CN108545944A - The preparation method and ship-and-galley tile of ship-and-galley tile - Google Patents
The preparation method and ship-and-galley tile of ship-and-galley tile Download PDFInfo
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- CN108545944A CN108545944A CN201810720736.4A CN201810720736A CN108545944A CN 108545944 A CN108545944 A CN 108545944A CN 201810720736 A CN201810720736 A CN 201810720736A CN 108545944 A CN108545944 A CN 108545944A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/66—Specific sintering techniques, e.g. centrifugal sintering
- C04B2235/661—Multi-step sintering
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The present invention discloses a kind of preparation method and ship-and-galley tile of ship-and-galley tile.The preparation method comprises the following steps：Blank forming carries out first time drying process, obtains floor tile blank, drenches ground-coat enamel to the surface of floor tile blank, then carries out ink-jet printed, and carries out second and is dried；Anti-skidding glaze is sprayed, preformed bricks are obtained；Anti-skidding glaze thickness is 0.5 1mm；Preformed bricks are put into kiln and carry out first time firing, by first time temperature programming to 1100 DEG C of firings；It after being cooled to 100 DEG C or less, is put into kiln and carries out second of firing, by second of temperature programming to 1200 DEG C of firings；It is put into the nitrogen atmosphere containing carbon dioxide and is cooled to room temperature, obtain semi-finished product, finished product is obtained after edging examines matter.A kind of ship-and-galley tile is made by the preparation method.Using ship-and-galley tile made from method disclosed by the invention, non-skid property is good, and thermal shock resistance and antifouling property protrude, and flexural strength is strong.
Description
Technical field
The present invention relates to chemical fields, in particular to the preparation method and ship-and-galley tile of a kind of ship-and-galley tile.
Background technology
In recent years, lead to accidental injuring event since ground is smooth, make non-skid property of the consumer to paving material
It especially pays close attention to, Ceramic Tiles are as a kind of most widely used paving material in various public places and house decoration, to it
The attention rate higher of non-skid property.With the development of ship-and-galley tile technique, the ship-and-galley tile of ultra-thin anti-skidding glaze layer increasingly by
It welcomes.
However, although thinning can bring of anti-skidding glaze layer promotes the Integral decoration effect of floor tile, reduces production materials cost
Etc. benefits, but there is antifouling properties not high, thermal shock resistance and the defects of flexural strength declines, properties of product are unstable.
In view of this, special propose the present invention.
Invention content
The main purpose of the present invention is to provide a kind of preparation methods of ship-and-galley tile, can be obtained well using this method
Anti-skidding, antifouling, thermal shock resistance and flexural strength, properties of product stablize.
The second object of the present invention is to provide a kind of ship-and-galley tile, and the ship-and-galley tile has non-skid property good, antifouling
The advantages that ability is strong, thermal shock resistance is good, High anti bending strength.
In order to realize that the above-mentioned purpose of the present invention, spy use following technical scheme：
A kind of preparation method of ship-and-galley tile, includes the following steps：
A. blank forming carries out first time drying process, obtains floor tile blank, drenches bottom to the surface of the floor tile blank
Glaze, then carries out ink-jet printed, and carries out second and is dried；
B. anti-skidding glaze is sprayed, preformed bricks are obtained；Anti-skidding glaze thickness is 0.5-1mm；
C. the preformed bricks are put into kiln and carry out first time firing, by first time temperature programming to 1100 DEG C of firings；
D. it after being cooled to 100 DEG C or less, is put into kiln and carries out second of firing, by second of temperature programming to 1200 DEG C
It fires；
E. it is put into the nitrogen atmosphere containing carbon dioxide and is cooled to room temperature, obtain semi-finished product, the semi-finished product are through overground
Finished product is obtained after frontier inspection matter.
Temperature programming method is fired, can be with effective solution preformed bricks, anti-skidding glaze layer and the stress between them
Problem improves the thermal shock resistance and flexural strength of product.
Preferably, the first time temperature programming is：First stage rises to 200 DEG C, and 10min, second stage is maintained to rise to
It 800 DEG C, maintains 25min, phase III to rise to 1100 DEG C, maintains 15min；Second of temperature programming be：First stage liter
To 200 DEG C, 5min, second stage is maintained to rise to 600 DEG C, maintains 20min, phase III to rise to 1200 DEG C, maintain 45min.
Preferably temperature programming parameter, can be by effect promoting to most preferably.
It is further preferred that the temperature of the first time drying is 100-180 DEG C.
The control of drying temperature, controllably the structural stability of brick blank, ensures the strength character on basis.
It is further preferred that second of drying carries out in isoperibol, temperature is 180 DEG C, and changing value is positive and negative not
More than 0.1 DEG C.
The use of isoperibol is conducive to steadily be combined between leaching ground-coat enamel and ink-jet printed process, is further ensured that product
Performance stablize.
Preferably, in step E, the volume fraction of the carbon dioxide is 10-20%.
It is cooled down using the nitrogen atmosphere containing carbon dioxide, is conducive to the improvement on anti-skid brick surface, it is antifouling to improve its
Performance and non-skid property.
Preferably, the anti-skidding glaze contains frit, and the frit includes dry granular A, dry granular B and dry granular C, the dry granular A, institute
The mass ratio for stating the dry granular B and dry granular C is (2-5):(1-3):1；The dry granular A includes based on mass fraction：SiO251-
53%, Al2O318-20%, Fe2O30.08-0.10%, CaO10-11%, MgO3-4%, K2O5-6%, Na2O5-6%,
ZnO3-4%, La2O30.15-0.20%；The dry granular B includes based on mass fraction：SiO254-56%, Al2O315-17%,
Fe2O30.05-0.10%, CaO8-9%, MgO2-3%, K2O7-8%, Na2O7-8%, ZnO2-3%, Ce2O30.20-
0.25%；The dry granular C includes based on mass fraction：SiO250-52%, Al2O323-24%, Fe2O30.05-0.06%,
CaO13-14%, MgO3-4%, K2O3-3.5%, Na2O2.5-3%, ZnO2-2.5%, Pr6O110.30-0.35%.
The control of the component and dosage of dry granular, the especially use of La2O3, Ce2O3 and Pr6O11, improve anti-in frit
The chemical component of sliding glaze, for the surface of conjugation, anti-skidding glaze layer between its structural strength and preformed bricks (mainly ground-coat enamel)
Micro-structure has prodigious change, and then obtains preferably anti-skidding, antifouling, thermal shock resistance and flexural strength.
It is further preferred that be ordered as dry granular C big for the grain size mesh number size of the dry granular A, the dry granular B and the dry granular C
It is more than dry granular B in dry granular A, and between 120-300 mesh.
The control of dry granular particle size, interaction between being conducive to dry granular A, B, C in anti-skidding glaze.Dry granular B
Melting temperature it is minimum, be in molten condition at first when firing, and (mesh number is bigger, and grain size is got over for the grain size of dry granular B
It is small) it is the largest, it is preferably wrapped so dry granular A and C stronger to non-skid property can be played the role of and had, to make A and C
Particle possesses better wear-resisting property, while the antifouling property of floor tile being made to obtain big improvement.
The application also provides a kind of ship-and-galley tile, is made by method above-mentioned.
Compared with prior art, beneficial effects of the present invention are：
Using the preparation method and ship-and-galley tile of ship-and-galley tile provided by the present application, product can obtain very excellent anti-skidding
Performance, flexural strength, thermal shock resistance and antifouling property.
Specific implementation mode
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
The description of " first ", " second " etc. is related in the embodiment of the present invention, then is somebody's turn to do the description of " first ", " second " etc. only
For descriptive purposes, it is not understood to indicate or imply its relative importance or implicitly indicates indicated technical characteristic
Quantity." first " is defined as a result, the feature of " second " can explicitly or implicitly include at least one of the features.In addition,
Technical solution between each embodiment can be combined with each other, but must can be implemented as with those of ordinary skill in the art
Basis will be understood that the combination of this technical solution is not deposited when conflicting or cannot achieve when occurs in the combination of technical solution
, also not the present invention claims protection domain within.
Overall description is carried out first.
Ground-coat enamel raw mineral materials used in the present invention is commercially available conventional glaze, and ground-coat enamel includes ground-coat enamel raw mineral materials, common molten
Block and water.Specifically, the ground-coat enamel raw mineral materials ingredient used in the embodiment of the present application is：Quartz 10%, boron oxide 15%, silicic acid
Zirconium 13%, middle aluminium powder 8%, albite 25%, kaolin 10%, desiliconization aluminium powder 5%, calcite 5%, dolomite 9%.It is common molten
The ingredient of block is：SiO2 65%, Al2O3 10.5%, CaO 10.25%, MgO 5.25%, K2O 2%, Na2O 7%.
The anti-skidding glaze of the embodiment of the present application includes clear frit and frit, and wherein clear frit is common glaze, and ingredient is：
SiO245%, Al2O319%, Fe2O30.2%, TiO20.1%, CaO8%, MgO8%, K2O5%, Na2O5.5%,
ZnO8%, BaO1.2%.
Embodiment 1
First, blank forming is carried out, and carry out first time drying process, drying temperature is 180 DEG C, obtains floor tile blank；
Then ground-coat enamel is drenched to the surface of floor tile blank, then carries out ink-jet printed, and carried out second and be dried, second dry to exist
It is carried out in isoperibol, temperature is 180 DEG C, and changing value is positive and negative to be no more than 0.1 DEG C；
Second, anti-skidding glaze is sprayed, preformed bricks are obtained；Anti-skidding glaze thickness is 0.5mm；Anti-skidding glaze includes frit, and frit accounts for anti-
The 5% of sliding glaze gross weight；Frit includes dry granular A, dry granular B and dry granular C, and the mass ratio of dry granular A, dry granular B and dry granular C are 5:3:1；It is dry
Grain A include based on mass fraction：SiO253%, Al2O318%, Fe2O30.08%, CaO10%, MgO3%, K2O6%,
Na2O6%, ZnO3.77%, La2O30.15%；Dry granular B includes based on mass fraction：SiO254%, Al2O317%,
Fe2O30.05%, CaO8%, MgO2%, K2O8%, Na2O7.7%, ZnO3%, Ce2O30.25%；Dry granular C is with mass fraction
Meter includes：SiO250%, Al2O323%, Fe2O30.06%, CaO14%, MgO4%, K2O3.5%, Na2O3%,
ZnO2.1%, Pr6O110.34%；It is big more than dry granular A that the grain size mesh number size of dry granular A, dry granular B and dry granular C are ordered as dry granular C
In dry granular B, and between 120-300 mesh；
Preformed bricks are put into kiln and carry out first time firing by third, by first time temperature programming to 1100 DEG C of firings；The
Temperature programming is：First stage rises to 200 DEG C, maintains 10min, second stage to rise to 800 DEG C, maintains 25min, third rank
1100 DEG C of Duan Shengzhi maintains 15min；
4th, after being cooled to 100 DEG C or less, it is put into kiln and carries out second of firing, extremely by second of temperature programming
1200 DEG C of firings；Second of temperature programming be：First stage rises to 200 DEG C, maintains 5min, second stage to rise to 600 DEG C, maintains
20min, phase III rise to 1200 DEG C, maintain 45min；
5th, it is put into containing being cooled to room temperature in the nitrogen atmosphere that volume fraction is 10% carbon dioxide, obtains semi-finished product,
Semi-finished product obtain finished product after edging examines matter.
Embodiment 2
First, blank forming is carried out, and carry out first time drying process, drying temperature is 150 DEG C, obtains floor tile blank；
Then ground-coat enamel is drenched to the surface of floor tile blank；Then it carries out ink-jet printed, and carries out second and be dried, second dry to exist
It is carried out in isoperibol, temperature is 180 DEG C, and changing value is positive and negative to be no more than 0.1 DEG C；
Second, anti-skidding glaze is sprayed, preformed bricks are obtained；Anti-skidding glaze thickness is 1mm；Anti-skidding glaze includes frit, and frit accounts for anti-skidding
The 3% of glaze gross weight；Frit includes dry granular A, dry granular B and dry granular C, and the mass ratio of dry granular A, dry granular B and dry granular C are 2:1:1；Dry granular
A includes based on mass fraction：SiO252%, Al2O319%, Fe2O30.09%, CaO11%, MgO3.5%, K2O5.5%,
Na2O5.73%, ZnO3%, La2O30.18%；Dry granular B includes based on mass fraction：SiO255%, Al2O315%,
Fe2O30.08%, CaO8.59%, MgO2.5%, K2O7.8%, Na2O8%, ZnO2.8%, Ce2O30.23%；Dry granular C with
Mass fraction meter includes：SiO251%, Al2O323.5%, Fe2O30.05%, CaO13%, MgO3.5%, K2O3.3%,
Na2O2.8%, ZnO2.5%, Pr6O110.35%；It is big that the grain size mesh number size of dry granular A, dry granular B and dry granular C are ordered as dry granular C
It is more than dry granular B in dry granular A, and between 120-300 mesh；
Preformed bricks are put into kiln and carry out first time firing by third, by first time temperature programming to 1100 DEG C of firings；The
Temperature programming is：First stage rises to 200 DEG C, maintains 10min, second stage to rise to 800 DEG C, maintains 25min, third rank
1100 DEG C of Duan Shengzhi maintains 15min；
4th, after being cooled to 100 DEG C or less, it is put into kiln and carries out second of firing, extremely by second of temperature programming
1200 DEG C of firings；Second of temperature programming be：First stage rises to 200 DEG C, maintains 5min, second stage to rise to 600 DEG C, maintains
20min, phase III rise to 1200 DEG C, maintain 45min；
5th, it is put into containing being cooled to room temperature in the nitrogen atmosphere that volume fraction is 15% carbon dioxide, obtains semi-finished product,
Semi-finished product obtain finished product after edging examines matter.
Embodiment 3
First, blank forming is carried out, and carry out first time drying process, drying temperature is 100 DEG C, obtains floor tile blank；
Then ground-coat enamel is drenched to the surface of floor tile blank, then carries out ink-jet printed, and carried out second and be dried, second dry to exist
It is carried out in isoperibol, temperature is 180 DEG C, and changing value is positive and negative to be no more than 0.1 DEG C；
Second, anti-skidding glaze is sprayed, preformed bricks are obtained；Anti-skidding glaze thickness is 0.8mm；Anti-skidding glaze includes frit, and frit accounts for anti-
The 10% of sliding glaze gross weight；Frit includes dry granular A, dry granular B and dry granular C, and the mass ratio of dry granular A, dry granular B and dry granular C are 2:3:1；
Dry granular A includes based on mass fraction：SiO251%, Al2O320%, Fe2O30.1%, CaO10.7%, MgO4%, K2O5%,
Na2O5%, ZnO4%, La2O30.2%；Dry granular B includes based on mass fraction：SiO256%, Al2O315.7%,
Fe2O30.1%, CaO9%, MgO3%, K2O7%, Na2O7%, ZnO2%, Ce2O30.2%；Dry granular C is wrapped based on mass fraction
It includes：SiO252%, Al2O324%, Fe2O30.05%, CaO13.15%, MgO3%, K2O3%, Na2O2.5%, ZnO2%,
Pr6O110.3%；The grain size mesh number size of dry granular A, dry granular B and dry granular C are ordered as dry granular C and are more than dry granular B more than dry granular A, and
Between 120-300 mesh；
Preformed bricks are put into kiln and carry out first time firing by third, by first time temperature programming to 1100 DEG C of firings；The
Temperature programming is：First stage rises to 200 DEG C, maintains 10min, second stage to rise to 800 DEG C, maintains 25min, third rank
1100 DEG C of Duan Shengzhi maintains 15min；
4th, after being cooled to 100 DEG C or less, it is put into kiln and carries out second of firing, extremely by second of temperature programming
1200 DEG C of firings；Second of temperature programming be：First stage rises to 200 DEG C, maintains 5min, second stage to rise to 600 DEG C, maintains
20min, phase III rise to 1200 DEG C, maintain 45min；
5th, it is put into containing being cooled to room temperature in the nitrogen atmosphere that volume fraction is 20% carbon dioxide, obtains semi-finished product,
Semi-finished product obtain finished product after edging examines matter.
Comparative example 1
Compared with Example 1, difference lies in also using the frit in ground-coat enamel, ingredient is the frit in anti-skidding glaze：SiO2
65%, Al2O3 10.5%, CaO 10.25%, MgO 5.25%, K2O 2%, Na2O 7%.
Comparative example 2
Compared with Example 2, difference lies in the grain size mesh number of dry granular A, B, C are less than 100 mesh, and three kinds of dry granular grain sizes
It is almost the same.
Comparative example 3
Compared with Example 3, difference lies in the firing of preformed bricks is disposably completed, not stage by stage, also without program
Heating.
Comparative example 4
Compared with Example 3, difference lies in after the completion of firing, nature cooling is not put into containing carbon dioxide
In nitrogen atmosphere.
Comparative example 5
Compared with Example 2, difference lies in second of drying does not carry out under isoperibol.
Finished product ship-and-galley tile made from embodiment 1-3, comparative example 1-5, is tested for the property, and as a result see the table below shown in 1.
1 the performance test results of table
By the test result of Examples and Comparative Examples in upper table it is found that frit ingredient, the granule size of dry granular A, B, C are done
In grain A in La2O3, dry granular B in Ce2O3, dry granular C Pr6O11 addition, anti-skid factor, thermal shock resistance that can be to ship-and-galley tile
The performances such as energy, soil resistance, flexural strength produce bigger effect, the addition of La2O3 and in the nitrogen atmosphere containing carbon dioxide
It is cooling, can be by the effect of La2O3 and carbon dioxide, generating lanthanum carbonate improves the micro- knot of microstructure and surface of anti-skidding glaze layer
Structure, to advanced optimize the soil resistance and non-skid property of product；Temperature programming can improve the effect that anti-skidding glaze layer is fired,
Enhance the intensity and thermal shock resistance of product.
For those skilled in the art, the application can have various modifications and variations.It is all in spirit herein
Within principle, any modification, equivalent replacement, improvement and so on should be included within the protection domain of the application.Although
The present invention is illustrate and described with specific embodiment, however will be appreciated that without departing substantially from the spirit and scope of the present invention
In the case of can make many other change and modification.It is, therefore, intended that including belonging to this hair in the following claims
All such changes and modifications in bright range.
Claims (8)
1. a kind of preparation method of ship-and-galley tile, which is characterized in that include the following steps：
A. blank forming carries out first time drying process, obtains floor tile blank, drenches ground-coat enamel to the surface of the floor tile blank, so
After carry out ink-jet printed, and carry out second and be dried；
B. anti-skidding glaze is sprayed, preformed bricks are obtained；Anti-skidding glaze thickness is 0.5-1mm；
C. the preformed bricks are put into kiln and carry out first time firing, by first time temperature programming to 1100 DEG C of firings；
D. it after being cooled to 100 DEG C or less, is put into kiln and carries out second of firing, by second of temperature programming to 1200 DEG C of burnings
System；
E. it is put into the nitrogen atmosphere containing carbon dioxide and is cooled to room temperature, obtain semi-finished product, the semi-finished product are examined by edging
Finished product is obtained after matter.
2. according to the method described in claim 1, it is characterized in that, the first time temperature programming is：First stage rises to 200
DEG C, it maintains 10min, second stage to rise to 800 DEG C, maintains 25min, phase III to rise to 1100 DEG C, maintain 15min；Described
Quadratic program heats up：First stage rises to 200 DEG C, maintains 5min, second stage to rise to 600 DEG C, maintains 20min, third rank
1200 DEG C of Duan Shengzhi maintains 45min.
3. according to the method described in claim 2, it is characterized in that, the temperature of first time drying is 100-180 DEG C.
4. according to the method described in claim 3, it is characterized in that, second drying carries out in isoperibol, temperature
It is 180, changing value is positive and negative to be no more than 0.1 DEG C.
5. according to the method described in claim 1, it is characterized in that, in step E, the volume fraction of the carbon dioxide is 10-
20%.
6. according to the method described in claim 1, it is characterized in that, the anti-skidding glaze contains frit, the frit includes dry granular
A, the mass ratio of dry granular B and dry granular C, the dry granular A, the dry granular B and the dry granular C are (2-5):(1-3):1；
The dry granular A includes based on mass fraction：SiO251-53%, Al2O318-20%, Fe2O30.08-0.10%,
CaO10-11%, MgO3-4%, K2O5-6%, Na2O5-6%, ZnO3-4%, La2O30.15-0.20%；
The dry granular B includes based on mass fraction：SiO254-56%, Al2O315-17%, Fe2O30.05-0.10%, CaO8-
9%, MgO2-3%, K2O7-8%, Na2O7-8%, ZnO2-3%, Ce2O30.20-0.25%；
The dry granular C includes based on mass fraction：SiO250-52%, Al2O323-24%, Fe2O30.05-0.06%,
CaO13-14%, MgO3-4%, K2O3-3.5%, Na2O2.5-3%, ZnO2-2.5%, Pr6O110.30-0.35%.
7. according to the method described in claim 6, it is characterized in that, the grain size of the dry granular A, the dry granular B and the dry granular C
Mesh number size is ordered as dry granular C and is more than dry granular B more than dry granular A, and between 120-300 mesh.
8. a kind of ship-and-galley tile, which is characterized in that be made by claim 1-7 any one of them methods.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810720736.4A CN108545944B (en) | 2018-06-29 | 2018-06-29 | Preparation method of anti-skid floor tile and anti-skid floor tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810720736.4A CN108545944B (en) | 2018-06-29 | 2018-06-29 | Preparation method of anti-skid floor tile and anti-skid floor tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108545944A true CN108545944A (en) | 2018-09-18 |
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| CN111217623A (en) * | 2020-04-21 | 2020-06-02 | 佛山市东鹏陶瓷有限公司 | Preparation method of anti-slip antifouling glazed tile and prepared anti-slip antifouling glazed tile |
| CN112679093A (en) * | 2021-01-29 | 2021-04-20 | 广东宏威陶瓷实业有限公司 | Novel glazed tile and preparation method thereof |
| CN112939465A (en) * | 2021-03-31 | 2021-06-11 | 江西太阳陶瓷有限公司 | Anti-slip glaze and processing method of anti-slip glazed brick |
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