CN107285812A - Easy clean Ceramic Tiles - Google Patents
Easy clean Ceramic Tiles Download PDFInfo
- Publication number
- CN107285812A CN107285812A CN201710605577.9A CN201710605577A CN107285812A CN 107285812 A CN107285812 A CN 107285812A CN 201710605577 A CN201710605577 A CN 201710605577A CN 107285812 A CN107285812 A CN 107285812A
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- easy clean
- easy
- ceramic tiles
- protection
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Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 66
- 239000002245 particle Substances 0.000 claims abstract description 53
- 239000008187 granular material Substances 0.000 claims abstract description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 39
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 34
- 239000005995 Aluminium silicate Substances 0.000 claims description 29
- 235000012211 aluminium silicate Nutrition 0.000 claims description 29
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000002994 raw material Substances 0.000 claims description 21
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 18
- 239000011787 zinc oxide Substances 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 16
- 239000010453 quartz Substances 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 229910052681 coesite Inorganic materials 0.000 claims description 13
- 229910052593 corundum Inorganic materials 0.000 claims description 13
- 229910052906 cristobalite Inorganic materials 0.000 claims description 13
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- 229910052682 stishovite Inorganic materials 0.000 claims description 13
- 229910052905 tridymite Inorganic materials 0.000 claims description 13
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 13
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 12
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 12
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 12
- 239000000454 talc Substances 0.000 claims description 12
- 235000012222 talc Nutrition 0.000 claims description 12
- 229910052623 talc Inorganic materials 0.000 claims description 12
- 239000000440 bentonite Substances 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 9
- 210000003298 dental enamel Anatomy 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 235000019738 Limestone Nutrition 0.000 claims description 8
- 229910052656 albite Inorganic materials 0.000 claims description 8
- 239000006028 limestone Substances 0.000 claims description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 5
- 239000010434 nepheline Substances 0.000 claims description 4
- 229910052664 nepheline Inorganic materials 0.000 claims description 4
- 239000010410 layer Substances 0.000 claims 6
- 238000010020 roller printing Methods 0.000 claims 1
- 239000002344 surface layer Substances 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 14
- 230000003670 easy-to-clean Effects 0.000 abstract description 10
- 238000005516 engineering process Methods 0.000 abstract description 7
- 230000003373 anti-fouling effect Effects 0.000 abstract description 6
- 238000012423 maintenance Methods 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 24
- 239000000203 mixture Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 11
- 239000011449 brick Substances 0.000 description 9
- 239000004576 sand Substances 0.000 description 9
- 238000005034 decoration Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000007641 inkjet printing Methods 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000010835 comparative analysis Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000010427 ball clay Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 210000000498 stratum granulosum Anatomy 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention belongs to ceramic technology field, it is related to a kind of easy clean Ceramic Tiles.The easy clean Ceramic Tiles that the present invention is provided include green body layer, cover coat, printed layer and easy clean protection dry granule layer successively from bottom to top, and the easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；The easy clean protection glaze includes the component of following mass fraction：20~40 parts of easy clean 90~110 parts of particle of protection, 230~270 parts of stamp-pad ink and clear frit.The easy clean Ceramic Tiles that the present invention is provided have the easy clean property of excellent anti-soil, and anti-fouling performance is good, it is easy to clean, and are easy to daily maintenance to alleviate the easy Tibetan dirt that existing Ceramic Tiles are present, technical problem not easy to clean with arranging, effectively.
Description
Technical field
The invention belongs to ceramics dress technical field, and in particular to a kind of easy clean Ceramic Tiles.
Background technology
With developing rapidly for science and technology, the life of people is maked rapid progress, and is followed the fashion, is shown while having cast one
In the epoch of individual character, architectural decoration material field is no exception.Ceramic Tiles are with its superior performance and decorative effect, by increasingly
The favor of many consumers, and be widely used in daily life.And ceramic antique bricks are in recent years popular rise
A kind of building and ornament materials come, pattern that it has had the splendid and ceramics of polished bricks concurrently is rich and varied, with the modern times or
Pseudo-classic charm, and it is personalized many advantages, such as, be received by the market in recent years and consumer like.
The continuous utilization of fast development and new technology, new material, new technology with architectural pottery etc., has promoted building
Ceramic product constantly develops towards more preferable direction, and architectural pottery product has broken through is only limitted to durable and decoration model in the past
Enclose, the direction towards functional diversities is developed, and then promote and build continuing to develop for potler's industry and ceramic product.However, existing
Ceramic product development process in, pay attention to how to improve the intensity of product, wear-resisting durability and rich color and pattern more
Research and development in terms of texture is good.For removing surface present in existing ceramic product it is difficult, hide dirty, anti-fouling effect it is poor, when
Between the defect such as long product blackening, do not find good solution also.Therefore, for the easy clean property of anti-soil of raising ceramic product
Research and development and design also have considerable room for improvement.
In consideration of it, special propose the present invention.
The content of the invention
It is an object of the invention to provide a kind of easy clean Ceramic Tiles, it has the excellent easy clean property of anti-soil, i.e. anti-fouling performance
It is good, it is easy to clean, greatly lift product quality.
To achieve the above object, the technical solution adopted by the present invention is：
The present invention provides a kind of easy clean Ceramic Tiles, the easy clean Ceramic Tiles include successively from bottom to top green body layer, cover coat,
Printed layer and easy clean protection dry granule layer, the easy clean protection dry granule layer are formed by the easy clean protection glaze of charity；
The easy clean protection glaze includes the component of following mass fraction：Easy clean 90~110 parts of particle of protection, stamp-pad ink 230~
270 parts and 20~40 parts of clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~0.3 part, TiO20.01~0.1 part, Na2O 4~
8 parts, K20.05~0.3 part of 2~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and loss on ignition.
As further preferred technical scheme, the easy clean protection glaze includes the component of following mass fraction：Easy clean protection
22~38 parts of 92~108 parts of particle, 240~260 parts of stamp-pad ink and clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO265~68 parts, Al2O318~22 parts, Fe2O30.12~0.22 part, TiO20.02~0.08 part, Na2O
5~7 parts, K20.1~0.2 part of 3~5 parts of O, 0.1~0.2 part of MgO, 1~2 part of CaO and loss on ignition.
As further preferred technical scheme, the easy clean protection glaze includes the component of following mass fraction：Easy clean protection
28~32 parts of 95~105 parts of particle, 245~250 parts of stamp-pad ink and clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO266~67 parts, Al2O320~21 parts, Fe2O30.15~0.2 part, TiO20.04~0.07 part, Na2O
5.5~6.5 parts, K20.14~0.18 part of 4~4.8 parts of O, 0.12~0.15 part of MgO, 1.5~1.8 parts of CaO and loss on ignition.
As further preferred technical scheme, the stamp-pad ink is mainly made up of the component of following mass fraction：Carboxymethyl is fine
60~80 parts of plain 1~2 part of the sodium of dimension, 20~40 parts of ethylene glycol, 1~5 part of bentonite and water.
As further preferred technical scheme, the clear frit is mainly made up of the component of following mass fraction：
12~16 parts of albite, 20~24 parts of potassium feldspar, 6~10 parts of kaolin, 10~14 parts of calcined kaolin, quartz 10
1~5 part of~14 parts, 13~17 parts of talcum of burning, 7~11 parts of lime stone, 8~12 parts of barium carbonate and zinc oxide.
As further preferred technical scheme, the proportion of the easy clean protection glaze is 1.2~1.5g/cm3。
As further preferred technical scheme, the grain composition of the easy clean protection particle is：The mesh of 80 mesh~120 is 50%
~60%, 120~200 mesh are 20%~30%, and remaining is below 200 mesh.
As further preferred technical scheme, the green body layer is the green body layer with convex-concave surface.
As further preferred technical scheme, the cover coat is mainly prepared from by cover-coat enamel, the cover-coat enamel it is main by with
The raw material of lower mass parts is prepared from：
20~30 parts of potassium feldspar, 15~30 parts of quartz, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, aluminum oxide 5~
15 parts, 1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, 10~20 parts of column kaolin, sodium humate
0.1~0.3 part of 0.1~0.3 part, 0.1~0.3 part of sodium carboxymethylcellulose and sodium tripolyphosphate.
As further preferred technical scheme, the printed layer includes one or multi-channel lamina printing decoration, one or multi-channel roller
Cylinder stamp and it is one or both of ink-jet printed more than combination.
Compared with prior art, the beneficial effects of the present invention are：
The easy clean Ceramic Tiles that the present invention is provided, pass through the cooperation of green body layer, cover coat, printed layer and easy clean protection dry granule layer
Set, the reasonable cooperation of each raw material and its component in especially easy clean protection dry granule layer so that the Ceramic Tiles are finer and close, have
The easy clean property of excellent anti-soil, anti-fouling performance is good, it is easy to clean, and is easy to daily maintenance to be alleviated with arranging, effectively existing
The easy Tibetan dirt that Ceramic Tiles are present, technical problem not easy to clean.
At the same time, the Ceramic Tiles also have higher glossiness, and solid layer feeling is strong, and definition is good, surface transparency
Height, the good advantage of rich color, pattern texture so that product has good combination property, greatly improves the product of product
Matter.
Embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment and embodiment, but this area skill
Art personnel will be understood that following embodiments and embodiment are merely to illustrate the present invention, and are not construed as the model of the limitation present invention
Enclose.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made
Every other embodiment, belongs to the scope of protection of the invention.Actual conditions person is indicated, is advised according to normal condition or manufacturer
Condition carry out.Agents useful for same or the unreceipted production firm person of instrument, are the conventional products that can be obtained by commercially available purchase.
Present embodiment provides a kind of easy clean Ceramic Tiles, and the easy clean Ceramic Tiles include green body layer, face successively from bottom to top
Glaze layer, printed layer and easy clean protection dry granule layer, the easy clean protection dry granule layer are formed by the easy clean protection glaze of charity；
The easy clean protection glaze includes the component of following mass fraction：Easy clean 90~110 parts of particle of protection, stamp-pad ink 230~
270 parts and 20~40 parts of clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~0.3 part, TiO20.01~0.1 part, Na2O 4~
8 parts, K20.05~0.3 part of 2~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and loss on ignition.
In view of ceramic brick product of the prior art is existed, surface is not fine and close enough, and flat smooth degree is poor, easily hides dirty, prevents
Dirty effect is poor, and the difficult defect of removing surface, present embodiment provides a kind of easy clean property of anti-soil that can effectively provide product
Easy clean Ceramic Tiles, and then the quality of Ceramic Tiles is lifted, promote application of the Ceramic Tiles in building field.
Present embodiment mainly stamp layer surface charity it is easy clean protection glaze formed it is easy clean protection dry granule layer by way of,
Enable the easy clean protection dry granule layer uniform fold in ceramic brick surface and effectively fill up the gap of ceramic brick surface, improve
The compactness of Ceramic Tiles, and then the stain resistance of product is improved, make it have the easy clean property of excellent anti-soil, it is easy to clean, be easy to
Daily maintenance is with arranging, while ceramic brick surface transparency is high, glossiness high, definition is good, it is both beautiful and practical.
In some specific embodiments, in terms of mass fraction, the easy clean protection typical but non-limiting content of particle
For：90 parts, 91 parts, 92 parts, 93 parts, 94 parts, 95 parts, 96 parts, 97 parts, 98 parts, 99 parts, 100 parts, 101 parts, 102 parts, 103 parts,
104 parts, 105 parts, 106 parts, 107 parts, 108 parts, 109 parts or 110 parts.The typical but non-limiting content of stamp-pad ink is：230 parts,
235 parts, 240 parts, 245 parts, 250 parts, 255 parts, 260 parts, 265 parts or 270 parts.The typical but non-limiting content of clear frit
For：20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34
Part, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts or 40 parts.
The easy clean protection particle that present embodiment is provided, preferably should be able to be melted mutually, and can guarantee that one at high temperature
Fixed granular sensation, can be uniformly covered on product surface, and the clear frit added can fill up void among particles, and ensure certain
High temperature viscosity, reached together with temperature resistant transparent light dry granular preferably antifouling, wear-resisting and easy clean and other effects.
The easy clean protection glaze that present embodiment is provided mainly is made up of easy clean protection particle, stamp-pad ink and clear frit, on the one hand,
It is above-mentioned it is easy clean protection particle have higher melting temperature and wider firing range, can at a temperature of 1175~1185 DEG C,
Preferably melt and have higher gloss degree to ensure purpose that Ceramic Tiles are easy clean；On the other hand, above-mentioned stamp-pad ink primarily serves raising easily
The effect of clean protection glaze high temperature viscosity, makes it be unlikely to melt flat at high temperature, to improve the stereoeffect of ceramic brick surface；This
Outside, above-mentioned clear frit primarily serve improve it is above-mentioned it is easy clean protection glaze transparency and glossiness effect, strengthen product texture and
Solid layer feeling.
In some specific embodiments, in terms of mass fraction, SiO2Typical but non-limiting content is：60 parts,
61 parts, 62 parts, 63 parts, 64 parts, 65 parts, 66 parts, 67 parts, 68 parts, 69 parts or 70 parts.Al2O3Typical but non-limiting content
For：15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts or 25 parts.Fe2O3It is typical but non-limiting
Content be：0.1 part, 0.12 part, 0.14 part, 0.15 part, 0.16 part, 0.18 part, 0.2 part, 0.22 part, 0.24 part, 0.25 part,
0.26 part, 0.28 part or 0.3 part.TiO2Typical but non-limiting content is：0.01 part, 0.02 part, 0.03 part, 0.04 part,
0.05 part, 0.06 part, 0.07 part, 0.08 part, 0.09 part or 0.1 part.Na2The typical but non-limiting contents of O are：4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts or 8 parts.K2The typical but non-limiting contents of O are：2 parts, 2.5 parts, 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts or 6 parts.The typical but non-limiting contents of MgO are：0.05 part, 0.1 part, 0.15
Part, 0.2 part, 0.25 part or 0.3 part.The typical but non-limiting contents of CaO are：0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts or 3
Part.The typical but non-limiting content of loss on ignition is：0.05 part, 0.1 part, 0.15 part, 0.2 part, 0.25 part or 0.3 part.
It should be noted that loss on ignition (Loss on ignition, be abbreviated as LOI) is the technology commonly used in ceramic field
Term, understands, the weight ratio before referring to the weight after raw material calcination and burning till according to the routine of this area.
Present embodiment, by being equipped with for green body layer, cover coat, printed layer and easy clean protection dry granule layer, is improved
The easy clean property of anti-soil, solid layer feeling, glossiness and the transparency of product so that the ceramic product has well comprehensive
Can, with higher intensity and hardness, pattern texture strong, good decorating effect, it is durable while with good stain resistance,
It is easy to clean.In addition, when above-mentioned easy clean protection glaze and easy clean protection particle are constituted and matched using said components, synergy
More preferably, the easy clean property of anti-soil of product can be strengthened.
In a kind of optional embodiment, the easy clean protection glaze includes the component of following mass fraction：Easy clean protection
22~38 parts of 92~108 parts of particle, 240~260 parts of stamp-pad ink and clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO265~68 parts, Al2O318~22 parts, Fe2O30.12~0.22 part, TiO20.02~0.08 part, Na2O
5~7 parts, K20.1~0.2 part of 3~5 parts of O, 0.1~0.2 part of MgO, 1~2 part of CaO and loss on ignition.
In a kind of optional embodiment, the easy clean protection glaze includes the component of following mass fraction：Easy clean protection
28~32 parts of 95~105 parts of particle, 245~250 parts of stamp-pad ink and clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO266~67 parts, Al2O320~21 parts, Fe2O30.15~0.2 part, TiO20.04~0.07 part, Na2O
5.5~6.5 parts, K20.14~0.18 part of 4~4.8 parts of O, 0.12~0.15 part of MgO, 1.5~1.8 parts of CaO and loss on ignition.
Pass through the proportioning between each component in the easy clean protection glaze of Reasonable adjustment, and each group that easy clean protection particle is included
Divide content, can further improve the stain resistance of Ceramic Tiles, be easy to daily cleaning and maintenance, and with higher gloss
Degree, transparency, solid layer feeling and pattern texture.
In a kind of optional embodiment, the stamp-pad ink is mainly made up of the component of following mass fraction：Carboxymethyl is fine
60~80 parts of plain 1~2 part of the sodium of dimension, 20~40 parts of ethylene glycol, 1~5 part of bentonite and water.
Preferably, the stamp-pad ink is mainly made up of the component of following mass fraction：1.2~1.8 parts of sodium carboxymethylcellulose,
65~75 parts of 25~35 parts of ethylene glycol, 2~4 parts of bentonite and water.
In some specific embodiments, in terms of mass fraction, sodium carboxymethylcellulose is typical but non-limiting to be contained
Measure and be：1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts or 2 parts.Ethylene glycol allusion quotation
Type but nonrestrictive content is：20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts,
31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts or 40 parts.The typical but non-limiting content of bentonite
For 1 part, 2 parts, 3 parts, 4 parts or 5 parts.The typical but non-limiting content of water is：60 parts, 61 parts, 62 parts, 63 parts, 64 parts, 65
Part, 66 parts, 67 parts, 68 parts, 69 parts, 70 parts, 71 parts, 72 parts, 73 parts, 74 parts, 75 parts, 76 parts, 77 parts, 78 parts, 79 parts or 80
Part.
The stamp-pad ink that present embodiment is provided primarily serves the effect for improving easy clean protection glaze high temperature viscosity, makes it at high temperature
It is unlikely to melt flat, to improve the stereoeffect of ceramic brick surface.
In a kind of optional embodiment, the clear frit is mainly made up of the component of following mass fraction：
12~16 parts of albite, 20~24 parts of potassium feldspar, 6~10 parts of kaolin, 10~14 parts of calcined kaolin, quartz 10
1~5 part of~14 parts, 13~17 parts of talcum of burning, 7~11 parts of lime stone, 8~12 parts of barium carbonate and zinc oxide.
Preferably, the clear frit is mainly made up of the component of following mass fraction：13~15 parts of albite, potassium feldspar 21
~23 parts, 7~9 parts of kaolin, 11~13 parts of calcined kaolin, quartz 11~13 parts, burn 14~16 parts of talcum, lime stone 8~
2~4 parts of 10 parts, 9~11 parts of barium carbonate and zinc oxide.
In some specific embodiments, in terms of mass fraction, the typical but non-limiting content of albite is：12
Part, 12.5 parts, 13 parts, 13.5 parts, 14 parts, 14.5 parts, 15 parts, 15.5 parts or 16 parts.Potassium feldspar is typical but non-limiting to be contained
Measure and be：20 parts, 21 parts, 22 parts, 23 parts or 24 parts.The typical but non-limiting content of kaolin is：6 parts, 6.5 parts, 7 parts, 7.5
Part, 8 parts, 8.5 parts, 9 parts, 9.5 parts or 10 parts.The typical but non-limiting content of calcined kaolin is：10 parts, 10.5 parts, 11
Part, 11.5 parts, 12 parts, 12.5 parts, 13 parts, 13.5 parts or 14 parts.The typical but non-limiting content of quartz is：10 parts, 10.5
Part, 11 parts, 11.5 parts, 12 parts, 12.5 parts, 13 parts, 13.5 parts or 14 parts.Burn that talcum is typical but non-limiting to be：13 parts,
13.5 parts, 14 parts, 14.5 parts, 15 parts, 15.5 parts, 16 parts, 16.5 parts or 17 parts.Lime stone is typical but non-limiting to be：7
Part, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts, 10 parts, 10.5 parts or 11 parts.Barium carbonate is typical but non-limiting to be：8 parts,
8.5 parts, 9 parts, 9.5 parts, 10 parts, 10.5 parts, 11 parts, 11.5 parts or 12 parts.Zinc oxide is typical but non-limiting to be：1 part,
1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts.
The clear frit that present embodiment is provided primarily serves the effect for improving easy clean protection glaze transparency and glossiness；Using
More than formula clear frit, its transparency is higher, color development ability more preferably, and brightness is high, it is ensured that the pattern of product and clear
Degree.
In a kind of optional embodiment, the proportion of the easy clean protection glaze is 1.2~1.5g/cm3。
Preferably, the proportion of the easy clean protection glaze is 1.25~1.35g/cm3。
In a detailed embodiment, optionally, the proportion of easy clean protection glaze is 1.2g/cm3、1.25g/cm3、1.3g/
cm3、1.35g/cm3、1.4g/cm3、1.45g/cm3Or 1.5g/cm3。
In a kind of optional embodiment, the grain composition of the easy clean protection particle is：The mesh of 80 mesh~120 is 50%
~60%, 120~200 mesh are 20%~30%, and remaining is below 200 mesh.
In some embodiments, optionally, the grain composition of easy clean protection particle is：The mesh of 80 mesh~120 is
60%, it is 10% below 30%, 200 mesh that 120~200 mesh, which are,；Or, the mesh of 80 mesh~120 is 55%, and 120~200 mesh are
30%, it is 15% below 200 mesh.
It should be noted that above-mentioned % refers to mass percent.
Easy clean protection particle can make the space between particle less from above-mentioned grain composition, after charity is in printed layer
It is even closer uniform, intergranular space is substantially reduced, the compactness of product is improved, further increases stain resistance.
In the present invention, described easy clean protection particle can be by the silicon containing elements Si, Al, Fe, Ti, Na, K, Mg and Ca
Silicate material is melted, then water quenching and crush obtain.Alternatively, the main original by following mass parts of the silicate material
Material composition：10~20 parts of alumina powder, 36~45 parts of potassium feldspar, 8~16 parts of soda ash, 5~15 parts of zinc oxide and quartz 15~35
Part.Further, 25 parts of 13 parts of alumina powder, 42 parts of potassium feldspar, 10 parts of soda ash, 10 parts of zinc oxide and quartz.
In some embodiments, according to the mass fraction, the typical but non-limiting content of alumina powder is：10
Part, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts；Potassium feldspar is typical but unrestricted
The content of property is：36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts or 45 parts；Soda ash is typical but non-limit
Property processed is：8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts or 16 parts；Zinc oxide is typical but non-limiting
For：5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts 13 parts, 14 parts or 15 parts；Quartz is typical but non-limiting to be：
15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30
Part, 31 parts, 32 parts, 33 parts, 34 parts or 35 parts.
In a kind of optional embodiment, the green body layer is the green body layer with convex-concave surface.
The Ceramic Tiles of different colours and texture can be presented in green body layer with convex-concave surface so that the product produced
Case shell is more rich；It is favorably improved the skidproof effect of product and the stereovision of product, solid sense.
Alternatively, blank formulation uses the body recipe of common glazed ceramic brick, and present embodiment offer one is exemplary
Formula.To ensure flatness and the ripple glaze deformation of product, base substrate aluminum content is 21% or so, and whiteness is at 35 degree or so.Institute
Stating blank includes the raw material of following mass parts：10~30 parts of Yichuan sand, 10~20 parts of Ganzhou low temperature potassium sodium sand, Qianshan washing mud 16
~20 parts, 6~10 parts of Guangxi White mud, 1~5 part of the white mud in Ji'an, 25~35 parts of Guangchang potassium sand, 0.5~1.5 part of Fuzhou City's bentonite and
2~3 parts of black talc.
Alternatively, the moisture content of blank is 6%~6.5%；The grain composition of the blank is：It is more than 20 mesh for 0~
1.5%, -20~+40 mesh are 30%~60%, and it is 0~6% below 72%~88%, 100 mesh that -20~+60 mesh, which are, remaining
For -60~+100 mesh.
Mesh, through frequently as the unit for weighing granular size, mesh number is bigger, represents that particle is thinner.For people in the art
Member for, often before the Arabic numerals of mesh number add "-(negative sign) " come represent particle can by selected sieve, "+(just
Number) " representing that particle can not be by selected sieve, expression can be by the particles of 20 mesh sieves such as " -20 mesh " if；"+100 mesh "
Then representing can not be by the particle of 100 mesh sieves.
In a kind of optional embodiment, the cover coat is mainly prepared from by cover-coat enamel, the cover-coat enamel it is main by with
The raw material of lower mass parts is prepared from：
20~30 parts of potassium feldspar, 15~30 parts of quartz, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, aluminum oxide 5~
15 parts, 1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, 10~20 parts of column kaolin, sodium humate
0.1~0.3 part of 0.1~0.3 part, 0.1~0.3 part of sodium carboxymethylcellulose and sodium tripolyphosphate.
Preferably, the cover-coat enamel is mainly prepared from by the raw material of following mass parts：22~28 parts of potassium feldspar, quartz 18~
25 parts, 18~22 parts of nepheline, 6~8 parts of calcined kaolin, 6~12 parts of aluminum oxide, 3~6 parts of wollastonite, zinc oxide 0.5~1.5
Part, 15~25 parts of zirconium silicate, 12~18 parts of column kaolin, 0.15~0.25 part of sodium humate, sodium carboxymethylcellulose 0.15
~0.25 part and 0.15~0.2 part of sodium tripolyphosphate.
The cover coat that present embodiment is provided can improve the mechanical strength of easy clean Ceramic Tiles, reduce the water absorption rate of base substrate.
In addition, enabling to the whiteness of product suitable using above-mentioned green body layer and cover coat, the inherent and external of product not only ensure that
Quality, lifts the combination property of product, and reduces production cost, with good economic benefit.
In a kind of optional embodiment, the printed layer includes one or multi-channel lamina printing decoration, one or multi-channel roller
Cylinder stamp and it is one or both of ink-jet printed more than combination.
Preferably, the printed layer is ink-jet printed layer.
The printed layer of present embodiment, carries out decoration stamp preferably by ink-jet printing apparatus and obtains.
On the one hand, pattern decorative is carried out to Ceramic Tiles by the way of inkjet printing so that printed layer texture variations are enriched
Vividly, color is naturally true to nature, shows individual character fully and makes widely known glamour.On the other hand, the pattern texture of printed layer and easy clean protection dry granule layer
Interlaced, the not only aesthetic feeling with perspective, solid layer feeling is strong, smooth and clean, and clean mark is graceful, bright in luster not lose
Very, and glossiness is good, transparency is high, and anti-fouling performance is good, enriches the level of product, improves product specification, with good
Good decorative effect.
With reference to specific embodiment and comparative example, the invention will be further described.
Embodiment 1-3
A kind of easy clean protection tile, includes green body layer, cover coat, printed layer and easy clean protection dry granule layer successively from bottom to top,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；The easy clean ratio for protecting glaze according to the mass parts of the raw material shown in table 1
Example is prepared from.
The easy clean protection glaze raw material compositions of the embodiment 1-3 of table 1
| Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Easy clean protection glaze | 90 parts | 100 parts | 110 parts |
| Stamp-pad ink | 230 parts | 250 parts | 270 parts |
| Clear frit | 20 parts | 30 parts | 40 parts |
Wherein, easy clean protection particle is mainly made up of the component of following mass fraction：SiO266 parts, Al2O321 parts,
Fe2O30.15 part, TiO20.06 part, Na26 parts of O, K20.15 part of 4 parts of O, 0.15 part of MgO, 1.5 parts of CaO and loss on ignition.
It is easy clean protection particle grain composition be：The mesh of 80 mesh~120 is 60%, and 120~200 mesh are below 30%, 200 mesh
For 10%.
Stamp-pad ink is mainly made up of the component of following mass fraction：1.2 parts of sodium carboxymethylcellulose, 30 parts of ethylene glycol, swelling
70 parts of 3 parts of soil and water.
Clear frit is mainly made up of the component of following mass fraction：14 parts of albite, 22 parts of potassium feldspar, 8 parts of kaolin, forge
Burn 12 parts of kaolin, 12 parts of quartz, burn 3 parts of 15 parts of talcum, 9 parts of lime stone, 10 parts of barium carbonate and zinc oxide.
Embodiment 4-6
A kind of easy clean protection tile, includes green body layer, cover coat, printed layer and easy clean protection dry granule layer successively from bottom to top,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection glaze is made up of the raw material of following mass fraction：It is easy clean
Protect 30 parts of 100 parts of particle, 250 parts of stamp-pad ink and clear frit.Wherein, the main mass fraction as shown in Table 2 of easy clean protection particle
Component constitute.
The easy clean protection grain fractions of the embodiment 4-6 of table 2 are constituted
| Component | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| SiO2 | 60 parts | 63 parts | 70 parts |
| Al2O3 | 15 parts | 18 parts | 25 parts |
| Fe2O3 | 0.1 part | 0.18 part | 0.3 part |
| TiO2 | 0.01 part | 0.04 part | 0.1 part |
| Na2O | 4 parts | 5 parts | 8 parts |
| K2O | 2 parts | 5 parts | 6 parts |
| MgO | 0.05 part | 0.1 part | 0.3 part |
| CaO | 0.5 part | 1 part | 3 parts |
| Loss on ignition | 0.05 part | 0.1 part | 0.3 part |
Wherein, the component of the grain composition of easy clean protection particle, stamp-pad ink and clear frit constitutes same as Example 1.
Embodiment 7
A kind of easy clean protection tile, as different from Example 1, the component of stamp-pad ink and clear frit are constituted, and remaining is with implementing 1
It is identical.
In the present embodiment, stamp-pad ink is mainly made up of the component of following mass fraction：2 parts of sodium carboxymethylcellulose, ethylene glycol
80 parts of 35 parts, 5 parts of bentonite and water.
Clear frit is mainly made up of the component of following mass fraction：16 parts of albite, 24 parts of potassium feldspar, 10 parts of kaolin,
5 parts of 14 parts of calcined kaolin, 13 parts of quartz, 17 parts of talcum of burning, 10 parts of lime stone, 12 parts of barium carbonate and zinc oxide.
Embodiment 8
A kind of easy clean protection tile, as different from Example 1, the grain composition of easy clean protection particle, remaining is with implementing 1
It is identical.
In the present embodiment, the grain composition of easy clean protection particle is：The mesh of 80 mesh~120 is 55%, and 120~200 mesh are
30%, it is 15% below 200 mesh.
Embodiment 9
A kind of easy clean protection tile, includes green body layer, cover coat, printed layer and easy clean protection dry granule layer successively from bottom to top,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection dry granule layer in the present embodiment is same as Example 1.
In the present embodiment, base substrate aluminum content is 21%, and whiteness is 35 degree, and the moisture content of blank is 6%.Blank includes following
The raw material of mass parts：20 parts of Yichuan sand, 15 parts of Ganzhou low temperature potassium sodium sand, 18 parts of mud of Qianshan washing, 8 parts of Guangxi White mud, Ji'an are white
2.5 parts of 3 parts of mud, 31 parts of Guangchang potassium sand, 1 part of Fuzhou City's bentonite and black talc.
The grain composition of blank is：More than 20 mesh it is 1%, -20~+40 mesh are 30%, -20~+60 mesh are 72%,
It is 0 below 100 mesh, remainder is -60~+100 mesh.
In the present embodiment, cover-coat enamel is mainly prepared from by the raw material of following mass parts：25 parts of potassium feldspar, quartzy 20 parts, rosy clouds
20 parts of stone, 7 parts of calcined kaolin, 10 parts of aluminum oxide, 4 parts of wollastonite, 1 part of zinc oxide, 20 parts of zirconium silicate, column kaolin 15
Part, 0.2 part of sodium humate, 0.2 part of sodium carboxymethylcellulose and 0.15 part of sodium tripolyphosphate.
In the present embodiment, described printed layer carries out decoration stamp by ink-jet printing apparatus and obtained.
Embodiment 10
A kind of easy clean protection tile, includes green body layer, cover coat, printed layer and easy clean protection dry granule layer successively from bottom to top,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection dry granule layer in the present embodiment is same as Example 1.
In the present embodiment, base substrate aluminum content is 21%, and whiteness is 35 degree, and the moisture content of blank is 6.5%.Blank include with
The raw material of lower mass parts：30 parts of Yichuan sand, 20 parts of Ganzhou low temperature potassium sodium sand, 20 parts of mud of Qianshan washing, 10 parts of Guangxi White mud, Ji'an
White 3 parts of 5 parts of mud, 35 parts of Guangchang potassium sand, 1.5 parts of Fuzhou City's bentonite and black talc.
The grain composition of blank is：More than 20 mesh it is 0%, -20~+40 mesh are 50%, -20~+60 mesh are 88%,
It is 2% below 100 mesh, remainder is -60~+100 mesh.
In the present embodiment, cover-coat enamel is mainly prepared from by the raw material of following mass parts：30 parts of potassium feldspar, quartzy 30 parts, rosy clouds
25 parts of stone, 10 parts of calcined kaolin, 15 parts of aluminum oxide, 8 parts of wollastonite, 2 parts of zinc oxide, 30 parts of zirconium silicate, column kaolin 20
Part, 0.3 part of sodium humate, 0.3 part of sodium carboxymethylcellulose and 0.3 part of sodium tripolyphosphate.
In the present embodiment, described printed layer carries out decoration stamp by ink-jet printing apparatus and obtained.
Comparative example 1
A kind of easy clean protection tile, includes green body layer, cover coat, printed layer and easy clean protection dry granule layer successively from bottom to top,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection glaze is made up of the raw material of following mass fraction：It is easy clean
Protect 15 parts of 60 parts of particle, 220 parts of stamp-pad ink and clear frit.
Comparative example 1 as different from Example 1 it is easy clean protection glaze raw material proportioning, remaining is same as Example 1.
Comparative example 2
A kind of easy clean protection tile, includes green body layer, cover coat, printed layer and easy clean protection dry granule layer successively from bottom to top,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection glaze is made up of the raw material of following mass fraction：It is easy clean
Protect 20 parts of 90 parts of particle, 230 parts of stamp-pad ink and clear frit.Wherein, easy clean protection particle is made up of the component of following mass fraction：
SiO285 parts, Al2O310 parts, Fe2O30.08 part, TiO20.15 part, Na22 parts of O, K21 part of O, 0.02 part of MgO, CaO
0.2 part and 0.35 part of loss on ignition.
Comparative example 2 as different from Example 1 it is easy clean protection particle component proportion, remaining is same as Example 1.
Comparative example 3
Comparative example 3 as different from Example 1 match somebody with somebody by easy clean protection grains level, and remaining is same as Example 1.
In comparative example 3, the grain composition of easy clean protection particle is：The mesh of 80 mesh~120 is 30%, and 120~200 mesh are
40%, it is 30% below 200 mesh.
Comparative example 4
The difference of comparative example 4 and embodiment 1 is clear frit, and remaining is same as Example 1.
In comparative example 4, clear frit is the clear frit of the ceramic Co., Ltd's production of Huanghua City Xingda.
Comparative example 5
The difference of comparative example 5 and embodiment 1 is stamp-pad ink and clear frit, and remaining is same as Example 1.
In comparative example 5, stamp-pad ink is mainly made up of the component of following mass fraction：0.5 part of sodium carboxymethylcellulose, ethylene glycol
50 parts of 18 parts, 0.8 part of bentonite and water.
Clear frit is mainly made up of the component of following mass fraction：10 parts of albite, 18 parts of potassium feldspar, 5 parts of kaolin, forge
Burn 6 parts of kaolin, 7 parts of quartz, burn 0.5 part of 10 parts of talcum, 5 parts of lime stone, 7 parts of barium carbonate and zinc oxide.
Comparative example 6
Easy clean protection dry granule layer is replaced using existing common glaze.The formula of the common glaze is：The mass parts of ball clay 20,
The mass parts of kaolin 30, the mass parts of talcum 15, the mass parts of potassium feldspar 10 and the mass parts of quartz sand 10.
Comparative example 7
It is not provided with easy clean protection dry granule layer.
Respectively to the easy clean Ceramic Tiles in embodiment 1-10 and comparative example 1-7, cleaning property of easy-cleaning test, test result are carried out
As shown in table 1.
The performance test results of table 1
Note：According to national standard：Rule in " photocatalytic self-cleaning material performance test method (GB/T23764-2009) "
It is fixed, cleaning property of easy-cleaning test is carried out to the easy clean Ceramic Tiles in embodiment 1-10 and comparative example 1-7, wherein, A represents Ceramic Tiles table
Face unit area greasy dirt residual volume, unit is g/m2。
As shown in Table 1, the performance easy to clean of embodiment 1-10 easy clean Ceramic Tiles, hence it is evident that better than comparative example 1-7, especially
It is the easy clean Ceramic Tiles that embodiment 2 and embodiment 5 are provided, more preferably, greasy dirt residual volume is respectively 0.40g/m to the easy clean property of anti-soil2
And 0.41g/m2.Thus illustrate, the easy clean Ceramic Tiles provided using the present invention, with the good easy clean property of anti-soil and anti-pollution
Property, it is easy to daily maintenance and arranges, application value is high.
From the comparative analysis of comparative example 1-3 and embodiment 1, change the proportioning of each raw material in easy clean protection glaze, make it
Raw material proportioning is not in the scope of protection of the invention；Or change the component composition of easy clean protection particle；Or change easy clean protect
The grain composition of particle is protected, the effect above can not be realized, its performance easy to clean is poor.Comparative example 1 and comparative example 2 also enter one
Step illustrates that the easy clean protection glaze in the present invention and each raw material mutual cooperation in easy clean protection particle are acted on, in the present invention
Under the proportioning of restriction, the easy clean property of anti-soil of Ceramic Tiles more preferably, can more meet the demand in market.
From the comparative analysis of comparative example 4-5 and embodiment 1, the stamp-pad ink and clear frit limited using the present invention, energy
It is enough to be cooperated with above-mentioned easy clean protection glaze, the easy clean property of anti-soil of easy clean protection stratum granulosum is further improved, using effect is more preferable.
From the comparative analysis of comparative example 6-7 and embodiment 1, the easy clean protection dry granule layer that the present invention is provided is set
On the surface of Ceramic Tiles, the easy clean property of anti-soil of Ceramic Tiles can be significantly improved, its performance easy to clean will be substantially better than existing general
Logical Ceramic Tiles.In addition, the easy clean Ceramic Tiles that the present invention is provided also have higher glossiness, solid layer feeling is strong, and definition is good,
The high advantage of surface transparency.
Finally it should be noted that：Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations；To the greatest extent
The present invention is described in detail with reference to foregoing embodiments for pipe, it will be understood by those within the art that：Its according to
The technical scheme described in foregoing embodiments can so be modified, or which part or all technical characteristic are entered
Row equivalent substitution；And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology
The scope of scheme.
Claims (10)
1. a kind of easy clean Ceramic Tiles, it is characterised in that the easy clean Ceramic Tiles include successively from bottom to top green body layer, cover coat,
Printed layer and easy clean protection dry granule layer, the easy clean protection dry granule layer are formed by the easy clean protection glaze of charity；
The easy clean protection glaze includes the component of following mass fraction：Easy clean 90~110 parts of particle of protection, 230~270 parts of stamp-pad ink
With 20~40 parts of clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~0.3 part, TiO20.01~0.1 part, Na24~8 parts of O,
K20.05~0.3 part of 2~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and loss on ignition.
2. easy clean Ceramic Tiles according to claim 1, it is characterised in that the easy clean protection glaze includes following mass fraction
Component：22~38 parts of easy clean 92~108 parts of particle of protection, 240~260 parts of stamp-pad ink and clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO265~68 parts, Al2O318~22 parts, Fe2O30.12~0.22 part, TiO20.02~0.08 part, Na2O 5~7
Part, K20.1~0.2 part of 3~5 parts of O, 0.1~0.2 part of MgO, 1~2 part of CaO and loss on ignition.
3. easy clean Ceramic Tiles according to claim 1, it is characterised in that the easy clean protection glaze includes following mass fraction
Component：28~32 parts of easy clean 95~105 parts of particle of protection, 245~250 parts of stamp-pad ink and clear frit；
Wherein, the easy clean protection particle is mainly made up of the component of following mass fraction：
SiO266~67 parts, Al2O320~21 parts, Fe2O30.15~0.2 part, TiO20.04~0.07 part, Na2O 5.5~
6.5 parts, K20.14~0.18 part of 4~4.8 parts of O, 0.12~0.15 part of MgO, 1.5~1.8 parts of CaO and loss on ignition.
4. the easy clean Ceramic Tiles according to any one of claims 1 to 3, it is characterised in that the stamp-pad ink is main by following matter
The component for measuring number is constituted：1~2 part of sodium carboxymethylcellulose, 20~40 parts of ethylene glycol, 1~5 part of bentonite and water 60~80
Part.
5. the easy clean Ceramic Tiles according to any one of claims 1 to 3, it is characterised in that the clear frit is main by following
The component of mass fraction is constituted：
12~16 parts of albite, 20~24 parts of potassium feldspar, 6~10 parts of kaolin, 10~14 parts of calcined kaolin, quartz 10~14
1~5 part of part, 13~17 parts of talcum of burning, 7~11 parts of lime stone, 8~12 parts of barium carbonate and zinc oxide.
6. the easy clean Ceramic Tiles according to any one of claims 1 to 3, it is characterised in that the proportion of the easy clean protection glaze
For 1.2~1.5g/cm3。
7. the easy clean Ceramic Tiles according to any one of claims 1 to 3, it is characterised in that of the easy clean protection particle
Grade is matched somebody with somebody：The mesh of 80 mesh~120 is 50%~60%, and 120~200 mesh are 20%~30%, and remaining is below 200 mesh.
8. easy clean Ceramic Tiles according to claim 1, it is characterised in that the green body layer is the base substrate with convex-concave surface
Layer.
9. easy clean Ceramic Tiles according to claim 1, it is characterised in that the cover coat is mainly prepared from by cover-coat enamel,
The cover-coat enamel is mainly prepared from by the raw material of following mass parts：
20~30 parts of potassium feldspar, quartz 15~30 parts, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, 5~15 parts of aluminum oxide,
1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, 10~20 parts of column kaolin, sodium humate 0.1~
0.1~0.3 part of 0.3 part, 0.1~0.3 part of sodium carboxymethylcellulose and sodium tripolyphosphate.
10. easy clean Ceramic Tiles according to claim 1, it is characterised in that the printed layer includes one or multi-channel web plate
Stamp, one or multi-channel roller printing and it is one or both of ink-jet printed more than combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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| CN108793960A (en) * | 2018-08-23 | 2018-11-13 | 广西亚欧瓷业有限公司 | A kind of preparation method of wear-resistant ceramic brick capable of releasing negative ion |
| CN109095910A (en) * | 2018-08-31 | 2018-12-28 | 湖北省当阳豪山建材有限公司 | Anion environmental protection self-cleaning ceramic tile and preparation method thereof |
| WO2019015237A1 (en) * | 2017-07-21 | 2019-01-24 | 广东金意陶陶瓷集团有限公司 | Anti-slip wear-resistant glaze, anti-slip wear-resistant easy-clean ceramic tile, and preparation method therefor |
| US10475264B2 (en) | 2017-08-14 | 2019-11-12 | Q & K International Group Limited | Application method of Bluetooth low-energy electronic lock based on built-in offline pairing passwords, interactive unlocking method of a Bluetooth electronic lock and electronic lock system |
| CN111333433A (en) * | 2020-05-19 | 2020-06-26 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance far-infrared ceramic glazed brick and preparation method thereof |
| CN115626775A (en) * | 2022-10-20 | 2023-01-20 | 新明珠集团股份有限公司 | Quick-drying printing fancy glaze, preparation method thereof and ceramic tile |
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| WO2019015237A1 (en) * | 2017-07-21 | 2019-01-24 | 广东金意陶陶瓷集团有限公司 | Anti-slip wear-resistant glaze, anti-slip wear-resistant easy-clean ceramic tile, and preparation method therefor |
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| CN109095910A (en) * | 2018-08-31 | 2018-12-28 | 湖北省当阳豪山建材有限公司 | Anion environmental protection self-cleaning ceramic tile and preparation method thereof |
| CN111333433A (en) * | 2020-05-19 | 2020-06-26 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance far-infrared ceramic glazed brick and preparation method thereof |
| WO2021232784A1 (en) * | 2020-05-19 | 2021-11-25 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance far-infrared ceramic polished glazed tile and preparation method therefor |
| CN115626775A (en) * | 2022-10-20 | 2023-01-20 | 新明珠集团股份有限公司 | Quick-drying printing fancy glaze, preparation method thereof and ceramic tile |
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