CN113698099B - Quick-fired colorful pearlescent glaze, rock plate and preparation method of rock plate - Google Patents
Quick-fired colorful pearlescent glaze, rock plate and preparation method of rock plate Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/001—Applying decorations on shaped articles, e.g. by painting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/04—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
- B28B11/044—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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Abstract
The invention relates to the field of rock plate glaze decoration, and discloses a quick-firing colorful pearlescent glaze, a rock plate and a preparation method of the rock plate. The quick-fired colorful pearlescent glaze comprises pearlescent glaze and pearlescent ground glaze, wherein the pearlescent glaze comprises: perlite, boric acid, strontium carbonate, zirconia, chalk, zircon, high-boron frit, lithium fluoride, cerium oxide and corundum; the pearlescent ground glaze comprises: potash feldspar, albite, quartz powder, nepheline, barium carbonate, alumina, dolomite, calcined talc and zirconium silicate. The pearlescent glaze has strong adhesive force and good glossiness, gives the ceramic product an excellent seven-color bead light-sensitive visual effect, can show color effects of different degrees under light rays of different angles, and is similar to a shell inner color layer; meanwhile, the method is suitable for being fired in a roller kiln at 1150-1200 ℃ to realize rapid firing.
Description
Technical Field
The invention relates to the field of rock plate glaze decoration, in particular to a quick-firing colorful pearlescent glaze, a rock plate and a preparation method of the rock plate.
Background
At present, the ceramic market shows the characteristics of high-grade, artistic and personalized products, and the like, and the decorative material with high taste becomes the mainstream of consumption. The colorful pearlescent glaze is a precious and unique art glaze with good decoration, is always applied to the field of art ceramics, and is rarely applied to the field of building ceramics.
The colorful pearlescent glaze contains perlite, the main component of which is mica, the pearlescent glaze is easy to decompose at high temperature, the pearlescent effect is not achieved any more, the colorful pearlescent glaze can only be used in low-temperature glaze, the application range is limited, and the problem that the mica is not decomposed at high temperature and does not react with other components to keep the original characteristic of the mica is solved if the pearlescent glaze can be used at high temperature.
The technical problem to be solved by the invention is as follows: how to maintain the colorful refraction light effect of mica at high temperature so as to obtain the colorful pearlescent glaze which can be rapidly fired.
Disclosure of Invention
The invention aims to provide a fast-firing colorful pearlescent glaze, a rock plate and a preparation method of the rock plate, wherein the fast-firing colorful pearlescent glaze, the rock plate and the rock plate are fired in a roller kiln at 1150-1200 ℃ without influencing the colorful refraction light effect of mica.
In order to achieve the purpose, the invention adopts the following technical scheme that the quick-firing seven-color pearlescent glaze comprises pearlescent glaze, wherein the pearlescent glaze comprises the following raw materials:
35-40 parts of perlite, 20-25 parts of boric acid, 6-10 parts of strontium carbonate, 6-10 parts of zirconia, 2-6 parts of chalk soil, 4-8 parts of zirconite, 3-8 parts of high-boron frit, 2-6 parts of lithium fluoride, 6-10 parts of cerium oxide and 1-3 parts of corundum.
In some embodiments, the chemical composition of the pearlescent glaze comprises the following components in percentage by mass:
SiO 2 40-50 wt％、Al 2 O 3 8-12 wt％、Fe 2 O 3 0.5-4.0wt％、ZnO 8-12wt％、CaO 2-5wt％、MgO 0-0.5wt％、K 2 O 1-3wt％、Na 2 O 1-4wt％、SrO 5-10wt％、ZrO 2 4-8wt％、B 2 O 3 12-18wt% and 0-10 wt% of loss on ignition.
In some embodiments, the pearlescent ground glaze further comprises a pearlescent ground glaze, and the pearlescent ground glaze comprises the following raw materials:
25-35 parts of potassium feldspar, 15-25 parts of albite, 20-25 parts of quartz powder, 6-12 parts of nepheline, 4-8 parts of barium carbonate, 5-8 parts of alumina, 1-3 parts of dolomite, 1-3 parts of calcined talc and 12-16 parts of zirconium silicate.
In some embodiments, the chemical composition of the pearlescent ground glaze comprises the following components in percentage by mass:
SiO 2 58-68wt％、Al 2 O 3 18.0-20.0wt％、Fe 2 O 3 0-0.1wt％、CaO 4.0-6.0wt％、TiO 2 0-0.1wt％、MgO 2.0-3.5wt％、K 2 O 0-2.0wt％、Na 2 o3.0-5.0 wt% and loss on ignition 0-8.0wt%.
In some embodiments, the chemical composition of the perlite comprises the following ingredients in mass percent:
SiO 2 66.0-72.0wt％、Al 2 O 3 10-14 wt％、Fe 2 O 3 0.5-4.0wt％、CaO0.5-1.0wt％、MgO 0-0.5wt％、K 2 O 2-3wt％、Na 2 O 4-5wt％、H 2 02.0-6.5wt％。
in some embodiments, the chemical composition of the high-boron frit comprises the following components in mass percent:
SiO 2 65～75wt％、Al 2 O 3 5～8wt％、K 2 O 1.5～2.2wt％、Na 2 O 4.0～5.0wt％、B 2 O 3 13～15wt％、MgO 0～0.5wt％。
the fast-burning colorful pearlite plate is produced with fast-burning colorful pearlite glaze, which includes pearlite glaze, auxiliary pattern layer, pearlite ground glaze and white rock plate blank.
The preparation method of the fast-burning colorful pearlite plate is used for preparing the fast-burning colorful pearlite plate and comprises the following steps:
s1, preparing a pearly luster glaze, a pearly luster ground glaze and a rock plate white blank;
s2, applying the pearl base glaze cloth on the surface of the white blank of the rock plate and drying;
s3, printing a preset pattern on the surface of the pearlescent ground glaze to form an auxiliary pattern layer;
s4, spraying pearl glaze on the surface of the auxiliary pattern layer;
and S5, firing.
In some embodiments, the pearlescent glaze has a glazing specific gravity of 1.50-1.60, a glazing amount of 50-80 g/disc (glazing amount tray specification 600mm × 200mm), and a glaze layer thickness of 0.4-1.0 mm; the glazing proportion of the pearlescent ground glaze is 1.30-1.40, the glazing amount is 20-30 g/disc (the specification of a glazing amount measuring tray is 600mm × 200mm), and the thickness of the glaze layer is 0.02-0.1 mm.
In some embodiments, the firing temperature in step S5 is 1150 to 1200 ℃, and the firing time is 75 to 90min.
The invention has the beneficial effects that: according to the preparation method of the fast-firing colorful pearlescent glaze, the rock plate and the rock plate, boric acid, strontium carbonate, zirconium oxide, chalk, zirconite, lithium fluoride, cerium oxide and corundum are added, and during firing in a roller kiln at 1150-1200 ℃, the materials wrap perlite, so that high-temperature decomposition of mica in the perlite is effectively reduced, the mica is flaky in glaze, growth of crystal of the glaze surface can be inhibited in the firing process, light diffuse reflection of the mica by the crystal is avoided, the colorful refraction light effect of the mica is ensured, the colorful light in the light is respectively refracted by the mica according to different spectral frequencies, a colorful color is formed, and fast firing of the colorful pearlescent rock plate at high temperature is realized; the pearlescent glaze provided by the invention has strong adhesive force and good glossiness, and gives excellent seven-color bead light-sensitive visual effect to the ceramic product, the product can show different degrees of color effect under different angles of light, the color effect is similar to that of the shell inner color layer, and the color of each rock plate is varied and natural and beautiful.
Drawings
FIG. 1 is a schematic structural view of a fast-burning colorful pearlite slab of the present invention;
FIG. 2 is a schematic diagram of the melting of the fast-fired colorful pearlescent glaze of the present invention at 1125 deg.C, 1140 deg.C, 1155 deg.C, 1175 deg.C, respectively.
FIG. 3 is a diagram of the effect of the fast-burning colorful pearlite plate;
fig. 4 is a schematic diagram of the actual paving effect of the fast-burning colorful pearlite plate.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings.
Example 1
The fast-fired colorful pearlescent glaze comprises pearlescent glaze, and the pearlescent glaze comprises the following raw materials:
35-40 parts of perlite, 20-25 parts of boric acid, 6-10 parts of strontium carbonate, 6-10 parts of zirconia, 2-6 parts of chalk soil, 4-8 parts of zirconite, 3-8 parts of high-boron frit, 2-6 parts of lithium fluoride, 6-10 parts of cerium oxide and 1-3 parts of corundum.
The pearlescent glaze comprises the following components in percentage by mass:
SiO 2 40-50 wt％、Al 2 O 3 8-12 wt％、Fe 2 O 3 0.5-4.0wt％、ZnO 8-12wt％、CaO 2-5wt％、MgO 0-0.5wt％、K 2 O 1-3wt％、Na 2 O 1-4wt％、SrO 5-10wt％、ZrO 2 4-8wt％、B 2 O 3 12-18wt% and 0-10 wt% of loss on ignition.
The pearlescent ground glaze also comprises a pearlescent ground glaze, and the pearlescent ground glaze comprises the following raw materials:
25-35 parts of potassium feldspar, 15-25 parts of albite, 20-25 parts of quartz powder, 6-12 parts of nepheline, 4-8 parts of barium carbonate, 5-8 parts of alumina, 1-3 parts of dolomite, 1-3 parts of calcined talc and 12-16 parts of zirconium silicate.
The pearlescent ground glaze comprises the following components in percentage by mass:
SiO 2 58-68wt％、Al 2 O 3 18.0-20.0wt％、Fe 2 O 3 0-0.1wt％、CaO 4.0-6.0wt％、TiO 2 0-0.1wt％、MgO 2.0-3.5wt％、K 2 O 0-2.0wt％、Na 2 o3.0-5.0 wt% and loss on ignition 0-8.0wt%.
The perlite is obsidian from Shanxi Lingzhou, and is characterized by having high opalescence and thermal stability of granularity at high temperature, and the chemical composition comprises the following components in percentage by mass:
SiO 2 66.0-72.0wt％、Al 2 O 3 10-14wt％、Fe 2 O 3 0.5-4.0wt％、CaO0.5-1.0wt％、MgO 0-0.5wt％、K 2 O 2-3wt％、Na 2 O 4-5wt％、H 2 02.0-6.5wt％。
the chemical composition of the high-boron frit comprises the following components in percentage by mass:
SiO 2 65～75wt％、Al 2 O 3 5～8wt％、K 2 O 1.5～2.2wt％、Na 2 O 4.0～5.0wt％、B 2 O 3 13～15wt％、MgO 0～0.5wt％。
the particle size of the high boron frit is less than 325 mesh.
The grain size of the pearl glaze powder is 50-200 mu m.
The boric acid, strontium carbonate, zirconia, chalk, zircon, lithium fluoride and cerium oxide are all selected from chemical materials selected by Dow corporation.
The following specific test proportions are adopted:
the melting temperature range of the glaze prepared by 40 parts of perlite, 20 parts of boric acid, 7 parts of strontium carbonate, 7 parts of zirconia, 4 parts of chalk, 5 parts of zircon, 5 parts of high-boron frit, 3 parts of lithium fluoride, 8 parts of cerium oxide and 1 part of corundum is shown in figure 2, and as can be seen from the figure, the glaze is melted from 1125 ℃, completely melted at 1175 ℃, has the melting range of about 50 ℃, is wide in melting range, is beneficial to firing, and can be directly fired by a roller kiln under the temperature control of 1125-1175 ℃, so that the quick firing effect can be realized.
Example 2
As shown in fig. 1, the fast-fired colorful pearlescent rock plate, to which the fast-fired colorful pearlescent glaze of example 1 is applied, includes pearlescent glaze 1, auxiliary pattern layer 2, pearlescent ground glaze 3 and rock plate white blank 4 arranged from top to bottom.
The rock plate white blank 4 preferably comprises the following components in parts by weight: 1.5 to 3.5 parts of water abrasive, 18.0 to 22.0 parts of water washing ball clay, 2.0 to 4.0 parts of ultra white ball clay, 1.0 to 3.0 parts of black talc, 36.0 to 41.0 parts of water abrasive sand, 16 to 20.0 parts of male Tian Sha, 8.0 to 12.0 parts of high temperature sand, 1.0 to 2.0 parts of bentonite and 2 to 4 parts of calcined bauxite; further preferably: 2.0 to 3.0 portions of water abrasive, 19.0 to 21.0 portions of water washing ball clay, 2.5 to 3.5 portions of ultra-white ball clay, 1.5 to 2.5 portions of black talc, 38.0 to 40.0 portions of water abrasive, tian Sha 17.0.0 to 19.0 portions of Gong 5363, 9.0 to 11.0 portions of high temperature sand, 1.0 to 2.0 portions of bentonite and 2.5 to 3.5 portions of calcined bauxite.
The chemical component content and the performance index of the rock plate white blank 4 are preferably as follows: siO 2 2 60.0～65.0wt％、Al 2 O 3 20.0～24.0wt％、Fe 2 O 3 0～1.2wt％、TiO 2 0～0.5wt％、CaO 0.2～1.0wt％、MgO0.5～1.0wt％、K 2 O 1.0～4.0wt％、Na 2 1.0 to 4.0 weight percent of O and 0 to 7.0 weight percent of loss on ignition; further preferably: siO 2 2 62.0～64.0wt％、Al 2 O 3 21.0～23.0wt％、Fe 2 O 3 0～0.5wt％、TiO 2 0～0.3wt％、CaO 0.3～0.6wt％、MgO 0.6～0.8wt％、K 2 O 2.0～3.0wt％、Na 2 O2.0-3.0 wt% and loss on ignition 0.0-5.0 wt%.
The thickness of the pearlescent glaze 1 is 0.4-1.0 mm, and the thickness of the pearlescent ground glaze 3 is 0.02-0.1 mm.
As shown in fig. 3 and 4, the object effect and the decoration effect of the rock plate of this embodiment are shown, the rock plate surface has a visual effect of seven-color bead light sense, and the product can show color effects of different degrees under light rays of different angles, and is similar to the color layer in the shell, so that the product is very beautiful.
Example 3
A method for producing a fast-burning colorful pearlite plate, which is used for the fast-burning colorful pearlite plate of embodiment 2, and comprises the following steps:
s1, preparing pearlescent glaze, pearlescent ground glaze and a rock plate blank;
s2, applying the pearl base glaze cloth on the surface of the white blank of the rock plate and drying;
s3, printing a preset pattern on the surface of the pearlescent ground glaze to form an auxiliary pattern layer;
s4, spraying pearlescent glaze on the surface of the auxiliary pattern layer;
and S5, firing.
The glazing proportion of the pearlescent glaze is 1.50-1.60, the glazing amount is 50-80 g/disc (the specification of a glazing amount measuring tray is 600mm × 200mm), and the thickness of a glaze layer is 0.4-1.0 mm; the glazing proportion of the pearlescent ground glaze is 1.30-1.40, the glazing amount is 20-30 g/disc (the specification of a glazing amount measuring tray is 600mm × 200mm), and the thickness of the glaze layer is 0.02-0.1 mm.
The sintering temperature in the step S5 is 1150-1200 ℃, and the sintering time is 75-90 min.
The pattern of the auxiliary pattern layer is printed on the surface of the pearl under-glaze by an Italian import equipment ink-jet printer. The glaze spraying cabinet is adopted as the glazing equipment, and in the embodiment, the multifunctional swinging glaze spraying cabinet of the Mordena company is adopted, so that the glazing is uniform.
What has been described above are merely some embodiments of the present invention. It will be apparent to those skilled in the art that various changes and modifications can be made without departing from the inventive concept thereof, and these changes and modifications can be made without departing from the spirit and scope of the invention.
Claims (9)
1. The fast-fired colorful pearlescent glaze is characterized by comprising a pearlescent glaze, wherein the pearlescent glaze comprises the following raw materials:
35-40 parts of perlite, 20-25 parts of boric acid, 6-10 parts of strontium carbonate, 6-10 parts of zirconia, 2-6 parts of chalk soil, 4-8 parts of zirconite, 3-8 parts of high-boron frit, 2-6 parts of lithium fluoride, 6-10 parts of cerium oxide and 1-3 parts of corundum.
2. The fast-firing seven-color pearlescent glaze according to claim 1, wherein the chemical composition of the pearlescent glaze comprises the following components in percentage by mass:
SiO 2 40-50 wt％、Al 2 O 3 8-12 wt％、Fe 2 O 3 0.5-4.0wt％、ZnO 8-12wt％、CaO 2-5wt％、MgO 0-0.5wt％、K 2 O 1-3wt％、Na 2 O 1-4wt％、SrO 5-10wt％、ZrO 2 4-8wt％、B 2 O 3 12-18wt% and 0-10 wt% of loss on ignition.
3. The fast-firing seven-color pearlescent glaze according to claim 1, further comprising a pearlescent ground glaze, wherein the pearlescent ground glaze comprises the following raw materials:
25-35 parts of potassium feldspar, 15-25 parts of albite, 20-25 parts of quartz powder, 6-12 parts of nepheline, 4-8 parts of barium carbonate, 5-8 parts of alumina, 1-3 parts of dolomite, 1-3 parts of calcined talc and 12-16 parts of zirconium silicate.
4. The fast-firing seven-color pearlescent glaze according to claim 3, wherein the chemical composition of the pearlescent ground glaze comprises the following components in percentage by mass:
SiO 2 58-68wt％、Al 2 O 3 18.0-20.0wt％、Fe 2 O 3 0-0.1wt％、CaO 4.0-6.0wt％、TiO 2 0-0.1wt％、MgO 2.0-3.5wt％、K 2 O 0-2.0wt％、Na 2 o3.0-5.0 wt% and loss on ignition 0-8.0wt%.
5. The fast-firing seven-color pearlescent glaze according to claim 1, wherein the chemical composition of the perlite comprises the following components in percentage by mass:
SiO 2 66.0-72.0wt％、Al 2 O 3 10-14 wt％、Fe 2 O 3 0.5-4.0wt％、CaO0.5-1.0wt％、MgO 0-0.5wt％、K 2 O 2-3wt％、Na 2 O 4-5wt％、H 2 02.0-6.5wt％。
6. the fast-firing colorful pearlescent rock plate is applied with the fast-firing colorful pearlescent glaze material as set forth in any one of claims 1 to 5, and is characterized by comprising a pearlescent glaze, an auxiliary pattern layer, a pearlescent ground coat and a rock plate white blank which are arranged from top to bottom.
7. A method for producing a fast-burning seven-color perlite board as claimed in claim 6, characterized by comprising the steps of:
s1, preparing pearlescent glaze, pearlescent ground glaze and a rock plate blank;
s2, applying the pearl base glaze cloth on the surface of the white blank of the rock plate and drying;
s3, printing a preset pattern on the surface of the pearlescent ground glaze to form an auxiliary pattern layer;
s4, spraying pearlescent glaze on the surface of the auxiliary pattern layer;
and S5, firing.
8. The method for preparing the fast-firing colorful pearlite slab as claimed in claim 7, wherein the glazing specific gravity of the pearlite glaze is 1.50-1.60, the glazing amount is 50-80 g/disc, the specification of the glazing amount measuring tray is 600mm x 200mm, and the thickness of the glaze layer is 0.4-1.0 mm; the glazing proportion of the pearlescent ground glaze is 1.30-1.40, the glazing amount is 20-30 g/disc, the specification of the glazing amount tray is 600mm × 200mm, and the thickness of the glaze layer is 0.02-0.1 mm.
9. The method for preparing a quick-firing colorful pearlite plate according to claim 7, wherein the firing temperature in the step S5 is 1150-1200 ℃ and the firing time is 75-90 min.
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| CN116354603A (en) * | 2023-06-01 | 2023-06-30 | 佛山市陶莹新型材料有限公司 | Ceramic pearlescent dry grain glaze and preparation method and application thereof |
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| CN107827363A (en) * | 2017-11-24 | 2018-03-23 | 广东道氏技术股份有限公司 | A kind of high temperature golden yellow pearly-lustre glaze and its application |
| CN109761649A (en) * | 2019-03-26 | 2019-05-17 | 东莞市唯美装饰材料有限公司 | A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect |
| CN112209618A (en) * | 2020-09-29 | 2021-01-12 | 广东金牌陶瓷有限公司 | Velvet ceramic rock plate and preparation method thereof |
| CN112707644A (en) * | 2020-12-24 | 2021-04-27 | 肇庆乐华陶瓷洁具有限公司 | Low-gloss transparent glaze, ceramic tile using same and preparation method thereof |
| CN113248282A (en) * | 2021-07-14 | 2021-08-13 | 广东欧文莱陶瓷有限公司 | Rock plate with comfortable human body touch feeling and preparation method thereof |
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| TWI250139B (en) * | 2003-06-27 | 2006-03-01 | R-Shin Tsai | Nano glaze with far infrared radiation functions |
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| JP2014201477A (en) * | 2013-04-04 | 2014-10-27 | 京都市 | Low melting point leadless glass composition for ceramics |
| CN106587624A (en) * | 2016-12-06 | 2017-04-26 | 钦州市高新技术产业服务中心 | Metallic luster glaze and preparation method thereof |
| CN106746670A (en) * | 2016-12-29 | 2017-05-31 | 湖南泰鑫瓷业有限公司 | A kind of unleaded low temperature pearly-lustre glaze without the low zirconium of bismuth and preparation method thereof |
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| CN109761649A (en) * | 2019-03-26 | 2019-05-17 | 东莞市唯美装饰材料有限公司 | A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect |
| CN112209618A (en) * | 2020-09-29 | 2021-01-12 | 广东金牌陶瓷有限公司 | Velvet ceramic rock plate and preparation method thereof |
| CN112707644A (en) * | 2020-12-24 | 2021-04-27 | 肇庆乐华陶瓷洁具有限公司 | Low-gloss transparent glaze, ceramic tile using same and preparation method thereof |
| CN113248282A (en) * | 2021-07-14 | 2021-08-13 | 广东欧文莱陶瓷有限公司 | Rock plate with comfortable human body touch feeling and preparation method thereof |
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