CN105924230B - Portoro glaze and production method with Portoro glaze ceramics - Google Patents

Portoro glaze and production method with Portoro glaze ceramics Download PDF

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Publication number
CN105924230B
CN105924230B CN201610272613.XA CN201610272613A CN105924230B CN 105924230 B CN105924230 B CN 105924230B CN 201610272613 A CN201610272613 A CN 201610272613A CN 105924230 B CN105924230 B CN 105924230B
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parts
glaze
portoro
golden flower
black
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CN201610272613.XA
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CN105924230A (en
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李奇生
李文溪
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Fujian Province Dehua Long Nan Ceramics Co Ltd
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Fujian Province Dehua Long Nan Ceramics Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/32—Burning methods
    • C04B33/34—Burning methods combined with glazing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

Abstract

The present invention relates to ceramic fabrication technique fields, are specifically related to a kind of Portoro glaze and the production method with Emperador Light glazing effect ceramics.This kind of Portoro glaze, it is characterized in that, including black ground-coat enamel and golden flower glaze, it selects special composition of raw materials and unique glazing and burning process is used according to the characteristic of glaze, the Portoro glaze ceramic surface burnt out has the key colour of black, golden yellow speckle is uniformly distributed in striated intermittently, as having spread one layer of bright yellow golden flower on the satin face of black, give people a kind of steady and noble feeling, with unique decoration and artistic effect, it can be used as the creation carrier of home decoration and the art work, to reduce the use to lithotome, reduce production cost, save rock material resource, with positive social and economic benefit.

Description

Portoro glaze and production method with Portoro glaze ceramics
Technical field
The present invention relates to ceramic fabrication technique field, it is specifically related to a kind of Portoro glaze and with Emperador Light glaze effect The production method of fruit ceramics.
Background technology
Portoro is very rare one of stone material kind, and texture is soft beautiful serious, and elegant style is that decoration is luxurious The ideal material of building and the traditional material of art sculpture, in fitting up indoors, Portoro stone material is often processed into various shapes Material, plank make metope, ground, platform, the column of building, are also commonly used for the material of monumental building such as upright stone tablet, tower, statue etc.； During the art work makes, Portoro stone material is engraved as the practical artworks such as stationery, lamps and lanterns, vessel.
With the continuous improvement of social and economic level, the requirement to high-grade interior decoration effect and ornament is also continuous Raising, but rock material resource is limited, high processing costs, so if a kind of glaze with Portoro stone effect can be provided simultaneously Existing Portoro stone material is substituted using ceramic material, as the carrier that interior decoration and the art work make, can be reduced to stone material Use, reduce production cost, save rock material resource, have positive social and economic benefit.
Invention content
In order to solve the deficiencies in the prior art, the present invention provides a kind of Portoro glaze and preparation method thereof and its make Technique.
To achieve the above object, described black the present invention provides a kind of Portoro glaze, including black ground-coat enamel and golden flower glaze Color ground-coat enamel is made of following component：20-30 parts of feldspar, kiln ash 15-20,10-15 parts of kaolin, sodium carbonate 15-20, part spodumene 5-10 parts, 5-10 parts of cobalt compounds, 5-10 parts of iron oxide, 1-5 parts of manganese dioxide, barium carbonate 1-5,1-5 parts of cryolite；
The following component of golden flower glaze is constituted：Potassium feldspar 25-10,10-15 parts of lime stone, 10-15 parts of zircon, kaolin 5-10, Calcite 5-10,5-10 parts of talcum, 5-10 parts of talcum, nickel sesquioxide 5-10, zinc oxide 1-5,1-5 parts of copper oxide, dioxy are burnt Change manganese 1-5, copper dioxide 1-5,1-5 parts of titanium dioxide, 1-5 parts of nickel oxide, 1-5 parts of quartz.
Optimization, black ground-coat enamel is made of following component：23 parts of feldspar, kiln ash 18,12 parts of kaolin, 16 parts of sodium carbonate, 6 parts of spodumene, 8 parts of cobalt compounds, 6 parts of iron oxide, 4 parts of manganese dioxide, barium carbonate 4,1 part of cryolite.
Optimization, the following component of golden flower glaze is constituted：Potassium feldspar 24,13 parts of lime stone, 14 parts of zircon, kaolin 7, calcite 6,8 parts of talcum, 6 parts of talcum, nickel sesquioxide 6, zinc oxide 2,3 parts of copper oxide, manganese dioxide 1, copper dioxide 4, titanium dioxide are burnt 3 parts of titanium, 2 parts of nickel oxide, 1 part of quartz.
Optimization, black ground-coat enamel is made of following component：25 parts of feldspar, kiln ash 16,14 parts of kaolin, 18 parts of sodium carbonate, 8 parts of spodumene, 5 parts of cobalt compounds, 8 parts of iron oxide, 1 part of manganese dioxide, barium carbonate 2,3 parts of cryolite.
Optimization, the following component of golden flower glaze is constituted：Potassium feldspar 18,12 parts of lime stone, 11 parts of zircon, kaolin 8, calcite 9,6 parts of talcum, 6 parts of talcum, nickel sesquioxide 7, zinc oxide 3,2 parts of copper oxide, manganese dioxide 4, copper dioxide 2, titanium dioxide are burnt 5 parts of titanium, 3 parts of nickel oxide, 4 parts of quartz.
A kind of production method with Portoro glaze ceramic prepares the Portoro having described in above-mentioned any one The ceramic of glaze, is as follows：
Step 1, it is for use that ceramic batch is made；
Step 2, black ground-coat enamel and golden flower glaze are made, and adjusts the concentration of black ground-coat enamel and golden flower glaze, black ground-coat enamel it is dense Degree is 50-55 Baume degrees, a concentration of 30-35 Baume degrees of golden flower glaze；
Step 3, black ground-coat enamel is first applied on ceramic body, applies golden flower glaze again；
Step 4, it is 1350-1400 DEG C of firing the ceramic body after glazing to be put into kiln through 6-8 hours, firing temperature Molding.
Further, in step 2, a concentration of the 32 of a concentration of 51, the golden flower glaze of black ground-coat enamel.
Further, in step 3, the glazing mode of black ground-coat enamel is to pour glaze or leaching glaze, and the glazing mode of golden flower glaze is spray Glaze or drop glaze.
Further, in step 3, after golden flower glaze glazings weak vibrations or rotation ceramic body, make golden flower glaze swoon open form at Natural decorative pattern.
By the above-mentioned description of this invention it is found that Portoro glaze provided by the invention and the system with Portoro glaze ceramics Make method, select special composition of raw materials and unique glazing and burning process are used according to the characteristic of glaze, is burnt out Portoro glaze ceramic surface has the key colour of black, and golden yellow speckle is uniformly distributed in striated intermittently, as black One layer of bright yellow golden flower has been spread on the satin face of color, gives people a kind of steady and noble feeling, there is unique decoration and art Effect can be used as the creation carrier of home decoration and the art work, to reduce the use to lithotome, reduce production cost, section About rock material resource has positive social and economic benefit.
Specific implementation mode
Below by way of specific implementation mode, the invention will be further described.
A kind of Portoro glaze, including black ground-coat enamel and golden flower glaze, the black ground-coat enamel are made of following component：Feldspar 20-30 parts, kiln ash 15-20,10-15 parts of kaolin, sodium carbonate 15-20,5-10 parts of part spodumene, 5-10 parts of cobalt compounds, oxidation 5-10 parts of iron, 1-5 parts of manganese dioxide, barium carbonate 1-5,1-5 parts of cryolite；
The following component of golden flower glaze is constituted：Potassium feldspar 25-10,10-15 parts of lime stone, 10-15 parts of zircon, kaolin 5-10, Calcite 5-10,5-10 parts of talcum, 5-10 parts of talcum, nickel sesquioxide 5-10, zinc oxide 1-5,1-5 parts of copper oxide, dioxy are burnt Change manganese 1-5, copper dioxide 1-5,1-5 parts of titanium dioxide, 1-5 parts of nickel oxide, 1-5 parts of quartz.
Specific embodiment one：
A kind of Portoro glaze, including black ground-coat enamel and golden flower glaze, the black ground-coat enamel are made of following component：Black bottom Glaze is made of following component：23 parts of feldspar, kiln ash 18,12 parts of kaolin, 16 parts of sodium carbonate, 6 parts of spodumene, 8 parts of cobalt compounds, oxygen Change 6 parts of iron, 4 parts of manganese dioxide, barium carbonate 4,1 part of cryolite；
The following component of golden flower glaze is constituted：Potassium feldspar 24,14 parts of zircon, kaolin 7, calcite 6, burns and slides 13 parts of lime stone 8 parts of stone, 6 parts of talcum, nickel sesquioxide 6, zinc oxide 2,3 parts of copper oxide, manganese dioxide 1, copper dioxide 4,3 parts of titanium dioxide, 2 parts of nickel oxide, 1 part of quartz.
Specific embodiment two：
A kind of Portoro glaze, including black ground-coat enamel and golden flower glaze, the black ground-coat enamel are made of following component：, black Ground-coat enamel is made of following component：25 parts of feldspar, kiln ash 16,14 parts of kaolin, 18 parts of sodium carbonate, 8 parts of spodumene, 5 parts of cobalt compounds, 8 parts of iron oxide, 1 part of manganese dioxide, barium carbonate 2,3 parts of cryolite.
The following component of golden flower glaze is constituted：Potassium feldspar 18,12 parts of lime stone, 11 parts of zircon, kaolin 8, calcite 9 burn and slide 6 parts of stone, 6 parts of talcum, nickel sesquioxide 7, zinc oxide 3,2 parts of copper oxide, manganese dioxide 4, copper dioxide 2,5 parts of titanium dioxide, 3 parts of nickel oxide, 4 parts of quartz.
A kind of production method with Portoro glaze ceramic, prepares described in specific embodiment one or 2 any one Portoro glaze ceramic, be as follows：
Step 1, it is for use that ceramic batch is made；
Step 2, black ground-coat enamel and golden flower glaze are made, and adjusts the concentration of black ground-coat enamel and golden flower glaze, black ground-coat enamel it is dense Degree be 50-55 Baume degrees, a concentration of 30-35 Baume degrees of golden flower glaze, a concentration of 51, the golden flower glaze of the black ground-coat enamel of optimization it is dense Degree is 32；
Step 3, black ground-coat enamel is first applied on ceramic body, applies golden flower glaze again, and wherein the glazing mode of black ground-coat enamel is to pour The glazing mode of glaze or leaching glaze, golden flower glaze is glaze spraying or drop glaze, and weak vibrations or rotation ceramic body, make gold after golden flower glaze glazings Fancy glaze swoons open form into natural decorative pattern；
Step 4, it is 1350-1400 DEG C of firing the ceramic body after glazing to be put into kiln through 6-8 hours, firing temperature Molding.
Above-mentioned Portoro glaze and production method with Portoro glaze ceramics, select special composition of raw materials and according to glaze The characteristic of material uses unique glazing and burning process, the Portoro glaze ceramic surface burnt out to have the Essential colour of black It adjusts, golden yellow speckle is uniformly distributed in striated, as one layer of bright yellow golden flower has been spread on the satin face of black, gives intermittently A kind of steady and noble feeling of people has unique decoration and artistic effect, can be used as home decoration and the creation of the art work Carrier reduces production cost, saves rock material resource to reduce the use to lithotome, has positive society and economic effect Benefit.
The specific embodiment of the present invention is above are only, but the design concept of the present invention is not limited thereto, all profits The change for carrying out unsubstantiality to the present invention with this design, should all belong to the behavior for invading the scope of the present invention.

Claims (5)

1. a kind of Portoro glaze, which is characterized in that including black ground-coat enamel and golden flower glaze, the black ground-coat enamel is by following component structure At：20-30 parts of feldspar, 15-20 parts of kiln ash, 10-15 parts of kaolin, 15-20 parts of sodium carbonate, 5-10 parts of spodumene, cobalt compounds 5- 10 parts, 5-10 parts of iron oxide, 1-5 parts of manganese dioxide, 1-5 parts of barium carbonate, 1-5 parts of cryolite；
Golden flower glaze is made of following component：25-10 parts of potassium feldspar, 10-15 parts of lime stone, 10-15 parts of zircon, kaolin 5-10 Part, burns 5-10 parts of talcum, 5-10 parts of talcum, 5-10 parts of nickel sesquioxide, 1-5 parts of zinc oxide, copper oxide 1- at 5-10 parts of calcite 5 parts, 1-5 parts of manganese dioxide, 1-5 parts of copper dioxide, 1-5 parts of titanium dioxide, 1-5 parts of nickel oxide, 1-5 parts of quartz.
2. Portoro glaze according to claim 1, it is characterised in that：The black ground-coat enamel is made of following component：It is long 23 parts of stone, 18 parts of kiln ash, 12 parts of kaolin, 16 parts of sodium carbonate, 6 parts of spodumene, 8 parts of cobalt compounds, 6 parts of iron oxide, manganese dioxide 4 Part, 4 parts of barium carbonate, 1 part of cryolite.
3. Portoro glaze according to claim 1 or 2, it is characterised in that：The golden flower glaze is made of following component：Potassium 24 parts of feldspar, 14 parts of zircon, 7 parts of kaolin, 6 parts of calcite, burns 8 parts of talcum, 6 parts of talcum, nickel sesquioxide at 13 parts of lime stone 6 parts, 2 parts of zinc oxide, 3 parts of copper oxide, 1 part of manganese dioxide, 4 parts of copper dioxide, 3 parts of titanium dioxide, 2 parts of nickel oxide, quartz 1 Part.
4. Portoro glaze according to claim 1, it is characterised in that：The black ground-coat enamel is made of following component：It is long 25 parts of stone, 16 parts of kiln ash, 14 parts of kaolin, 18 parts of sodium carbonate, 8 parts of spodumene, 5 parts of cobalt compounds, 8 parts of iron oxide, manganese dioxide 1 Part, 2 parts of barium carbonate, 3 parts of cryolite.
5. Portoro glaze according to claim 1 or 4, it is characterised in that：The golden flower glaze is made of following component：Potassium 18 parts of feldspar, 12 parts of lime stone, 11 parts of zircon, 8 parts of kaolin, burn 6 parts of talcum, 6 parts of talcum, nickel sesquioxide at 9 parts of calcite 7 parts, 3 parts of zinc oxide, 2 parts of copper oxide, 4 parts of manganese dioxide, 2 parts of copper dioxide, 5 parts of titanium dioxide, 3 parts of nickel oxide, quartz 4 Part.
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CN107162602A (en) * 2017-06-07 2017-09-15 景德镇陶瓷大学 A kind of formula of glaze base bonding agent and preparation method thereof
CN107759090B (en) * 2017-11-21 2020-12-01 广东道氏技术股份有限公司 Glaze material with effect of imitating black gold sand marble and application thereof
CN108483909B (en) * 2018-05-22 2021-03-30 泉州市德化县艾慕陶瓷有限公司 Carbon-absorbing crack glaze for firewood burning pottery, preparation method of carbon-absorbing crack glaze, ceramic prepared from carbon-absorbing crack glaze and preparation method of ceramic
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CN109231824A (en) 2019-01-18
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Denomination of invention: Black-golden pattern glaze and manufacturing method of ceramic with black-golden pattern glaze

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