CN111995437A - Super wear-resistant anti-skid ceramic tile and preparation method thereof - Google Patents
Super wear-resistant anti-skid ceramic tile and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of ceramic tile preparation, and particularly relates to a super wear-resistant anti-slip ceramic tile and a preparation method thereof. The glaze comprises a body layer, a glaze cover layer and an anti-skid wear-resistant glaze layer, wherein the anti-skid wear-resistant glaze layer consists of anti-skid wear-resistant glaze particles, a dispersing agent, water and sodium hexametaphosphate, and the anti-skid wear-resistant glaze particles consist of potassium feldspar, kaolin, calcined alumina, quartz sand, talcum powder, diatomite, barium carbonate, magnesium oxide, zinc oxide, yttrium oxide and lanthanum oxide. According to the super wear-resistant anti-skidding ceramic tile, the body layer, the cover glaze layer and the anti-skidding wear-resistant glaze layer are matched with one another, raw materials of the layers are mutually synergistic, and the proportion is reasonable, so that the finally prepared ceramic tile is high in surface friction coefficient and hardness, anti-skidding, wear-resistant and high in comprehensive quality.
Description
Technical Field
The invention belongs to the technical field of ceramic tile preparation, and particularly relates to a super wear-resistant anti-slip ceramic tile and a preparation method thereof.
Background
With the development of economy and the continuous improvement of the living standard of people, the consumption level of people and the pursuit of visual beauty are continuously improved. High-grade smooth ground material products are rapidly seizing the market of decorative materials, the production technology of ceramic floor tiles is continuously improved, and ceramic floor tiles which integrate a plurality of advantages of economy, practicability, attractiveness, easiness in cleaning and the like are gradually becoming main ground decorative materials. And the overall visual effect of the device is too much pursued, so that the surface of most ceramic floor tile products is too smooth, thereby bringing about a great safety hazard. The selection of ceramic tiles with appropriate coefficients of friction is a necessary condition to prevent slip.
The preparation technology of the antiskid wear-resistant ceramic tile is rich, but the market feedback is always poor, the product always has some consumption pain points, or the antiskid effect is poor in persistence; or poor soil resistance and easy cleaning; or a large compromise in aesthetic properties; or the surface hardness is not enough, so that the wear resistance is poor and the scratch is easy to occur.
Therefore, it is necessary to search for a ceramic tile having excellent wear resistance and non-slip properties.
Disclosure of Invention
The purpose of the invention is: provides a super wear-resistant anti-skid ceramic tile. The ceramic tile has high surface friction coefficient and hardness, is antiskid and wear-resistant, and has high comprehensive quality; the invention also provides a preparation method thereof.
The invention relates to a super wear-resistant anti-slip ceramic tile, which comprises a green body layer, a cover glaze layer and an anti-slip wear-resistant glaze layer, wherein the anti-slip wear-resistant glaze layer consists of anti-slip wear-resistant glaze particles, a dispersing agent, water and sodium hexametaphosphate, and the anti-slip wear-resistant glaze particles consist of the following raw materials in parts by weight: 20-25 parts of potassium feldspar, 15-20 parts of kaolin, 35-38 parts of calcined alumina, 35-40 parts of quartz sand, 8-12 parts of talcum powder, 10-15 parts of diatomite, 5-10 parts of barium carbonate, 5-8 parts of magnesium oxide, 3-5 parts of zinc oxide, 3-4 parts of yttrium oxide and 1-2 parts of lanthanum oxide.
Wherein:
in the anti-skid wear-resistant glaze layer, the weight part ratio of the anti-skid wear-resistant glaze particles, the dispersing agent, the water and the sodium hexametaphosphate is 110-120:0.3-0.4:50-55: 0.3-0.8.
The dispersant is sodium carboxymethyl cellulose.
The antiskid wear-resistant glaze comprises the following chemical components: al (Al)2O3 50-55％、SiO2 30-35％、K2O 5-7％、Na2O 2-3％、BaO 1-3％、MgO 0.5-1.5％、CaO 1-3％、ZnO 1-2％、Fe2O3 0.8-1.0％、Y2O3 0.5-0.8％、La2O30.3-0.5% and loss on ignition 2-4.5%.
The green body layer is prepared from the following raw materials in parts by weight: 15-20 parts of potash feldspar, 10-15 parts of albite, 5-8 parts of diopside, 30-35 parts of zircon sand, 3-5 parts of iron ore, 20-25 parts of calcined kaolin, 1-5 parts of nepheline, 8-10 parts of bentonite and 1-3 parts of magnesium sulfate.
The overglaze layer comprises the following raw materials in parts by weight: 15-20 parts of potassium feldspar, 5-10 parts of cordierite, 20-35 parts of high alumina, 15-20 parts of quartz sand, 10-15 parts of brown corundum, 5-8 parts of zinc oxide, 20-30 parts of zirconium silicate, 5-8 parts of calcined talc, 0.5-1 part of titanium dioxide and 0.3-0.5 part of sodium benzoate.
The super wear-resistant anti-slip ceramic tile further comprises a decorative layer.
The preparation method of the super wear-resistant anti-slip ceramic tile comprises the following steps:
(1) the green body raw materials are ball-milled into slurry to form green body dry powder, and the dry powder is pressed in a mould pressing mode to prepare a ceramic tile green body;
(2) drying the ceramic tile green body at the temperature of 150-;
(3) and (3) applying surface glaze slurry to the ceramic tile green body dried in the step (2) to obtain a surface glaze layer, applying anti-skid and wear-resistant glaze slurry to obtain an anti-skid and wear-resistant glaze layer, and drying and sintering to obtain the super-wear-resistant and anti-skid ceramic tile.
Wherein:
the ball milling time in the step (1) is 5-8h, and the density of the slurry is 1.70-1.75g/cm3。
And (2) performing compression molding under the pressure of 70-75MPa in the step (1).
The water content of the ceramic tile green body in the step (1) is 5.5-6.0%.
The water content of the ceramic tile green body dried in the step (2) is 0.5-1%.
The overglaze raw material and the water in the step (3) are placed in a ball mill for ball milling to 100-200 meshes to obtain overglaze slurry, and the density of the overglaze slurry is 1.60-1.65g/cm3。
The anti-skid wear-resistant glaze particles, the dispersing agent and the hexametaphosphoric acid in the step (3)Sodium and water are placed in a ball mill for ball milling to 300-400 meshes to obtain the anti-skid and wear-resistant slurry, and the density of the anti-skid and wear-resistant slurry is 1.55-1.6g/cm3。
The drying in the step (3) is carried out at 650 ℃ of 550-650 ℃ for 0.5-1h, and then the temperature is raised to 1150 ℃ at the rate of 3-5 ℃/min for 2-3 h.
Compared with the prior art, the invention has the following beneficial effects:
(1) according to the super wear-resistant anti-skidding ceramic tile, the body layer, the cover glaze layer and the anti-skidding wear-resistant glaze layer are mutually cooperated, and raw materials of all layers are mutually matched in a reasonable ratio, so that the finally prepared ceramic tile is high in surface friction coefficient and hardness, anti-skidding and wear-resistant, and high in comprehensive quality.
(2) According to the super wear-resistant anti-skidding ceramic tile, raw materials of anti-skidding and wear-resistant glaze particles in the anti-skidding and wear-resistant glaze layer are matched with each other, so that the prepared anti-skidding and wear-resistant glaze layer has high hardness and high dry-wet friction coefficient, and has high wear resistance and skid resistance.
(3) The preparation method of the super wear-resistant anti-slip ceramic tile is simple and easy to implement, reasonable in parameter design, long in service life and wide in market prospect.
Detailed Description
The present invention is further described below with reference to examples.
Example 1
The super wear-resistant anti-slip ceramic tile of the embodiment 1 comprises a green body layer, a cover glaze layer and an anti-slip wear-resistant glaze layer, wherein the anti-slip wear-resistant glaze layer is composed of anti-slip wear-resistant glaze particles, a dispersing agent, water and sodium hexametaphosphate, and the anti-slip wear-resistant glaze particles are composed of the following raw materials in parts by weight: 20 parts of potassium feldspar, 20 parts of kaolin, 35 parts of calcined alumina, 35 parts of quartz sand, 10 parts of talcum powder, 10 parts of diatomite, 8 parts of barium carbonate, 5 parts of magnesium oxide, 3 parts of zinc oxide, 3 parts of yttrium oxide and 1 part of lanthanum oxide.
Wherein:
in the anti-skid wear-resistant glaze layer, the weight part ratio of the anti-skid wear-resistant glaze particles to the dispersant to the water to the sodium hexametaphosphate is 110:0.3:52: 0.3.
The antiskid wear-resistant glaze comprises the following chemical components: al (Al)2O3 53％、SiO2 32％、K2O 5％、Na2O 2％、BaO 1.5％、MgO0.6％、CaO1％、ZnO1％、Fe2O3 0.8％、Y2O3 0.5％、La2O30.3% and loss on ignition 2.3%.
The dispersant is sodium carboxymethyl cellulose.
The green body layer is prepared from the following raw materials in parts by weight: 15 parts of potash feldspar, 10 parts of albite, 5 parts of diopside, 30 parts of zircon sand, 4 parts of iron ore, 20 parts of calcined kaolin, 2 parts of nepheline, 8 parts of bentonite and 1 part of magnesium sulfate.
The overglaze layer comprises the following raw materials in parts by weight: 15 parts of potash feldspar, 5 parts of cordierite, 20 parts of high alumina, 15 parts of quartz sand, 10 parts of brown corundum, 5 parts of zinc oxide, 25 parts of zirconium silicate, 5 parts of calcined talc, 0.5 part of titanium dioxide and 0.3 part of sodium benzoate.
The super wear-resistant anti-slip ceramic tile further comprises a decorative layer.
The preparation method of the super wear-resistant anti-slip ceramic tile in the embodiment 1 comprises the following steps:
(1) the green body raw materials are ball-milled into slurry to form green body dry powder, and the dry powder is pressed in a mould pressing mode to prepare a ceramic tile green body;
(2) drying the ceramic tile green body at 150 ℃ for 15 h;
(3) and (3) applying surface glaze slurry to the ceramic tile green body dried in the step (2) to obtain a surface glaze layer, applying anti-skid and wear-resistant glaze slurry to obtain an anti-skid and wear-resistant glaze layer, and drying and sintering to obtain the super-wear-resistant and anti-skid ceramic tile.
Wherein:
the ball milling time in the step (1) is 8h, and the density of the slurry is 1.70g/cm3。
And (2) performing compression molding under the pressure of 70MPa in the step (1).
The water content of the ceramic tile green body in the step (1) is 5.5%.
And (3) the water content of the ceramic tile green body after drying in the step (2) is 0.5%.
Putting the overglaze raw material and water in the step (3) into a ball mill to ball-mill to 100 meshes to obtain overglaze slurry, wherein the density of the overglaze slurry is 1.65g/cm3。
Putting the anti-skid wear-resistant glaze particles, the dispersing agent, the sodium hexametaphosphate and the water in the step (3) into a ball mill to be ball-milled to 300 meshes to obtain the anti-skid wear-resistant slurry, wherein the density of the anti-skid wear-resistant slurry is 1.6g/cm3。
Drying at 550 ℃ for 1h in the step (3), and then heating to 950 ℃ at the speed of 3 ℃/min for 3 h.
The ceramic tile obtained in example 1 had a wet-water static friction coefficient of 0.96, a dry-process static friction coefficient of 0.99, a glaze abrasion resistance of 12000 rpm, 4 th and 5 th levels of contamination resistance (the wet-water static friction coefficient was measured by GB/T4100, the dry-process static friction coefficient was measured by GB/T4100, the abrasion resistance of the glaze was measured by GB/T3810.7 and the contamination resistance of the glaze was measured by GB/T3810.14).
Example 2
The super wear-resistant anti-slip ceramic tile of the embodiment 2 comprises a green body layer, a cover glaze layer and an anti-slip wear-resistant glaze layer, wherein the anti-slip wear-resistant glaze layer is composed of anti-slip wear-resistant glaze particles, a dispersing agent, water and sodium hexametaphosphate, and the anti-slip wear-resistant glaze particles are composed of the following raw materials in parts by weight: 25 parts of potash feldspar, 18 parts of kaolin, 38 parts of calcined alumina, 40 parts of quartz sand, 12 parts of talcum powder, 13 parts of diatomite, 5 parts of barium carbonate, 8 parts of magnesium oxide, 5 parts of zinc oxide, 4 parts of yttrium oxide and 1.5 parts of lanthanum oxide.
Wherein:
in the anti-skid wear-resistant glaze layer, the weight part ratio of the anti-skid wear-resistant glaze particles to the dispersing agent to the water to the sodium hexametaphosphate is 120:0.4:55: 0.8.
The dispersant is sodium carboxymethyl cellulose.
The antiskid wear-resistant glaze comprises the following chemical components: al (Al)2O3 50％、SiO2 34％、K2O 5.8％、Na2O 2％、BaO 1％、MgO0.6％、CaO 1.0％、ZnO1.5％、Fe2O3 0.9％、Y2O3 0.8％、La2O30.4% and 2% loss on ignition.
The green body layer is prepared from the following raw materials in parts by weight: 20 parts of potassium feldspar, 15 parts of albite, 8 parts of diopside, 35 parts of zircon sand, 5 parts of iron ore, 25 parts of calcined kaolin, 3 parts of nepheline, 10 parts of bentonite and 2 parts of magnesium sulfate.
The overglaze layer comprises the following raw materials in parts by weight: 20 parts of potash feldspar, 10 parts of cordierite, 35 parts of high alumina, 20 parts of quartz sand, 12 parts of brown corundum, 8 parts of zinc oxide, 20 parts of zirconium silicate, 7 parts of calcined talc, 1 part of titanium dioxide and 0.5 part of sodium benzoate.
The super wear-resistant anti-slip ceramic tile further comprises a decorative layer.
The preparation method of the super wear-resistant anti-slip ceramic tile in the embodiment 2 comprises the following steps:
(1) the green body raw materials are ball-milled into slurry to form green body dry powder, and the dry powder is pressed in a mould pressing mode to prepare a ceramic tile green body;
(2) drying the ceramic tile green body for 10 hours at the temperature of 200 ℃;
(3) and (3) applying surface glaze slurry to the ceramic tile green body dried in the step (2) to obtain a surface glaze layer, applying anti-skid and wear-resistant glaze slurry to obtain an anti-skid and wear-resistant glaze layer, and drying and sintering to obtain the super-wear-resistant and anti-skid ceramic tile.
Wherein:
the ball milling time in the step (1) is 5 hours, and the density of the slurry is 1.75g/cm3。
And (2) performing compression molding under the pressure of 75MPa in the step (1).
The water content of the ceramic tile green body in the step (1) is 6.0%.
And (3) the water content of the ceramic tile green body after drying in the step (2) is 1%.
Putting the overglaze raw material and water in the step (3) into a ball mill to ball-mill to 150 meshes to obtain overglaze slurry, wherein the density of the overglaze slurry is 1.63g/cm3。
Putting the anti-skid wear-resistant glaze particles, the dispersing agent, the sodium hexametaphosphate and the water in the step (3) into a ball mill to be ball-milled to 350 meshes,obtaining the anti-skid wear-resistant slurry with the density of 1.58g/cm3。
Drying at 600 ℃ for 0.8h in the step (3), and then heating to 1150 ℃ at the speed of 5 ℃/min for 2 h.
The ceramic tile obtained in example 2 had a wet-water static friction coefficient of 1.05, a dry-process static friction coefficient of 1.10, a glaze abrasion resistance of 12000 rpm, 4 grades, and a stain resistance of 5 grades (the wet-water static friction coefficient was measured by GB/T4100, the dry-process static friction coefficient was measured by GB/T4100, the abrasion resistance of the glaze was measured by GB/T3810.7, and the stain resistance of the glaze was measured by GB/T3810.14).
Example 3
The super wear-resistant anti-slip ceramic tile comprises a green body layer, a cover glaze layer and an anti-slip wear-resistant glaze layer, wherein the anti-slip wear-resistant glaze layer is composed of anti-slip wear-resistant glaze particles, a dispersing agent, water and sodium hexametaphosphate, and the anti-slip wear-resistant glaze particles are composed of the following raw materials in parts by weight: 23 parts of potassium feldspar, 15 parts of kaolin, 37 parts of calcined alumina, 38 parts of quartz sand, 8 parts of talcum powder, 15 parts of diatomite, 10 parts of barium carbonate, 6 parts of magnesium oxide, 4 parts of zinc oxide, 3.5 parts of yttrium oxide and 2 parts of lanthanum oxide.
Wherein:
in the anti-skid wear-resistant glaze layer, the weight part ratio of the anti-skid wear-resistant glaze particles to the dispersing agent to the water to the sodium hexametaphosphate is 115:0.35:53: 0.6.
The antiskid wear-resistant glaze comprises the following chemical components: al (Al)2O3 50％、SiO2 33％、K2O 5％、Na2O 2.5％、BaO 1％、MgO0.6％、CaO 2％、ZnO 1％、Fe2O3 0.8％、Y2O3 0.6％、La2O30.5% and loss on ignition 3.0%.
The dispersant is sodium carboxymethyl cellulose.
The green body layer is prepared from the following raw materials in parts by weight: 18 parts of potash feldspar, 12 parts of albite, 6.5 parts of diopside, 33 parts of zircon sand, 3 parts of iron ore, 22 parts of calcined kaolin, 5 parts of nepheline, 9 parts of bentonite and 3 parts of magnesium sulfate.
The overglaze layer comprises the following raw materials in parts by weight: 18 parts of potash feldspar, 8 parts of cordierite, 30 parts of high alumina, 18 parts of quartz sand, 15 parts of brown corundum, 6 parts of zinc oxide, 30 parts of zirconium silicate, 8 parts of calcined talc, 0.8 part of titanium dioxide and 0.4 part of sodium benzoate.
The super wear-resistant anti-slip ceramic tile further comprises a decorative layer.
The preparation method of the super wear-resistant anti-slip ceramic tile in the embodiment 3 comprises the following steps:
(1) the green body raw materials are ball-milled into slurry to form green body dry powder, and the dry powder is pressed in a mould pressing mode to prepare a ceramic tile green body;
(2) drying the ceramic tile green body at 180 ℃ for 13 h;
(3) and (3) applying surface glaze slurry to the ceramic tile green body dried in the step (2) to obtain a surface glaze layer, applying anti-skid and wear-resistant glaze slurry to obtain an anti-skid and wear-resistant glaze layer, and drying and sintering to obtain the super-wear-resistant and anti-skid ceramic tile.
Wherein:
the ball milling time in the step (1) is 6.5h, and the density of the slurry is 1.73g/cm3。
And (2) performing compression molding under the pressure of 73MPa in the step (1).
The water content of the ceramic tile green body in the step (1) is 5.8%.
And (3) the water content of the ceramic tile green body after drying in the step (2) is 0.8%.
Putting the overglaze raw material and water in the step (3) into a ball mill for ball milling to 200 meshes to obtain overglaze slurry, wherein the density of the overglaze slurry is 1.60g/cm3。
Putting the anti-skid wear-resistant glaze particles, the dispersing agent, the sodium hexametaphosphate and the water in the step (3) into a ball mill to be ball-milled to 400 meshes to obtain the anti-skid wear-resistant slurry, wherein the density of the anti-skid wear-resistant slurry is 1.55g/cm3。
And (4) drying at 650 ℃ for 0.5h in the step (3), and then heating to 1100 ℃ at the speed of 4 ℃/min to sinter for 2.5 h.
The ceramic tile obtained in example 3 had a wet-water static friction coefficient of 1.03, a dry-process static friction coefficient of 1.05, a glaze abrasion resistance of 12000 rpm, 4 th and 5 th levels of contamination resistance (the wet-water static friction coefficient was measured by GB/T4100, the dry-process static friction coefficient was measured by GB/T4100, the abrasion resistance of the glaze was measured by GB/T3810.7 and the contamination resistance of the glaze was measured by GB/T3810.14).
Comparative example 1
The ceramic tile of the comparative example 1 is the same as that of the example 3, and the only difference is that the antiskid wear-resistant glaze layer has different weight parts ratios of antiskid wear-resistant glaze particles, a dispersing agent, water and sodium hexametaphosphate, and the antiskid wear-resistant glaze layer has the weight parts ratio of the antiskid wear-resistant glaze particles, the dispersing agent, the water and the sodium hexametaphosphate of 130:0.50:60: 1.0.
The ceramic tile obtained in the comparative example 1 has the wet-water static friction coefficient of 0.48, the dry-method static friction coefficient of 0.50, the glaze abrasion resistance of 12000 turns, 3 grades and the pollution resistance of 4 grades (the wet-water static friction coefficient is tested by GB/T4100, the dry-method static friction coefficient is tested by GB/T4100, the glaze abrasion resistance is tested by GB/T3810.7 and the glaze pollution resistance is tested by GB/T3810.14).
Comparative example 2
The ceramic tile of the comparative example 2 is the same as that of the example 3, and the only difference is that the antiskid wear-resistant glaze layer and the antiskid wear-resistant glaze particles have different compositions, and the antiskid wear-resistant glaze particles comprise the following raw materials in parts by weight: 23 parts of potassium feldspar, 15 parts of kaolin, 45 parts of calcined alumina, 45 parts of quartz sand, 8 parts of talcum powder, 15 parts of diatomite, 10 parts of barium carbonate, 6 parts of magnesium oxide, 4 parts of zinc oxide, 3.5 parts of yttrium oxide and 2 parts of lanthanum oxide.
The ceramic tile obtained in the comparative example 2 has the wet-water static friction coefficient of 0.38, the dry-method static friction coefficient of 0.42, the glaze abrasion resistance of 12000 turns, 3 grades and the pollution resistance of 4 grades (the wet-water static friction coefficient is tested by GB/T4100, the dry-method static friction coefficient is tested by GB/T4100, the glaze abrasion resistance is tested by GB/T3810.7, and the glaze pollution resistance is tested by GB/T3810.14).
Comparative example 3
The ceramic tile of the comparative example 3 is the same as that of the example 3, and the only difference is that the antiskid wear-resistant glaze layer and the antiskid wear-resistant glaze particles have different compositions, and the antiskid wear-resistant glaze particles comprise the following raw materials in parts by weight: 23 parts of potassium feldspar, 15 parts of kaolin, 37 parts of calcined alumina, 38 parts of quartz sand, 8 parts of talcum powder, 15 parts of diatomite, 10 parts of barium carbonate, 6 parts of magnesium oxide and 2 parts of lanthanum oxide.
The ceramic tile obtained in the comparative example 3 has the wet-water static friction coefficient of 0.35, the dry-method static friction coefficient of 0.38, the glaze abrasion resistance of 12000 turns, 3 grades and the pollution resistance of 4 grades (the wet-water static friction coefficient is tested by GB/T4100, the dry-method static friction coefficient is tested by GB/T4100, the glaze abrasion resistance is tested by GB/T3810.7, and the glaze pollution resistance is tested by GB/T3810.14).
Comparative example 4
The ceramic tile of the comparative example 4 is the same as that of the example 3, and the only difference is that the raw materials of the overglaze layer are different, and the overglaze layer comprises the following raw materials in parts by weight: 20 parts of potash feldspar, 10 parts of cordierite, 35 parts of high alumina, 30 parts of quartz sand, 20 parts of brown corundum, 8 parts of zinc oxide, 20 parts of zirconium silicate, 7 parts of calcined talc, 1 part of titanium dioxide and 0.5 part of sodium benzoate.
The ceramic tile obtained in the comparative example 4 has the wet-water static friction coefficient of 0.33, the dry-method static friction coefficient of 0.36, the glaze abrasion resistance of 12000 turns, 3 grades and the pollution resistance of 4 grades (the wet-water static friction coefficient is tested by GB/T4100, the dry-method static friction coefficient is tested by GB/T4100, the glaze abrasion resistance is tested by GB/T3810.7, and the glaze pollution resistance is tested by GB/T3810.14).
Comparative example 5
The ceramic tile of the comparative example 5 is the same as that of the ceramic tile of the example 3, the preparation method is different at the only different point, and the overglaze raw material and water in the step (3) are placed in a ball mill to be ball-milled to 300 meshes to obtain overglaze slurry.
And (4) placing the antiskid wear-resistant glaze particles, the dispersing agent, the sodium hexametaphosphate and the water in the step (3) into a ball mill for ball milling to 450 meshes to obtain the antiskid wear-resistant slurry.
The ceramic tile obtained in the comparative example 5 has the wet-water static friction coefficient of 0.28, the dry-method static friction coefficient of 0.32, the glaze abrasion resistance of 12000 turns, 3 grades and the pollution resistance of 4 grades (the wet-water static friction coefficient is tested by GB/T4100, the dry-method static friction coefficient is tested by GB/T4100, the glaze abrasion resistance is tested by GB/T3810.7, and the glaze pollution resistance is tested by GB/T3810.14).
Claims (10)
1. The super wear-resistant anti-skid ceramic tile is characterized in that: the glaze comprises a body layer, a glaze cover layer and an anti-skid wear-resistant glaze layer, wherein the anti-skid wear-resistant glaze layer consists of anti-skid wear-resistant glaze particles, a dispersing agent, water and sodium hexametaphosphate, and the anti-skid wear-resistant glaze particles consist of the following raw materials in parts by weight: 20-25 parts of potassium feldspar, 15-20 parts of kaolin, 35-38 parts of calcined alumina, 35-40 parts of quartz sand, 8-12 parts of talcum powder, 10-15 parts of diatomite, 5-10 parts of barium carbonate, 5-8 parts of magnesium oxide, 3-5 parts of zinc oxide, 3-4 parts of yttrium oxide and 1-2 parts of lanthanum oxide.
2. The super wear resistant non-slip ceramic tile as claimed in claim 1, wherein: in the anti-skid wear-resistant glaze layer, the weight part ratio of the anti-skid wear-resistant glaze particles, the dispersing agent, the water and the sodium hexametaphosphate is 110-120:0.3-0.4:50-55: 0.3-0.8.
3. The super wear resistant non-slip ceramic tile as claimed in claim 1, wherein: the dispersant is sodium carboxymethyl cellulose.
4. The super wear resistant non-slip ceramic tile as claimed in claim 1, wherein: the antiskid wear-resistant glaze comprises the following chemical components: al (Al)2O3 50-55％、SiO2 30-35％、K2O 5-7％、Na2O 2-3％、BaO 1-3％、MgO 0.5-1.5％、CaO 1-3％、ZnO 1-2％、Fe2O3 0.8-1.0％、Y2O3 0.5-0.8％、La2O30.3-0.5% and loss on ignition 2-4.5%.
5. The super wear resistant non-slip ceramic tile as claimed in claim 1, wherein: the green body layer is prepared from the following raw materials in parts by weight: 15-20 parts of potash feldspar, 10-15 parts of albite, 5-8 parts of diopside, 30-35 parts of zircon sand, 3-5 parts of iron ore, 20-25 parts of calcined kaolin, 1-5 parts of nepheline, 8-10 parts of bentonite and 1-3 parts of magnesium sulfate.
6. The super wear resistant non-slip ceramic tile as claimed in claim 1, wherein: the overglaze layer comprises the following raw materials in parts by weight: 15-20 parts of potassium feldspar, 5-10 parts of cordierite, 20-35 parts of high alumina, 15-20 parts of quartz sand, 10-15 parts of brown corundum, 5-8 parts of zinc oxide, 20-30 parts of zirconium silicate, 5-8 parts of calcined talc, 0.5-1 part of titanium dioxide and 0.3-0.5 part of sodium benzoate.
7. A method for preparing the super wear-resistant anti-slip ceramic tile as claimed in claim 1, wherein: the method comprises the following steps:
(1) the green body raw materials are ball-milled into slurry to form green body dry powder, and the dry powder is pressed in a mould pressing mode to prepare a ceramic tile green body;
(2) drying the ceramic tile green body at the temperature of 150-;
(3) and (3) applying surface glaze slurry to the ceramic tile green body dried in the step (2) to obtain a surface glaze layer, applying anti-skid and wear-resistant glaze slurry to obtain an anti-skid and wear-resistant glaze layer, and drying and sintering to obtain the super-wear-resistant and anti-skid ceramic tile.
8. The method for preparing the super wear-resistant anti-slip ceramic tile according to claim 7, wherein the method comprises the following steps:
the ball milling time in the step (1) is 5-8h, and the density of the slurry is 1.70-1.75g/cm3；
Compression molding under the pressure of 70-75MPa in the step (1);
the water content of the ceramic tile green body in the step (1) is 5.5-6.0%;
the water content of the ceramic tile green body dried in the step (2) is 0.5-1%.
9. The method for preparing the super wear-resistant anti-slip ceramic tile according to claim 7, wherein the method comprises the following steps:
putting the overglaze raw material and water in the step (3) into a ball millBall-milling to 100-200 meshes to obtain the overglaze slurry with the density of 1.60-1.65g/cm3；
Placing the anti-skid wear-resistant glaze particles, the dispersing agent, the sodium hexametaphosphate and the water in the step (3) into a ball mill to be ball-milled to 300-400 meshes to obtain the anti-skid wear-resistant slurry, wherein the density of the anti-skid wear-resistant slurry is 1.55-1.6g/cm3。
10. The method for preparing the super wear-resistant anti-slip ceramic tile according to claim 7, wherein the method comprises the following steps: the drying in the step (3) is carried out at 650 ℃ of 550-650 ℃ for 0.5-1h, and then the temperature is raised to 1150 ℃ at the rate of 3-5 ℃/min for 2-3 h.
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