CN109761647B - Titanium-series multilayer fancy glaze ceramic tile and preparation method thereof - Google Patents
Titanium-series multilayer fancy glaze ceramic tile and preparation method thereof Download PDFInfo
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- CN109761647B CN109761647B CN201910208139.8A CN201910208139A CN109761647B CN 109761647 B CN109761647 B CN 109761647B CN 201910208139 A CN201910208139 A CN 201910208139A CN 109761647 B CN109761647 B CN 109761647B
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Abstract
The invention discloses a titanium-based multilayer fancy glaze ceramic tile and a preparation method thereof. The titanium-based multilayer fancy glaze ceramic tile comprises the following components in part by weight: the ceramic tile comprises a brick blank layer, a first titanium glaze layer, a fancy glaze layer and a second titanium glaze layer; the first titanium glaze layer comprises a first titanium glaze and a color developing agent, the fancy glaze layer comprises fancy glaze and a color developing agent, and the second titanium glaze layer comprises a second titanium glaze. In the invention, the basic glaze of the titanium-based multiple-layer fancy glaze is a split-phase bright glaze with a split-phase function, so that the glaze surface changes abundantly, and simultaneously, the mutual fusion and diffusion between the low-viscosity titanium glaze, the high-viscosity titanium glaze and the fancy glaze are further intensified by the mutual diffusion and reaction between the low-viscosity basic glaze and the high-viscosity basic glaze of the same system and the addition of the vanadium pentoxide with low surface tension in the fancy glaze, so that the bright ceramic tile with rich and colorful surface patterns, which is similar to the kiln-changed glaze effect, of the product is formed.
Description
Technical Field
The invention relates to the field of architectural ceramic production, in particular to a titanium-series multilayer fancy glaze ceramic tile and a preparation method thereof.
Background
With the continuous transformation of consumer groups and consumption concepts, the development of traditional ceramics gradually enters a transformation period, so that the industries continuously generate a plurality of new technologies, new devices and new materials in recent years. However, the popularization and application of advanced equipment, technology and inkjet decoration also make ceramic products seriously homogeneous and competitive, so how to develop new ceramic products of different categories and find a new profit growth point is a problem that various large ceramic enterprises are thinking.
Modern antique tiles have recently become popular in the market. However, the once-fired bright antique product is difficult to popularize vigorously due to the process difficulty. The abundant change of the furnace transmutation bright surface products is still highly favored by the consumers, but the production is difficult to continue due to the production instability.
Accordingly, the prior art is yet to be improved and developed.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide a titanium-based multi-layer fancy glaze ceramic tile and a preparation method thereof, and aims to solve the problem that the existing bright product or transmutation product is unstable in production.
The technical scheme of the invention is as follows:
a titanium series multilayer fancy glaze ceramic tile comprises the following components in part by weight: the ceramic tile comprises a brick blank layer, a first titanium glaze layer, a fancy glaze layer and a second titanium glaze layer; the first titanium glaze layer comprises a first titanium glaze and a color developing agent, the fancy glaze layer comprises a fancy glaze and a color developing agent, and the second titanium glaze layer comprises a second titanium glaze;
the first titanium glaze comprises the following raw materials in parts by weight: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 0.2-0.5 part of methyl and 0.2-0.5 part of trimerization;
the fancy glaze comprises the following raw materials in parts by mass: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 0.1-2 parts of vanadium pentoxide, 3-8 parts of lithium carbonate and 40-65 parts of printing paste;
the second titanium glaze comprises the following raw materials in parts by weight: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 8-15 parts of quartz, 0.2-0.5 part of methyl and 0.2-0.5 part of trimerization.
Further, the 1801 frit comprises the following components in percentage by mass: SiO 22 60.49%，Al2O36.62%，CaO 13.58%，MgO 2.72%，K2O 4.02%，Na2O 0.56%，ZnO 11.81%，The burn was reduced by 0.2%.
Further, the color developers are CoO and Fe2O3、CuO、MnO2、Cr2O3、NiO2One or more of (a).
Furthermore, in the first titanium glaze layer, the mass ratio of the first titanium glaze to the color developing agent is 100: 1-100: 10.
Furthermore, in the fancy glaze layer, the mass ratio of the fancy glaze to the color developing agent is 100: 1-100: 20.
The invention relates to a preparation method of a titanium-based multilayer fancy glaze ceramic tile, which comprises the following steps:
forming and drying a ceramic green brick to form a green brick layer;
forming a first titanium glaze layer on the brick blank layer;
printing the first titanium glaze layer by using a silk screen or a rubber roller to form a fancy glaze layer;
forming a second titanium glaze layer on the fancy glaze layer;
and firing in a kiln to obtain the titanium series multilayer fancy glaze ceramic tile.
Further, the step of forming the first titanium glaze layer on the brick blank layer comprises the step of adding a coloring agent into the first titanium glaze layer to perform ball milling and mixing uniformly, wherein the ball milling time is as follows: ball-milling for 3-10 minutes by a wet method for every 100g of dry materials; ball milling fineness: the residue is 2-3% of 325 mesh.
Further, the step of forming the fancy glaze layer on the first titanium glaze layer comprises the step of adding a color developing agent into the fancy glaze to perform ball milling and mixing uniformly, wherein the ball milling time is as follows: ball-milling for 3-10 minutes by a wet method for every 100g of dry materials; ball milling fineness: the residue is 2-3% of 325 mesh.
Further, the sintering temperature is 1150-1250 ℃, and the sintering time is 45-65 min.
Has the advantages that: in the invention, the basic glaze of the titanium-based multiple-layer fancy glaze is a split-phase bright glaze with a split-phase function, so that the glaze surface has rich change, and simultaneously, the mutual fusion and diffusion between the bottom glaze and the fancy glaze are further intensified through the mutual diffusion and reaction between the basic glaze of the same system with low viscosity and high viscosity and the matching of vanadium pentoxide with low surface tension and different fancy net patterns added in the fancy glaze, so that the bright ceramic tile with rich and colorful surface patterns, which is similar to the kiln-transformed glaze effect, of the product is formed. Meanwhile, different metal oxides are added between the titanium glaze and the fancy glaze, so that the series of color systems can be enriched.
Detailed Description
The invention provides a titanium-based multilayer fancy glaze ceramic tile and a preparation method thereof, and the invention is further described in detail below in order to make the purpose, technical scheme and effect of the invention clearer and more clear. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The embodiment of the invention provides a titanium-based multilayer fancy glaze ceramic tile which comprises the following components in part by weight: the ceramic tile comprises a brick blank layer, a first titanium glaze layer, a fancy glaze layer and a second titanium glaze layer; the first titanium glaze layer comprises a first titanium glaze and a color developing agent, the fancy glaze layer comprises a fancy glaze and a color developing agent, and the second titanium glaze layer comprises a second titanium glaze;
the first titanium glaze comprises the following raw materials in parts by weight: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 0.2-0.5 part of methyl and 0.2-0.5 part of trimerization;
the fancy glaze comprises the following raw materials in parts by mass: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 0.1-2 parts of vanadium pentoxide, 3-8 parts of lithium carbonate and 40-65 parts of printing paste;
the second titanium glaze comprises the following raw materials in parts by weight: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 8-15 parts of quartz, 0.2-0.5 part of methyl and 0.2-0.5 part of trimerization.
In the present embodiment, the first and second electrodes are,the first titanium glaze is low-viscosity titanium glaze, and the viscosity of the low-viscosity titanium glaze is 0.5-0.7 x 10 at 1200 DEG C3Poise.
In this embodiment, the second titanium glaze is a high-viscosity titanium glaze, and the viscosity of the high-viscosity titanium glaze is 0.8 to 1.1 x 10 at about 1200 ℃3Poise.
The preparation of the titanium series multiple layer fancy glaze ceramic tile is developed by utilizing the phase splitting principle, the titanium series glaze formula is taken as the basis, phosphate is introduced into the formula to promote the phase splitting of the glaze surface, and the glaze surface formed by the phase splitting can obtain the pattern effect similar to the kiln transmutation glaze product with rich surface change.
In this embodiment, the formula systems of the first titanium glaze, the fancy glaze and the second titanium glaze of the ceramic tile are basically the same, the formula system is called as a base glaze, and the base glaze is a phase-splitting bright glaze with a phase-splitting function, so that the glaze surface changes abundantly, and meanwhile, the mutual fusion and diffusion between the low-viscosity titanium glaze, the high-viscosity titanium glaze and the fancy glaze are further intensified through the mutual diffusion and reaction between the base glazes of the same system with low viscosity and high viscosity, and the vanadium pentoxide with low surface tension is added into the fancy glaze, so that the bright ceramic tile with the colorful surface pattern and the similar kiln-change glaze effect of the ceramic tile is formed. Meanwhile, different metal oxides are added into the titanium glaze and the fancy glaze formula, so that the series of color systems can be enriched.
In one embodiment, the 1801 frit comprises the following components in mass percent: SiO 22 60.49%，Al2O3 6.62%，CaO 13.58%，MgO 2.72%，K2O 4.02%，Na20.56% of O, 11.81% of ZnO and 2% of ignition loss.
In one embodiment, the color former is CoO, Fe2O3、CuO、MnO2、Cr2O3、NiO2And the like.
In one embodiment, in the first titanium glaze layer, the mass ratio of the first titanium glaze to the color developing agent is 100: 1-100: 10, the ratio is too large, the color is light, and no change is seen; if the ratio is too small, the addition of too much metal oxide will affect the physical and chemical properties of the titanium glaze.
In one embodiment, in the fancy glaze layer, the mass ratio of the fancy glaze to the color developing agent is 100: 1-100: 20, the ratio is too large, the color is light, and no change is seen; if the ratio is too small, the addition of too much metal oxide will affect the physical and chemical properties of the fancy glaze.
The preparation method of the titanium-based multilayer fancy glaze ceramic tile provided by the embodiment of the invention comprises the following steps:
forming and drying a ceramic green brick to form a green brick layer;
forming a first titanium glaze layer on the brick blank layer;
printing the first titanium glaze layer by using a silk screen or a rubber roller to form a fancy glaze layer;
forming a second titanium glaze layer on the fancy glaze layer;
and firing in a kiln to obtain the titanium series multilayer fancy glaze ceramic tile. It should be noted that the order of the fancy glaze layer and the second titanium glaze layer can be changed, and different surface effects can be achieved through different process combinations.
At present, bright antique bricks and transmutation glaze products on the market are deeply loved by consumers, but the continuous and stable production is difficult due to the problem of difficult process. According to the embodiment of the invention, the split-phase bright effect of the titanium base glaze is utilized to prepare new products with variable air lattices and rich color systems, so that bright products in the market are enriched, a high-end market is occupied, and the market competitiveness is improved.
The preparation of the titanium series multiple layer fancy glaze ceramic tile is developed by utilizing the phase splitting principle, the titanium series glaze formula is taken as the basis, phosphate is introduced into the formula to promote the phase splitting of the glaze surface, and the glaze surface formed by the phase splitting can obtain the pattern effect similar to the kiln transmutation glaze product with rich surface change. Meanwhile, bright products which are more abundant in change and wider in color system than the transmutation glaze products can be obtained through different process combinations.
In one embodiment, the step of forming the first titanium glaze layer on the brick blank layer comprises the step of adding a color former into the first titanium glaze layer to perform ball milling and mixing uniformly, wherein the ball milling time is as follows: ball-milling for 3-10 minutes by a wet method for every 100g of dry materials; ball milling fineness: the residue is 2-3% of 325 mesh. And after the ball milling is finished, covering the mixed material of the first titanium glaze and the coloring agent on the brick blank layer in a spraying or showering mode to form a first titanium glaze layer.
In one embodiment, the step of forming a fancy glaze layer on the first titanium glaze layer comprises the step of adding a color developing agent into the fancy glaze for ball milling and mixing uniformly, wherein the ball milling time is as follows: ball-milling for 3-10 minutes by a wet method for every 100g of dry materials; ball milling fineness: the residue is 2-3% of 325 mesh. After the ball milling is finished, covering a mixed material of the fancy glaze and the coloring agent on the first titanium glaze layer in a screen mesh or rubber roller mode to form the fancy glaze layer.
In one embodiment, the firing temperature is 1150-1250 ℃ and the firing time is 45-65 min.
The present invention will be described in further detail with reference to specific examples.
Example (b):
a titanium series multilayer fancy glaze ceramic tile has the structure from bottom to top: the ceramic tile comprises a brick blank layer, a first titanium glaze layer, a fancy glaze layer and a second titanium glaze layer.
The preparation method comprises the following steps:
(1) forming and drying a ceramic green brick;
(2) spraying low-viscosity titanium glaze;
(3) screen printing glaze;
(4) spraying high-viscosity titanium glaze;
(5) and putting into a kiln for sintering.
The formula of the low-viscosity titanium glaze layer is as follows: 30 parts of potassium feldspar, 10 parts of albite, 8 parts of kaolin, 2 parts of calcium phosphate, 12 parts of wollastonite, 20 parts of calcined zinc oxide, 15 parts of 1801 frit, 10 parts of titanium dioxide, 5 parts of CuO, 0.3 part of methyl and 0.3 part of trimerization. Wherein the ball milling time is as follows: ball milling for 8 minutes by a wet method; ball milling fineness: and 3% of 325 mesh sieve residue. Glaze amount: 600g/m2Specific gravity: 1.5g/cm3；
The formula of the fancy glaze layer is as follows: 30 parts of potassium feldspar, 10 parts of albite, 8 parts of kaolin, 2 parts of calcium phosphate, 12 parts of wollastonite, 20 parts of calcined zinc oxide, 15 parts of 1801 frit, 10 parts of titanium dioxide, 5 parts of cobalt oxide, 0.4 part of vanadium pentoxide, 5 parts of lithium carbonate and printing paste50 parts, wherein the ball milling time is: ball milling for 8 minutes by a wet method; ball milling fineness: and 2% of 325 mesh sieve residue. Specific gravity: 1.5g/cm3；
The formula of the high-viscosity titanium glaze layer is as follows: 30 parts of potassium feldspar, 10 parts of albite, 8 parts of kaolin, 2 parts of calcium phosphate, 126 parts of wollastonite, 20 parts of calcined zinc oxide, 15 parts of 1801 frit, 10 parts of titanium dioxide, 10 parts of quartz, 0.3 part of methyl and 0.3 part of trimerization. Wherein the ball milling time is as follows: ball milling for 8 minutes by a wet method; ball milling fineness: and 3% of 325 mesh sieve residue. Glaze amount: 600g/m2Specific gravity: 1.5g/cm3；
The firing temperature of the kiln is as follows: the sintering time is 48min at 1220 ℃.
In summary, the titanium-based multi-layer fancy glaze ceramic tile and the preparation method thereof provided by the invention have the advantages that the base glaze of the titanium-based multi-layer fancy glaze is a phase-splitting bright glaze with a phase-splitting function, so that the glaze surface changes abundantly, and meanwhile, the mutual diffusion and reaction among the base glaze of the same system with low viscosity and high viscosity, and the vanadium pentoxide with low surface tension are added into the fancy glaze, so that the mutual fusion and diffusion among the low-viscosity titanium glaze, the high-viscosity titanium glaze and the fancy glaze are further intensified, and the bright ceramic tile with rich and colorful surface patterns and similar to the kiln-change glaze effect is formed. Meanwhile, different metal oxides are added into the titanium glaze and the fancy glaze formula, so that the series of color systems can be enriched.
It is to be understood that the invention is not limited to the examples described above, but that modifications and variations may be effected thereto by those of ordinary skill in the art in light of the foregoing description, and that all such modifications and variations are intended to be within the scope of the invention as defined by the appended claims.
Claims (9)
1. A titanium series multilayer fancy glaze ceramic tile is characterized by comprising the following components in percentage by weight: the ceramic tile comprises a brick blank layer, a first titanium glaze layer, a fancy glaze layer and a second titanium glaze layer; the first titanium glaze layer comprises a first titanium glaze and a color developing agent, the fancy glaze layer comprises a fancy glaze and a color developing agent, and the second titanium glaze layer comprises a second titanium glaze; the first titanium glaze comprises the following raw materials in parts by weight: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 0.2-0.5 part of methyl and 0.2-0.5 part of trimerization;
the fancy glaze comprises the following raw materials in parts by mass: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 0.1-2 parts of vanadium pentoxide, 3-8 parts of lithium carbonate and 40-65 parts of printing paste;
the second titanium glaze comprises the following raw materials in parts by weight: 20-40 parts of potassium feldspar, 5-20 parts of albite, 4-12 parts of kaolin, 1-5 parts of calcium phosphate, 8-16 parts of wollastonite, 8-25 parts of calcined zinc oxide, 10-25 parts of 1801 frit, 5-15 parts of titanium dioxide, 8-15 parts of quartz, 0.2-0.5 part of methyl and 0.2-0.5 part of trimerization;
the 1801 frit comprises the following components in percentage by mass: SiO 22 60.49％，Al2O3 6.62％，CaO 13.58％，MgO 2.72％，K2O 4.02％，Na20.56 percent of O, 11.81 percent of ZnO and 0.2 percent of ignition loss.
2. The titanium-based multi-layer fancy glaze ceramic tile as claimed in claim 1, wherein the color developers are CoO and Fe2O3、CuO、MnO2、Cr2O3、NiO2One or more of (a).
3. The titanium-based multi-layer fancy glaze ceramic tile as claimed in claim 1, wherein the mass ratio of the first titanium glaze to the color former in the first titanium glaze layer is 100: 1-100: 10.
4. The titanium-based multi-layer fancy glaze ceramic tile as claimed in claim 1, wherein the mass ratio of the fancy glaze to the color former in the fancy glaze layer is 100: 1-100: 20.
5. A method for preparing titanium-based multi-layer fancy glaze ceramic tiles according to any one of claims 1 to 4, which comprises the steps of:
forming and drying a ceramic green brick to form a green brick layer;
forming a first titanium glaze layer on the brick blank layer;
printing the first titanium glaze layer by using a silk screen or a rubber roller to form a fancy glaze layer;
forming a second titanium glaze layer on the fancy glaze layer;
and firing in a kiln to obtain the titanium series multilayer fancy glaze ceramic tile.
6. The method for preparing the titanium-based multi-layer fancy glaze ceramic tile according to claim 5, wherein the step of forming the first titanium glaze layer on the tile blank layer comprises the step of adding a coloring agent into the first titanium glaze layer for ball milling and mixing uniformly, wherein the ball milling time is as follows: ball-milling for 3-10 minutes by a wet method for every 100g of dry materials; ball milling fineness: the residue is 2-3% of 325 mesh.
7. The method for preparing the titanium-based multi-layer fancy glaze ceramic tile according to claim 5, wherein the step of forming the fancy glaze layer on the first titanium glaze layer comprises the step of adding a color developing agent into the fancy glaze for ball milling and mixing uniformly, wherein the ball milling time is as follows: ball-milling for 3-10 minutes by a wet method for every 100g of dry materials; ball milling fineness: the residue is 2-3% of 325 mesh.
8. The method for preparing the titanium-based multiple-layer fancy glaze ceramic tile as claimed in claim 5, wherein the firing temperature is 1150-1250 ℃.
9. The method for preparing the titanium-based multi-layer fancy glaze ceramic tile according to claim 5, wherein the sintering time is 45-65 min.
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| DE102005057853A1 (en) * | 2005-12-03 | 2007-06-06 | Degussa Gmbh | Aqueous resins |
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