum are glued
12 parts of soil, attaclay 6,8 parts of wollastonite in powder, 2 parts of kaolin, 3 parts of barium sulphide, 3 parts of lithium feldspar；
The ground glaze layer, its parts by weight are as follows：26 parts of smolmitza, 18 parts of barium carbonate of calcining, 17 parts of sericite, feldspar mine tailing
14 parts of powder, 11 parts of potassium feldspar, 6 parts of chromium oxide, 8 parts of kaolin；
The cover coat, its parts by weight are as follows：29 parts of potassium feldspar, 28 parts of quartz, 13 parts of kaolin, 6 parts of tin frit, glass
9 parts, glutinous rice flour 3,4 parts of cupric oxalate, 2 parts of zinc oxide, 3 parts of sodium oxide molybdena, 1 part of bamboo charcoal, 2 parts of feldspar mine tailing powder.
The porcelain burnt out has the background color of dark reddish brown, the spot of pink is distributed on the ground-coat enamel of dark reddish brown, due to cover-coat enamel
The organic material of middle introducing can be sent out after firing to be formed substantially on spot in the scarce glaze pore of plum blossom-shaped arrangement.
Specific embodiment three：
Low temperature transmutation plum blossom glaze porcelain, including ceramic body, it is characterised in that：Also include base substrate and be arranged at ceramic body
The ground glaze layer and cover coat on surface,
The ceramic body, its parts by weight are as follows：Feldspar mine tailing powder 33,19 parts of kiln slag, 16 parts of calcination of talc, aluminum are glued
11 parts of soil, attaclay 6,6 parts of wollastonite in powder, 4 parts of kaolin, 3 parts of barium sulphide, 2 parts of lithium feldspar；
The ground glaze layer, its parts by weight are as follows：28 parts of smolmitza, 19 parts of barium carbonate of calcining, 16 parts of sericite, feldspar mine tailing
11 parts of powder, 12 parts of potassium feldspar, 6 parts of chromium oxide, 8 parts of kaolin；
The cover coat, its parts by weight are as follows：Potassium feldspar 20-30 parts, quartzy 20-30 parts, kaolin 10-15 parts, tin are brilliant
Expect 5-10 parts, glass 5-10 parts, glutinous rice flour 1-5, cupric oxalate 1-5 parts, zinc oxide 1-5 parts, sodium oxide molybdena 1-5 parts, bamboo charcoal 1-5 parts,
Feldspar mine tailing powder 1-5 parts.
The porcelain burnt out has the background color of dark reddish brown, the spot of pink is distributed on the ground-coat enamel of dark reddish brown, due to cover-coat enamel
The organic material of middle introducing can be sent out after firing to be formed substantially on spot in the scarce glaze pore of plum blossom-shaped arrangement.
The preparation technology of low temperature transmutation plum blossom glaze porcelain, above-mentioned low temperature transmutation plum blossom glaze porcelain is prepared, specific steps are such as
Under：
Step 1, carry out proportioning by ceramic body composition of raw materials to weigh, ceramic body glaze slip be made,；
Step 2, carry out proportioning by ground glaze layer composition of raw materials to weigh, ground-coat enamel, material are made respectively after adding water for ball milling：Ball：Water
Mass ratio is 3：1-2：1-3 carries out wet ball grinding 1h~3h, and the mesh sieve of 80 mesh -100 is crossed after ball milling；
Step 3, carry out proportioning by cover-coat enamel composition of raw materials to weigh, cover-coat enamel, material are made respectively after adding water for ball milling：Ball：The matter of water
Amount is than being 2：1：2-3, wet ball grinding 5h~8h is carried out, the mesh sieve of 200 mesh -300 is crossed after ball milling；
Step 4, ceramic body is waited to be completely dried to moisture content as after 1-2%, ground-coat enamel is applied on ceramic body surface；
Step 5, ceramic body is made using glaze slip, after waiting ceramic body to be completely dried, one is applied on ceramic body surface
Layer ground-coat enamel, after waiting cover-coat enamel to dry, to ground-coat enamel surface spraying cover-coat enamel, the B concentration of ground-coat enamel is 50-60 degree during glazing, cover-coat enamel
B concentration is 30-40 degree；
Step 6, the ceramic body for applying cracking ground glaze layer and cover coat is put into kiln and once formed by a firing, burn till temperature
Spend for 1220-1260 DEG C, firing temperature control is divided into five sections, specific as follows：
A：Under oxidizing atmosphere, kiln is at the uniform velocity warming up to 500 DEG C through 30-40 minutes；
B：Kiln continues to heat up, and is warming up to 800 DEG C through 1.5-2 hours, is incubated 20-30 minutes；
C：Turn reducing atmosphere, through 3-5 minutes, furnace heating-up to firing temperature, be incubated 2-3 hours；
D：Kiln is cooled to 1000 DEG C with 100 DEG C/h-120 DEG C/h rate of temperature fall under reducing atmosphere；
E：Turn oxidizing atmosphere, fast cooling is cooled to 600 DEG C by 1000 DEG C of degree through 10-30 minutes, is being naturally cooling to out
Kiln.
Ceramic body raw material and the feldspar mine tailing used in ground-coat enamel wherein in step 1, step 2, successively through crushing, magnetic separation
Afterwards, 1080 degrees Celsius are calcined.
Above-mentioned low temperature transmutation plum blossom glaze porcelain and preparation method thereof, the porcelain burnt out has the background color of brown, dark reddish brown,
Pink, pink spot is distributed on the ground-coat enamel of dark color, the scarce glaze pore substantially arranged in plum blossom-shaped is formed on every piece of spot,
Seem coarse dry and astringent, water can fill up scarce glaze pore rapidly after meeting water, make glaze paint one integrated mass, naturally just glittering and translucent, just like " rain
Hua Shi " water breakthroughs have unique artistic effect with regard to bright speciality.The ceramic body of this kind of low temperature transmutation plum blossom glaze porcelain, ground-coat enamel,
Feldspar mine tailing powder has largely been used to there is the significant value of environmental protection, while effectively reduce former as raw material in the raw material of cover-coat enamel
The production cost of material, increases economic efficiency and the market competitiveness.
The specific embodiment of the present invention is above are only, but the design concept of the present invention is not limited thereto, all profits
The change of unsubstantiality is carried out to the present invention with this design, the behavior for invading the scope of the present invention all should be belonged to.
Claims (10)
1. low temperature transmutation plum blossom glaze porcelain, including ceramic body, it is characterised in that：Also include base substrate and be arranged at ceramic blank body surface
The ground glaze layer and cover coat in face,
The ceramic body, its parts by weight are as follows：Feldspar mine tailing powder 25-35, kiln slag 15-20 parts, calcination of talc 15-20 parts,
Bauxite clay 10-15 parts, attaclay 5-10, wollastonite in powder 5-10 parts, kaolin 1-5 parts, barium sulphide 1-5 parts, lithium feldspar 1-5
Part；
The ground glaze layer, its parts by weight are as follows：Smolmitza 20-30 parts, calcining barium carbonate 15-20 parts, sericite 15-20 parts, length
Stone mine tailing powder 10-15 parts, potassium feldspar 10-15 parts, chromium oxide 5-15 parts, kaolin 2-10 parts；
The cover coat, its parts by weight are as follows：Potassium feldspar 20-30 parts, quartzy 20-30 parts, kaolin 10-15 parts, tin frit 5-
10 parts, glass 5-10 parts, glutinous rice flour 1-5, cupric oxalate 1-5 parts, zinc oxide 1-5 parts, sodium oxide molybdena 1-5 parts, bamboo charcoal 1-5 parts, feldspar
Mine tailing powder 1-5 parts.
2. low temperature transmutation plum blossom glaze porcelain according to claim 1, it is characterised in that：The parts by weight of the ceramic body are such as
Under：Feldspar mine tailing powder 28,19 parts of kiln slag, 16 parts of calcination of talc, 13 parts of bauxite clay, attaclay 7,6 parts of wollastonite in powder, height
3 parts of ridge soil, 4 parts of barium sulphide, 4 parts of lithium feldspar.
3. low temperature transmutation plum blossom glaze porcelain according to claim 1, it is characterised in that：The ground glaze layer, its parts by weight is such as
Under：26 parts of smolmitza, 17 parts of barium carbonate of calcining, 16 parts of sericite, 13 parts of feldspar mine tailing powder, 14 parts of potassium feldspar, chromium oxide 6
Part, 8 parts of kaolin.
4. low temperature transmutation plum blossom glaze porcelain according to claim 1, it is characterised in that：The cover coat, its parts by weight is such as
Under：26 parts of potassium feldspar, 24 parts of quartz, 14 parts of kaolin, 9 parts of tin frit, 8 parts of glass, glutinous rice flour 4,3 parts of cupric oxalate, zinc oxide 4
Part, 3 parts of sodium oxide molybdena, 2 parts of bamboo charcoal, feldspar mine tailing powder 3.
5. low temperature transmutation plum blossom glaze porcelain according to claim 1, it is characterised in that：The thickness of the cover coat is 0.1-
0.2mm, the thickness of the ground glaze layer is 0.3-0.5mm.
6. the preparation technology of low temperature transmutation plum blossom glaze porcelain, it is characterised in that prepare low described in claim 1-5 any one
Warm transmutation plum blossom glaze porcelain, is comprised the following steps that：
Step 1, carry out proportioning by ceramic body composition of raw materials to weigh, ceramic body glaze slip be made,；
Step 2, carry out proportioning by ground glaze layer composition of raw materials to weigh, ground-coat enamel, material are made respectively after adding water for ball milling：Ball：The quality of water
Than for 3：1-2：1-3 carries out wet ball grinding 1h~3h, and the mesh sieve of 80 mesh -100 is crossed after ball milling；
Step 3, carry out proportioning by cover-coat enamel composition of raw materials to weigh, cover-coat enamel, material are made respectively after adding water for ball milling：Ball：The mass ratio of water
For 2：1：2-3, wet ball grinding 5h~8h is carried out, the mesh sieve of 200 mesh -300 is crossed after ball milling；
Step 4, after waiting ceramic body to be completely dried, ground-coat enamel is applied on ceramic body surface；
Step 5, ceramic body is made using glaze slip, after waiting ceramic body to be completely dried, one layer of bottom is applied on ceramic body surface
Glaze, after waiting cover-coat enamel to dry, to ground-coat enamel surface spraying cover-coat enamel；
Step 6, the ceramic body for applying cracking ground glaze layer and cover coat is put into kiln and once formed by a firing, firing temperature is
1220-1260 DEG C, after kiln reaches firing temperature, at the uniform velocity it is cooled to natural cooling.
7. the preparation technology of low temperature transmutation plum blossom glaze porcelain according to claim 6, it is characterised in that：The step 1, step
Ceramic body raw material and the feldspar mine tailing used in ground-coat enamel, successively through crushing, after magnetic separation, calcine 1080 degrees Celsius in rapid 2.
8. the preparation technology of low temperature transmutation plum blossom glaze porcelain according to claim 6, it is characterised in that：Ground-coat enamel during glazing
B concentration is 50-60 degree, and the B concentration of cover-coat enamel is 30-40 degree during glazing.
9. the preparation technology of low temperature transmutation plum blossom glaze porcelain according to claim 6, it is characterised in that：Step 4 base substrate is done
Moisture content after dry is 1-2%.
10. the preparation technology of low temperature transmutation plum blossom glaze porcelain according to claim 6, it is characterised in that：Burnt till in step 6
When, in step 6 the firing temperature control of kiln be divided into five sections, it is specific as follows：
A：Under oxidizing atmosphere, kiln is at the uniform velocity warming up to 500 DEG C through 30-40 minutes；
B：Kiln continues to heat up, and is warming up to 800 DEG C through 1.5-2 hours, is incubated 20-30 minutes；
C：Turn reducing atmosphere, through 3-5 minutes, furnace heating-up to firing temperature, be incubated 2-3 hours；
D：Kiln is cooled to 1000 DEG C with 100 DEG C/h-120 DEG C/h rate of temperature fall under reducing atmosphere；
E：Turn oxidizing atmosphere, fast cooling is cooled to 600 DEG C by 1000 DEG C of degree through 10-30 minutes, is being naturally cooling to kiln discharge.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110963781A (en) * | 2019-11-14 | 2020-04-07 | 福建省嘉顺艺品股份有限公司 | Craft porcelain with glaze surface having raised particle effect and preparation method thereof |
| CN111548012A (en) * | 2020-05-20 | 2020-08-18 | 福建省德化县瓷言坊陶瓷工艺有限公司 | Low-temperature environment-friendly shallow brown white furnace transmutation glazed porcelain and preparation process thereof |
| CN111960801A (en) * | 2020-08-28 | 2020-11-20 | 福建泉州顺美集团有限责任公司 | Low-temperature once-fired ceramic with opaque glaze and preparation method thereof |
| CN112341147A (en) * | 2018-03-28 | 2021-02-09 | 福建省德化县臻晖陶瓷有限公司 | Firm greasy-white water-resistant shadowy celadon blank and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080199708A1 (en) * | 2007-02-16 | 2008-08-21 | Nichiha Corporation | Glaze composition |
| CN102826872A (en) * | 2012-08-17 | 2012-12-19 | 广东宏陶陶瓷有限公司 | Formula and preparation method of national flag bright red glazed brick |
| CN103739279A (en) * | 2013-12-16 | 2014-04-23 | 广州锦盈新型材料有限公司 | Full-glazed tile and preparation method thereof |
| CN105000916A (en) * | 2015-07-10 | 2015-10-28 | 广东宏海陶瓷实业发展有限公司 | Glazed tile manufactured from ceramic wastes and having surface with stone-like luster and preparation method therefor |
-
2017
- 2017-05-18 CN CN201710352272.1A patent/CN107417102B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080199708A1 (en) * | 2007-02-16 | 2008-08-21 | Nichiha Corporation | Glaze composition |
| CN102826872A (en) * | 2012-08-17 | 2012-12-19 | 广东宏陶陶瓷有限公司 | Formula and preparation method of national flag bright red glazed brick |
| CN103739279A (en) * | 2013-12-16 | 2014-04-23 | 广州锦盈新型材料有限公司 | Full-glazed tile and preparation method thereof |
| CN105000916A (en) * | 2015-07-10 | 2015-10-28 | 广东宏海陶瓷实业发展有限公司 | Glazed tile manufactured from ceramic wastes and having surface with stone-like luster and preparation method therefor |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112341147A (en) * | 2018-03-28 | 2021-02-09 | 福建省德化县臻晖陶瓷有限公司 | Firm greasy-white water-resistant shadowy celadon blank and preparation method thereof |
| CN112341147B (en) * | 2018-03-28 | 2022-05-31 | 福建省德化县臻晖陶瓷有限公司 | Firm greasy-white water-resistant shadowy celadon blank and preparation method thereof |
| CN110963781A (en) * | 2019-11-14 | 2020-04-07 | 福建省嘉顺艺品股份有限公司 | Craft porcelain with glaze surface having raised particle effect and preparation method thereof |
| CN110963781B (en) * | 2019-11-14 | 2022-01-21 | 福建省嘉顺艺品股份有限公司 | Craft porcelain with glaze surface having raised particle effect and preparation method thereof |
| CN111548012A (en) * | 2020-05-20 | 2020-08-18 | 福建省德化县瓷言坊陶瓷工艺有限公司 | Low-temperature environment-friendly shallow brown white furnace transmutation glazed porcelain and preparation process thereof |
| CN111960801A (en) * | 2020-08-28 | 2020-11-20 | 福建泉州顺美集团有限责任公司 | Low-temperature once-fired ceramic with opaque glaze and preparation method thereof |
| CN111960801B (en) * | 2020-08-28 | 2022-01-28 | 福建泉州顺美集团有限责任公司 | Low-temperature once-fired ceramic with opaque glaze and preparation method thereof |
| CN114276018A (en) * | 2022-01-18 | 2022-04-05 | 德化县如瓷生活文化有限公司 | Lubao underglaze ceramic and preparation method thereof |
| CN114276018B (en) * | 2022-01-18 | 2023-09-01 | 德化县如瓷生活文化有限公司 | Road-treasure underglaze color ceramic and preparation method thereof |
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