CN108706879A - Color material and its manufacture craft of ceramics under furnace transmutation glaze - Google Patents

Color material and its manufacture craft of ceramics under furnace transmutation glaze Download PDF

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Publication number
CN108706879A
CN108706879A CN201810485711.0A CN201810485711A CN108706879A CN 108706879 A CN108706879 A CN 108706879A CN 201810485711 A CN201810485711 A CN 201810485711A CN 108706879 A CN108706879 A CN 108706879A
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China
Prior art keywords
glaze
parts
under
color material
furnace transmutation
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CN201810485711.0A
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Chinese (zh)
Inventor
颜松疆
颜晓杰
陈乙坤
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Fujian Province Dehua County Hengsheng Ceramics Co Ltd
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Fujian Province Dehua County Hengsheng Ceramics Co Ltd
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Publication of CN108706879A publication Critical patent/CN108706879A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

Abstract

The present invention relates to ceramic fabrication technique field, it is specifically related to color material and its manufacture craft of ceramics under a kind of furnace transmutation glaze.Color material under this kind of furnace transmutation glaze, including raw mineral materials and water, wherein raw mineral materials are made of feldspar, quartz, kaolin, titanium dioxide, di-iron trioxide, inorganic color, and the ratio of raw mineral materials and water is 3-4:1.Color material and its manufacture craft of ceramics under furnace transmutation glaze provided by the invention, due to containing in color material under furnace transmutation glaze, there are many pigmentation elements, by the temperature change of kiln when firing, oxidized or reduction, color material generates reaction under furnace transmutation glaze, colorful transmutation effect is formed under transparent glaze layer, seems very unique and marvellous using color material decoration porcelain under this kind of furnace transmutation glaze.This kind of transmutation under-glaze decoration ceramic provides a kind of completely new ceramic kind, to pushing the development of ceramic product with positive meaning and with positive economic benefit.

Description

Color material and its manufacture craft of ceramics under furnace transmutation glaze
Technical field
The present invention relates to ceramic fabrication technique field, it is specifically related to color material and its making work of ceramics under a kind of furnace transmutation glaze Skill.
Background technology
Underglaze colour is one kind of porcelain muffle painting decoration, You Cheng "Kiln kiln ".Underglaze colour is a kind of primary decoration hand of ware Section, is to draw various decorative patterns on the molded biscuit (i.e. semi-finished product) dried with colorant, then cover with white clear glaze or Other light overglazes, once-firing.Pattern after firing is covered in below by the glaze film of layer of transparent, and surface-brightening is soft, flat Cunning is non-bulging, it appears sparkling and crystal-clear bright.
Traditional underglaze colour includes brown coloured silk, breen coloured silk etc. under three coloured silks, five color painting in the glaze, glaze under blue and white, under-glaze red, glaze.As specially Profit number is related to ceramics technique for color under glaze in high temp for " ceramics technique for color under glaze in high temp " patent of CN02136786.8, which includes Molding, biscuiting, polishing, colored drawing, color burn, pour glaze, grand feu, at processing steps such as porcelain, and existing technique for color under glaze in high temp needs Will be by biscuiting, color be burnt, klining is burnt into could be molded three times, wherein biscuiting temperature is 700-800 DEG C, color burning temperature is 700- 800 DEG C, temperature of glaze firing be 1320-1400 DEG C;The requirement color development of good underglaze colour is bright, and color stable just can guarantee the five colours The effect of in riotous profusion firing.Constantly change with the aesthetic consciousness of people, transmutation effect gradually obtains liking for people, existing The transmutation effect of ceramic surface can only realize that is, furnace transmutation glaze can only decorate the whole surface of ceramic body by glaze; Therefore, if can provide it is a kind of by way of underglaze colour to ceramic surface carry out furnace transmutation decoration, especially part decoration, can carry For a kind of completely new ceramic decoration method, it can not only meet the aesthetic diversified demand of people, moreover it is possible to provide a kind of completely new pottery Ceramic products, to pushing the development of ceramic product with positive meaning and with positive economic benefit.
Invention content
In order to solve the deficiencies in the prior art, the present invention provides color material under a kind of furnace transmutation glaze and preparation method thereof and its systems Make technique.
To achieve the above object, color material under furnace transmutation glaze, which is characterized in that under the furnace transmutation glaze color material include raw mineral materials and The component of water, wherein raw mineral materials is as follows:32-40 parts of feldspar, 25-32 parts of quartz, 8-10 parts of kaolin, titanium dioxide 8-16 Part, 6-15 parts of di-iron trioxide, 3-5 parts of inorganic color, and the ratio of raw mineral materials and water are 3-4:1.
Further, the component of color material is as follows under furnace transmutation glaze:36 parts of feldspar, 30 parts of quartz, 8 parts of kaolin, titanium dioxide 9 Part, 14 parts of di-iron trioxide, 3 parts of inorganic color, and the ratio of raw mineral materials and water are 3.5:1.
Further,:33 parts of feldspar, 31 parts of quartz, 10 parts of kaolin, 10 parts of titanium dioxide, 11 parts of di-iron trioxide, nothing 5 parts of machine colorant, and the ratio of raw mineral materials and water is 3.8:1.
Further, the component of color material is as follows under furnace transmutation glaze:38 parts of feldspar, 26 parts of quartz, 9 parts of kaolin, titanium dioxide 15 parts, 8 parts of di-iron trioxide, 4 parts of inorganic color, and the ratio of raw mineral materials and water are 3.2:1.
A kind of manufacture craft of transmutation under-glaze decoration ceramic, using color material under the furnace transmutation glaze described in above-mentioned any one, specifically Steps are as follows:
Step 1, ceramic body is prepared;
Step 2, it according to the material component of color material under furnace transmutation glaze, configures, prepare color material under furnace transmutation glaze;
Step 3, ceramic body made from step 1 is put into biscuiting in kiln, obtains biscuit;
Step 4, color material under furnace transmutation glaze made from step 2 is plotted on biscuit of ceramics;
Step 5, clear frit is applied on biscuit of ceramics;
Step 6, the biscuit of ceramics after glazing is put into kiln and is formed by a firing, firing temperature is 1250 ± 50 DEG C.
Further, ceramic body is light color.
Further, in step 2, under furnace transmutation glaze the preparation of color material be as follows:
S1 weighs mixing according to the raw mineral materials component of color material under furnace transmutation glaze;
S2 will add water for ball milling in raw mineral materials that step 1 configures;
S3, after ball milling sieving be prepared into Freehandhand-drawing colorant under furnace transmutation glaze.
Further, the sieve in S3 is 300 mesh or less.
Further, the thickness of clear frit is 0.5-8mm in step 5.
Further, firing control is divided into five sections of controls in step 6, respectively:
Low-temperature zone, kiln pass through 2-3 hours, and 600 DEG C are warming up to by 250 DEG C;
Middle-temperature section, kiln pass through 1-2 hours, and 1000 DEG C are warming up to by 600 DEG C;
Become temperature section, kiln is cooled to 800 DEG C through 0.5-1 hours, by 1000 DEG C;
High temperature section, kiln pass through 2-3 hours, are warming up to firing temperature by 1000 DEG C, and small in firing temperature heat preservation 0.5-1 When;
Slow cooling section, kiln are cooled to 200 DEG C through 2.5-3 hours, by firing temperature, kiln natural cooling are opened, by 200 DEG C It is cooled to 20 degrees Celsius.
Further, step firing temperature is 1265 DEG C.
Color material and its manufacture craft of ceramics under furnace transmutation glaze provided by the invention, it is former to pass through mineral for color material under the furnace transmutation glaze Material, inorganic color and water match, due in color material under furnace transmutation glaze containing there are many pigmentation element, by the temperature of kiln when firing Degree changes, oxidized or reduction, and color material generates reaction under furnace transmutation glaze, and colorful transmutation effect is formed under transparent glaze layer, Seem very unique and marvellous using color material decoration porcelain under this kind of furnace transmutation glaze;In addition, the firing of this kind of transmutation under-glaze decoration ceramic It only needs to be burnt into twice by biscuiting and glaze firing, firing temperature is low, is conducive to environmental protection and energy-saving and emission-reduction;Under this kind of furnace transmutation glaze Color ceramic provides a kind of completely new ceramic kind, to pushing the development of ceramic product with positive meaning and with actively Economic benefit.
Specific implementation mode
Below by way of specific implementation mode, the invention will be further described.
Color material under furnace transmutation glaze, which is characterized in that color material includes raw mineral materials and water, wherein raw mineral materials under the furnace transmutation glaze Component it is as follows:32-40 parts of feldspar, 25-32 parts of quartz, 8-10 parts of kaolin, 8-16 parts of titanium dioxide, di-iron trioxide 6-15 Part, 3-5 parts of inorganic color, and the ratio of raw mineral materials and water are 3-4:1.
A kind of manufacture craft of transmutation under-glaze decoration ceramic is as follows using color material under above-mentioned furnace transmutation glaze:
Step 1, ceramic body is prepared;
Step 2, it according to the material component of color material under furnace transmutation glaze, configures, prepare color material under furnace transmutation glaze, first according to furnace transmutation glaze The raw mineral materials component of lower color material is weighed mixing, then water for ball milling will be added in the raw mineral materials of configuration, finally ball milling 300 mesh or less are crossed afterwards to sieve, and are prepared into Freehandhand-drawing colorant under furnace transmutation glaze;
Step 3, ceramic body made from step 1 is put into biscuiting in kiln, obtains biscuit;
Step 4, color material under furnace transmutation glaze made from step 2 is plotted on biscuit of ceramics;
Step 5, clear frit is applied on biscuit of ceramics;
Step 6, the biscuit of ceramics after glazing is put into kiln and is formed by a firing, firing temperature is 1250 ± 50 DEG C.
Specific embodiment one:
Color material under furnace transmutation glaze, color material includes raw mineral materials and water under the furnace transmutation glaze, and the component of wherein raw mineral materials is as follows: 36 parts of feldspar, 30 parts of quartz, 8 parts of kaolin, 9 parts of titanium dioxide, 14 parts of di-iron trioxide, 3 parts of inorganic color, and raw mineral materials Ratio with water is 3.5:1, wherein inorganic color is red, yellow and green, and the ratio of the red, yellow and green is 1:1:1.
A kind of manufacture craft of transmutation under-glaze decoration ceramic, using color material under the furnace transmutation glaze described in above-mentioned any one, specifically Steps are as follows:
Step 1, ceramic body is prepared, ceramic body is ecru;
Step 2, it according to the material component of color material under furnace transmutation glaze, configures, prepare color material under furnace transmutation glaze, first according to furnace transmutation glaze The raw mineral materials component of lower color material is weighed mixing, then water for ball milling will be added in the raw mineral materials of configuration, finally ball milling Sieving is prepared into Freehandhand-drawing colorant under furnace transmutation glaze afterwards;
Step 3, ceramic body made from step 1 is put into biscuiting in kiln, obtains biscuit;
Step 4, color material under furnace transmutation glaze made from step 2 is plotted in biscuit of ceramics part by writing brush;
Step 5, clear frit is applied on biscuit of ceramics, the thickness of clear frit is 0.55mm;
Step 6, the biscuit of ceramics after glazing is put into kiln and is formed by a firing, firing control is divided into five sections of controls, respectively For:
Low-temperature zone, kiln pass through 2.5 hours, and 600 DEG C are warming up to by 250 DEG C;
Middle-temperature section, kiln pass through 1.3 hours, and 1000 DEG C are warming up to by 600 DEG C;
Become temperature section, kiln is cooled to 800 DEG C through 0.8 hour, by 1000 DEG C;
High temperature section, kiln pass through 2.1 hours, are warming up to 1255 DEG C by 1000 DEG C, and keep the temperature 1 hour at 1265 DEG C;
Slow cooling section, kiln are cooled to 200 DEG C through 2.5 hours, by firing temperature, open kiln natural cooling, dropped by 200 DEG C Temperature is to 20 degrees Celsius.
This kind of transmutation under-glaze decoration ceramic has smooth, bright glazed surface, and under clear frit, transmutation color material forms colorful Transmutation effect staggeredly.
Specific embodiment two:
Color material under furnace transmutation glaze, color material includes raw mineral materials and water under the furnace transmutation glaze, and the component of wherein raw mineral materials is as follows: The component for stating color material under furnace transmutation glaze is as follows:33 parts of feldspar, 31 parts of quartz, 10 parts of kaolin, 10 parts of titanium dioxide, di-iron trioxide 11 parts, 5 parts of inorganic color, and the ratio of raw mineral materials and water is 3.8:1, wherein inorganic color is copper red color colorant.
A kind of manufacture craft of transmutation under-glaze decoration ceramic, using color material under the furnace transmutation glaze described in above-mentioned any one, specifically Steps are as follows:
Step 1, ceramic body is prepared, ceramic body is white;
Step 2, it according to the material component of color material under furnace transmutation glaze, configures, prepare color material under furnace transmutation glaze, first according to furnace transmutation glaze The raw mineral materials component of lower color material is weighed mixing, then water for ball milling will be added in the raw mineral materials of configuration, finally ball milling Sieving is prepared into Freehandhand-drawing colorant under furnace transmutation glaze afterwards;
Step 3, ceramic body made from step 1 is put into biscuiting in kiln, obtains biscuit;
Step 4, color material under furnace transmutation glaze made from step 2 is plotted in block-like on biscuit of ceramics using brush;
Step 5, clear frit is applied on biscuit of ceramics, the thickness of clear frit is 0.7mm;
Step 6, the biscuit of ceramics after glazing is put into kiln and is formed by a firing, firing control is divided into five sections of controls, respectively For:
Low-temperature zone, kiln pass through 2.8 hours, and 600 DEG C are warming up to by 250 DEG C;
Middle-temperature section, kiln pass through 1.8 hours, and 1000 DEG C are warming up to by 600 DEG C;
Become temperature section, kiln is cooled to 800 DEG C through 0.6 hour, by 1000 DEG C;
High temperature section, kiln pass through 2.6 hours, are warming up to 1277 DEG C by 1000 DEG C, and keep the temperature 1 hour at 1265 DEG C;
Slow cooling section, kiln are cooled to 200 DEG C through 3 hours, by firing temperature, open kiln natural cooling, cooled down by 200 DEG C To 20 degrees Celsius.
This kind of transmutation under-glaze decoration ceramic has smooth, bright glazed surface, and under clear frit, transmutation color material forms gradual change Copper red color effect.
Specific embodiment three:
Color material under furnace transmutation glaze, color material includes raw mineral materials and water under the furnace transmutation glaze, and the component of wherein raw mineral materials is as follows: 38 parts of feldspar, 26 parts of quartz, 9 parts of kaolin, 15 parts of titanium dioxide, 8 parts of di-iron trioxide, 4 parts of inorganic color, and raw mineral materials Ratio with water is 3.2:1, wherein its inorganic color is black, golden colorant, and the wherein ratio of black pigment and golden colorant is 7: 1。
A kind of manufacture craft of transmutation under-glaze decoration ceramic, using color material under the furnace transmutation glaze described in above-mentioned any one, specifically Steps are as follows:
Step 1, ceramic body is prepared, ceramic body is ivory buff;
Step 2, it according to the material component of color material under furnace transmutation glaze, configures, prepare color material under furnace transmutation glaze, first according to furnace transmutation glaze The raw mineral materials component of lower color material is weighed mixing, then water for ball milling will be added in the raw mineral materials of configuration, finally ball milling Sieving is prepared into Freehandhand-drawing colorant under furnace transmutation glaze afterwards;
Step 3, ceramic body made from step 1 is put into biscuiting in kiln, obtains biscuit;
Step 4, color material under furnace transmutation glaze made from step 2 is sprayed on by spray gun on biscuit of ceramics;
Step 5, clear frit is applied on biscuit of ceramics, the thickness of clear frit is 0.6mm;
Step 6, the biscuit of ceramics after glazing is put into kiln and is formed by a firing, firing control is divided into five sections of controls, respectively For:
Low-temperature zone, kiln pass through 2-3 hours, and 600 DEG C are warming up to by 250 DEG C;
Middle-temperature section, kiln pass through 1-2 hours, and 1000 DEG C are warming up to by 600 DEG C;
Become temperature section, kiln is cooled to 800 DEG C through 0.5-1 hours, by 1000 DEG C;
High temperature section, kiln pass through 2-3 hours, are warming up to 1265 DEG C by 1000 DEG C, and keep the temperature 0.5-1 hours at 1265 DEG C;
Slow cooling section, kiln are cooled to 200 DEG C through 2.5-3 hours, by firing temperature, kiln natural cooling are opened, by 200 DEG C It is cooled to 20 degrees Celsius.
This kind of transmutation under-glaze decoration ceramic has smooth, bright glazed surface, and under clear frit, transmutation color material has black Background color, show on black background color golden transmutation speckle, effect is unique.
The specific embodiment of the present invention is above are only, but the design concept of the present invention is not limited thereto, all profits The change for carrying out unsubstantiality to the present invention with this design, should all belong to the behavior for invading the scope of the present invention.

Claims (10)

1. color material under furnace transmutation glaze, which is characterized in that under the furnace transmutation glaze color material includes raw mineral materials and water, wherein raw mineral materials Component is as follows:32-40 parts of feldspar, 25-32 parts of quartz, 8-10 parts of kaolin, 8-16 parts of titanium dioxide, di-iron trioxide 6-15 Part, 3-5 parts of inorganic color, and the ratio of raw mineral materials and water are 3-4:1.
2. color material under furnace transmutation glaze according to claim 1, which is characterized in that the component of color material is as follows under the furnace transmutation glaze: 36 parts of feldspar, 30 parts of quartz, 8 parts of kaolin, 9 parts of titanium dioxide, 14 parts of di-iron trioxide, 3 parts of inorganic color, and raw mineral materials Ratio with water is 3.5:1.
3. color material under furnace transmutation glaze according to claim 1, which is characterized in that the component of color material is as follows under the furnace transmutation glaze: 33 parts of feldspar, 31 parts of quartz, 10 parts of kaolin, 10 parts of titanium dioxide, 11 parts of di-iron trioxide, 5 parts of inorganic color, and mineral are former The ratio of material and water is 3.8:1.
4. color material under furnace transmutation glaze according to claim 1, which is characterized in that the component of color material is as follows under the furnace transmutation glaze: 38 parts of feldspar, 26 parts of quartz, 9 parts of kaolin, 15 parts of titanium dioxide, 8 parts of di-iron trioxide, 4 parts of inorganic color, and raw mineral materials Ratio with water is 3.2:1.
5. a kind of manufacture craft of transmutation under-glaze decoration ceramic, using color material under the furnace transmutation glaze described in claim 1-4 any one, It is as follows:
Step 1, ceramic body is prepared;
Step 2, it according to the material component of color material under furnace transmutation glaze, configures, prepare color material under furnace transmutation glaze;
Step 3, ceramic body made from step 1 is put into biscuiting in kiln, obtains biscuit;
Step 4, color material under furnace transmutation glaze made from step 2 is plotted on biscuit of ceramics;
Step 5, clear frit is applied on biscuit of ceramics;
Step 6, the biscuit of ceramics after glazing is put into kiln and is formed by a firing, firing temperature is 1250 ± 50 DEG C.
6. the manufacture craft of transmutation under-glaze decoration ceramic according to claim 5, which is characterized in that the ceramic body is shallow Colour system.
7. the manufacture craft of transmutation under-glaze decoration ceramic according to claim 5, which is characterized in that in the step 2, transmutation The preparation of underglaze colour material is as follows:
S1 weighs mixing according to the raw mineral materials component of color material under furnace transmutation glaze;
S2 will add water for ball milling in raw mineral materials that step 1 configures;
S3, after ball milling sieving be prepared into Freehandhand-drawing colorant under furnace transmutation glaze.
8. the manufacture craft of transmutation under-glaze decoration ceramic according to claim 5, which is characterized in that transparent in the step 5 The thickness of glaze is 0.5-8mm.
9. the manufacture craft of transmutation under-glaze decoration ceramic according to claim 5, which is characterized in that be burnt into the step 6 Control is divided into five sections of controls, respectively:
Low-temperature zone, kiln pass through 2-3 hours, and 600 DEG C are warming up to by 250 DEG C;
Middle-temperature section, kiln pass through 1-2 hours, and 1000 DEG C are warming up to by 600 DEG C;
Become temperature section, kiln is cooled to 800 DEG C through 0.5-1 hours, by 1000 DEG C;
High temperature section, kiln pass through 2-3 hours, are warming up to firing temperature by 1000 DEG C, and keep the temperature 0.5-1 hours in firing temperature;
Slow cooling section, kiln are cooled to 200 DEG C through 2.5-3 hours, by firing temperature, open kiln natural cooling, cooled down by 200 DEG C To 20 degrees Celsius.
10. the manufacture craft of the transmutation under-glaze decoration ceramic according to claim 5 or 8, which is characterized in that the step firing Temperature is 1265 DEG C.
CN201810485711.0A 2017-10-30 2018-05-21 Color material and its manufacture craft of ceramics under furnace transmutation glaze Pending CN108706879A (en)

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CN109851222A (en) * 2019-04-17 2019-06-07 福建省德化云水窑陶瓷有限公司 A kind of preparation method of gold sand glaze and preparation method thereof and gold sand glaze ceramic
CN109879596A (en) * 2019-04-23 2019-06-14 福建省德化云水窑陶瓷有限公司 Furnace transmutation glaze colorant and the method for preparing furnace transmutation glaze ceramic under glaze with it under glaze
CN110066178A (en) * 2019-04-12 2019-07-30 佛山市乐陶工艺陶瓷有限公司 The manufacture craft of transmutation background ceramic board pictures
CN110407469A (en) * 2019-08-26 2019-11-05 福建省德化县天俊陶瓷有限公司 A kind of transparent glase fired at lower temperature, ceramic and preparation method with the glaze
CN111454079A (en) * 2020-04-09 2020-07-28 广东皓明陶瓷科技有限公司 Method for forming black substrate golden wafer ceramic product in glaze firing process
CN111548012A (en) * 2020-05-20 2020-08-18 福建省德化县瓷言坊陶瓷工艺有限公司 Low-temperature environment-friendly shallow brown white furnace transmutation glazed porcelain and preparation process thereof
CN112759355A (en) * 2019-11-01 2021-05-07 江苏新嘉理生态环境材料股份有限公司 Argil plate with reduction and oxidation sintering combined transmutation effect and preparation method and application thereof
CN114656289A (en) * 2022-04-19 2022-06-24 德化县厚德陶瓷厂 Under-glaze transmutation glaze ceramic with rust-controllable lines and preparation method thereof

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CN109879596A (en) * 2019-04-23 2019-06-14 福建省德化云水窑陶瓷有限公司 Furnace transmutation glaze colorant and the method for preparing furnace transmutation glaze ceramic under glaze with it under glaze
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CN110407469A (en) * 2019-08-26 2019-11-05 福建省德化县天俊陶瓷有限公司 A kind of transparent glase fired at lower temperature, ceramic and preparation method with the glaze
CN112759355A (en) * 2019-11-01 2021-05-07 江苏新嘉理生态环境材料股份有限公司 Argil plate with reduction and oxidation sintering combined transmutation effect and preparation method and application thereof
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CN114656289A (en) * 2022-04-19 2022-06-24 德化县厚德陶瓷厂 Under-glaze transmutation glaze ceramic with rust-controllable lines and preparation method thereof

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