CN107417121A - A kind of ceramics with anti-skidding glaze - Google Patents

A kind of ceramics with anti-skidding glaze Download PDF

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Publication number
CN107417121A
CN107417121A CN201710714239.9A CN201710714239A CN107417121A CN 107417121 A CN107417121 A CN 107417121A CN 201710714239 A CN201710714239 A CN 201710714239A CN 107417121 A CN107417121 A CN 107417121A
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CN
China
Prior art keywords
parts
coat enamel
ground
glaze
ceramics
Prior art date
Application number
CN201710714239.9A
Other languages
Chinese (zh)
Inventor
梁裕恩
Original Assignee
佛山市石湾裕龙陶瓷有限公司
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Priority to CN201710714239.9A priority Critical patent/CN107417121A/en
Publication of CN107417121A publication Critical patent/CN107417121A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

Abstract

The invention discloses a kind of ceramics with anti-skidding glaze, wherein, ground-coat enamel is sprayed with ceramic surface, wherein, the ground-coat enamel raw material component meter, including following components by weight:30 49 parts of feldspar powder, 6 12 parts of calcite, 6 15 parts of calcined kaolin, 5 10 parts of ball clay of washing, 8 14 parts of aluminum oxide, 7 10 parts of barium carbonate, 13 parts of zinc oxide, 12 parts of methylcellulose, 49 parts of solvent, 12 parts of sodium tripolyphosphate, 11 15 parts of zirconium silicate.The preparation method of wherein ground-coat enamel comprises the following steps:Each raw material in ground-coat enamel is added in ball mill by number, quality is added and carries out ball milling for the water of 0.3 0.5 times of raw material gross mass, the fineness to glaze slip is 250 500 mesh, and ground-coat enamel is made.The glaze of the present invention can be sprayed directly on on the base substrate of ceramic flat surface with regard to that can play anti-skidding and antifouling efficacy, eliminated and changed cost caused by mould, while is increased without protective layer again, realize energy-conserving and environment-protective.

Description

A kind of ceramics with anti-skidding glaze
Technical field
The present invention relates to ceramic glaze technical field, more particularly to a kind of ceramics with anti-skidding glaze.
Background technology
Substantially it is floor tile in places such as kitchen, toilet, washrooms in actual life, and these are local Easily be spread across water, cause ground wet and slippery, be very easy to allow people to slip tumble injury, therefore, anti-skidding floor tile to the safety of people, Sanitary, improve the quality of living with positive role.The anti-skidding of Ceramic glaze mainly adds one layer of spray in ceramic surface at present Anti-skidding protective layer, so not only increase process difficulty raising cost but also wearability is not high, service life is not grown, and how to open Send out and develop a kind of problem that need not separately add protective layer the anti-skidding ceramics of energy to be turned into current industry development generally existing.
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, a kind of ceramics with anti-skidding glaze are provided in of the invention, it is intended to solve to pass System Ceramic glaze does not possess anti-skidding effect and additionally carries out anti-skidding processing and cause production cost high, and the bad technology of action effect is asked Topic.
Technical scheme is as follows:
A kind of ceramics with anti-skidding glaze, wherein, ground-coat enamel is sprayed with ceramic surface, wherein, the ground-coat enamel raw material is by weight Component meter, including following components:Feldspar powder 30-49 parts, calcite 6-12 parts, calcined kaolin 6-15 parts, washing ball clay 5-10 Part, aluminum oxide 8-14 parts, barium carbonate 7-10 parts, zinc oxide 1-3 parts, methylcellulose 1-2 parts, solvent 4-9 parts, sodium tripolyphosphate 1-2 parts, zirconium silicate 11-15 parts.
The described ceramics with anti-skidding glaze, wherein, the preparation method of the ground-coat enamel comprises the following steps:By in ground-coat enamel Each raw material is added in ball mill by number, adds water progress ball milling of the quality for 0.3-0.5 times of raw material gross mass, thin to glaze slip Spend for 250-500 mesh, obtained ground-coat enamel.
The described ceramics with anti-skidding glaze, wherein, the ground-coat enamel surface is also sprayed with cover-coat enamel, and the cover-coat enamel raw material is pressed Components by weight percent meter, including following components:Feldspar powder 20-33 parts, hyper-dispersant 2-8 parts, quartzy 6-8 parts, calcite 6-10 parts, water Wash ball clay 6-8 parts, calcined kaolin 5-9 parts, aluminum oxide 5-10 parts, barium carbonate 9-12 parts, zirconium silicate 12-16 parts, Methyl cellulose Plain 1-2 parts and sodium tripolyphosphate 1-3 parts.
The described ceramics with anti-skidding glaze, wherein, the preparation method of the cover-coat enamel comprises the following steps:By in cover-coat enamel Each raw material is added in ball mill by number, adds water progress ball milling of the quality for 0.2-0.4 times of raw material gross mass, thin to glaze slip Spend for 350-550 mesh, obtained cover-coat enamel.
Using ceramics made from the anti-skidding glaze of the present invention at it in use, obtained ground-coat enamel first is sprayed directly on into ceramic body On, cover-coat enamel then is sprayed on ground-coat enamel surface again, ground-coat enamel is completely covered in cover-coat enamel, largely it was verified that spraying anti-skidding glaze of the present invention The ceramics or ceramic tile of material can play efficient skidproof effect, even if wearing the weak shoes of the grabs ground abilities such as leather shoes, walking shoes, incline Oblique angle can also reach anti-skidding technique effect at 30 ° of tilted station on ceramic tile.
The described ceramics with anti-skidding glaze, wherein, the solvent is at least one in ether solvent or esters solvent Kind.
The described ceramics with anti-skidding glaze, wherein, the hyper-dispersant is polyester type ultra-dispersant agent, polyether-type oversubscription Any one or more in powder and polyacrylie-type hyper-dispersant.
Described ceramic anti-skidding glaze, wherein, the cover-coat enamel also includes talcum 8-11 parts.
By inventor largely it was verified that the talcum that certain component is added in cover-coat enamel can be such that ceramics prevent with certain Dirty effect, make foul be not easy to be attached to ceramic surface, and easily rinse decontamination, there is very big application value.
Described ceramic anti-skidding glaze, wherein, the cover-coat enamel also includes zinc oxide 5-7 parts.
The zinc oxide of addition can make ceramics antifouling capacity further strengthen, and make it have good heat resistance and Anti-wear performance, improve its use value.
Beneficial effect:The glaze of the present invention can be sprayed directly on on the ceramic body of plane with regard to the anti-skidding and antifouling work(that can get up Effect, eliminates and changes cost caused by mould, while is increased without protective layer again, can reduce technique, solve traditional ceramics glaze Face does not possess anti-skidding effect and additionally carries out anti-skidding processing and cause production cost high, the bad technical problem of action effect, realizes Energy-conservation and environmental protection.
Embodiment
The present invention provides a kind of ceramics with anti-skidding glaze, to make the purpose of the present invention, technical scheme and effect more Clear, clear and definite, the present invention is described in more detail below.It should be appreciated that specific embodiment described herein only to The present invention is explained, is not intended to limit the present invention.
Embodiment 1
A kind of ceramics with anti-skidding glaze, wherein, ground-coat enamel is sprayed with ceramic surface, wherein, the ground-coat enamel raw material is by weight Component meter, including following components:49 parts of feldspar powder, 12 parts of calcite, 15 parts of calcined kaolin, 10 parts of ball clay of washing, aluminum oxide 14 parts, 10 parts of barium carbonate, 3 parts of zinc oxide, 2 parts of methylcellulose, 9 parts of solvent, 2 parts of sodium tripolyphosphate, 15 parts of zirconium silicate.
In practical application, the preparation method of ground-coat enamel comprises the following steps:Each raw material in ground-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0.5 times of raw material gross mass, the fineness to glaze slip is 500 mesh, and ground-coat enamel is made.
Further, cover-coat enamel raw material component meter, including following components by weight:33 parts of feldspar powder, 8 parts of hyper-dispersant, stone 8 parts of English, 10 parts of calcite, washing 8 parts of ball clay, 9 parts of calcined kaolin, 10 parts of aluminum oxide, 12 parts of barium carbonate, 16 parts of zirconium silicate, 3 parts of 2 parts of methylcellulose and sodium tripolyphosphate.
Further, the preparation method of cover-coat enamel comprises the following steps:Each raw material in cover-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0.4 times of raw material gross mass, the fineness to glaze slip is 550 mesh, and cover-coat enamel is made.
In practical application, solvent is ether solvent.
In practical application, hyper-dispersant is polyester type ultra-dispersant agent.
Further, cover-coat enamel also includes 11 parts of talcum.
Further, cover-coat enamel also includes 7 parts of zinc oxide.
Embodiment 2
A kind of ceramics with anti-skidding glaze, wherein, ground-coat enamel is sprayed with ceramic surface, wherein, the ground-coat enamel raw material is by weight Component meter, including following components:32 parts of feldspar powder, 8 parts of calcite, 8 parts of calcined kaolin, 7 parts of ball clay of washing, aluminum oxide 10 Part, 9 parts of barium carbonate, 2 parts of zinc oxide, 1 part of methylcellulose, 6 parts of solvent, 1 part of sodium tripolyphosphate, 13 parts of zirconium silicate.
In practical application, the preparation method of ground-coat enamel comprises the following steps:Each raw material in ground-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0.4 times of raw material gross mass, the fineness to glaze slip is 270 mesh, and ground-coat enamel is made.
Further, cover-coat enamel raw material component meter, including following components by weight:22 parts of feldspar powder, 4 parts of hyper-dispersant, stone 7 parts of English, 8 parts of calcite, 7 parts of ball clay of washing, 7 parts of calcined kaolin, 7 parts of aluminum oxide, 11 parts of barium carbonate, 14 parts of zirconium silicate, first 1 part of 2 parts of base cellulose and sodium tripolyphosphate.
Further, the preparation method of cover-coat enamel comprises the following steps:Each raw material in cover-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0.3 times of raw material gross mass, the fineness to glaze slip is 380 mesh, and cover-coat enamel is made.
In practical application, solvent is esters solvent.
In practical application, hyper-dispersant is polyether-type hyper-dispersant.
Further, cover-coat enamel also includes 10 parts of talcum.
Further, cover-coat enamel also includes 7 parts of zinc oxide.
Embodiment 3
A kind of ceramics with anti-skidding glaze, wherein, ground-coat enamel is sprayed with ceramic surface, wherein, the ground-coat enamel raw material is by weight Component meter, including following components:45 parts of feldspar powder, 11 parts of calcite, 14 parts of calcined kaolin, 9 parts of ball clay of washing, aluminum oxide 13 Part, 9 parts of barium carbonate, 2 parts of zinc oxide, 2 parts of methylcellulose, 8 parts of solvent, 2 parts of sodium tripolyphosphate, 14 parts of zirconium silicate.
In practical application, the preparation method of ground-coat enamel comprises the following steps:Each raw material in ground-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0.4 times of raw material gross mass, the fineness to glaze slip is 400 mesh, and ground-coat enamel is made.
Further, cover-coat enamel raw material component meter, including following components by weight:30 parts of feldspar powder, 7 parts of hyper-dispersant, stone 7 parts of English, 9 parts of calcite, 8 parts of ball clay of washing, 8 parts of calcined kaolin, 9 parts of aluminum oxide, 11 parts of barium carbonate, 15 parts of zirconium silicate, first 3 parts of 1 part of base cellulose and sodium tripolyphosphate.
Further, the preparation method of cover-coat enamel comprises the following steps:Each raw material in cover-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0. 4 times of raw material gross mass, the fineness to glaze slip is 450 mesh, and cover-coat enamel is made.
In practical application, solvent is ether solvent.
In practical application, hyper-dispersant is polyacrylie-type hyper-dispersant.
Further, cover-coat enamel also includes 10 parts of talcum.
Further, cover-coat enamel also includes 6 parts of zinc oxide.
Embodiment 4
A kind of ceramics with anti-skidding glaze, wherein, ground-coat enamel is sprayed with ceramic surface, wherein, the ground-coat enamel raw material is by weight Component meter, including following components:30 parts of feldspar powder, 6 parts of calcite, 6 parts of calcined kaolin, washing 5 parts of ball clay, 8 parts of aluminum oxide, 7 parts of barium carbonate, 1 part of zinc oxide, 1 part of methylcellulose, 4 parts of solvent, 1 part of sodium tripolyphosphate, 11 parts of zirconium silicate.
In practical application, the preparation method of ground-coat enamel comprises the following steps:Each raw material in ground-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0.3 times of raw material gross mass, the fineness to glaze slip is 250 mesh, and ground-coat enamel is made.
Further, cover-coat enamel raw material component meter, including following components by weight:20 parts of feldspar powder, 2 parts of hyper-dispersant, stone 6 parts of English, 6 parts of calcite, 6 parts of ball clay of washing, 5 parts of calcined kaolin, 5 parts of aluminum oxide, 9 parts of barium carbonate, 12 parts of zirconium silicate, methyl 1 part of 1 part of cellulose and sodium tripolyphosphate.
Further, the preparation method of cover-coat enamel comprises the following steps:Each raw material in cover-coat enamel is added into ball mill by number In, add quality and carry out ball milling for the water of 0.2 times of raw material gross mass, the fineness to glaze slip is 350 mesh, and cover-coat enamel is made.
In practical application, solvent is esters solvent.
In practical application, hyper-dispersant is polyester type ultra-dispersant agent.
Further, cover-coat enamel also includes 8 parts of talcum.
Further, cover-coat enamel also includes 5 parts of zinc oxide.
It is produced by the invention ceramics its using when can efficiently play anti-skidding and antifouling effect, eliminate change mould produce Raw cost, while be increased without protective layer again, can reduce technique, solve traditional ceramics glaze paint do not possess anti-skidding effect and Additionally carrying out anti-skidding processing causes production cost high, the bad technical problem of action effect, realizes energy-conservation and environmental protection.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention Protect scope.

Claims (8)

  1. A kind of 1. ceramics with anti-skidding glaze, it is characterised in that ground-coat enamel is sprayed with ceramic surface, wherein, the ground-coat enamel is former Expect component meter, including following components by weight:Feldspar powder 30-49 parts, calcite 6-12 parts, calcined kaolin 6-15 parts, washing Ball clay 5-10 parts, aluminum oxide 8-14 parts, barium carbonate 7-10 parts, zinc oxide 1-3 parts, methylcellulose 1-2 parts, solvent 4-9 parts, three Polyphosphate sodium 1-2 parts, zirconium silicate 11-15 parts.
  2. 2. the ceramics according to claim 1 with anti-skidding glaze, it is characterised in that the preparation method of the ground-coat enamel includes Following steps:Each raw material in ground-coat enamel is added in ball mill by number, quality is added and enters for the water of 0.3-0.5 times of raw material gross mass Row ball milling, the fineness to glaze slip are 250-500 mesh, and ground-coat enamel is made.
  3. 3. the ceramics according to claim 1 with anti-skidding glaze, it is characterised in that the ground-coat enamel surface is also sprayed with face Glaze, the cover-coat enamel raw material component meter, including following components by weight:Feldspar powder 20-33 parts, hyper-dispersant 2-8 parts, quartzy 6-8 Part, calcite 6-10 parts, washing ball clay 6-8 parts, calcined kaolin 5-9 parts, aluminum oxide 5-10 parts, barium carbonate 9-12 parts, silicic acid Zirconium 12-16 parts, methylcellulose 1-2 parts and sodium tripolyphosphate 1-3 parts.
  4. 4. the ceramics according to claim 3 with anti-skidding glaze, it is characterised in that the preparation method of the cover-coat enamel includes Following steps:Each raw material in cover-coat enamel is added in ball mill by number, quality is added and enters for the water of 0.2-0.4 times of raw material gross mass Row ball milling, the fineness to glaze slip are 350-550 mesh, and cover-coat enamel is made.
  5. 5. the ceramics according to claim 1 with anti-skidding glaze, it is characterised in that the solvent is ether solvent or ester At least one of class solvent.
  6. 6. the ceramics according to claim 1 with anti-skidding glaze, it is characterised in that the hyper-dispersant surpasses for polyester-type Any one or more in dispersant, polyether-type hyper-dispersant and polyacrylie-type hyper-dispersant.
  7. 7. the ceramics according to claim 3 with anti-skidding glaze, it is characterised in that the cover-coat enamel also includes talcum 8-11 Part.
  8. 8. the ceramics according to claim 3 with anti-skidding glaze, it is characterised in that the cover-coat enamel also includes zinc oxide 5- 7 parts.
CN201710714239.9A 2017-08-18 2017-08-18 A kind of ceramics with anti-skidding glaze CN107417121A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108545946A (en) * 2018-06-29 2018-09-18 佛山石湾鹰牌陶瓷有限公司 A kind of anti-skid brick and preparation method thereof
CN108545944A (en) * 2018-06-29 2018-09-18 佛山石湾鹰牌陶瓷有限公司 The preparation method and ship-and-galley tile of ship-and-galley tile
CN109761647A (en) * 2019-03-19 2019-05-17 重庆唯美陶瓷有限公司 A kind of titanium system cladding fancy glaze Ceramic Tiles and preparation method thereof
CN108545946B (en) * 2018-06-29 2021-04-27 佛山石湾鹰牌陶瓷有限公司 Anti-slip brick and preparation method thereof

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CN101880177A (en) * 2010-08-10 2010-11-10 唐山梦牌瓷业有限公司 Self-cleaning antibacterial glaze used for sanitary ceramic ware
CN103588510A (en) * 2013-11-28 2014-02-19 广东金牌陶瓷有限公司 Method for manufacturing anti-slip glazed tile
CN103771904A (en) * 2013-12-13 2014-05-07 九牧厨卫股份有限公司 Dirt-repellent overglaze and method for manufacturing ceramic products by using dirt-repellent overglaze
CN104261897A (en) * 2014-09-25 2015-01-07 佛山市三水新明珠建陶工业有限公司 Ceramic tile having antiskid effect and manufacturing method thereof
CN104530828A (en) * 2014-12-23 2015-04-22 佛山欧神诺陶瓷股份有限公司 Negative ion functional ink as well as preparation method and production method thereof
CN105131716A (en) * 2015-10-16 2015-12-09 佛山市明朝科技开发有限公司 Ceramic glossy glaze ink and preparation method thereof
CN105271751A (en) * 2015-10-16 2016-01-27 湖南天欣科技股份有限公司 High-temperature glaze for anti-skid ceramic tiles as well as production method and application method of high-temperature glaze
CN105837172A (en) * 2016-03-23 2016-08-10 广东宏陶陶瓷有限公司 Resource-saving glazed ceramic tile having antiskid effect on surface and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN101880177A (en) * 2010-08-10 2010-11-10 唐山梦牌瓷业有限公司 Self-cleaning antibacterial glaze used for sanitary ceramic ware
CN103588510A (en) * 2013-11-28 2014-02-19 广东金牌陶瓷有限公司 Method for manufacturing anti-slip glazed tile
CN103771904A (en) * 2013-12-13 2014-05-07 九牧厨卫股份有限公司 Dirt-repellent overglaze and method for manufacturing ceramic products by using dirt-repellent overglaze
CN104261897A (en) * 2014-09-25 2015-01-07 佛山市三水新明珠建陶工业有限公司 Ceramic tile having antiskid effect and manufacturing method thereof
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CN105131716A (en) * 2015-10-16 2015-12-09 佛山市明朝科技开发有限公司 Ceramic glossy glaze ink and preparation method thereof
CN105271751A (en) * 2015-10-16 2016-01-27 湖南天欣科技股份有限公司 High-temperature glaze for anti-skid ceramic tiles as well as production method and application method of high-temperature glaze
CN105837172A (en) * 2016-03-23 2016-08-10 广东宏陶陶瓷有限公司 Resource-saving glazed ceramic tile having antiskid effect on surface and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108545946A (en) * 2018-06-29 2018-09-18 佛山石湾鹰牌陶瓷有限公司 A kind of anti-skid brick and preparation method thereof
CN108545944A (en) * 2018-06-29 2018-09-18 佛山石湾鹰牌陶瓷有限公司 The preparation method and ship-and-galley tile of ship-and-galley tile
CN108545944B (en) * 2018-06-29 2021-02-26 佛山石湾鹰牌陶瓷有限公司 Preparation method of anti-skid floor tile and anti-skid floor tile
CN108545946B (en) * 2018-06-29 2021-04-27 佛山石湾鹰牌陶瓷有限公司 Anti-slip brick and preparation method thereof
CN109761647A (en) * 2019-03-19 2019-05-17 重庆唯美陶瓷有限公司 A kind of titanium system cladding fancy glaze Ceramic Tiles and preparation method thereof

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