CN113307497A - Method for preparing underglaze transmutation glaze pigment and ceramic product prepared from underglaze transmutation glaze pigment - Google Patents
Method for preparing underglaze transmutation glaze pigment and ceramic product prepared from underglaze transmutation glaze pigment Download PDFInfo
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- CN113307497A CN113307497A CN202110699493.2A CN202110699493A CN113307497A CN 113307497 A CN113307497 A CN 113307497A CN 202110699493 A CN202110699493 A CN 202110699493A CN 113307497 A CN113307497 A CN 113307497A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 61
- 239000000049 pigment Substances 0.000 title claims abstract description 54
- 238000009377 nuclear transmutation Methods 0.000 title claims abstract description 49
- 239000000463 material Substances 0.000 claims abstract description 110
- 238000000498 ball milling Methods 0.000 claims abstract description 69
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 238000000227 grinding Methods 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 49
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 36
- 239000010433 feldspar Substances 0.000 claims description 32
- 239000010453 quartz Substances 0.000 claims description 32
- 229910052904 quartz Inorganic materials 0.000 claims description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 32
- 239000005995 Aluminium silicate Substances 0.000 claims description 31
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 31
- 235000012211 aluminium silicate Nutrition 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 229910052923 celestite Inorganic materials 0.000 claims description 29
- WUKWITHWXAAZEY-UHFFFAOYSA-L Calcium fluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 18
- 239000010436 fluorite Substances 0.000 claims description 18
- 229910001941 lanthanum oxide Inorganic materials 0.000 claims description 18
- 229910000616 Ferromanganese Inorganic materials 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 17
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 claims description 16
- 239000002023 wood Substances 0.000 claims description 15
- BJQHLKABXJIVAM-UHFFFAOYSA-N Bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 13
- 229940117972 Triolein Drugs 0.000 claims description 12
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 6
- 241001071917 Lithospermum Species 0.000 claims 2
- 238000003756 stirring Methods 0.000 claims 1
- 239000002002 slurry Substances 0.000 abstract description 15
- 238000010304 firing Methods 0.000 description 72
- AYJRCSIUFZENHW-UHFFFAOYSA-L Barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 28
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 24
- 235000015895 biscuits Nutrition 0.000 description 22
- 238000000034 method Methods 0.000 description 16
- 238000001816 cooling Methods 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 15
- 239000000454 talc Substances 0.000 description 13
- 229910052623 talc Inorganic materials 0.000 description 13
- 229960003563 Calcium Carbonate Drugs 0.000 description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 description 12
- 238000010422 painting Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 2
- 230000001050 lubricating Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 241001479541 Lithospermum erythrorhizon Species 0.000 description 1
- 210000002356 Skeleton Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- -1 chromium-lead Chemical compound 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention discloses a preparation method of an underglaze transmutation glaze material and a ceramic product prepared from the underglaze transmutation glaze material, and belongs to the technical field of ceramics. The preparation method of the underglaze transmutation glaze pigment comprises the following steps: mixing materials, ball milling and preparing a glaze slurry pigment. The underglaze kiln-changed glaze ceramic product prepared by the method has the advantages of attractive pattern, high glaze strength, almost no flaw and strong appreciation.
Description
The present patent application is a divisional application directed to application No. 201910330648.8.
Technical Field
The invention belongs to the technical field of ceramics, and particularly relates to a preparation method of an underglaze transmutation glaze pigment and a ceramic product prepared from the underglaze transmutation glaze pigment.
Background
The process for preparing ceramic products in China is pure green. The ceramic products have various types, the types of glaze materials on the surface of the ceramic products are more than enough, and the more common glaze materials comprise ice crack glaze, wood grain imitation glaze, transmutation glaze, white glaze and the like. Most of the common ceramic products are manufactured by glazing ceramic biscuit and finally firing, if the surface of the finished product is required to be provided with patterns, additional processes such as printing or hand painting are required, the printing efficiency is high, and the ceramic products are suitable for mass production. In the process of preparing the underglaze transmutation glaze ceramic product, in order to achieve the hand-drawing process, the hand-drawing requirement of a painter is higher, certain requirements are also provided for hand-drawing materials, otherwise unqualified products are easily generated in the glazing and firing processes, for example, the glaze has flaws, the strength of the glaze is not high, the pattern deformation of the glaze cannot achieve the expected aesthetic effect, and the like.
Therefore, there is a need for an underglaze transmutation glazed ceramic article having an aesthetically pleasing pattern, a high strength glaze surface, and an almost flawless glaze surface.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the underglaze transmutation glaze ceramic product which has beautiful pattern of glaze surface, high strength of the glaze surface and almost no flaw.
The invention adopts the following technical scheme:
the underglaze transmutation glaze material comprises the following components in parts by weight: 8-10 parts of kaolin, 32-40 parts of feldspar, 25-32 parts of quartz, 8-10 parts of rutile, 6-8 parts of lanthanum oxide, 1-2 parts of glycerol trioleate, 1-2 parts of dioctyl phthalate, 3-5 parts of celestite, 3-4 parts of fluorite, 3-5 parts of ferromanganese ore, 6-9 parts of lithospermum segments and 3-8 parts of pigment.
The method for preparing the underglaze transmutation glazed ceramic product by using the underglaze transmutation glaze pigment comprises the following steps:
step one, mixing materials:
according to the mass parts, the kaolin, the feldspar, the quartz, the rutile, the lanthanum oxide, the celestite, the fluorite, the ferromanganese ore and the purple wood knots are crushed separately to obtain crushed materials of all the components, and then the crushed materials of all the components are mixed and stirred uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
sequentially adding water, glyceryl trioleate, dioctyl phthalate and a pigment into the ball grinding material obtained in the second step to obtain a glaze slurry pigment;
step four, colored drawing and glazing:
hand-painting patterns on the outer surface of the ceramic biscuit to obtain a colored drawing biscuit, and glazing the outer surface of the colored drawing biscuit to obtain a glazed ceramic body;
step five, firing:
and (4) firing the glazed ceramic blank obtained in the step four, and cooling to obtain the underglaze kiln-changed glazed ceramic product.
Further, in the second step, water is added for ball milling during ball milling, wherein the ball milling material and the water are in mass percent: and (3) 1: 0.25-0.35, wherein the rotation speed during ball milling is 40-50 r/min, and the mixture after ball milling is sieved by a 300-325 mesh screen to obtain the ball grinding material.
Furthermore, the mass ratio of water to the ball grinding material in the third step is 1.54-1.56: 1.
Further, in the glazing step of the fourth step, the glaze is transparent glaze.
Further, the transparent glaze comprises the following components in parts by weight: 40-45 parts of feldspar, 30-32 parts of quartz, 5-8 parts of kaolin, 15-18 parts of heavy calcium carbonate, 2-5 parts of barium carbonate, 3-5 parts of talc and 3-4 parts of celestite.
Further, the preparation method of the transparent glaze comprises the following steps:
s1, preparing materials:
mixing the feldspar, the quartz, the kaolin, the calcium carbonate, the barium carbonate, the talc and the celestite according to the mass parts to obtain a transparent glaze mixture, and crushing and ball-milling the transparent glaze mixture to obtain a transparent glaze ball grinding material;
s2, preparing glaze:
and (5) adjusting the concentration of the ball milling material obtained in the step S1 to 46-48 Baume degrees, and obtaining the transparent glaze slurry.
And further, in the S1, the rotating speed during ball milling is 40-50 r/min, and the transparent glaze mixture after ball milling is sieved by a mesh screen of 800-900 meshes to obtain the transparent glaze ball grinding material.
Further, the firing process in the fifth step is as follows:
and (3) firing in the first stage: the firing temperature is increased from room temperature to 700-800 ℃, and the heating rate is 2.9-3.3 ℃/min;
second stage firing: heating the firing temperature from 700-800 ℃ to 1100-1200 ℃, and keeping the temperature for 2-2.5 h, wherein the heating rate is 3.1-3.3 ℃/min;
and (3) third stage firing: the firing temperature is increased from 1100-1200 ℃ to 1250-1300 ℃, the temperature is kept constant for 1-1.5 h, and then cooling is carried out, wherein the cooling rate is 5.9-7.0 ℃/min.
Compared with the prior art, the invention has the following beneficial effects:
firstly, in order to make the color of the color material bright, the underglaze transmutation glaze color material adopts triolein with lubricating property to improve the dispersion degree among all components and improve the coloring performance of all components, and meanwhile, celestite not only has the function of improving the transparency of glaze, but also has the lubricating function, so that the components of the color material are uniformly mixed; meanwhile, the fluorite is added, so that the under-glaze pattern is more bright and has strong appreciation;
secondly, as the patterns on the surface of the ceramic blank body are drawn by hands, in order to improve the viscosity and plasticity of the underglaze transmutation glaze pigment, the viscous lanthanum oxide can be improved through the purple wood knots with the forming function after being influenced by high temperature, the effective forming of the patterns in the drawing process is ensured, the pigment is effectively adhered to the outer surface of the ceramic blank body, and the attractiveness of the patterns is prevented from being damaged when the transparent glaze is glazed;
thirdly, in order to improve the strength of the transparent glaze, feldspar and quartz are used as main components of the glaze and are used as a skeleton of the glaze, and double-fly powder and talc are used as a filling agent of the glaze, so that the generation of pinholes can be effectively reduced in the firing process, the strength of the glaze is improved, and the celestite with the improved transparency of the glaze is adopted, so that the transparency of the glaze is improved, and patterns of the glaze can be more visually appreciated;
fourthly, in the firing process, the first section firing is a preheating section which mainly discharges glaze free water to prevent the glaze cracking phenomenon in the subsequent high-temperature firing, and in the second section firing process, glaze high-temperature salt and crystal water can be effectively discharged, and meanwhile, gas bubbles discharged in the first section firing process can be discharged, so that the pinhole phenomenon is reduced, and the glaze strength is effectively improved; and finally, firing at the high temperature of 1300 ℃ to ensure that the components of the glaze fully react, the underglaze transmutation glaze pigment is effectively bonded with the outer surface of the ceramic blank, the underglaze transmutation glaze pigment is more fully bonded with the transparent glaze, and the attractiveness of the pattern is improved.
Detailed Description
The raw materials used in the present invention are all commercially available products.
Example 1
The underglaze transmutation glaze material comprises the following components in parts by weight: 8 parts of kaolin, 32 parts of feldspar, 25 parts of quartz, 8-10 parts of rutile, 6-8 parts of lanthanum oxide, 1-2 parts of triolein, 1 part of dioctyl phthalate, 3 parts of celestite, 3 parts of fluorite, 3 parts of ferromanganese ore, 6 parts of purple wood knots and 3 parts of pigment.
The method for preparing the underglaze transmutation glazed ceramic product by using the underglaze transmutation glaze pigment comprises the following steps:
step one, mixing materials:
according to the mass parts, the kaolin, the feldspar, the quartz, the rutile, the lanthanum oxide, the celestite, the fluorite, the ferromanganese ore and the purple wood knots are crushed separately to obtain crushed materials of all the components, and then the crushed materials of all the components are mixed and stirred uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
during ball milling, water is added for ball milling, wherein the ball grinding material and the water are in mass percentage: 1:0.25, wherein the rotation speed during ball milling is 40r/min, and the mixture after ball milling is sieved by a 300-325 mesh screen to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
sequentially adding water, glyceryl trioleate, dioctyl phthalate and a pigment into the ball grinding material obtained in the second step to obtain a glaze slurry pigment; wherein the mass ratio of water to the ball grinding material is 1.54: 1;
step four, colored drawing and glazing:
hand-painting patterns on the outer surface of the ceramic biscuit to obtain a colored drawing biscuit, and glazing the outer surface of the colored drawing biscuit to obtain a glazed ceramic body;
the glaze is transparent glaze, and the transparent glaze comprises the following components in parts by weight: 40 parts of feldspar, 30 parts of quartz, 5 parts of kaolin, 15 parts of heavy calcium carbonate, 2 parts of barium carbonate, 3 parts of talc and 3 parts of celestite;
the preparation method of the transparent glaze comprises the following steps:
s1, preparing materials:
mixing the feldspar, the quartz, the kaolin, the calcium carbonate, the barium carbonate, the talc and the celestite according to the mass parts to obtain a transparent glaze mixture, and crushing and ball-milling the transparent glaze mixture to obtain a transparent glaze ball grinding material;
s2, preparing glaze:
adjusting the concentration of the ball milling material obtained in the step S1 to 46 Baume degrees to obtain transparent glaze slurry;
s1, the rotating speed during ball milling is 40r/min, and the transparent glaze mixture after ball milling is sieved by a mesh screen of 800-900 meshes to obtain a transparent glaze ball grinding material;
step five, firing:
firing the glazed ceramic blank obtained in the step four, and cooling to obtain an underglaze kiln-changed glazed ceramic product;
the firing process is specifically as follows:
and (3) firing in the first stage: the firing temperature is increased from room temperature to 700 ℃, and the heating rate is 2.9 ℃/min;
second stage firing: the firing temperature is increased from 700 ℃ to 1100 ℃, and the temperature is kept for 2h, wherein the heating rate is 3.1 ℃/min;
and (3) third stage firing: the firing temperature is increased from 1100 ℃ to 1250 ℃, the temperature is kept constant for 1h, and then the material is cooled, wherein the cooling rate is 5.9 ℃/min.
Example 2
The underglaze transmutation glaze material comprises the following components in parts by weight: 9 parts of kaolin, 34 parts of feldspar, 28 parts of quartz, 9 parts of rutile, 7 parts of lanthanum oxide, 2 parts of triolein, 2 parts of dioctyl phthalate, 4 parts of celestite, 4 parts of fluorite, 4 parts of ferromanganese ore, 7 parts of laccolite and 4 parts of pigment.
The method for preparing the underglaze transmutation glazed ceramic product by using the underglaze transmutation glaze pigment comprises the following steps:
step one, mixing materials:
according to the mass parts, the kaolin, the feldspar, the quartz, the rutile, the lanthanum oxide, the celestite, the fluorite, the ferromanganese ore and the purple wood knots are crushed separately to obtain crushed materials of all the components, and then the crushed materials of all the components are mixed and stirred uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
during ball milling, water is added for ball milling, wherein the ball grinding material and the water are in mass percentage: 1:0.28, wherein the rotation speed during ball milling is 45r/min, and the ball-milled mixture is sieved by a 300-mesh screen to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
sequentially adding water, glyceryl trioleate, dioctyl phthalate and a pigment into the ball grinding material obtained in the second step to obtain a glaze slurry pigment; wherein the mass ratio of water to the ball grinding material is 1.55: 1;
step four, colored drawing and glazing:
hand-painting patterns on the outer surface of the ceramic biscuit to obtain a colored drawing biscuit, and glazing the outer surface of the colored drawing biscuit to obtain a glazed ceramic body;
the glaze is transparent glaze, and the transparent glaze comprises the following components in parts by weight: 42 parts of feldspar, 31 parts of quartz, 6 parts of kaolin, 6 parts of heavy calcium carbonate, 3 parts of barium carbonate, 4 parts of talc and 4 parts of celestite;
the preparation method of the transparent glaze comprises the following steps:
s1, preparing materials:
mixing the feldspar, the quartz, the kaolin, the calcium carbonate, the barium carbonate, the talc and the celestite according to the mass parts to obtain a transparent glaze mixture, and crushing and ball-milling the transparent glaze mixture to obtain a transparent glaze ball grinding material;
s2, preparing glaze:
adjusting the concentration of the ball milling material obtained in the step S1 to 47 Baume degrees to obtain transparent glaze slurry;
s1, the rotating speed during ball milling is 45r/min, and the transparent glaze mixture after ball milling is sieved by a 800-mesh screen to obtain a transparent glaze ball grinding material;
step five, firing:
firing the glazed ceramic blank obtained in the step four, and cooling to obtain an underglaze kiln-changed glazed ceramic product;
the firing process is specifically as follows:
and (3) firing in the first stage: the firing temperature is increased from room temperature to 750 ℃, and the heating rate is 3.0 ℃/min;
second stage firing: the firing temperature is increased from 750 ℃ to 1150 ℃, and the temperature is kept for 2h, wherein the heating rate is 3.2 ℃/min;
and (3) third stage firing: the firing temperature is increased from 1150 ℃ to 1250 ℃, the temperature is kept for 1h, and then the mixture is cooled, wherein the cooling rate is 6.2 ℃/min.
Example 3
The underglaze transmutation glaze material comprises the following components in parts by weight: 10 parts of kaolin, 38 parts of feldspar, 30 parts of quartz, 8 parts of rutile, 6 parts of lanthanum oxide, 2 parts of triolein, 1 part of dioctyl phthalate, 3 parts of celestite, 4 parts of fluorite, 4 parts of ferromanganese ore, 8 parts of purple wood knot and 5 parts of pigment.
The method for preparing the underglaze transmutation glazed ceramic product by using the underglaze transmutation glaze pigment comprises the following steps:
step one, mixing materials:
according to the mass parts, the kaolin, the feldspar, the quartz, the rutile, the lanthanum oxide, the celestite, the fluorite, the ferromanganese ore and the purple wood knots are crushed separately to obtain crushed materials of all the components, and then the crushed materials of all the components are mixed and stirred uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
during ball milling, water is added for ball milling, wherein the ball grinding material and the water are in mass percentage: 1:0.30, wherein the rotation speed during ball milling is 50r/min, and the ball-milled mixture is sieved by a 325-mesh screen to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
sequentially adding water, glyceryl trioleate, dioctyl phthalate and a pigment into the ball grinding material obtained in the second step to obtain a glaze slurry pigment; wherein the mass ratio of water to the ball grinding material is 1.56: 1;
step four, colored drawing and glazing:
hand-painting patterns on the outer surface of the ceramic biscuit to obtain a colored drawing biscuit, and glazing the outer surface of the colored drawing biscuit to obtain a glazed ceramic body;
the glaze is transparent glaze, and the transparent glaze comprises the following components in parts by weight: 44 parts of feldspar, 32 parts of quartz, 6 parts of kaolin, 17 parts of heavy calcium carbonate, 4 parts of barium carbonate, 4 parts of talc and 4 parts of celestite;
the preparation method of the transparent glaze comprises the following steps:
s1, preparing materials:
mixing the feldspar, the quartz, the kaolin, the calcium carbonate, the barium carbonate, the talc and the celestite according to the mass parts to obtain a transparent glaze mixture, and crushing and ball-milling the transparent glaze mixture to obtain a transparent glaze ball grinding material;
s2, preparing glaze:
adjusting the concentration of the ball milling material obtained in the step S1 to 47 Baume degrees to obtain transparent glaze slurry;
s1, the rotating speed during ball milling is 50r/min, and the transparent glaze mixture after ball milling is screened by a 900-mesh screen to obtain a transparent glaze ball grinding material;
step five, firing:
firing the glazed ceramic blank obtained in the step four, and cooling to obtain an underglaze kiln-changed glazed ceramic product;
the firing process is specifically as follows:
and (3) firing in the first stage: the firing temperature is increased from room temperature to 800 ℃, and the heating rate is 3.3 ℃/min;
second stage firing: the firing temperature is increased from 800 ℃ to 1200 ℃, and the temperature is kept constant for 2.5h, wherein the heating rate is 3.3 ℃/min;
and (3) third stage firing: the firing temperature is increased from 1200 ℃ to 1300 ℃, the temperature is kept constant for 1.5h, and then the mixture is cooled, wherein the cooling rate is 7.0 ℃/min.
Example 4
The underglaze transmutation glaze material comprises the following components in parts by weight: 10 parts of kaolin, 40 parts of feldspar, 32 parts of quartz, 10 parts of rutile, 8 parts of lanthanum oxide, 2 parts of triolein, 2 parts of dioctyl phthalate, 5 parts of celestite, 4 parts of fluorite, 5 parts of ferromanganese ore, 9 parts of purple wood knot and 8 parts of pigment.
The method for preparing the underglaze transmutation glazed ceramic product by using the underglaze transmutation glaze pigment comprises the following steps:
step one, mixing materials:
according to the mass parts, the kaolin, the feldspar, the quartz, the rutile, the lanthanum oxide, the celestite, the fluorite, the ferromanganese ore and the purple wood knots are crushed separately to obtain crushed materials of all the components, and then the crushed materials of all the components are mixed and stirred uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
during ball milling, water is added for ball milling, wherein the ball grinding material and the water are in mass percentage: 1:0.35, wherein the rotation speed during ball milling is 50r/min, and the ball-milled mixture is sieved by a 325-mesh screen to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
sequentially adding water, glyceryl trioleate, dioctyl phthalate and a pigment into the ball grinding material obtained in the second step to obtain a glaze slurry pigment; wherein the mass ratio of water to the ball grinding material is 1.56: 1;
step four, colored drawing and glazing:
hand-painting patterns on the outer surface of the ceramic biscuit to obtain a colored drawing biscuit, and glazing the outer surface of the colored drawing biscuit to obtain a glazed ceramic body;
the glaze is transparent glaze, and the transparent glaze comprises the following components in parts by weight: 45 parts of feldspar, 32 parts of quartz, 8 parts of kaolin, 18 parts of calcium carbonate, 5 parts of barium carbonate, 5 parts of talc and 4 parts of celestite;
the preparation method of the transparent glaze comprises the following steps:
s1, preparing materials:
mixing the feldspar, the quartz, the kaolin, the calcium carbonate, the barium carbonate, the talc and the celestite according to the mass parts to obtain a transparent glaze mixture, and crushing and ball-milling the transparent glaze mixture to obtain a transparent glaze ball grinding material;
s2, preparing glaze:
adjusting the concentration of the ball milling material obtained in the step S1 to 48 Baume degrees to obtain transparent glaze slurry;
s1, the rotating speed during ball milling is 50r/min, and the transparent glaze mixture after ball milling is screened by a 900-mesh screen to obtain a transparent glaze ball grinding material;
step five, firing:
firing the glazed ceramic blank obtained in the step four, and cooling to obtain an underglaze kiln-changed glazed ceramic product;
the firing process is specifically as follows:
and (3) firing in the first stage: the firing temperature is increased from room temperature to 800 ℃, and the heating rate is 3.3 ℃/min;
second stage firing: the firing temperature is increased from 800 ℃ to 1200 ℃, and the temperature is kept constant for 2.5h, wherein the heating rate is 3.3 ℃/min;
and (3) third stage firing: the firing temperature is increased from 1200 ℃ to 1300 ℃, the temperature is kept constant for 1.5h, and then the mixture is cooled, wherein the cooling rate is 7.0 ℃/min.
Comparative example 1
The underglaze transmutation glaze material comprises the following components in parts by weight: 10 parts of kaolin, 40 parts of feldspar, 32 parts of quartz, 10 parts of rutile, 8 parts of lanthanum oxide, 4 parts of fluorite, 5 parts of ferromanganese ore, 9 parts of purple wood knots and 8 parts of pigment.
The method for preparing the underglaze transmutation glazed ceramic product by using the underglaze transmutation glaze pigment comprises the following steps:
step one, mixing materials:
according to the mass parts, the kaolin, the feldspar, the quartz, the rutile, the lanthanum oxide, the fluorite, the ferromanganese ore and the purple wood knots are crushed separately to obtain crushed materials of all the components, and then the crushed materials of all the components are mixed and stirred uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
during ball milling, water is added for ball milling, wherein the ball grinding material and the water are in mass percentage: 1:0.35, wherein the rotation speed during ball milling is 50r/min, and the ball-milled mixture is sieved by a 325-mesh screen to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
sequentially adding water and a pigment into the ball grinding material obtained in the second step to obtain a glaze slurry pigment; wherein the mass ratio of water to the ball grinding material is 1.56: 1;
step four, colored drawing and glazing:
hand-painting patterns on the outer surface of the ceramic biscuit to obtain a colored drawing biscuit, and glazing the outer surface of the colored drawing biscuit to obtain a glazed ceramic body;
the glaze is transparent glaze, and the transparent glaze comprises the following components in parts by weight: 45 parts of feldspar, 32 parts of quartz, 8 parts of kaolin, 18 parts of calcium carbonate, 5 parts of barium carbonate, 5 parts of talc and 4 parts of celestite;
the preparation method of the transparent glaze comprises the following steps:
s1, preparing materials:
mixing the feldspar, the quartz, the kaolin, the calcium carbonate, the barium carbonate, the talc and the celestite according to the mass parts to obtain a transparent glaze mixture, and crushing and ball-milling the transparent glaze mixture to obtain a transparent glaze ball grinding material;
s2, preparing glaze:
adjusting the concentration of the ball milling material obtained in the step S1 to 48 Baume degrees to obtain transparent glaze slurry;
s1, the rotating speed during ball milling is 50r/min, and the transparent glaze mixture after ball milling is screened by a 900-mesh screen to obtain a transparent glaze ball grinding material;
step five, firing:
firing the glazed ceramic blank obtained in the step four, and cooling to obtain an underglaze kiln-changed glazed ceramic product;
the firing process is specifically as follows:
and (3) firing in the first stage: the firing temperature is increased from room temperature to 800 ℃, and the heating rate is 3.3 ℃/min;
second stage firing: the firing temperature is increased from 800 ℃ to 1200 ℃, and the temperature is kept constant for 2.5h, wherein the heating rate is 3.3 ℃/min;
and (3) third stage firing: the firing temperature is increased from 1200 ℃ to 1300 ℃, the temperature is kept constant for 1.5h, and then the mixture is cooled, wherein the cooling rate is 7.0 ℃/min.
Comparative example 2
The underglaze transmutation glaze material comprises the following components in parts by weight: 10 parts of kaolin, 40 parts of feldspar, 32 parts of quartz, 10 parts of rutile, 8 parts of lanthanum oxide, 5 parts of celestite, 4 parts of fluorite, 5 parts of ferromanganese ore, 9 parts of laccolite and 8 parts of pigment.
The method for preparing the underglaze transmutation glazed ceramic product by using the underglaze transmutation glaze pigment comprises the following steps:
step one, mixing materials:
according to the mass parts, the kaolin, the feldspar, the quartz, the rutile, the lanthanum oxide, the celestite, the fluorite, the ferromanganese ore and the purple wood knots are crushed separately to obtain crushed materials of all the components, and then the crushed materials of all the components are mixed and stirred uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
during ball milling, water is added for ball milling, wherein the ball grinding material and the water are in mass percentage: 1:0.35, wherein the rotation speed during ball milling is 50r/min, and the ball-milled mixture is sieved by a 325-mesh screen to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
sequentially adding water and a pigment into the ball grinding material obtained in the second step to obtain a glaze slurry pigment; wherein the mass ratio of water to the ball grinding material is 1.56: 1;
step four, colored drawing and glazing:
hand-painting patterns on the outer surface of the ceramic biscuit to obtain a colored drawing biscuit, and glazing the outer surface of the colored drawing biscuit to obtain a glazed ceramic body;
the glaze is transparent glaze, and the transparent glaze comprises the following components in parts by weight: 45 parts of feldspar, 32 parts of quartz, 8 parts of kaolin and 5 parts of barium carbonate;
the preparation method of the transparent glaze comprises the following steps:
s1, preparing materials:
mixing the feldspar, the quartz, the kaolin and the barium carbonate according to the mass parts to obtain a transparent glaze mixture, and crushing and ball-milling the transparent glaze mixture to obtain a transparent glaze ball grinding material;
s2, preparing glaze:
adjusting the concentration of the ball milling material obtained in the step S1 to 48 Baume degrees to obtain transparent glaze slurry;
s1, the rotating speed during ball milling is 50r/min, and the transparent glaze mixture after ball milling is screened by a 900-mesh screen to obtain a transparent glaze ball grinding material;
step five, firing:
firing the glazed ceramic blank obtained in the step four, and cooling to obtain an underglaze kiln-changed glazed ceramic product;
the firing process is specifically as follows:
and (3) firing in the first stage: the firing temperature is increased from room temperature to 800 ℃, and the heating rate is 3.3 ℃/min;
second stage firing: the firing temperature is increased from 800 ℃ to 1200 ℃, and the temperature is kept constant for 2.5h, wherein the heating rate is 3.3 ℃/min;
and (3) third stage firing: the firing temperature is increased from 1200 ℃ to 1300 ℃, the temperature is kept constant for 1.5h, and then the mixture is cooled, wherein the cooling rate is 7.0 ℃/min.
Detecting crack resistance of the underglaze transmutation glaze ceramic product by using a GB/T34252 and 2017 daily ceramic ware crack resistance test method;
detecting the chromium-lead dissolution amount and the glossiness of the underglaze transmutation glaze ceramic product by adopting GB/T3532-containing 2009 domestic porcelain;
the performance of the underglaze transmutation glaze ceramic products obtained in the embodiments 1 to 4 and the comparative examples 1 to 2 is detected, and the detection results are shown in the following table 1:
table 1: results of testing of underglaze transmutation glazed ceramic articles obtained in examples 1 to 4 and comparative examples 1 to 2
As can be seen from table 1, the underglaze transmutation glazed ceramic products prepared in examples 1 to 4 do not crack once exchanged at 180 ℃ to 20 ℃, have strong thermal shock resistance, are beneficial to prolonging the service life, have low lead and chromium elution, reduce the harm to human bodies, have high glossiness and high appreciation. In contrast, in comparative examples 1 and 2, the underglaze pattern was blurred, and the color brightness was insufficient, and the appreciation was poor.
It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (4)
1. The preparation method of the underglaze transmutation glaze pigment is characterized by comprising the following steps:
step one, mixing materials:
the following components are mixed: independently crushing kaolin, feldspar, quartz, rutile, lanthanum oxide, celestite, fluorite, ferromanganese ore and lithospermum wood knots to obtain crushed materials of all components, and then mixing and stirring the crushed materials of all components uniformly to obtain a mixture;
step two, ball milling:
ball milling the mixture obtained in the step one to obtain a ball grinding material;
step three, preparing a glaze slip pigment:
and (4) sequentially adding water, glyceryl trioleate, dioctyl phthalate and a pigment into the ball grinding material obtained in the second step to obtain the underglaze kiln-changed glaze pigment.
2. The preparation method of the underglaze transmutation glaze material according to claim 1, characterized in that the dosage of each component of the underglaze transmutation glaze material is as follows according to parts by mass: 9-10 parts of kaolin, 34-38 parts of feldspar, 28-30 parts of quartz, 8-9 parts of rutile, 6-7 parts of lanthanum oxide, 1-2 parts of glycerol trioleate, 1-2 parts of dioctyl phthalate, 3-4 parts of celestite, 3-4 parts of fluorite, 3-4 parts of ferromanganese ore, 7-8 parts of lithospermum segments and 4-5 parts of pigment.
3. The preparation method of the underglaze transmutation glaze material according to claim 2, characterized in that the dosage of each component of the underglaze transmutation glaze material is as follows according to parts by mass: 10 parts of kaolin, 38 parts of feldspar, 30 parts of quartz, 8 parts of rutile, 6 parts of lanthanum oxide, 2 parts of triolein, 1 part of dioctyl phthalate, 3 parts of celestite, 4 parts of fluorite, 4 parts of ferromanganese ore, 8 parts of purple wood knot and 5 parts of pigment.
4. An underglaze transmuted glazed ceramic article made with the underglaze transmutation glaze pigment of claim 1.
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