CN110054510A - A kind of anti-skidding ink-jet Ceramic Tiles of wet water height and preparation method thereof with sagging glaze effect - Google Patents
A kind of anti-skidding ink-jet Ceramic Tiles of wet water height and preparation method thereof with sagging glaze effect Download PDFInfo
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- CN110054510A CN110054510A CN201910535126.1A CN201910535126A CN110054510A CN 110054510 A CN110054510 A CN 110054510A CN 201910535126 A CN201910535126 A CN 201910535126A CN 110054510 A CN110054510 A CN 110054510A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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Abstract
The present invention provides a kind of anti-skidding ink-jet Ceramic Tiles of wet water height and preparation method thereof with sagging glaze effect; the preparation method includes: successively to apply anti-skidding overglaze on green body, decorative pattern, Shi Liangguang effect glaze, apply anti-skidding protection glaze, is then burnt into, the mineral composition of the formula of the anti-skidding overglaze are as follows: potassium feldspar 40~50%; albite 0~10%; kaolin 7~10%, quartz 8~12%, calcined alumina 8~11%; nepheline 0~5%; zinc oxide 2~4%, zirconium silicate 7~10%, barium carbonate 6~10%;The mineral composition of the formula of the anti-skidding protection glaze are as follows: potassium feldspar 48~58%, albite 0~10%, kaolin 10~20%, quartz 0~5%, nepheline 0~4%, calcined alumina 2~5%, barium carbonate 10~15%, zinc oxide 5~8%.Skid-proof ceramic tile of the invention can be used as that a kind of decorative effect is good, and stain resistance is excellent and ornament materials with non-skid property, can be applied to house ornamentation field.
Description
Technical field
High anti-skidding ink-jet Ceramic Tiles of the wet water with sagging glaze effect and preparation method thereof that the present invention relates to a kind of, belong to pottery
Ceramic tile manufacturing technology field.
Background technique
Ceramic Tiles are good as a kind of decorative effect, and the excellent ornament materials of anti-fouling performance is widely used in luxurious height
The places such as In Public Places of Hotels, mall, office building and the family apartment of shelves, but Ceramic Tiles but have ignored while beautifying the environment
Ground is wet and slippery and easily leads to the problem of slipping, and causes the accident to fall and hurt oneself frequently to occur because ground is too smooth.
The ceramic tile with antiskid effect is substantially all using the convex glaze of silk-screen printing or some high temperature of spray on a small quantity currently on the market
Dry granular causes the rough effect of glaze presentation after firing to carry out on-slip.Using the Ceramic Tiles of this technique, its glaze is uneven,
Not only it had been easy the dirty more difficult cleaning in hiding, but also has influenced visually aesthetics.The glaze glossiness of usual anti-skid brick it is lower at 10 degree hereinafter, giving
The decorative visual effects of people are more dull.
Summary of the invention
In view of the above-mentioned problems, the purpose of the present invention is to provide a kind of light, dumb lights to combine, " sagging glaze " effect is realized
Anti-skidding glazed tile, to the visual impression that people is scintillating while having non-skid property.
In a first aspect, the present invention provides a kind of preparation method of skid-proof ceramic tile, comprising: successively apply non slip surface on green body
Glaze, Shi Liangguang effect glaze, applies anti-skidding protection glaze at decorative pattern, is then burnt into, the mineral composition of the formula of the anti-skidding overglaze
Are as follows: potassium feldspar 40~50%, albite 0~10%, kaolin 7~10%, quartz 8~12%, calcined alumina 8~11%, nepheline 0
~5%, zinc oxide 2~4%, zirconium silicate 7~10%, barium carbonate 6~10%;The mineral composition of the formula of the anti-skidding protection glaze are as follows:
Potassium feldspar 48~58%, albite 0~10%, kaolin 10~20%, quartz 0~5%, nepheline 0~4%, calcined alumina 2~5%,
Barium carbonate 10~15%, zinc oxide 5~8%.
The wet water confficient of static friction of skid-proof ceramic tile of the invention is up to 0.8 or more, and dry, wet water confficient of static friction difference
0.03 or more;Anti-skidding overglaze combines anti-skidding protection glaze to make pattern color development bright-coloured;Glaze wear resistance can reach 4 grades, 2100 turns;
5 grades of stain resistance;It is fused by light effect glaze and anti-skidding protection glaze, realizes the effect for " the sagging glaze " that light, dumb light combine,
It can be used as that a kind of decorative effect is good, stain resistance is excellent and ornament materials with non-skid property, can be applied to house ornamentation field.
Preferably, the chemical composition of the anti-skidding overglaze are as follows: SiO2: 51~55%, Al2O3: 19~23%, Fe2O3: 0~
0.4%、TiO2: 0~0.2%, CaO:0~0.5%, MgO:0~0.2%, K2O:3.5~5.0%, Na2O:2.0~3.0%, BaO:4.5
~8.0%, ZnO:2~4%, ZrO2: 4.0~6.5%, it burns and loses: 2.0~4.0%.
Preferably, the anti-skidding overglaze is using leaching glaze mode glazing, glaze pouring parameter are as follows: specific gravity is 1.80~1.84,
Weight is 420~500g/m2。
Preferably, the method for decorative pattern is inkjet printing.
Preferably, the mineral composition of the light effect glaze are as follows: albite 58~68%: calcined kaolin: 13~15%, silicon
Lime stone: 10~15%, burning talcum: 6~10%, calcining zinc oxide 1~3%, barium carbonate: 0~1%.
Preferably, the chemical composition of the light effect glaze are as follows: SiO2: 63.0~67.0%, Al2O3: 15.0~18.5%,
Fe2O3: 0~0.3%, TiO2: 0~0.3%, CaO:4.5~7.5%, MgO:2.0~3.5%, K2O:0.2~0.5%, Na2O:5.0~
6.5%, BaO:0~1.0%, ZnO:0.5~3.0% burn and lose: 0.5~1.2%.
Preferably, the light effect glaze uses silk screen according to ceramic ink design and the matched web plate of ink pattern
Mode of printing glazing.
Preferably, the chemical composition of the anti-skidding protection glaze are as follows: SiO2: 50.0~53.0%, Al2O3: 18.0~20.0%,
Fe2O3: 0~0.4%, TiO2: 0~0.2%, CaO:0~0.5%, MgO:0~0.2%, K2O:4.5~6.0%, Na2O:2.0~
3.0%, BaO:7.0~12.0%, ZnO:4.0~8.0% burn and lose 3.5~6.0%.
Preferably, the anti-skidding protection glaze use the glazing of glaze spraying mode, glaze spraying technological parameter are as follows: specific gravity be 1.26~
1.30, weight is 110~140 g/m2。
Second aspect, the present invention provide a kind of skid-proof ceramic tile prepared by any of the above-described preparation method.
Detailed description of the invention
Fig. 1 is the flow sheet of an embodiment of the present invention.
Specific embodiment
The present invention is further illustrated below by way of following embodiments, it should be appreciated that following embodiments are merely to illustrate this
Invention, is not intended to limit the present invention.Following percentage composition refers both to mass percentage unless otherwise instructed.
Fig. 1 shows the flow sheet of an embodiment of the present invention.
As shown in Figure 1, firstly, preparing green body.Green body can be suppressed by ceramic matrix commonly used in the art and be obtained.
It then, can be by body drying.Drying time can be 50~75min, and dry base moisture control is within 0.5%.
Then, anti-skidding overglaze is applied on green body.In some embodiments, the mineral composition of anti-skidding overglaze glaze formula is that potassium is long
Stone 40~50%, albite 0~10%, kaolin 7~10%, quartz 8~12%, calcined alumina 8~11%, nepheline 0~5%, oxygen
Change zinc 2~4%, zirconium silicate 7~10%, barium carbonate 6~10%.Using the non slip surface glaze formula of the system, potassium content is higher, firing
Wider range does not introduce calcium carbonate in formula, dolomite, wollastonite, burns the calcium, magnesium class material such as talcum, is conducive to ceramics yet
The color development of ink, and keep ceramic ink color development bright-coloured.The non slip surface glaze formula of the system is while glaze exquisite in texture itself
With preferable antiskid effect, not needing silk screen or the dotted glaze of roller printing or sprinkling high temperature dry granular causes to present after being burnt into
Rough effect is come anti-skidding.
In some embodiments, the chemical composition of anti-skidding overglaze can are as follows: SiO2: 51~55%, Al2O3: 19~23%, Fe2O3:
0~0.4%, TiO2: 0~0.2%, CaO:0~0.5%, MgO:0~0.2%, K2O:3.5~5.0%, Na2O:2.0~3.0%, BaO:
4.5~8.0%, ZnO:2~4%, ZrO2: 4.0~6.5%, it burns and loses 2.0~4.0%.
Anti-skidding overglaze can be used leaching the glazing of glaze mode, take leaching non slip surface glaze Ceramic Tiles glaze exquisite in texture, glaze without
Concave-convex sense flatness is good, can reach it is puckery without thick, carefully without sliding glaze antiskid effect.Glaze pouring parameter can are as follows: specific gravity
1.80~1.84, weight is 420~500g/m2。
Then, the decorative pattern on anti-skidding cover coat.In preferred embodiment, the method for decorative pattern is inkjet printing figure
Case.It can be printed using digital ink-jet printer.Ink commonly used in the art can be used in the ceramic ink used.
Then, Shi Liangguang effect glaze.In some embodiments, the mineral composition of light effect glaze formula can are as follows: albite
58~68%: calcined kaolin: 13~15%, wollastonite: 10~15%, burning talcum: 6~10%, calcining zinc oxide 1~3%, carbonic acid
Barium: 0~1%.The glossiness of light effect glaze can be 65~85 degree.Using the mineral composition glaze glossiness can reach with it is anti-skidding
The glossiness (10 degree of glossiness or less) of glaze presents a contrast, and glaze beginning fusing point is high, and glaze is pin-free.
In some embodiments, light effect glaze chemical composition are as follows: SiO2: 63~67%, Al2O3: 15~18.5%, Fe2O3:
0~0.3%, TiO2: 0~0.3%, CaO:4.5~7.5%, MgO:2.0~3.5%, K2O:0.2~0.5%, Na2O:5.0~6.5%,
BaO:0~1.0%, ZnO:0.5~3.0% burn and lose: 0.5~1.2%.
In some embodiments, light effect glaze can design according to ink-jetting pattern and use silk with the matched web plate of ink pattern
Net mode of printing glazing, that is to say, that dotted or linear web plate silk-screen printing light effect can be designed according to ink pattern
Glaze.The technology of silk-screen printing is highly developed, easy to operate, and use cost is relatively low relative to roller printing.Silk-screen printing is adopted
Web plate can be 80~140 mesh, can achieve sagging effect using the web plate of the mesh number, and effect glaze layer is spent thoroughly and can dash forward
The color of aobvious ink;Light effect can only occur greater than 140 mesh, then without obvious effect of sinking.
Then, anti-skidding protection glaze is applied.Anti-skidding protection glaze is matte effect, and glossiness is at 10 degree hereinafter, with light effect glaze
Mutually fusion goes out the light effect that recess is presented in glaze, the position of no light effect glaze in the position for having printed light effect glaze
It is then matte effect, the bright dumb light for not only realizing glaze combines, but also has " sagging glaze " effect.The light effect glaze is
Colourless transparence not will lead to ceramic ink discoloration.Sagging glaze in usual industry is inclined by introducing inside low temperature glaze
The surface tension such as ammonium vanadate or vanadic anhydride are sintering process is caused to generate contracting glaze effect for the oxide of negative value and is in now
Sunken effect, but the tone of vanadium zirconium Huang is then presented using the sagging glaze of barium oxide, easily lead to the discoloration of glaze ink color.
In some embodiments, it is anti-skidding protection glaze formula mineral composition be potassium feldspar 48~58%, albite 0~10%,
Kaolin 10~20%, quartz 0~5%, nepheline 0~4%, calcined alumina 2~5%, barium carbonate 10~15%, zinc oxide 5~8%.
Using the anti-skidding protection glaze formula of the system, potassium content is higher, and firing range is wider, does not introduce calcium carbonate, white in formula
Marble, burns the calcium, magnesium class material such as talcum at wollastonite, is not only conducive to the color development of ceramic ink, but also keep ceramic ink color development fresh
It is gorgeous.Using the anti-skidding protection glaze formula of the system, transparency is preferable, and anti-fouling performance is good, and has preferable wearability.The body
The anti-skidding protection glaze formula of system has preferable antiskid effect while glaze exquisite in texture itself, does not need silk screen or roller
Cylinder prints dotted glaze or sprinkling high temperature dry granular cause to present after firing rough effect come it is anti-skidding.
In some embodiments, anti-skidding protection glaze chemical composition are as follows: SiO2: 50.0~53.0%, Al2O3: 18.0~
20.0%、Fe2O3: 0~0.4%, TiO2: 0~0.2%, CaO:0~0.5%, MgO:0~0.2%, K2O:4.5~6.0%, Na2O:2.0
~3.0%, BaO:7.0~12.0%, ZnO:5.0~8.0% burn and lose 3.5~6.0%.
No matter anti-skidding overglaze or anti-skidding protection glaze all have preferable antiskid effect, and anti-skidding protection glaze in the present invention
It can also promote the color development of ceramic ink and improve the stain resistance of glaze.
Glaze spraying mode glazing can be used in anti-skidding protection glaze, and only need to spray a small amount of anti-skidding protection glaze can reach promotion ceramic ink
The color development of water had not only guaranteed that glaze had good stain resistance, but also can guarantee that glaze face color is persistently wear-resisting.Glaze spraying technological parameter can
Are as follows: specific gravity 1.26~1.30, weight are 110~140 g/m2.Since the formulation cost of anti-skidding protection glaze is higher, using the glaze spraying
Technique can achieve that glaze volume is few, reduce the purpose of production cost.
Then, resulting green body is burnt into, obtains Ceramic Tiles.Firing period can be 55~65 minutes, maximum sintering temperature
It can be 1210~1230 DEG C.
Edging classification etc. can also be carried out after firing.
Resulting Ceramic Tiles can from bottom to top successively include: green body, anti-skidding cover coat, pattern layer, light effect glaze layer, prevent
Sliding protection glaze layer.
Ceramic Tiles of the invention especially can be used as ship-and-galley tile use.The wet water of the Ceramic Tiles of some embodiments of the present invention
Confficient of static friction is up to 0.8 or more, and dry, wet water confficient of static friction difference can be 0.03 or more.
In the Ceramic Tiles of some embodiments of the present invention, anti-skidding overglaze combines anti-skidding protection glaze that ink color development can be made bright-coloured,
The material for not introducing calcium, magnesium class in anti-skidding glaze formula introduces the materials such as high potassium, Gao Xin, high barium class conducive to ceramic ink color development
And keep ceramic ink color development bright-coloured.
The glaze wear resistance of the Ceramic Tiles of some embodiments of the present invention can reach 4 grades, 2100 turns;5 grades of stain resistance.
Ceramic Tiles of the invention, the technique combined by light effect glaze with anti-skidding protection glaze, realize light, dumb light knot
The effect of " the sagging glaze " that closes, can be used as that a kind of decorative effect is good, and anti-fouling performance is excellent and decoration with non-skid property
Material can be applied to house ornamentation field.
Enumerate embodiment further below with the present invention will be described in detail.It will similarly be understood that following embodiment is served only for this
Invention is further described, and should not be understood as limiting the scope of the invention, those skilled in the art is according to this hair
Some nonessential modifications and adaptations that bright above content is made all belong to the scope of protection of the present invention.Following examples are specific
Technological parameter etc. is also only an example in OK range, i.e. those skilled in the art can be done properly by the explanation of this paper
In the range of select, and do not really want to be defined in hereafter exemplary specific value.
Embodiment 1
Step 1: green body is prepared.Green body is suppressed by ceramic matrix commonly used in the art and is obtained.
Step 2: preparing anti-skidding overglaze: potassium feldspar 50% according to the proportion, kaolin 7%, quartz 12%, calcined alumina 11%,
Nepheline 5%, zirconium silicate 7%, zinc oxide 2%, barium carbonate 6%.The chemical composition of anti-skidding overglaze are as follows: SiO2: 54.82%, Al2O3:
22.96%、Fe2O3: 0.2%, TiO2: 0.06%, CaO:0.5%, MgO:0.17%, K2O:4.83%, Na2O:2.74%, BaO:4.65%,
ZnO:2%, ZrO2: 4.46%, it burns and loses: 2.83%.Anti-skidding overglaze is drenched by the way of drenching glaze in adobe after the drying.Glaze ratio
1.84 are weighed, glaze amount 420g/m is drenched2。
Step 3: inkjet printing pattern is carried out with ink jet printer.
Step 4: light effect glaze: albite 68%: calcined kaolin is prepared according to the proportion: 15%, wollastonite: 10%, it burns
Talcum: 6%, calcining zinc oxide 1%.The chemical composition of light effect glaze are as follows: SiO2: 66.51%, Al2O3: 18.18%, Fe2O3:
0.16%、TiO2: 0.13%, CaO:4.78%, MgO:2.16%, K2O:0.34%, Na2O:6.11%, ZnO:0.99% burn and lose: 0.5%.
Corresponding point, lines web plate are designed according to ink-jetting pattern, with 80~140 mesh screen printing light effect glaze.
Step 5: anti-skidding protection glaze: potassium feldspar 48%, albite 10%, kaolin 20%, calcined oxide are prepared according to the proportion
Aluminium 2%, barium carbonate: 15%, zinc oxide 5%.The chemical composition of anti-skidding protection glaze are as follows: SiO2: 50.56%, Al2O3: 18.25%, Fe2O3:
0.32%、TiO2: 0.05%, CaO:0.29%, MgO:0.18%, K2O:4.78%, Na2O:2.72%, BaO:11.63%, ZnO:
4.96%, it burns and loses: 5.86%.Spray anti-skidding protection glaze, specific gravity 1.30, glaze volume 110g/ m2。
Step 6: roller kilns are rapidly fired to.1230 DEG C of maximum sintering temperature, firing period 55min.
Step 7: edging classification.
Wet water static friction is tested using the wet process test method in GB/T 4100-2015 annex M " measurement of coefficient of friction "
Coefficient tests dry method static friction system using the dry method test method in GB/T 4100-2015 annex M " measurement of coefficient of friction "
Number is tested glaze wear resistance using the test method in GB/T 3810.7-2016 " measurement of glazed tile surface abrasion resistance ", is adopted
Glaze stain resistance is tested with the test method in GB/T 3810.14-2016 " measurement of stain resistance ".Using GB/T
The test method of 13891-2008 " measurement of building facing material mirror luster degree " tests glaze glossiness.
The wet water confficient of static friction of the resulting Ceramic Tiles of embodiment 1 is 0.8, and dry method confficient of static friction is 0.83, and glaze is resistance to
Grit is 2100 turns, and 4 grades, 5 grades of stain resistance, matte surface glossiness is 5 degree, 65 degree of light glossiness.
Embodiment 2
Step 1: green body is prepared.Green body is suppressed by ceramic matrix commonly used in the art and is obtained.
Step 2: preparing anti-skidding overglaze: potassium feldspar 40% according to the proportion, albite 10%, kaolin 10%, quartz: 8%, it forges
Burn aluminium oxide 8%, zirconium silicate 10%, barium carbonate 10%, zinc oxide 4%.The chemical composition of anti-skidding overglaze are as follows: SiO2: 51.40%,
Al2O3: 19.60%, Fe2O3: 0.22%, TiO2: 0.06%, CaO:0.25%, MgO:0.17%, K2O:3.84%, Na2O:2.34%,
BaO:7.75%, ZnO:3.99%, ZrO2: 6.37%, it burns and loses: 3.76%.It is drenched by the way of drenching glaze in adobe after the drying anti-
Sliding surface glaze.Glaze specific gravity 1.80 drenches glaze amount 500g/m2。
Step 3: inkjet printing pattern is carried out with ink jet printer.
Step 4: light effect glaze: albite 58%: calcined kaolin is prepared according to the proportion: 13%, wollastonite: 15%, it burns
Talcum: 10%, calcining zinc oxide 3%, barium carbonate 1%.The chemical composition of light effect glaze are as follows: SiO2: 63.28%, Al2O3:
15.66%、Fe2O3: 0.16%, TiO2: 0.13%, CaO:7.05%, MgO:3.49%, K2O:0.31%, Na2O:5.24%, BaO:
0.78%, ZnO:2.98% burn and lose: 0.8%.According to the corresponding point of ceramic ink jet design, lines web plate, with 80~140 mesh nets
Plate prints light effect glaze.
Step 5: preparing anti-skidding protection glaze: potassium feldspar 58% according to the proportion, and kaolin 10% is quartzy: 5%, nepheline: and 4%, it forges
Aluminium oxide 5% is burnt, barium carbonate: 10%, zinc oxide 8%.The chemical composition of anti-skidding protection glaze are as follows: SiO2: 52.33%, Al2O3:
19.30%、Fe2O3: 0.23%, TiO2: 0.04%, CaO:0.48%, MgO:0.16%, K2O:5.55%, Na2O:2.31%, BaO:
7.75%, ZnO:7.94% burn and lose: 3.88%.Spray anti-skidding protection glaze, specific gravity 1.26, glaze volume 140g/ m2。
Step 6: roller kilns are rapidly fired to.1210 DEG C of maximum sintering temperature, firing period 65min.
Step 7: edging classification.
The wet water confficient of static friction of the resulting Ceramic Tiles of embodiment 2 is 0.81, and dry method confficient of static friction is 0.84, and glaze is resistance to
Grit is 2100 turns, and 4 grades, 5 grades of stain resistance, matte surface glossiness is 6 degree, 85 degree of light glossiness.
Embodiment 3
Step 1: green body is prepared.Green body is suppressed by ceramic matrix commonly used in the art and is obtained.
Step 2: preparing anti-skidding overglaze: potassium feldspar 45% according to the proportion, albite 5%, kaolin 8.5%, quartz: 10%, it forges
Aluminium oxide 9.5% is burnt, nepheline: 2.5%, zinc oxide 3%, zirconium silicate 8.5%, barium carbonate 8%.The chemical composition of anti-skidding overglaze are as follows:
SiO2: 53.04%, Al2O3: 21.28%, Fe2O3: 0.22%, TiO2: 0.06%, CaO:0.39%, MgO:0.17%, K2O:4.33%,
Na2O:2.54%, BaO:6.20%, ZnO:2.99%, ZrO2: 5.42%, it burns and loses: 3.36%.Using leaching glaze in adobe after the drying
Mode drench anti-skidding overglaze.Glaze specific gravity 1.82 drenches glaze amount 460g/m2。
Step 3: inkjet printing pattern is carried out with ink jet printer.
Step 4: light effect glaze: albite 63%: calcined kaolin is prepared according to the proportion: 14%, wollastonite: 12.5%,
Burning talcum: 8%, calcining zinc oxide 2%, barium carbonate 0.5%.The chemical composition of light effect glaze are as follows: SiO2: 64.90%, Al2O3:
16.92%、Fe2O3: 0.16%, TiO2: 0.13%, CaO:5.92%, MgO:2.82%, K2O:0.32%, Na2O:5.68%, BaO:
0.39%, ZnO:1.99% burn and lose: 0.65%.Corresponding point, lines web plate are designed according to ink-jetting pattern, with 80~140 mesh web plates
Print light effect glaze.
Step 5: anti-skidding protection glaze: potassium feldspar 53% is prepared according to the proportion, albite 5%: kaolin 15%, quartz: 2.5%,
Nepheline: 2%, calcined alumina 3.5%, barium carbonate: 12.5%, zinc oxide 6.5%.The chemical composition of anti-skidding protection glaze are as follows: SiO2:
51.65%、Al2O3: 18.68%, Fe2O3: 0.28%, TiO2: 0.04%, CaO:0.39%, MgO:0.16%, K2O:5.16%, Na2O:
2.51%, BaO:9.69%, ZnO:6.45% burn and lose: 4.88%.Spray anti-skidding protection glaze, specific gravity 1.28, glaze volume 125g/ m2。
Step 6: roller kilns are rapidly fired to.1220 DEG C of maximum sintering temperature, firing period 60min.
Step 7: edging classification.
The wet water confficient of static friction of the resulting Ceramic Tiles of embodiment 3 is 0.80, and dry method confficient of static friction is 0.83, and glaze is resistance to
Grit is 2100 turns, and 4 grades, 5 grades of stain resistance, matte surface glossiness is 5 degree, and light glossiness is 75 degree.
Claims (9)
1. a kind of preparation method of skid-proof ceramic tile characterized by comprising successively apply anti-skidding overglaze, decoration figure on green body
Case, applies anti-skidding protection glaze at Shi Liangguang effect glaze, is then burnt into, the mineral composition of the formula of the anti-skidding overglaze are as follows: potassium feldspar 40
~50%, albite 0~10%, kaolin 7~10%, quartz 8~12%, calcined alumina 8~11%, nepheline 0~5%, zinc oxide 2
~4%, zirconium silicate 7~10%, barium carbonate 6~10%;The mineral composition of the formula of the anti-skidding protection glaze are as follows: potassium feldspar 48~
58%, albite 0~10%, kaolin 10~20%, quartz 0~5%, nepheline 0~4%, calcined alumina 2~5%, barium carbonate 10~
15%, zinc oxide 5~8%.
2. preparation method according to claim 1, which is characterized in that the chemical composition of the anti-skidding overglaze are as follows: SiO2: 51
~55%, Al2O3: 19~23%, Fe2O3: 0~0.4%, TiO2: 0~0.2%, CaO:0~0.5%, MgO:0~0.2%, K2O:3.5
~5.0%, Na2O:2.0~3.0%, BaO:4.5~8.0%, ZnO:2~4%, ZrO2: 4.0~6.5%, it burns and loses: 2.0~4.0%.
3. preparation method according to claim 1, which is characterized in that the anti-skidding overglaze is using leaching glaze mode glazing, leaching
Glaze handicraft parameter are as follows: specific gravity is 1.80~1.84, and weight is 420~500g/m2。
4. preparation method according to claim 1, which is characterized in that the method for decorative pattern is inkjet printing.
5. preparation method according to claim 1, which is characterized in that the mineral composition of the light effect glaze are as follows: sodium is long
Stone 58~68%: calcined kaolin: 13~15%, wollastonite: 10~15%, burning talcum: 6~10%, calcining zinc oxide 1~3%, carbon
Sour barium: 0~1%, the chemical composition of the light effect glaze are as follows: SiO2: 63.0~67.0%, Al2O3: 15.0~18.5%, Fe2O3:
0~0.3%, TiO2: 0~0.3%, CaO:4.5~7.5%, MgO:2.0~3.5%, K2O:0.2~0.5%, Na2O:5.0~6.5%,
BaO:0~1.0%, ZnO:0.5~3.0% burn and lose: 0.5~1.2%.
6. preparation method according to claim 1, which is characterized in that the light effect glaze is set according to ceramic ink pattern
Meter uses screen printing mode glazing with the matched web plate of ink pattern.
7. preparation method according to claim 1, which is characterized in that the chemical composition of the anti-skidding protection glaze are as follows: SiO2:
50.0~53.0%, Al2O3: 18.0~20.0%, Fe2O3: 0~0.4%, TiO2: 0~0.2%, CaO:0~0.5%, MgO:0~
0.2%、K2O:4.5~6.0%, Na2O:2.0~3.0%, BaO:7.0~12.0%, ZnO:4.0~8.0% burn and lose: 3.5~6.0%.
8. preparation method according to any one of claim 1 to 7, which is characterized in that the anti-skidding protection glaze is using spray
Glaze mode glazing, glaze spraying technological parameter are as follows: specific gravity is 1.26~1.30, and weight is 110~140 g/m2。
9. a kind of skid-proof ceramic tile prepared by preparation method described in any item of the claim 1 to 8.
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2947057A1 (en) * | 2013-01-21 | 2015-11-25 | Torrecid, S.A. | Digital glaze for high grammage, without the use of anti-settling agents |
EP3075714A1 (en) * | 2015-03-31 | 2016-10-05 | Consejo Superior De Investigaciones Cientificas | Glass-ceramic material of albite and/or anorthite exhibing warmth |
CN206069715U (en) * | 2016-09-26 | 2017-04-05 | 广东协进陶瓷有限公司 | A kind of production line of magic glazed tile |
CN107265861A (en) * | 2017-07-21 | 2017-10-20 | 广东金意陶陶瓷集团有限公司 | The preparation method of the easy clean Ceramic Tiles of anti-skid wearable |
CN107285737A (en) * | 2017-07-21 | 2017-10-24 | 广东金意陶陶瓷集团有限公司 | The easy clean Ceramic Tiles of anti-skid wearable |
CN107382061A (en) * | 2017-07-14 | 2017-11-24 | 东莞市唯美陶瓷工业园有限公司 | A kind of anti-skidding glaze, anti-skid brick and preparation method thereof |
CN107540345A (en) * | 2017-09-30 | 2018-01-05 | 福建德胜新建材有限公司 | A kind of ultra-fine dry granular porcelain glazed brick |
CN109279920A (en) * | 2018-10-09 | 2019-01-29 | 肇庆乐华陶瓷洁具有限公司 | A kind of wear-resisting antiskid brick and preparation method thereof |
CN109354406A (en) * | 2018-11-14 | 2019-02-19 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
CN106554156B (en) * | 2016-11-28 | 2019-06-07 | 蒙娜丽莎集团股份有限公司 | The primary preparation method for firing porcelain heap ornamental slab for paving the floor |
-
2019
- 2019-06-20 CN CN201910535126.1A patent/CN110054510B/en active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2947057A1 (en) * | 2013-01-21 | 2015-11-25 | Torrecid, S.A. | Digital glaze for high grammage, without the use of anti-settling agents |
EP3075714A1 (en) * | 2015-03-31 | 2016-10-05 | Consejo Superior De Investigaciones Cientificas | Glass-ceramic material of albite and/or anorthite exhibing warmth |
CN206069715U (en) * | 2016-09-26 | 2017-04-05 | 广东协进陶瓷有限公司 | A kind of production line of magic glazed tile |
CN106554156B (en) * | 2016-11-28 | 2019-06-07 | 蒙娜丽莎集团股份有限公司 | The primary preparation method for firing porcelain heap ornamental slab for paving the floor |
CN107382061A (en) * | 2017-07-14 | 2017-11-24 | 东莞市唯美陶瓷工业园有限公司 | A kind of anti-skidding glaze, anti-skid brick and preparation method thereof |
CN107265861A (en) * | 2017-07-21 | 2017-10-20 | 广东金意陶陶瓷集团有限公司 | The preparation method of the easy clean Ceramic Tiles of anti-skid wearable |
CN107285737A (en) * | 2017-07-21 | 2017-10-24 | 广东金意陶陶瓷集团有限公司 | The easy clean Ceramic Tiles of anti-skid wearable |
CN107540345A (en) * | 2017-09-30 | 2018-01-05 | 福建德胜新建材有限公司 | A kind of ultra-fine dry granular porcelain glazed brick |
CN109279920A (en) * | 2018-10-09 | 2019-01-29 | 肇庆乐华陶瓷洁具有限公司 | A kind of wear-resisting antiskid brick and preparation method thereof |
CN109354406A (en) * | 2018-11-14 | 2019-02-19 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
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