CN112876077B - Protective glaze for matte antique brick, antique brick and preparation method of protective glaze - Google Patents
Protective glaze for matte antique brick, antique brick and preparation method of protective glaze Download PDFInfo
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- CN112876077B CN112876077B CN202110246386.4A CN202110246386A CN112876077B CN 112876077 B CN112876077 B CN 112876077B CN 202110246386 A CN202110246386 A CN 202110246386A CN 112876077 B CN112876077 B CN 112876077B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a protective glaze for a matte antique brick, the antique brick and a preparation method thereof, wherein the protective glaze comprises the following raw materials in parts by weight: 30-45 parts of potash feldspar, 10-20 parts of quartz, 12-20 parts of nepheline, 5-10 parts of air knife soil, 7-15 parts of calcined kaolin, 15-20 parts of alumina powder, 1-3 parts of calcined talc, 10-20 parts of zirconium silicate, 0.12-0.4 part of methyl cellulose, 0.2-0.6 part of sodium tripolyphosphate and 38-50 parts of water. The protective glaze for the matte antique brick adopts conventional raw materials in the field, and solves the problem of 'lattice printing at the bottom of the matte antique brick' by optimizing and improving the formula of the protective glaze.
Description
Technical Field
The invention relates to the field of ceramic tile preparation, and mainly relates to a protective glaze for a matte antique brick, the antique brick and a preparation method of the protective glaze and the antique brick.
Background
The archaized tile is one of glazed ceramic tiles, the embryo body is stoneware (water absorption rate is about 3%) or stoneware (water absorption rate is about 8%), and is used for building walls and floors. The brick bottom check mark refers to a production defect that when the brick bottom and the brick surface are stacked in the production process, storage, transportation and construction process of the ceramic wall and floor brick, the brick bottom grain with the brick bottom slurry powder is printed on the brick surface and is difficult to erase, so that the visual and beautiful effect of the brick surface is influenced. The 'lattice mark at the bottom of the tile' is very common in the production process of the glazed tile for a long time, and is very easy to 'regenerate' even in storage, thereby seriously affecting the quality of the glazed tile. The same problem also exists with archaized tiles as one type of glazed tile. If the glazed tile in the warehouse has the 'brick bottom check mark', the glazed tile can only be unpacked, and the glazed tile is cleaned one tile by one tile with Tianna water, which is time-consuming and labor-consuming, and the Tianna water has health hazard to constructors. In order to overcome the 'brick bottom lattice mark', the common practice in the industry at present is to glue, place separation paper, paste a diaphragm and the like on the brick surface to isolate the brick bottom from contacting with the brick surface. Although this method is effective, it is labor and material consuming and is not solved from the essential source of the glaze layer.
Accordingly, the prior art is yet to be improved and developed.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide a protective glaze for a matte antique brick, the antique brick and a preparation method thereof, and aims to solve the problem that the glaze surface can generate 'lattice marks at the bottom of the brick' when the existing antique brick is stacked.
The technical scheme of the invention is as follows:
a protective glaze for a matte antique brick comprises the following raw materials in parts by weight:
30-40 parts of potash feldspar, 3-6 parts of calcite, 6-9 parts of calcined talc, 30-40 parts of quartz, 5-10 parts of barium carbonate, 10-12 parts of alumina powder, 5-10 parts of air knife soil, 2-6 parts of zinc oxide, 0.6-1.0 part of methyl cellulose, 0.6-0.8 part of sodium tripolyphosphate and 50-80 parts of water.
The preparation method of the protective glaze for the matte antique brick comprises the following steps:
ball-milling the raw materials until the fineness is controlled to be 325 meshes, the screen residue is 0.1-0.3%, and the specific gravity is controlled to be 1.25-1.4 g/mL; sieving with 200 mesh sieve, and removing iron.
The matte archaized brick comprises a green brick, a cover glaze and a protective glaze from bottom to top in sequence; the protective glaze is the protective glaze for the matte antique brick.
The matte archaized brick comprises the following raw materials in parts by weight:
30-45 parts of potash feldspar, 10-20 parts of quartz, 12-20 parts of nepheline, 5-10 parts of air knife soil, 7-15 parts of calcined kaolin, 15-20 parts of alumina powder, 1-3 parts of calcined talc, 10-20 parts of zirconium silicate, 0.12-0.4 part of methyl cellulose, 0.2-0.6 part of sodium tripolyphosphate and 38-50 parts of water.
The preparation method of the matte antique brick comprises the following steps:
pressing green bricks;
drying;
spraying water on the glaze surface;
applying surface glaze:
ink-jet printing;
applying a protective glaze:
firing;
and (6) edging.
The preparation method of the matte antique brick comprises the step of glazing the protective glaze by using a spray gun glaze spraying method.
The preparation method of the matte antique brick comprises the step of glazing the overglaze by adopting a bell jar glaze spraying method.
The preparation method of the matte antique brick comprises the following steps:
ball-milling the raw materials until the fineness is controlled to be 325 meshes, the screen residue is 0.1-0.3%, and the specific gravity is controlled to be 1.25-1.4 g/mL; sieving with 200 mesh sieve, and removing iron.
The preparation method of the matte antique brick comprises the following steps:
ball-milling the raw materials until the fineness is controlled to be 325 meshes, the residue on sieve is 0.4-0.8%, the specific gravity is controlled to be 1.85-1.95 g/mL, the flow rate is 26-35 seconds, and the glaze slurry is aged for 24 hours; sieving with 200 mesh sieve, and removing iron.
The preparation method of the matte antique brick comprises the steps of controlling the glazing amount of the protective glaze to be 100-150 g/600 x 600 brick, and controlling the glazing amount of the overglaze to be 180-250 g/600 x 600 brick.
Has the advantages that: the protective glaze for the matte antique brick is suitable for the antique brick with the luminosity of 30-50 degrees, and the protective glaze is adopted on the surface of the antique brick, so that the phenomenon that the glaze surface of the antique brick has 'brick bottom lattice marks' can be avoided even if the contact between the brick bottom and the brick surface is not isolated.
Detailed Description
The invention provides a protective glaze for a matte antique brick, the antique brick and a preparation method thereof, and the invention is further explained in detail below in order to make the purpose, technical scheme and effect of the invention clearer and clearer. It should be understood that the specific embodiments described herein are merely illustrative of the invention and do not limit the invention.
A ceramic brick with low water absorption rate belongs to a vitrified brick, a ceramic blank inevitably generates liquid phase under the condition of high-temperature calcination, a layer of high-temperature-resistant brick bottom powder, namely magnesium powder, is coated on the brick bottom to prevent a blank body liquid phase from being bonded with a kiln roller rod, the magnesium powder is changed into magnesium oxide (MgO) after high-temperature calcination, and the magnesium oxide attached to the brick bottom absorbs moisture in the air to generate magnesium hydroxide Mg (OH)2The glaze layer of the glazed tile stacked together is corroded due to strong alkalinity; on the other hand, the glaze layer has a plurality of dense small pores to absorb magnesium powder after being calcined, so that 'brick bottom lattice imprint' is formed.
The invention aims to radically prevent the production of 'brick bottom lattice mark' by researching the mechanism of 'brick bottom lattice mark' and starting from the formula of the glaze layer and debugging the alkali-resistant and efficient glaze layer. A large amount of quartz components are introduced into the formula of the protective glaze, so that a compact glass phase is fully formed under high-temperature calcination, the glass phase has strong transparency and good corrosion resistance, and the generation of 'brick bottom lattice marks' is avoided when bricks are stacked mutually. The protective glaze for the matte antique brick is only suitable for the antique brick with the luminosity of 30-50 degrees, and the protective glaze is adopted on the surface of the antique brick, so that the phenomenon that the glaze surface of the antique brick has 'brick bottom lattice marks' can be avoided even if the contact between the brick bottom and the brick surface is not isolated.
The protective glaze for the matte antique brick is a transparent thin glaze layer with high alkali resistance and high compactness, and has a protective effect on the brick surface. Specifically, the protective glaze for the matte archaized brick comprises the following raw materials in parts by weight:
30-40 parts of potash feldspar, 3-6 parts of calcite, 6-9 parts of calcined talc, 30-40 parts of quartz, 5-10 parts of barium carbonate, 10-12 parts of alumina powder, 5-10 parts of air knife soil, 2-6 parts of zinc oxide, 0.6-1.0 part of methyl cellulose, 0.6-0.8 part of sodium tripolyphosphate and 50-80 parts of water.
The invention also provides a preparation method of the protective glaze for the matte antique brick, which comprises the following steps:
ball-milling the raw materials until the fineness is controlled to be 325 meshes, controlling the screen residue to be 0.1-0.3% and the specific gravity to be 1.25-1.4 g/mL, sieving the raw materials by a 200-mesh sieve, and removing iron in an enhanced manner.
The protective glaze for the matte antique brick adopts conventional raw materials in the field, and solves the problem of 'lattice printing at the bottom of the matte antique brick' by optimizing and improving the formula of the protective glaze. By introducing a large amount of quartz components, the quartz components can form a compact glass phase after being mixed with other raw materials and calcined at high temperature, so that the magnesium powder at the bottom of the brick is prevented from being adsorbed on the surface of the brick. In addition, the protective glaze has low specific gravity, small glazing amount, simple process flow, simple operation and low cost. After the product is covered with the protective glaze for the matte antique brick, the advantages are as follows:
the glaze layer is compact, has few pores and good antifouling performance, reduces the adsorption of the glaze layer on dust or magnesium powder at the bottom of a brick, and has the antifouling performance reaching grade 5;
secondly, the acid and alkali resistance is obviously improved, and the corrosion resistance of alkali-resistant substances is improved;
the wear resistance of the glaze layer is improved and can reach more than 4 grades;
fourthly, the color development ability is improved, the color is bright and the sense of transparency is strong.
The invention also provides a matte archaized brick which sequentially comprises a green brick, a cover glaze and a protective glaze from bottom to top; the protective glaze is the protective glaze for the matte antique brick.
Further, the invention also provides a preferable overglaze formula, wherein the overglaze is an overglaze with high expansion coefficient, and can stabilize pattern texture and color and control the smoothness of brick surfaces. The matte archaized brick with high pattern definition and rich color and pattern effect can be obtained by matching the protective glaze for the matte archaized brick.
Specifically, the overglaze comprises the following raw materials in parts by weight:
30-45 parts of potash feldspar, 10-20 parts of quartz, 12-20 parts of nepheline, 5-10 parts of air knife soil, 7-15 parts of calcined kaolin, 15-20 parts of alumina powder, 1-3 parts of calcined talc, 10-20 parts of zirconium silicate, 0.12-0.4 part of methyl cellulose, 0.2-0.6 part of sodium tripolyphosphate and 38-50 parts of water.
The preparation process of the overglaze comprises the steps of ball-milling raw materials until the fineness is controlled to be 325 meshes, controlling the screen residue to be 0.4-0.8%, controlling the specific gravity to be 1.85-1.95 g/mL, controlling the flow rate to be 26-35 seconds, and ageing the glaze slurry for 24 hours; sieving with 200 mesh sieve, and removing iron.
The invention also provides a preparation method of the matte archaized brick, which comprises the following steps:
pressing the green bricks by a press;
drying in a drying kiln;
spraying water on the glaze line;
applying surface glaze: the glazing mode of the overglaze can adopt a conventional bell jar glaze spraying method, the overglaze is applied to the surface of the green brick, and the glazing amount of the overglaze is controlled to be 180-250 g/600 × 600 brick;
ink jet printing by an ink jet machine;
applying a protective glaze: the glaze applying mode of the protective glaze can adopt a spray gun glaze spraying method, and the protective glaze is applied to the brick blank after ink jet patterning, and the glaze applying amount of the protective glaze is controlled to be 100-150 g/600 x 600 brick;
firing;
edging;
and (5) packaging in a grading manner and warehousing.
The above steps are conventional technical means in the art except for applying the cover glaze and applying the protective glaze, and are not described herein again.
The present invention is further illustrated by the following specific examples.
Example 1
The preparation process of the archaized brick comprises the following steps:
pressing the green bricks by a press; drying in a drying kiln; spraying water by using a glaze line; applying a surface glaze; ink jet printing by an ink jet machine; applying a protective glaze; firing; edging; and (5) packaging in a grading manner and warehousing.
The overglaze comprises the following raw materials in parts by weight:
potassium feldspar: 35 parts, quartz: 10 parts, nepheline: 18 parts of air knife soil: 7 parts of calcined kaolin: 10 parts of alumina powder: 16 parts, calcined talc: 2 parts, zirconium silicate: 15 parts, methylcellulose: 0.35 part, sodium tripolyphosphate: 0.5 part, water: 38 parts of the raw materials.
3 tons of the overglaze formula are mixed, put into balls and ball-milled until the fineness is 325 meshes, the screen residue is 0.6 percent, the specific gravity of the ball-out glaze slurry is controlled to be 1.9 g/mL-1.95 g/mL, and the flow rate is controlled to be 40 +/-5 seconds; the glaze slip is aged for 24 hours for standby; sieving with 200 mesh sieve before use, and removing iron. The overglaze is sprayed on the biscuit by adopting a bell jar glaze spraying method, and the glaze spraying amount of each 600 x 600 brick blank is controlled to be 220 +/-2 g.
The protective glaze comprises the following raw materials in parts by weight:
potassium feldspar: 30 parts, 6 parts of calcite, and 6 parts of calcined talc: 9 parts, quartz: 35 parts, barium carbonate: 7 parts of alumina powder: 10 parts, 7 parts of air knife soil, zinc oxide: 4 parts, methylcellulose: 0.6 part, sodium tripolyphosphate: 0.6 part, water: 60 parts.
500 kg of materials are mixed according to the formula of the protective glaze, and are ball-milled until the fineness is 325 meshes, the screen residue is 0.15 percent, and the specific gravity is controlled between 1.3g/mL and 1.35 g/mL. The protective glaze is sprayed on the green brick with the ink-jet pattern by a spray gun glaze spraying method, and each 600 x 600 brick is sprayed with 120 +/-2 g.
Example 2
The preparation process of the archaized brick comprises the following steps:
pressing the green bricks by a press; drying in a drying kiln; spraying water on the glaze line; applying a surface glaze; ink jet printing by an ink jet machine; applying a protective glaze; firing; edging; and (5) packaging in a grading manner and warehousing.
The overglaze comprises the following raw materials in parts by weight:
potassium feldspar: 40 parts, quartz: 12 parts, nepheline: 15 parts, air knife soil: 7 parts of calcined kaolin: 15 parts of alumina powder: 12 parts, calcined talc: 1.0 part, zirconium silicate: 15 parts, methylcellulose: 0.3 part, sodium tripolyphosphate: 0.5 part, water: 38 parts of the raw materials.
3 tons of the overglaze formula are mixed, put into balls, ball-milled to the fineness of 325 meshes, the screen residue is 0.6 percent, the specific gravity of the ball-out glaze slurry is controlled to be 1.9-1.95 g/ml, the flow rate is 38-42 seconds, and the ball-out glaze slurry is sieved by a 200-mesh sieve; removing iron, and putting into a glaze jar for aging for 24 hours. The overglaze is sprayed on the biscuit by adopting a bell jar glaze spraying method, and the glaze spraying amount of each 600 x 600 brick blank is controlled to be 220 +/-2 g.
The protective glaze comprises the following raw materials in parts by weight:
potassium feldspar: 35 parts of dendrobe, 5 parts of baked talc: 8 parts of quartz: 40 parts, barium carbonate: 7 parts of alumina powder: 10 parts, 7 parts of air knife soil, zinc oxide: 5 parts, methylcellulose: 0.6 part, sodium tripolyphosphate: 0.7 part, water: 60 parts.
500 kg of materials are mixed according to the formula of the protective glaze, and are ball-milled until the fineness is 325 meshes, the screen residue is 0.2 percent, and the specific gravity is controlled between 1.28g/ml plus or minus 0.02 g/ml. The protective glaze is sprayed on the green brick with the ink-jet pattern by a spray gun glaze spraying method, and each 600 x 600 brick is sprayed with 120 +/-2 g.
The production flow and the production process parameters of the embodiment 1 and the embodiment 2 are the same except that the overglaze and the protective glaze are applied. The glazed tile produced by the two schemes has 5 degrees of glossiness higher than that of the glazed tile produced by the embodiment 1, other performances are close, and the performance test results are shown in the table 1.
TABLE 1
| Detection methods or standards | Example 1 | Example 2 | |
| Check mark prevention | Taking 50 600 ceramic tiles, stacking the tile bottom and the tile surface in sequence, and placing 3 ceramic tiles at normal temperature After the month, the brick surface was inspected | The surface of each tile is kept smooth and clean, and each tile surface is smooth and clean Lattice stamp | The surface of each tile is kept smooth and clean, and each tile surface is smooth and clean Grid print without lifting |
| Antifouling property | GB/T3810.14-2016 ceramic tile test method part 14: contamination resistance Determination of sex | Grade 5 | Grade 5 |
| Wear resistance | GB/T3810.14-2016 ceramic tile test method part 7: glazed brick surface Determination of surface abrasion resistance | 4 stage | 4 stage |
| Chemical corrosion resistance Corrosion property | GB/T3810.14-2016 ceramic tile test method part 14: resistance to chemical change Determination of chemical Corrosion | Class A | Class A |
It is to be understood that the invention is not limited to the examples described above, but that modifications and variations may be effected thereto by those of ordinary skill in the art in light of the foregoing description, and that all such modifications and variations are intended to be within the scope of the invention as defined by the appended claims.
Claims (6)
1. The preparation method of the matte antique brick is characterized in that the matte antique brick sequentially comprises a brick blank, a surface glaze and a protective glaze from bottom to top;
the protective glaze comprises the following raw materials in parts by weight:
30-40 parts of potash feldspar, 3-6 parts of calcite, 6-9 parts of calcined talc, 30-40 parts of quartz, 5-10 parts of barium carbonate, 10-12 parts of alumina powder, 5-10 parts of air knife soil, 2-6 parts of zinc oxide, 0.6-1.0 part of methyl cellulose, 0.6-0.8 part of sodium tripolyphosphate and 50-80 parts of water;
the preparation method of the protective glaze comprises the steps of ball-milling raw materials until the fineness is controlled to be 325 meshes, the screen residue is 0.1-0.3%, and the specific gravity is controlled to be 1.25-1.4 g/mL; sieving with 200 mesh sieve, and removing iron;
the overglaze comprises the following raw materials in parts by weight:
30-45 parts of potash feldspar, 10-20 parts of quartz, 12-20 parts of nepheline, 5-10 parts of air knife soil, 7-15 parts of calcined kaolin, 15-20 parts of alumina powder, 1-3 parts of calcined talc, 10-20 parts of zirconium silicate, 0.12-0.4 part of methyl cellulose, 0.2-0.6 part of sodium tripolyphosphate and 38-50 parts of water;
the preparation method of the matte antique brick comprises the following steps:
pressing green bricks;
drying;
spraying water on the glaze surface;
applying a surface glaze;
ink-jet printing;
applying a protective glaze;
firing;
and (6) edging.
2. The method for preparing the matte antique brick according to claim 1, wherein the protective glaze is applied by a spray gun glaze spraying method.
3. The method for preparing the matte antique brick according to claim 2, wherein the overglaze is applied by a bell jar glaze spraying method.
4. The process for preparing the matte archaized brick according to claim 2, wherein the process for preparing the protective glaze comprises the following steps:
ball-milling the raw materials until the fineness is controlled to be 325 meshes, the screen residue is 0.1-0.3%, and the specific gravity is controlled to be 1.25-1.4 g/mL; sieving with 200 mesh sieve, and removing iron.
5. The method for preparing the matte antique brick according to claim 2, wherein the overglaze comprises the following steps:
ball-milling the raw materials until the fineness is controlled to be 325 meshes, the residue on sieve is 0.4-0.8%, the specific gravity is controlled to be 1.85-1.95 g/mL, the flow rate is 26-35 seconds, and the glaze slurry is aged for 24 hours; sieving with 200 mesh sieve, and removing iron.
6. The method for preparing the matte antique brick according to claim 1, wherein the glazing amount of the protective glaze is controlled to be 100-150 g/600 x 600 brick piece, and the glazing amount of the overglaze is controlled to be 180-250 g/600 x 600 brick piece.
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| CN110482859A (en) * | 2019-09-17 | 2019-11-22 | 广东新润成陶瓷有限公司 | A kind of starlight glaze Ceramic Tiles and preparation method thereof |
| CN110550958A (en) * | 2019-09-17 | 2019-12-10 | 广东新润成陶瓷有限公司 | Fine, soft and matte black brick and preparation method thereof |
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