CN109354413B - Dry-grain glaze ceramic tile and preparation method thereof - Google Patents

Dry-grain glaze ceramic tile and preparation method thereof Download PDF

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Publication number
CN109354413B
CN109354413B CN201811514807.1A CN201811514807A CN109354413B CN 109354413 B CN109354413 B CN 109354413B CN 201811514807 A CN201811514807 A CN 201811514807A CN 109354413 B CN109354413 B CN 109354413B
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parts
dry
glaze
ceramic tile
overglaze
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CN109354413A (en
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陈柏铨
陈建薇
杨华平
杨新文
邓光万
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Taizhou jinzai Intellectual Property Service Co.,Ltd.
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Taizhou Jinzai Intellectual Property Service Co ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

Abstract

The invention discloses a dry grain glaze ceramic tile and a preparation method thereof, wherein the dry grain glaze ceramic tile comprises a ceramic blank body, and overglaze and dry grain glaze are sequentially applied on the ceramic blank body, and the preparation method comprises the following steps of (1) spraying water on the dried ceramic blank body to a wet state with the surface water content of 5-10%, and then applying overglaze; (2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns; (3) calcining the ceramic tile for 1 hour at high temperature in a kiln to obtain the dry-grain glaze ceramic tile, wherein the calcining temperature is 1100-1190 ℃. The application provides a brand-new overglaze and dry particle glaze formula, and the formula is matched with a production process different from the prior art, so that the dry particle glaze ceramic tile with excellent performance can be prepared, the obtained dry particle glaze ceramic tile has good anti-slip performance, the water absorption rate is 0.03-0.08%, the wear resistance reaches 4-5 grades, and the pollution resistance reaches 4-5 grades. The preparation process of the dry grain glaze ceramic tile is simple and easy to operate, the obtained product has excellent performance, the material consumption and energy consumption are easy to control, and the pollution to the environment is effectively reduced.

Description

Dry-grain glaze ceramic tile and preparation method thereof
Technical Field
The invention relates to the technical field of ceramic tile preparation, in particular to a dry grain glazed ceramic tile and a preparation method thereof.
Background
The dry glazed ceramic tile is a new decorative ceramic tile product produced and researched by rubber roll printing technology, and has the advantages of skid resistance, wear resistance, pollution resistance and the like, so that the dry glazed ceramic tile is widely applied. In the prior art, the preparation of dry glazed ceramic tiles generally adopts the traditional dry particle machine material distribution or high-pressure spray cabinet, particle spraying and other modes, and the preparation mode has the disadvantages of complicated manufacture, huge material consumption and energy consumption and serious pollution.
Accordingly, the prior art is in need of improvement and development.
Disclosure of Invention
The invention aims to provide a dry grain glaze ceramic tile and a preparation method thereof, and aims to solve the technical problems of complex preparation, huge material consumption and energy consumption and serious pollution of the existing preparation method of the dry grain glaze ceramic tile.
The technical scheme of the invention is as follows:
a dry grain glaze ceramic tile comprises a ceramic blank body, wherein overglaze and dry grain glaze are sequentially applied on the ceramic blank body; the overglaze is prepared from the following raw materials in parts by weight: 8-15 parts of frit, 35-38 parts of feldspar, 5-18 parts of calcite, 10-13 parts of spodumene, 7 parts of washing kaolin, 8-12 parts of calcined soil, 10-12 parts of aluminum oxide, 6 parts of barium carbonate, 2 parts of zinc oxide, 6-8 parts of zirconium silicate, 1-1.5 parts of sodium tripolyphosphate and 0.2 part of methyl cellulose; the dry granular glaze is prepared from the following raw materials in parts by weight: 8-10 parts of calcite, 7-10 parts of quartz, 20-22 parts of calcined soil, 2-7 parts of washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 4-7 parts of talc particles, 4 parts of zinc oxide, 14 parts of clinker, 4-5 parts of spodumene and 0-3 parts of calcium phosphate.
The dry particle glaze ceramic tile is characterized in that the calcined soil is calcined pottery clay or calcined kaolin.
The dry-grain glazed ceramic tile is characterized in that the frit is any one of transparent frit glaze, milky-white frit glaze, lead-containing frit glaze and lead-free frit glaze.
The dry particle glaze ceramic tile is characterized in that the fineness of the overglaze is 325-400 meshes.
The dry grain glaze ceramic tile is characterized in that the fineness of the dry grain glaze is 300-400 meshes.
A preparation method of a dry grain glaze ceramic tile comprises the following preparation steps:
(1) firstly, spraying water on the dried ceramic blank until the surface of the ceramic blank is in a wet state with the water content of 5-10%, and then applying overglaze;
(2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns;
(3) calcining the ceramic tile for 1 hour at high temperature in a kiln to obtain the dry-grain glaze ceramic tile, wherein the calcining temperature is 1100-1190 ℃.
The preparation method of the dry grain glaze ceramic tile comprises the following steps: adding the raw materials into a ball mill according to parts, adding water with the weight of 0.35-0.5 time of the total weight of the raw materials, performing ball milling until the fineness is 325-400 meshes, preparing an overglaze, and aging for more than 24 hours for later use.
The preparation method of the dry grain glaze ceramic tile comprises the following steps: adding the raw materials into a ball mill according to parts, adding printing oil which is 0.3-0.5 time of the total weight, and carrying out ball milling until the fineness of glaze slip is 300-400 meshes to obtain dry granular glaze.
Has the advantages that: the application provides a brand-new overglaze and dry particle glaze formula, and the formula is matched with a production process different from the prior art, so that the dry particle glaze ceramic tile with excellent performance can be prepared, the obtained dry particle glaze ceramic tile has good anti-slip performance, the water absorption rate is 0.03-0.08%, the wear resistance reaches 4-5 grades, and the pollution resistance reaches 4-5 grades. The preparation process of the dry grain glaze ceramic tile is simple and easy to operate, the obtained product has excellent performance, the material consumption and energy consumption are easy to control, and the pollution to the environment is effectively reduced.
Detailed Description
In order to make the objects, technical solutions and effects of the present invention more clear, the present invention is described in further detail below.
Example 1
A dry grain glaze ceramic tile comprises a ceramic blank body, wherein a surface glaze and a dry grain glaze are sequentially applied on the ceramic blank body.
A preparation method of a dry grain glaze ceramic tile comprises the following steps of (1) spraying water on a dried ceramic blank to a wet state with the surface water content of 5-10%, and applying overglaze; (2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns; (3) calcining the mixture for 1 hour in a kiln at a high temperature of 1190 ℃ to obtain the dry-grain glazed ceramic tile.
The ceramic body is a common ceramic glaze body, and the cover glaze can be applied by a bell jar type glaze spraying device in the prior art.
The overglaze is prepared from the following raw materials in parts by weight: 8 parts of opal fritted glaze, 35 parts of feldspar, 5 parts of calcite, 10 parts of spodumene, 7 parts of washed kaolin, 8 parts of calcined kaolin, 10 parts of alumina, 6 parts of barium carbonate, 2 parts of zinc oxide, 6 parts of zirconium silicate, 1 part of sodium tripolyphosphate and 0.2 part of methyl cellulose. The preparation method of the overglaze comprises the following steps: adding the raw materials in the overglaze into a ball mill according to parts, adding water with the weight being 0.35 time of the total weight of the raw materials, carrying out ball milling until the fineness is 325 meshes, thus obtaining the overglaze, and ageing for 26 hours for later use.
The dry granular glaze is prepared from the following raw materials in parts by weight: 8 parts of calcite, 7 parts of quartz, 20 parts of calcined argil, 2 parts of washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 4 parts of talc particles, 4 parts of zinc oxide, 14 parts of transparent fritted glaze and 4 parts of spodumene. The preparation method of the dry granular glaze comprises the following steps: adding the raw materials of the dry granular glaze into a ball mill according to parts, adding printing oil which is 0.4 time of the total weight, and carrying out ball milling until the fineness of glaze slurry is 350 meshes to obtain the dry granular glaze.
Example 2
A preparation method of a dry grain glaze ceramic tile comprises the following preparation steps:
(1) firstly, spraying water on the dried ceramic blank until the surface of the ceramic blank is in a wet state with the water content of 5-10%, and then applying overglaze; (2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns; (3) calcining the mixture for 1 hour in a kiln at a high temperature of 1190 ℃ to obtain the dry-grain glazed ceramic tile.
The ceramic body is a common ceramic glaze body, and the cover glaze can be applied by a bell jar type glaze spraying device in the prior art.
The overglaze is prepared from the following raw materials in parts by weight: the overglaze is prepared from the following raw materials in parts by weight: 15 parts of opal fritted glaze, 38 parts of feldspar, 18 parts of calcite, 13 parts of spodumene, 7 parts of washed kaolin, 12 parts of calcined kaolin, 12 parts of alumina, 6 parts of barium carbonate, 2 parts of zinc oxide, 8 parts of zirconium silicate, 1.5 parts of sodium tripolyphosphate and 0.2 part of methyl cellulose. The preparation method of the overglaze comprises the following steps: adding the raw materials in the overglaze into a ball mill according to parts, adding water with the weight being 0.35 time of the total weight of the raw materials, carrying out ball milling until the fineness is 325 meshes, thus obtaining the overglaze, and ageing for 26 hours for later use.
The dry granular glaze is prepared from the following raw materials in parts by weight: the dry granular glaze is prepared from the following raw materials in parts by weight: 10 parts of calcite, 10 parts of quartz, 22 parts of calcined argil, 7 parts of water-washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 7 parts of talc particles, 4 parts of zinc oxide, 14 parts of transparent fritted glaze and 5 parts of spodumene. The preparation method of the dry granular glaze comprises the following steps: adding the raw materials of the dry granular glaze into a ball mill according to parts, adding printing oil which is 0.4 time of the total weight, and carrying out ball milling until the fineness of glaze slurry is 350 meshes to obtain the dry granular glaze.
Example 3
A preparation method of a dry grain glaze ceramic tile comprises the following preparation steps:
(1) firstly, spraying water on the dried ceramic blank until the surface of the ceramic blank is in a wet state with the water content of 5-10%, and then applying overglaze; (2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns; (3) calcining the mixture for 1 hour in a kiln at a high temperature of 1190 ℃ to obtain the dry-grain glazed ceramic tile.
The ceramic body is a common ceramic glaze body, and the cover glaze can be applied by a bell jar type glaze spraying device in the prior art.
The overglaze is prepared from the following raw materials in parts by weight: 12 parts of clinker, 36 parts of feldspar, 15 parts of calcite, 12 parts of spodumene, 7 parts of washed kaolin, 10 parts of calcined soil, 11 parts of alumina, 6 parts of barium carbonate, 2 parts of zinc oxide, 7 parts of zirconium silicate, 1.5 parts of sodium tripolyphosphate and 0.2 part of methyl cellulose. The preparation method of the overglaze comprises the following steps: adding the raw materials in the overglaze into a ball mill according to parts, adding water with the weight being 0.35 time of the total weight of the raw materials, carrying out ball milling until the fineness is 325 meshes, thus obtaining the overglaze, and ageing for 26 hours for later use.
The dry granular glaze is prepared from the following raw materials in parts by weight: 9 parts of calcite, 9 parts of quartz, 21 parts of calcined soil, 5 parts of water-washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 6 parts of talc particles, 4 parts of zinc oxide, 14 parts of clinker and 5 parts of spodumene. The preparation method of the dry granular glaze comprises the following steps: adding the raw materials of the dry granular glaze into a ball mill according to parts, adding printing oil which is 0.4 time of the total weight, and carrying out ball milling until the fineness of glaze slurry is 350 meshes to obtain the dry granular glaze.
Example 4
A preparation method of a dry grain glaze ceramic tile comprises the following preparation steps:
(1) firstly, spraying water on the dried ceramic blank until the surface of the ceramic blank is in a wet state with the water content of 5-10%, and then applying overglaze; (2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns; (3) calcining the mixture for 1 hour in a kiln at a high temperature of 1190 ℃ to obtain the dry-grain glazed ceramic tile.
The ceramic body is a common ceramic glaze body, and the cover glaze can be applied by a bell jar type glaze spraying device in the prior art.
The overglaze is prepared from the following raw materials in parts by weight: 12 parts of clinker, 36 parts of feldspar, 15 parts of calcite, 12 parts of spodumene, 7 parts of washed kaolin, 10 parts of calcined soil, 11 parts of alumina, 6 parts of barium carbonate, 2 parts of zinc oxide, 7 parts of zirconium silicate, 1.5 parts of sodium tripolyphosphate and 0.2 part of methyl cellulose. The preparation method of the overglaze comprises the following steps: adding the raw materials in the overglaze into a ball mill according to parts, adding water with the weight being 0.35 time of the total weight of the raw materials, carrying out ball milling until the fineness is 325 meshes, thus obtaining the overglaze, and ageing for 26 hours for later use.
The dry granular glaze is prepared from the following raw materials in parts by weight: 9 parts of calcite, 9 parts of quartz, 21 parts of calcined soil, 5 parts of water-washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 6 parts of talc particles, 4 parts of zinc oxide, 14 parts of clinker, 5 parts of spodumene and 1 part of calcium phosphate. The preparation method of the dry granular glaze comprises the following steps: adding the raw materials of the dry granular glaze into a ball mill according to parts, adding printing oil which is 0.4 time of the total weight, and carrying out ball milling until the fineness of glaze slurry is 350 meshes to obtain the dry granular glaze.
Example 5
A preparation method of a dry grain glaze ceramic tile comprises the following preparation steps:
(1) firstly, spraying water on the dried ceramic blank until the surface of the ceramic blank is in a wet state with the water content of 5-10%, and then applying overglaze; (2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns; (3) calcining the mixture for 1 hour in a kiln at a high temperature of 1190 ℃ to obtain the dry-grain glazed ceramic tile.
The ceramic body is a common ceramic glaze body, and the cover glaze can be applied by a bell jar type glaze spraying device in the prior art.
The overglaze is prepared from the following raw materials in parts by weight: 12 parts of clinker, 36 parts of feldspar, 15 parts of calcite, 12 parts of spodumene, 7 parts of washed kaolin, 10 parts of calcined soil, 11 parts of alumina, 6 parts of barium carbonate, 2 parts of zinc oxide, 7 parts of zirconium silicate, 1.5 parts of sodium tripolyphosphate and 0.2 part of methyl cellulose. The preparation method of the overglaze comprises the following steps: adding the raw materials in the overglaze into a ball mill according to parts, adding water with the weight being 0.35 time of the total weight of the raw materials, carrying out ball milling until the fineness is 325 meshes, thus obtaining the overglaze, and ageing for 26 hours for later use.
The dry granular glaze is prepared from the following raw materials in parts by weight: 9 parts of calcite, 9 parts of quartz, 21 parts of calcined soil, 5 parts of water-washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 6 parts of talc particles, 4 parts of zinc oxide, 14 parts of clinker, 5 parts of spodumene and 2 parts of calcium phosphate. The preparation method of the dry granular glaze comprises the following steps: adding the raw materials of the dry granular glaze into a ball mill according to parts, adding printing oil which is 0.4 time of the total weight, and carrying out ball milling until the fineness of glaze slurry is 350 meshes to obtain the dry granular glaze.
Example 6
A preparation method of a dry grain glaze ceramic tile comprises the following preparation steps:
(1) firstly, spraying water on the dried ceramic blank until the surface of the ceramic blank is in a wet state with the water content of 5-10%, and then applying overglaze; (2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns; (3) calcining the mixture for 1 hour in a kiln at a high temperature of 1190 ℃ to obtain the dry-grain glazed ceramic tile.
The ceramic body is a common ceramic glaze body, and the cover glaze can be applied by a bell jar type glaze spraying device in the prior art.
The overglaze is prepared from the following raw materials in parts by weight: 12 parts of clinker, 36 parts of feldspar, 15 parts of calcite, 12 parts of spodumene, 7 parts of washed kaolin, 10 parts of calcined soil, 11 parts of alumina, 6 parts of barium carbonate, 2 parts of zinc oxide, 7 parts of zirconium silicate, 1.5 parts of sodium tripolyphosphate and 0.2 part of methyl cellulose. The preparation method of the overglaze comprises the following steps: adding the raw materials in the overglaze into a ball mill according to parts, adding water with the weight being 0.35 time of the total weight of the raw materials, carrying out ball milling until the fineness is 325 meshes, thus obtaining the overglaze, and ageing for 26 hours for later use.
The dry granular glaze is prepared from the following raw materials in parts by weight: 9 parts of calcite, 9 parts of quartz, 21 parts of calcined soil, 5 parts of water-washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 6 parts of talc particles, 4 parts of zinc oxide, 14 parts of clinker, 5 parts of spodumene and 3 parts of calcium phosphate. The preparation method of the dry granular glaze comprises the following steps: adding the raw materials of the dry granular glaze into a ball mill according to parts, adding printing oil which is 0.4 time of the total weight, and carrying out ball milling until the fineness of glaze slurry is 350 meshes to obtain the dry granular glaze.
The products obtained in the above examples 1 to 6 were prepared into samples with the same size for performance testing, and the test results are shown in the following table:
and (3) wear resistance test: according to the 7 th part of GB/T3810.7-2006 ceramic tile test method: and (3) measuring the surface abrasion resistance of the glazed brick. The grade of the wear resistance is 1-5, and 5 is the highest grade of the wear resistance.
Stain resistance test: according to GB/T4100-2015 ceramic tile annex G standard, GB/T3810.14 ceramic tile test method part 14: method for measuring contamination resistance. The grade of the pollution resistance is 1-5, and 5 is the highest grade of the pollution resistance.
Water absorption test: the test was carried out according to the standard Q/XRC 3-2015 (second edition) ceramic brick (water absorption E is less than or equal to 0.5%), and the pass standard is water absorption less than or equal to 0.5%.
It is known that ceramics, which is a product of a specific combination of water, clay and fire, is an existing final product obtained from materials which are most unpredictable and possibly "human-like", with different formulations, different manufacturing processes and process parameters, and the properties and effects of which are not predictable in the hundreds of millions, because the combination of different elements varies widely. The application provides a brand-new overglaze and dry particle glaze formula, and the formula is matched with a production process different from the prior art, so that the dry particle glaze ceramic tile with excellent performance can be prepared, the obtained dry particle glaze ceramic tile has good anti-slip performance, the water absorption rate is 0.03-0.08%, the wear resistance reaches 4-5 grades, and the pollution resistance reaches 4-5 grades. The preparation process of the dry grain glaze ceramic tile is simple and easy to operate, the obtained product has excellent performance, the material consumption and energy consumption are easy to control, and the pollution to the environment is effectively reduced.
In summary, although the present invention has been described with reference to the preferred embodiments, the above-described preferred embodiments are not intended to limit the present invention, and those skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention, therefore, the scope of the present invention shall be determined by the appended claims.

Claims (7)

1. The dry-grain glaze ceramic tile is characterized by comprising a ceramic blank body, wherein overglaze and dry-grain glaze are sequentially applied on the ceramic blank body;
the overglaze is prepared from the following raw materials in parts by weight: 8-15 parts of frit, 35-38 parts of feldspar, 5-18 parts of calcite, 10-13 parts of spodumene, 7 parts of washing kaolin, 8-12 parts of calcined soil, 10-12 parts of aluminum oxide, 6 parts of barium carbonate, 2 parts of zinc oxide, 6-8 parts of zirconium silicate, 1-1.5 parts of sodium tripolyphosphate and 0.2 part of methyl cellulose;
the dry granular glaze is prepared from the following raw materials in parts by weight: 8-10 parts of calcite, 7-10 parts of quartz, 20-22 parts of calcined soil, 2-7 parts of water-washed kaolin, 32 parts of feldspar, 3 parts of barium carbonate, 4-7 parts of talc particles, 4 parts of zinc oxide, 14 parts of clinker, 4-5 parts of spodumene and 1-3 parts of calcium phosphate;
the preparation steps of the dry grain glaze ceramic tile are as follows:
(1) firstly, spraying water on the dried ceramic blank until the surface of the ceramic blank is in a wet state with the water content of 5-10%, and then applying overglaze;
(2) printing the dry grain glaze on the ceramic blank body with the overglaze by using a rubber roller engraved with the granular patterns;
(3) calcining the ceramic tile for 1 hour at high temperature in a kiln to obtain the dry-grain glaze ceramic tile, wherein the calcining temperature is 1100-1190 ℃.
2. The dry-glazed ceramic tile according to claim 1, wherein the calcined clay is calcined china clay or calcined kaolin.
3. The dry-glazed ceramic tile according to claim 1, wherein the frit is any one of a transparent frit glaze, a milky-white frit glaze, a lead-containing frit glaze, and a lead-free frit glaze.
4. The dry-glazed ceramic tile according to claim 1, wherein the overglaze has a fineness of 325 to 400 mesh.
5. The dry-glazed ceramic tile according to claim 1, wherein the dry glaze has a fineness of 300 to 400 mesh.
6. The dry-glazed ceramic tile according to claim 1, wherein the overglaze is prepared by a method comprising: adding the raw materials into a ball mill according to parts, adding water with the weight of 0.35-0.5 time of the total weight of the raw materials, performing ball milling until the fineness is 325-400 meshes, preparing an overglaze, and aging for more than 24 hours for later use.
7. The dry-glazed ceramic tile according to claim 1, wherein the dry glaze is prepared by a method comprising: adding the raw materials into a ball mill according to parts, adding printing oil which is 0.3-0.5 time of the total weight, and carrying out ball milling until the fineness of glaze slip is 300-400 meshes to obtain dry granular glaze.
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