CN103159506B - High-temperature ceramic grisaille painting decorating method - Google Patents
High-temperature ceramic grisaille painting decorating method Download PDFInfo
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- CN103159506B CN103159506B CN201310094333.0A CN201310094333A CN103159506B CN 103159506 B CN103159506 B CN 103159506B CN 201310094333 A CN201310094333 A CN 201310094333A CN 103159506 B CN103159506 B CN 103159506B
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Abstract
The invention provides a high-temperature ceramic grisaille painting decorating method. The method is characterized in that high-temperature ceramic grisaille painting decorating is served as an application background, high-temperature glaze, high-temperature coloring materials and various additives are reasonably mixed, a technical barrier of decorating before glazing in a high-temperature glaze grisaille painting decorating process is broken through, decorating and glazing are integrated so as to realize an artistic effect of simultaneous decorating and glazing, complicated processes are simplified, and a unique artistic style is obtained. A fired product has the advantages of smooth and bright surface, unique decoration pattern style, various random patterns, smoothness, naturality, full quality and vividity, various decorative effects, accurate expression and wide market prospect.
Description
Technical field
The present invention relates to ceramic product and decorate field, be specifically related to a kind of ceramic high temperature grisaille painting trailing.
Background technology
Grisaille painting wound was burnt in the clear Yongzheng's reign, was originally the one of porcelain over-glaze decoration, and take gorgeous black in main, the color material that is equipped with other is described pattern on white glaze face, after low temperature (700-800 ℃) baking, made.
Grisaille painting develops into the modern times, art present and Technology aspect had larger change.Aspect Technology, to decorate to have developed under glaze from glaze and decorate, firing temperature increases substantially.Color is also that dominant hue develops into multiple color tones from gorgeous black, and in general, the modern ceramic decoration effect the artistic effect as ink and wash suitable color, that picture is elegant, color is pleasant all calls for grisaille painting.
No matter being high temperature grisaille painting under low temperature grisaille painting (700-800 ℃) or glaze, is all by the comparatively complicated decorative technique of a kind of technique of grisaille painting decoration and glazing proceed step by step.As high temperature grisaille painting under glaze, generally adopting and first on biscuit, creating on the creation, execute again the bluish white glaze of high temperature, at high temperature (1300 ℃ of >) is once fired into porcelain finally, product has unique artistic effect, and under the ceramic glaze occurring in recent years, sprinkling color equipment decorations is exactly a kind of manifestation that high temperature grisaille painting is decorated.
But because the color decorative technique process implementing of current ceramic ink process is comparatively loaded down with trivial details, and then restrict the application of grisaille painting decorative technique in ceramic decoration industry.
Summary of the invention
The technical problem to be solved in the present invention is to provide the ceramic high temperature grisaille painting trailing that a kind of grisaille painting is decorated and glazing is carried out simultaneously.
For solving above technical problem, technical scheme of the present invention is: a kind of ceramic high temperature grisaille painting trailing, in turn includes the following steps:
The first step: preparation surface tension≤340mNm
-1, melt temperature scope is for subsequent use at the high temperature glaze slip of 1220-1330 ℃;
Second step: in the glaze slip of choosing in the first step after additional 1-3wt% dextrin and 0.1-0.3wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, crosses 325 mesh sieves and obtains modification glaze slips after ball milling;
The 3rd step: the tensio-active agent of additional 0.2-0.6wt% in high temperature pigment of ceramic, put into ball mill and mix post-drying, cross 250 mesh sieves and obtain modification high temperature pigment of ceramic;
The 4th step: be spilled into the modification high temperature pigment of ceramic that 1-5wt% makes through the 3rd step in the modification glaze slip making at second step, make high temperature grisaille painting glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high temperature grisaille painting glaze with writing brush, on the ceramic body after biscuiting, apply glaze layer, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1220-1330 ℃ of high temperature, obtain grisaille painting decorating ceramic products.
In the described the first step, the chemical quality per-cent of glaze slip consists of:
SiO
2:45-72wt%、Al
2O
3:10-15wt%、PbO:0-5wt%、V
2O
5:0-2.5wt%、B
2O
3:0-5wt%、K
2O:2-5wt%、Na
2O:?0.8-4wt%、CaO:?0-18wt%、MgO:?0-10wt%、ZnO:?1-35wt%、Fe
2O
3:?0-1wt%、BaO:?0-7wt%、ZrO
2:?0-12wt%。
Tensio-active agent in described the 3rd step is one or more in oleic acid, stearic acid, sulfated castor oil.
In described the 5th step, the thickness of glaze layer is 5 millimeters of 0.18-1..
When described product is tabular pottery, the thickness of glaze layer is preferably 0.8-1.2 millimeter.
When described product is ampuliform pottery, glaze layer thickness is preferably 0.3-0.5 millimeter.
When described product is special-shaped ceramics, glaze layer thickness is preferably 1-1.5 millimeter.
The present invention decorates as application background take ceramic high temperature grisaille painting, on lot of experiments basis, to high melting glaze, high temperature decorating colour, multiple additives is carried out rational allocation, break through grisaille painting under high melting glaze decorate in the technology barriers of glazing after first illuminated, illuminated and glaze decorating are combined together, reach illuminated glazing simultaneously, glazing is the technological effect of illuminated simultaneously, simplify, represent artistic style very, product burns till smoothly light of rear surface, decorative pattern unique style, shape changeable, texture remarkable fluency, be rich in texture and anima, decorative effect is abundant, passing expectation reaches accurately.
Embodiment
The tabular ceramic product that the blue grisaille painting transparent of embodiment 1 is decorated
The first step: by mass percentage: talcum 5%, calcining zinc oxide 2%, glaze fruit 85.5%, glaze ash 6%, V
2o
51.5%, after raw material is mixed, through ball mill pulverizing, mistake 320 mesh sieves, obtaining surface tension is 326mNm
-1, melt temperature is the transparent glaze slip of the high temperature of 1320 ℃;
Second step: after additional 1.5wt% dextrin and 0.2wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, cross 325 mesh sieves after ball milling and obtain modification glaze slip in the glaze slip of the first step preparation;
The 3rd step: the oleic acid of additional 0.4wt% in the bright material of pearl (cobalt blue), put into ball mill and mix post-drying, cross 250 mesh sieves and obtain the bright material of modification pearl (cobalt blue);
The 4th step: be spilled into the bright material of modification pearl (cobalt blue) that 1 wt% makes through the 3rd step in the modification glaze slip making at second step, make high temperature blue ink colored glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high temperature blue ink colored glaze with writing brush, on tabular ceramic body after biscuiting, apply the glaze layer of 0.9 millimeter, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1320 ℃ of high temperature, obtain the tabular ceramic product that blue grisaille painting transparent is decorated.
The tabular ceramic product that the red grisaille painting opaque glaze of embodiment 2 is decorated
The first step: by mass percentage: the high ridge 5% of planetesimal, feldspar 45%, quartz 19%, calcite 4%, barium carbonate 2%, burning talcum 8%, zirconium silicate 12%, calcining zinc oxide 2%, V
2o
53%, after raw material is mixed, through ball mill pulverizing, mistake 320 mesh sieves, obtaining surface tension is 333mNm
-1, melt temperature is the high temperature milkiness glaze slip of 1250 ℃;
Second step: the glaze slip China and foreign countries in the first step preparation add after 1wt% dextrin and 0.15wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, crosses 325 mesh sieves and obtains modification glaze slip after ball milling;
The 3rd step: add the sulfated castor oil of 0.6wt% in red colorant (cadmium-selenium red) China and foreign countries, put into ball mill and mix post-drying, cross 250 mesh sieves and obtain the red colorant of modification (cadmium-selenium red);
The 4th step: be spilled into the red colorant of modification (cadmium-selenium red) that 2 wt% make through the 3rd step in the modification glaze slip making at second step, make high-temperature red grisaille painting glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high-temperature red grisaille painting glaze with writing brush, on tabular ceramic body after biscuiting, apply the glaze layer of 1.1 millimeters, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1250 ℃ of high temperature, obtain the tabular ceramic product that red grisaille painting opaque glaze is decorated.
The ampuliform ceramic product that embodiment 3 black grisaille painting crystalline glazes are decorated
The first step: by mass percentage: the high ridge 2% of planetesimal, feldspar 25%, quartz 26.5%, calcite 8%, barium carbonate 8%, calcining zinc oxide 28%, V
2o
52.5%, after raw material is mixed, through ball mill pulverizing, mistake 320 mesh sieves, obtaining surface tension is 323mNm
-1, melt temperature is the high temperature crystallization glaze slip of 1290 ℃;
Second step: the glaze slip China and foreign countries in the first step preparation add after 2.5wt% dextrin and 0.25wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, crosses 325 mesh sieves and obtains modification glaze slip after ball milling;
The 3rd step: China and foreign countries add 0.2wt% oleic acid and 1wt% stearic acid at black pigment (siderochrome cobalt manganese black), puts into ball mill and mixes post-drying, crosses 250 mesh sieves and obtains modification black pigment (siderochrome cobalt manganese black);
The 4th step: be spilled into the modification black pigment (siderochrome cobalt manganese black) that 1.5wt% makes through the 3rd step in the modification glaze slip making at second step, make high temperature black ink colored glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high temperature black ink colored glaze with writing brush, on ampuliform ceramic body after biscuiting, apply the glaze layer of 0.4 millimeter, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1290 ℃ of high temperature, obtain the ampuliform ceramic product that black grisaille painting crystalline glaze is decorated.
The ampuliform ceramic product that embodiment 4 purple grisaille painting translucent glazes are decorated
The first step: by mass percentage: the high ridge 8% of planetesimal, feldspar 34%, quartz 30%, calcite 8%, zirconium silicate 2%, calcining zinc oxide 10%, V
2o
52%, after raw material is mixed, through ball mill pulverizing, mistake 320 mesh sieves, obtaining surface tension is 325mNm
-1, melt temperature is at the translucent glaze slip of high temperature of 1280 ℃;
Second step: the glaze slip China and foreign countries in the first step preparation add after 1.5wt% dextrin and 0.2wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, crosses 325 mesh sieves and obtains modification glaze slip after ball milling;
The 3rd step: China and foreign countries add 0.2wt% oleic acid, 1wt% stearic acid and 0.3 wt% sulfated castor oil in purple (neodymium silicon purple), puts into ball mill and mixes post-drying, crosses 250 mesh sieves and obtains modification purple (neodymium silicon purple);
The 4th step: be spilled into the modification purple (neodymium silicon purple) that 2.5wt% makes through the 3rd step in the modification glaze slip making at second step, make high temperature purple grisaille painting glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high temperature purple grisaille painting glaze with writing brush, on ampuliform ceramic body after biscuiting, apply the glaze layer of 0.5 millimeter, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1280 ℃ of high temperature, obtain the ampuliform ceramic product that purple grisaille painting translucent glaze is decorated.
The special-shaped ceramics product that the yellow grisaille painting matt glaze of embodiment 5 is decorated
The first step: by mass percentage: the high ridge 5% of planetesimal, feldspar 48%, quartz 10%, calcite 16%, rhombspar 18%, calcining zinc oxide 2%, V
2o
51%, after raw material is mixed, through ball mill pulverizing, mistake 320 mesh sieves, obtaining surface tension is 319mNm
-1, melt temperature is the unglazed glaze slip of the high temperature of 1230 ℃;
Second step: the glaze slip China and foreign countries in the first step preparation add after 2wt% dextrin and 0.2wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, crosses 325 mesh sieves and obtains modification glaze slip after ball milling;
The 3rd step: China and foreign countries add 0.5wt% oleic acid and 1.5wt% stearic acid at yellow colorant (vanadium zirconium Huang), puts into ball mill and mixes post-drying, crosses 250 mesh sieves and obtains the yellow colorant of modification (vanadium zirconium Huang);
The 4th step: be spilled into the yellow colorant of modification (vanadium zirconium Huang) that 3wt% makes through the 3rd step in the modification glaze slip making at second step, make high temperature yellow ink colored glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high temperature yellow ink colored glaze with writing brush, on special-shaped ceramics base substrate after biscuiting, apply the glaze layer of 1.2 millimeters, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1230 ℃ of high temperature, obtain the special-shaped ceramics product that yellow grisaille painting matt glaze is decorated.
The special-shaped ceramics product that the green grisaille painting transparent of embodiment 6 is decorated
The first step: by mass percentage: the high ridge 5% of planetesimal, feldspar 31%, quartz 30%, calcite 15%, barium carbonate 5%, calcining zinc oxide 3%, V
2o
51%, boron frit 5%, lead frit 5%, after raw material is mixed, through ball mill pulverizing, mistake 320 mesh sieves, obtaining surface tension is 330mNm
-1, melt temperature is the transparent glaze slip of the high temperature of 1220 ℃;
Second step: the glaze slip China and foreign countries in the first step preparation add after 3wt% dextrin and 0.3wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, crosses 325 mesh sieves and obtains modification glaze slip after ball milling;
The 3rd step: China and foreign countries add 2wt% stearic acid and 0.5wt% sulfated castor oil at green pigment (chrome green), puts into ball mill and mixes post-drying, crosses 250 mesh sieves and obtains modification green pigment (chrome green);
The 4th step: be spilled into the modification green pigment (chrome green) that 4wt% makes through the 3rd step in the modification glaze slip making at second step, make high temperature green ink colored glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high temperature green ink colored glaze with writing brush, on special-shaped ceramics base substrate after biscuiting, apply the glaze layer of 1.4 millimeters, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1220 ℃ of high temperature, obtain the special-shaped ceramics product that green grisaille painting transparent is decorated.
The vision grisaille painting effect of the grisaille painting decorating ceramic products that above-described embodiment makes sees the following form:
| Embodiment | Grisaille painting effect |
| 1 | Blue pattern is naturally dispersed in transparent |
| 2 | Red pattern is naturally dispersed in opaque glaze |
| 3 | Black texture is naturally dispersed in crystalline glaze |
| 4 | Purple pattern is naturally dispersed in translucent glaze |
| 5 | Yellow texture is naturally dispersed in matt glaze |
| 6 | Green pattern is naturally dispersed in transparent |
Listed grisaille painting decorating ceramic products is preferred embodiment above, in fact can on a ceramic body, apply the high temperature grisaille painting glaze of multiple color, can form more rich and varied grisaille painting decorating ceramic products, therefore the equivalent variations of doing according to the present patent application the scope of the claims, still belongs to the scope that the present invention is contained.
Claims (2)
1. a ceramic high temperature grisaille painting trailing, in turn includes the following steps:
The first step: preparation surface tension≤340mNm
-1, melt temperature scope is for subsequent use at the high temperature glaze slip of 1220-1330 ℃;
Second step: after additional 1-3wt% dextrin and 0.1-0.3wt%CMC, to expect: ball: water=1:1.8:0.65 carries out ball milling, cross 325 mesh sieves after ball milling and obtain modification glaze slip in the glaze slip of the first step preparation;
The 3rd step: the tensio-active agent of additional 0.2-0.6wt% in high temperature pigment of ceramic, put into ball mill and mix post-drying, cross 250 mesh sieves and obtain modification high temperature pigment of ceramic;
The 4th step: be spilled into the modification high temperature pigment of ceramic that 1-5wt% makes through the 3rd step in the modification glaze slip making at second step, make high temperature grisaille painting glaze;
The 5th step: adopt the pattern that applies glazing, dip in upper high temperature grisaille painting glaze with writing brush, on the ceramic body after biscuiting, apply glaze layer, utilize the shape of writing brush control decorative pattern simultaneously, after glaze layer is dry, burn till in 1220-1330 ℃ of high temperature, obtain grisaille painting decorating ceramic products;
In the described the first step, the chemical quality per-cent of glaze slip consists of:
SiO
2:45-72wt%、Al
2O
3:10-15wt%、PbO:0-5wt%、V
2O
5:0-2.5wt%、B
2O
3:0-5wt%、K
2O:2-5wt%、Na
2O:?0.8-4wt%、CaO:?0-18wt%、MgO:?0-10wt%、ZnO:?1-35wt%、Fe
2O
3:?0-1wt%、BaO:?0-7wt%、ZrO
2:?0-12wt%。
2. a kind of ceramic high temperature grisaille painting trailing according to claim 1, is characterized in that: the tensio-active agent in described the 3rd step is one or more in oleic acid, stearic acid, sulfated castor oil.
3
.a kind of ceramic high temperature grisaille painting trailing according to claim 1, is characterized in that: in described the 5th step, the thickness of glaze layer is 5 millimeters of 0.18-1..
4
.a kind of ceramic high temperature grisaille painting trailing according to claim 3, is characterized in that: when described product is tabular pottery, the thickness of glaze layer is 0.8-1.2 millimeter.
5
.a kind of ceramic high temperature grisaille painting trailing according to claim 3, is characterized in that: when described product is ampuliform pottery, glaze layer thickness is 0.3-0.5 millimeter.
6
.a kind of ceramic high temperature grisaille painting trailing according to claim 3, is characterized in that: when described product is special-shaped ceramics, glaze layer thickness is 1-1.5 millimeter.
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|---|---|---|---|
| CN201310094333.0A CN103159506B (en) | 2013-03-23 | 2013-03-23 | High-temperature ceramic grisaille painting decorating method |
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| CN103159506B true CN103159506B (en) | 2014-05-14 |
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| CN103407322B (en) * | 2013-08-26 | 2016-01-20 | 郑剑峰 | There is the burning fabrication technique of the insect wing artwork of texture feature |
| CN103467141A (en) * | 2013-09-03 | 2013-12-25 | 张次绪 | High-temperature glaze surface pigment decoration method for chinaware |
| CN104072203B (en) * | 2014-06-30 | 2016-02-10 | 江苏南瓷绝缘子股份有限公司 | A kind of electroceramics ash glaze reparation glaze composition and preparation method thereof |
| CN106517793B (en) * | 2016-11-16 | 2020-09-01 | 合众（佛山）化工有限公司 | Superfine self-cleaning glaze and preparation process thereof |
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|---|---|---|---|---|
| CN1350995A (en) * | 2000-10-31 | 2002-05-29 | 王晓朝 | Process for preparing green-enamel black porcelain |
| CN1765817A (en) * | 2004-10-31 | 2006-05-03 | 王晓朝 | Green glaze ink color ceramics production method |
| CN101066893A (en) * | 2007-06-14 | 2007-11-07 | 湖南华联溢百利瓷业有限公司 | Medium temperature alabastrine galze and its pren process |
| CN102249654A (en) * | 2011-04-29 | 2011-11-23 | 广西南山瓷器有限公司 | Ancient blue and white porcelain and production method thereof |
-
2013
- 2013-03-23 CN CN201310094333.0A patent/CN103159506B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1350995A (en) * | 2000-10-31 | 2002-05-29 | 王晓朝 | Process for preparing green-enamel black porcelain |
| CN1765817A (en) * | 2004-10-31 | 2006-05-03 | 王晓朝 | Green glaze ink color ceramics production method |
| CN101066893A (en) * | 2007-06-14 | 2007-11-07 | 湖南华联溢百利瓷业有限公司 | Medium temperature alabastrine galze and its pren process |
| CN102249654A (en) * | 2011-04-29 | 2011-11-23 | 广西南山瓷器有限公司 | Ancient blue and white porcelain and production method thereof |
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