CN109279920A - A kind of wear-resisting antiskid brick and preparation method thereof - Google Patents
A kind of wear-resisting antiskid brick and preparation method thereof Download PDFInfo
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- CN109279920A CN109279920A CN201811172836.4A CN201811172836A CN109279920A CN 109279920 A CN109279920 A CN 109279920A CN 201811172836 A CN201811172836 A CN 201811172836A CN 109279920 A CN109279920 A CN 109279920A
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- glaze
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- glaze slip
- slip
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention discloses a kind of preparation methods of wear-resisting antiskid brick, comprising: is sequentially prepared ground coat enamel, protection glaze, decorative pattern, overglaze in billet surface, then dries, obtains wear-resisting antiskid brick finished product after firing.The present invention effectively improves the glaze volume on ceramic tile blank surface by applying overglaze, the mode of application protection glaze at least twice, so that the wearability of ceramic tile surface is improved, ceramic tile surface Mohs' hardness >=7 in the present invention;On the other hand, by special glaze paint, so that ceramic tile has achieved the effect that anti-skidding, ceramic tile coefficient of friction >=0.8 in the present invention.
Description
Technical field
The invention belongs to Ceramic Tiles preparation fields more particularly to a kind of wear-resisting antiskid brick and preparation method thereof.
Background technique
Antique Imitation Tiles are a kind of bricks with antique effect glaze paint, are generally Shi porcelain or porcelain.Antique Imitation Tiles glaze paint is unique,
It is the product quite to get consumer reception often with classic flavor.In order to enrich the type of Antique Imitation Tiles, mostly uses apply ground coat enamel-at present
The technique that overglaze is applied in ink jet printing-is produced;Ink jet printing greatly improves the diversity of decorative pattern, so that Antique Imitation Tiles kind
Class is more various.But when using ink jet printing decorative pattern, in order to enable decorative effect is more obvious, generally use transparent
Overglaze protects decorative pattern;However, this transparent overglaze often has the problem of several aspects: 1, this transparent overglaze
General crystalline content is lower, so that brick surface hardness is too low, Mohs' hardness is often in 5-6 or so;This was installing Antique Imitation Tiles
It is very easy to scratch in journey;Also it is easy to grind off overglaze after used a period of time, grinds off decorative pattern, strong influence decoration
Effect;2, the melting temperature of overglaze is reduced, so that Antique Imitation Tiles brick face is excessively smooth, the non-skid property in brick face is caused to reduce;Danger
It is dangerous higher;3, it during subsequent production, generally requires to polish glaze paint, not only causes the waste of raw material, also
Reluctant polishing slag is arrived.
On the other hand, ink-jet ink usually adds a large amount of solvent in order to enable pattern adhesive ability is strong in formula, this
A little solvents can penetrate among ground coat enamel in sintering process, so that printed patterns dizzy dye, reduces yield rate.
Summary of the invention
Technical problem to be solved by the present invention lies in, a kind of preparation method of wear-resisting antiskid brick is provided, method is simple,
High-efficient, ceramic tile decorative pattern obtained is clear and will never fade;Surface anti-skidding function admirable.
The present invention also technical problems to be solved are, provide a kind of wear-resisting antiskid brick, skid resistance is excellent, surface abrasion resistance
Property is excellent.
In order to solve the above-mentioned technical problems, the present invention provides a kind of preparation methods of wear-resisting antiskid brick, comprising:
(1) green body, ground coat enamel glaze slip, protection glaze glaze slip, overglaze glaze slip and ink-jet ink are prepared respectively;
(2) ground coat enamel glaze slip is applied to form ground glaze layer in the billet surface of drying;
(3) protection glaze glaze slip is applied in the billet surface to form protection glaze glaze layer;
(4) ink-jet ink printed decoration pattern is used in the protection glaze glaze layer;
(5) green body that step (4) obtains is placed into preset time so that decorative pattern penetrates into protection glaze glaze layer;
(6) the billet surface apply at least twice overglaze glaze slip to form cover coat;
(7) green body that step (6) obtains is dried;
(8) green body of drying is burnt into, obtains wear-resisting antiskid brick finished product.
As an improvement of the above technical solution, the protection glaze glaze slip is prepared by the raw material of following parts by weight: potassium is long
25-30 parts of stone, kaolin 15-20 parts is burnt, 3-5 parts of calcining zinc oxide, 15-18 parts of barium carbonate, 7-10 parts of calcinated talc powder, is forged
Burn aluminium oxide 6-10 parts;
The chemical component of the protection glaze glaze slip are as follows: SiO242-45%, Al2O321-25%, Fe2O30.2-0.3%,
TiO20.3-0.5%, CaO 0.5-0.8%, MgO 2-5%, K2O 2.5-4%, Na2O 0.8-1.5%, ZnO 3-5%,
BaO 15-17%, surplus are impurity.
As an improvement of the above technical solution, the overglaze glaze slip is made of raw material from the following weight: albite 18-25
Part, 7-10 parts of calcined alumina, 2-4 parts of calcining zinc oxide, 5-7 parts of dolomite, 8-12 parts of wollastonite, 25-30 parts of additive;
The chemical component of the overglaze glaze slip are as follows: SiO251-55%, Al2O322-25%, Fe2O30.1-0.3%,
TiO20.15-0.3%, CaO 1.5-3%, MgO 0.5-0.9%, K2O 0.5-1.0%, Na2O 1.5-3.0%, ZnO 5-
7%, BaO 7-9%, surplus are impurity;
The additive component are as follows: SiO245-48%, Al2O318-20%, Fe2O30.6-0.8%, TiO2 0.15-
0.3%, CaO 14-16%, MgO 4-8%, K2O 0.5-1.0%, Na2O 0.2-0.5%, ZnO 5-10%, BaO 5-
7.5%, surplus is impurity.
As an improvement of the above technical solution, the protection glaze is applied in step (3) and step (6) by the way of silk-screen printing
With the overglaze.
As an improvement of the above technical solution, the step (1) further includes preparing glitter particles slurry;Step (6) is also wrapped
It includes, glitter particles slurry is applied on cover coat;The applied amount of the glitter particles slurry is 65-70 g/m2。
As an improvement of the above technical solution, the glitter particles slurry is prepared by the raw material of following parts by weight: mica
0.1-5 parts of piece, 20-60 parts of water, 20-60 parts of wetting agent;The specific gravity of the glitter particles slurry is 1.01-1.1g/mL, and flow velocity is
15-25 seconds.
As an improvement of the above technical solution, the ground coat enamel glaze slip is prepared by the raw material of following parts by weight: potassium feldspar
50-55 parts, 12-15 parts of calcined alumina, 8-12 parts of kaolin, kaolin 5-7 parts is burnt, 12-15 parts quartzy, calcination of talc 3-5
Part, 3-5 parts of wollastonite, 5-10 parts of zirconium silicate;
The chemical component of the ground coat enamel glaze slip are as follows: SiO255-59%, Al2O325-30%, Fe2O30.1-0.2%,
TiO20.15-0.2%, CaO 0.7-0.9%, MgO 0.6-0.9%, K2O 5.5-7.5%, Na2O 0.5-1.5%, ZrO2
8-12%, surplus are impurity.
As an improvement of the above technical solution, in step (2), the glaze volume of ground coat enamel glaze slip is 350-420g/m2;Step
(3) in, the glaze volume of protection glaze glaze slip is 150-160g/m2;In step (6), the glaze volume of overglaze glaze slip is 240-260g/m2。
As an improvement of the above technical solution, the fineness of the ground coat enamel glaze slip is that 325 meshes tail over as 0.5-0.9%, than
Weight is 1.83-1.85g/ml, and flow velocity is 30-35 seconds;
The fineness of the protection glaze glaze slip is that 325 meshes tail over as 0.4-0.8%, specific gravity 1.55-1.60g/ml;
The fineness of the overglaze glaze slip is that 325 meshes tail over as 0.4-0.8%, specific gravity 1.55-1.60g/ml.
Correspondingly, using above-mentioned preparation method to be made the invention also discloses a kind of wear-resisting antiskid brick.
The present invention provides a kind of preparation method of wear-resisting antiskid brick, using apply ground coat enamel, ink-jet seep flower, finishing impression, apply overglaze, burning
At technique, wear-resisting antiskid brick has been prepared.Carry out having the beneficial effect that for technical solution of the present invention:
1. the present invention applies the mode of protection glaze, effectively improves ceramic tile blank surface by applying overglaze at least twice
Glaze volume improves the wearability of ceramic tile surface.
2. the present invention before printed decoration pattern billet surface apply protection glaze by way of so that ink-jet ink seep
Enter to protect glaze layer;Since protection glaze layer uses the higher formula of high temperature viscosity, so that ink is not printed and dyed in sintering process,
Finished product ceramic tile patterns clean mark.
3. the present invention is effectively improved the content of crystal in protection glaze and overglaze, is improved by reasonable formula system
Its hardness;So that ceramic tile surface is more wear-resisting;Make the decorative pattern for penetrating into protection glaze more wear-resisting simultaneously, it is will never fade;This
Ceramic tile surface Mohs' hardness in invention can reach >=7.
4. the present invention effectively improves the camber of ceramic tile surface, makes in such a way that glaze and overglaze are protected in silk-screen printing
The non-skid property for obtaining ceramic tile is substantially improved;Ceramic tile coefficient of friction >=0.8 in the present invention.
5. the present invention is prepared for having flash of light clipped wire in overglaze, the decorative effect of ceramic tile is enriched.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is used only for explaining the present invention, it is not used to
Limit the present invention.
The present invention provides a kind of preparation method of wear-resisting antiskid brick, comprising:
(1) green body, ground coat enamel glaze slip, protection glaze glaze slip, overglaze glaze slip and ink-jet ink are prepared respectively;
Wherein, there is no special limitation for the raw material of the specific formula of green body and use, those skilled in the art can
It is selected according to the corresponding condition of production;Preferably, using Imitation Rock Porcelain Tiles body recipe, and green body thermal expansion coefficient and glaze of the present invention
It is adapted, the defect that glaze is split is not occurred with guarantee.
Preferably, the ground coat enamel glaze slip in the present invention is prepared by the raw material of following parts by weight: 50-55 parts of potassium feldspar, being forged
Aluminium oxide 12-15 parts is burnt, 8-12 parts of kaolin, kaolin 5-7 parts of burning is 12-15 parts quartzy, and 3-5 parts of calcination of talc, wollastonite
3-5 parts, 5-10 parts of zirconium silicate;In order to promote the wearability on surface, corundum (calcined alumina) is added in glaze slip, corundum can
The crystal amount after being burnt into glaze paint is effectively promoted, the wear resistance of glaze paint is promoted;Simultaneously as the addition of corundum, improves firing
Temperature, therefore it is fluxing to use the talcum of strong fluxing effect to carry out with wollastonite auxiliary potassium feldspar;It is slided using calcined alumina, calcining
Stone burns kaolin and can effectively remove aluminium oxide, kaolin, the impurity in talcum, and the glaze of good properties is prepared.
Preferably, ground coat enamel glaze slip chemical component are as follows: SiO255-59%, Al2O325-30%, Fe2O30.1-0.2%,
TiO20.15-0.2%, CaO 0.7-0.9%, MgO 0.6-0.9%, K2O 5.5-7.5%, Na2O 0.5-1.5%, ZrO2
8-12%, surplus are impurity;Ground coat enamel in the present invention uses zirconium opaque glaze, and contains a small amount of MgO, MgO in formula
It can be used as good mineralizer, promote the precipitation of crystal in ground coat enamel, promote opaque effect.Preferably, the ground coat enamel glaze slip
Fineness be 325 mesh screen residue 0.5-0.9%, specific gravity 1.83-1.85g/ml, flow velocity 30-35 seconds;Glaze within the scope of this fineness
There is slurry relatively good mobility can be dispersed in ceramic tile blank surface during drenching glaze;Being prepared has well
The glaze paint of performance.
Preferably, the protection glaze glaze slip in the present invention is prepared by the raw material of following parts by weight: 25-30 parts of potassium feldspar,
Kaolin 15-20 parts of burning, 3-5 parts of calcining zinc oxide, 15-18 parts of barium carbonate, 7-10 parts of calcinated talc powder, calcined alumina 6-10
Part;Wherein, barium carbonate and zinc oxide can play the role of extraordinary milkiness, can preferably cover the defect of billet surface;
Calcined alumina (corundum) can effectively promote the wear-resisting property of glaze paint after firing;Meanwhile barium carbonate, talcum, zinc oxide can
The melting temperature of protection glaze is effectively reduced, so that protection glaze is evenly dispersed in ceramic tile brick face in sintering process.This formula
Protection glaze enable to ink-jet ink fully penetrated, the ceramic tile of clear patterns is prepared.Using burning kaolin, calcined oxide
Zinc, calcinated talc powder, calcined alumina can effectively remove kaolin, zinc oxide, talcum powder, the impurity in aluminium oxide, be prepared into
To the glaze of good properties.
Preferably, the chemical component of the protection glaze glaze slip are as follows: SiO242-45%, Al2O321-25%, Fe2O3
0.2-0.3%, TiO20.3-0.5%, CaO 0.5-0.8%, MgO 2-5%, K2O 2.5-4%, Na2O 0.8-1.5%,
ZnO 3-5%, BaO 15-17%, surplus are impurity;Protection glaze in the present invention uses SiO2-Al2O3-K2O-MgO system
Glaze slip, high temperature viscosity is higher, and in sintering process, dizzy dye will not be occurred by penetrating into ink-jet ink therein, so that decorative pattern
Clean mark.It should be noted that general ceramic tile, mostly directly directly prints decorative pattern on ground coat enamel, and ground coat enamel usually contains
There is higher CaO, high temperature viscosity is very low, so that decorative pattern is easy to happen dizzy dye in sintering process.The present invention passes through conjunction
The protection glaze formula of reason, effectively prevents the above problem.Preferably, it is described protection glaze glaze slip fineness be 325 meshes tail over for
0.4~0.8%, specific gravity is 1.55~1.60g/ml;Glaze slip within the scope of this fineness has relatively good mobility, in glazing
Cheng Zhong can be dispersed in ceramic tile blank surface;The glaze paint with superperformance is prepared.
Preferably, the overglaze glaze slip is made of raw material from the following weight: 18-25 parts of albite, calcined alumina 7-
10 parts, 2-4 parts of calcining zinc oxide, 5-7 parts of dolomite, 8-12 parts of wollastonite, 25-30 parts of additive;Wherein, the present invention uses
It helps to melt and acts on stronger albite, talcum as main fluxing, improve the content of corundum (calcined alumina) in overglaze glaze slip,
The hardness of overglaze is also effectively improved in the case where guaranteeing watery fusion;Meanwhile in sintering process, overglaze system is due to tool
There is strong fluxing system, there is lower high temperature viscosity, so as to be evenly distributed in ceramic tile surface, reduces surface pores,
Promote anti-pollution.
Wherein, the additive component are as follows: SiO245-48%, Al2O318-20%, Fe2O30.6-0.8%, TiO2
0.15-0.3%, CaO 14-16%, MgO 4-8%, K2O 0.5-1.0%, Na2O 0.2-0.5%, ZnO 5-10%, BaO
5-7.5%, surplus are impurity;Additive is frit, and the addition of frit reduces firing temperature, expands firing range, simultaneously
Also the stability of glaze is improved.
Preferably, the chemical component of overglaze glaze slip are as follows:: SiO251-55%, Al2O322-25%, Fe2O3 0.1-
0.3%, TiO20.15-0.3%, CaO 1.5-3%, MgO 0.5-0.9%, K2O 0.5-1.0%, Na2O 1.5-3.0%,
ZnO 5-7%, BaO 7-9%, surplus are impurity;Na in overglaze glaze slip2O, the alkali metal oxide contents such as ZnO, BaO are higher,
Therefore it can be melted at a lower temperature.It should be noted that talcum is not introduced in overglaze of the invention as fluxing agent,
Ceramic tile surface glossiness is effectively reduced, so that ceramic tile more has texture more similar to natural stone.Preferably, the overglaze glaze slip
Fineness be 325 mesh screen residue 0.4-0.8%, specific gravity 1.55-1.60g/ml;Glaze slip within the scope of this fineness has relatively good
Mobility can be dispersed in ceramic tile blank surface during drenching glaze;The glaze paint with superperformance is prepared.
Wherein, the ink-jet ink is using ink common in the market, if Crow is than the TSG-40001 that sub- company produces
The ink-jet ink etc. of model, those skilled in the art can select adaptable ink according to the color effect of brick mask body.
Preferably, step (1) further includes preparing glitter particles slurry;Wherein, the glitter particles slurry is by following parts by weight
Raw material is prepared: 0.1-5 parts of mica sheet, 20-60 parts of water, 20-60 parts of wetting agent;Wherein, mica sheet contains metallic element,
The crystal of dendroid or sheet is precipitated in crystallization after firing, with metallic luster, plays the role of abundant ceramic tile decoration;It is described
Wetting agent selects one of glycerol, ethylene glycol, carboxymethyl cellulose, polyethylene glycol or combination, it is preferred that selects glycerol and second
The combination of glycol, wherein glycerol: ethylene glycol=1:1;Good wetting agent enables to mica sheet to be uniformly dispersed.Preferably, institute
The specific gravity for stating glitter particles slurry is 1.01-1.1g/mL, and flow velocity is 15-25 seconds, and the glitter particles slurry of the flow rates can be preferable
Meet subsequent glazing process.
(2) ground coat enamel glaze slip is applied to form ground glaze layer in the billet surface of drying;
Wherein, the technique for applying ground coat enamel to billet surface is not particularly limited, can be used and the side such as drenches glaze, glaze spraying, gets rid of glaze
Formula carries out.Preferably, using the glazing mode of leaching glaze, leaching glaze is specifically carried out using bell jar.Bell jar leaching glaze can effectively ensure glaze
Material is uniformly distributed, and can recycle extra glaze slip, saves cost.
Preferably, the leaching glaze amount of ground coat enamel is 350-420g/m2, preferably 380-420g/m2, further preferably 380-
400g/m2, suitable glaze volume can effectively cover billet surface defect, provide good condition for the abundant color development of decorative pattern.
(3) protection glaze glaze slip is applied in the billet surface to form protection glaze glaze layer;
Wherein, the technique for applying ground coat enamel to billet surface is not particularly limited, leaching glaze, glaze spraying can be used, get rid of glaze, silk screen
The modes such as printing carry out.Preferably, by the way of silk-screen printing, depth difference can be formed in brick face using silk-screen printing technique
The concaveconvex shape being worth within 5 microns, the non-skid property of ceramic tile is effectively promoted in the case where not influencing visual experience.
Preferably, the glaze volume for protecting glaze glaze slip is 150-160g/m2, suitable glaze volume enables to ink-jet ink to have
Effect penetrates into protection glaze layer, so that ink-jet ink color development is complete.Obtain the ceramic tile of good decorative effect.
It should be noted that general ceramic tile, surface glaze volume is larger, and the glaze volume of usual single glaze can reach
300-450g/m2, therefore generally use the modes such as the biggish leaching glaze of single glaze volume, glaze spraying and carry out glazing operation;Especially when logical
Promotion glaze thickness is crossed come when improving ceramic tile wear-resisting property, the glaze volume of surface single glaze often >=500g/m2, in order to promote production
Efficiency is then necessarily required to using the higher glazing mode of glaze volume;These glazing modes can make glaze uniformly be distributed
On ceramic tile blank surface, but micro concavo-convex structure cannot be built, the antiskid effect in brick face cannot be promoted.It is reasonable that the present invention passes through
Glaze formula, reduce glaze volume in the case where guaranteeing brick face wear-resisting property, thus can be used silk-screen printing carry out glazing;Together
The technique of Shi Caiyong silk-screen printing forms micro concavo-convex structure in ceramic tile surface, improves the antiskid effect of ceramic tile.Therefore it is overall and
Speech, protection glaze formula and silk-screen printing synergistic effect improve the non-skid property of ceramic tile surface.
(4) ink-jet ink printed decoration pattern is used in the protection glaze glaze layer;
Preferably, ink jet printing is carried out between 40-60 DEG C;It is further preferred that carrying out ink-jet print at 50-60 DEG C
Brush, the temperature for controlling ink jet printing can accelerate the infiltration rate that brick faces ink-jet ink, reduce ink dizzy dye effect, so that
It is more life-like to permeate lines.
(5) green body that step (3) obtains is placed into preset time so that decorative pattern penetrates into protection glaze glaze layer;
Preferably, green body is placed 3-10 minutes, so that ink-jet ink penetrates sufficiently into protection glaze layer;It is further excellent
Choosing, green body is placed 3-5 minutes, too long standing time will affect production efficiency.
(6) the billet surface apply at least twice overglaze glaze slip to form cover coat;
Wherein, the technique for applying overglaze to billet surface is not particularly limited, leaching glaze, glaze spraying can be used, get rid of glaze, silk screen
The modes such as printing carry out.Preferably, by the way of silk-screen printing, depth difference can be formed in brick face using silk-screen printing technique
Be worth concaveconvex shape within 5 microns, in sintering process will not levelling, effectively promoted in the case where not influencing visual experience
The non-skid property of ceramic tile.Overglaze glaze slip is printed in two times, can effectively promote the uniformity of glaze slip distribution.
Preferably, the glaze volume of overglaze glaze slip is 240-260g/m2, excessive glaze volume can block 3D pattern, and waste
Raw material.Very few overglaze cannot then play the effect of enhancing surface abrasion resistance.
It should be noted that general ceramic tile, surface glaze volume is larger, and the glaze volume of usual single glaze can reach
300-450g/m2, therefore generally use the modes such as the biggish leaching glaze of single glaze volume, glaze spraying and carry out glazing operation;Especially when logical
Promotion glaze thickness is crossed come when improving ceramic tile wear-resisting property, the glaze volume of surface single glaze often >=500g/m2, in order to promote production
Efficiency is then necessarily required to using the higher glazing mode of glaze volume;These glazing modes can make glaze uniformly be distributed
On ceramic tile blank surface, but micro concavo-convex structure cannot be built, the antiskid effect in brick face cannot be promoted.It is reasonable that the present invention passes through
Glaze formula, reduce glaze volume in the case where guaranteeing brick face wear-resisting property, thus can be used silk-screen printing carry out glazing;Together
The technique of Shi Caiyong silk-screen printing forms micro concavo-convex structure in ceramic tile surface, improves the antiskid effect of ceramic tile.Therefore it is overall and
Speech, protection glaze, overglaze formula and silk-screen printing synergistic effect improve the non-skid property of ceramic tile surface.
Preferably, step (8) further includes that glitter particles slurry is applied on cover coat;The present invention is for applying glitter particles slurry
Mode there is no special limitation, it is preferred that applied by the way of getting rid of glaze glitter particles slurry;It gets rid of glaze and enables to glitter particles
Slurry is dispersed in cover coat, promotes decorative effect.Preferably, the applied amount of the glitter particles slurry is 65-70g/m2。
(7) green body that step (6) obtains is dried;
Preferably, after drying, moisture content≤1% of the green body, it is further preferred that moisture content≤0.8%;Due to this
The glaze paint of ceramic tile in invention is thicker, therefore before entering kiln firing, needs sufficiently to dry it, to prevent brick face from cracking
The defects of.
(8) green body of drying is burnt into, obtains wear-resisting antiskid brick finished product.
Preferably, firing temperature is 1155-1200 DEG C, and firing period is 55-65 minutes.It is burnt at this temperature, it can
So that green body, glaze paint are sufficiently sintered, the stable Imitation Rock Porcelain Tiles of performance are obtained.Corundum in sintering process in overglaze can in overglaze
Other compositions reaction or be individually precipitated, protrude glaze paint, the concaveconvex structure that cooperation silk-screen printing is formed further promotes ceramic tile
Non-skid property.
Preferably, the preparation method in the present invention further include: (9) will be obtained after the green body progress edging chamfering after firing resistance to
Grind anti-skid brick finished product.Edging chamfering enables to tile specification unitized, and the later period is facilitated to case and use.
The present invention effectively improves the glaze volume on ceramic tile blank surface by applying overglaze, the mode of application protection glaze twice,
Simultaneously by promoting the content of corundum in various glaze slips, the wearability of ceramic tile surface, ceramic tile surface in the present invention are effectively improved
Mohs' hardness >=7;On the other hand, the present invention has made micro concavo-convex structure in brick wheat flour, simultaneously by the glazing process of silk-screen printing
By the precipitation of aluminate in sintering process and alpha-alumina crystals, ceramic tile surface roughness is improved, porcelain is effectively improved
The non-skid property of brick.Ceramic tile coefficient of friction >=0.8 in the present invention;Finally, the present invention by before printed decoration pattern in green body
Surface applies the mode of protection glaze, so that ink-jet ink penetrates into protection glaze layer;Ink is not printed and dyed in sintering process, so that
Finished product ceramic tile patterns clean mark;Simultaneously by preparation flash of light metal glaze, the decorative effect of ceramic tile is improved.
Correspondingly, using the above method to prepare the invention also discloses a kind of wear-resisting antiskid brick.The wear-resisting antiskid brick
Including green body and it is sequentially arranged in the ground glaze layer of billet surface, protects glaze layer and cover coat;Infiltration has decoration in the ground glaze layer
Pattern, mixed with glitter particles in the cover coat;
Preferably, the ground glaze layer is with a thickness of 0.4-0.6mm;The cover coat is with a thickness of 0.5-1.0mm, as cover coat <
When 0.5mm, metallic crystallizes emersion glaze paint, will affect glaze paint glossiness;And when cover coat > 1mm, metallic crystallizes quilt
It is buried enter cover coat, metallic luster can not be issued.
Preferably, ceramic tile surface coefficient of friction >=0.6, Mohs' hardness >=7, water absorption rate≤0.1%, the modulus of rupture >=
45MPa。
With specific embodiment, the present invention is further explained below
Embodiment 1
(1) green body, ground coat enamel glaze slip, protection glaze glaze slip, overglaze glaze slip, ink-jet ink and glitter particles slurry are prepared respectively;
Ground coat enamel glaze slurry formula: 55 parts of potassium feldspar, 12 parts of calcined alumina, 8 parts of kaolin, 5 parts of kaolin are burnt, quartz 12
Part, 5 parts of calcination of talc, 5 parts of wollastonite, 5 parts of zirconium silicate;Ground coat enamel glaze slip chemical component are as follows: SiO258.68%, Al2O3
25.33%, Fe2O30.1%, TiO20.15%, CaO 0.87%, MgO 0.81%, K2O 6.5%, Na2O 0.5%, ZrO21.5%;Surplus is impurity.325 mesh screen residue of ground coat enamel is 0.55%, specific gravity 1.85g/mL, and flow velocity is 35 seconds.
Protect glaze glaze slurry formula are as follows: 25 parts of potassium feldspar, burn 20 parts of kaolin, 3 parts of calcining zinc oxide, 15 parts of barium carbonate, forge
9 parts of burning talcum powder, 10 parts of calcined alumina;Protect the chemical component of glaze glaze slip are as follows: SiO242.15%, Al2O324.33%,
Fe2O30.25%, TiO20.32%, CaO 0.58%, MgO 4.52%, K2O 2.68%, Na2O 0.9%, ZnO 3%,
BaO 15.24%, surplus are impurity;The fineness of protection glaze glaze slip is that 325 meshes tail over 0.55%, specific gravity 1.58g/mL.
Overglaze glaze slurry formula are as follows: 25 parts of albite, 7 parts of calcined alumina, 7 parts of dolomite, 4 parts of calcining zinc oxide, silicon ash
8 parts of stone, 25 parts of additive;
Wherein, additive component are as follows: SiO245.05%, Al2O318.22%, Fe2O30.62%, TiO20.15%,
CaO 14.48%, MgO 6.18%, K2O 0.5%, Na2O 0.2%, ZnO 8.15%, BaO 6%, surplus are impurity;Overglaze
Glaze slip chemical component are as follows: SiO253.14%, Al2O322.55%, Fe2O30.2%, TiO20.15%, CaO 1.8%,
MgO 0.5%, K2O 0.5%, Na2O 2.9%, ZnO 6.44%, BaO 7.68%, surplus are impurity;325 mesh of overglaze glaze slip
Tailing over is 0.65%, specific gravity 1.58g/mL.
Glitter particles slurry formula are as follows: 0.1 part of mica sheet, 60 parts of water, 20 parts of wetting agent, wherein wetting agent is glycerol and second
The mixture of glycol, glycerol: ethylene glycol=1:1;The specific gravity of glitter particles slurry is 1.01 g/mL, flow velocity 15s.
(2) use bell jar leaching ground coat enamel glaze slip to form ground glaze layer in the billet surface of drying;
Ground coat enamel glaze slip glaze volume is 380g/m2。
(3) glaze glaze slip is protected in the billet surface silk-screen printing to form protection glaze glaze layer;
The glaze volume for protecting glaze glaze slip is 150g/m2。
(4) ink-jet ink printed decoration pattern is used in the protection glaze glaze layer;When printing, green body temperature is 40 DEG C.
(5) green body that step (3) obtains is placed 3 minutes so that decorative pattern penetrates into protection glaze glaze layer;
(6) silk-screen printing is used in the billet surface overglaze glaze slip, and will using glaze method is got rid of to form cover coat twice
Metallic slurry is embedded in cover coat;
Overglaze glaze slip glaze volume is 240g/m2;The applied amount of glitter particles slurry is 65g/m2。
(7) green body that step (6) obtains is dried;
Green body water absorption rate≤0.8% after drying
(8) wear-resisting antiskid brick is obtained after being burnt into the green body that step (7) obtains at 1200 DEG C;Firing period is 55 points
Clock.
Embodiment 2
(1) green body, ground coat enamel glaze slip, protection glaze glaze slip, overglaze glaze slip, ink-jet ink and glitter particles slurry are prepared respectively;
Ground coat enamel glaze slurry formula: 52 parts of potassium feldspar, 14 parts of calcined alumina, 10 parts of kaolin, 6 parts of kaolin are burnt, quartz 13
Part, 5 parts of calcination of talc, 4 parts of wollastonite, 8 parts of zirconium silicate;Ground coat enamel glaze slip chemical component are as follows: SiO257.48%, Al2O3
27.44%, Fe2O30.1%, TiO20.18%, CaO 0.77%, MgO 0.8%, K2O 5.65%, Na2O 0.75%,
ZrO 21.45%;Surplus is impurity.325 mesh screen residue of ground coat enamel is 0.53%, specific gravity 1.85g/mL, and flow velocity is 32 seconds.
Protect glaze glaze slurry formula are as follows: 28 parts of potassium feldspar, burn 17 parts of kaolin, 4 parts of calcining zinc oxide, 16 parts of barium carbonate, forge
7 parts of burning talcum powder, 8 parts of calcined alumina;Protect the chemical component of glaze glaze slip are as follows: SiO244.12%, Al2O322.56%,
Fe2O30.26%, TiO20.31%, CaO 0.52%, MgO 3.05%, K2O 3.35%, Na2O 1.21%, ZnO
3.87%, BaO 16.55%, surplus are impurity;The fineness of protection glaze glaze slip is that 325 meshes tail over 0.45%, and specific gravity is
1.56g/mL。
Overglaze glaze slurry formula are as follows: 23 parts of albite, 9 parts of calcined alumina, 7 parts of dolomite, 3 parts of calcining zinc oxide, silicon ash
11 parts of stone, 28 parts of additive;
Wherein, additive component are as follows: SiO247.32%, Al2O319.25%, Fe2O30.62%, TiO20.18%,
CaO 15.99%, MgO 4.2%, K2O 0.5%, Na2O 0.25%, ZnO 5.8%, BaO 5.24%, surplus are impurity;Face
Glaze glaze slip chemical component are as follows: SiO251.33%, Al2O323.45%, Fe2O30.25%, TiO20.25%, CaO
2.5%, MgO 0.6%, K2O 0.85%, Na2O 1.7%, ZnO 5.45%, BaO 8.05%, surplus are impurity;Overglaze glaze
Starching 325 mesh screen residues is 0.45%, specific gravity 1.57g/mL.
Glitter particles slurry formula are as follows: 1.2 parts of mica sheet, 50 parts of water, 40 parts of wetting agent, wherein wetting agent is glycerol and second
The mixture of glycol, glycerol: ethylene glycol=1:1;The specific gravity of glitter particles slurry is 1.08g/mL, flow velocity 21s.
(2) use bell jar leaching ground coat enamel glaze slip to form ground glaze layer in the billet surface of drying;
Ground coat enamel glaze slip glaze volume is 390g/m2。
(3) glaze glaze slip is protected in the billet surface silk-screen printing to form protection glaze glaze layer;
The glaze volume for protecting glaze glaze slip is 155g/m2。
(4) ink-jet ink printed decoration pattern is used in the protection glaze glaze layer;When printing, green body temperature is 55 DEG C.
(5) green body that step (3) obtains is placed 4.5 minutes so that decorative pattern penetrates into protection glaze glaze layer;
(6) silk-screen printing is used in the billet surface overglaze glaze slip, and will using glaze method is got rid of to form cover coat twice
Metallic slurry is embedded in cover coat;
Overglaze glaze slip glaze volume is 250g/m2;The applied amount of glitter particles slurry is 68g/m2。
(7) green body that step (6) obtains is dried;
Green body moisture content≤0.5% after drying
(8) wear-resisting antiskid brick is obtained after being burnt into the green body that step (7) obtains at 1185 DEG C;Firing period is 50 points
Clock.
Embodiment 3
(1) green body, ground coat enamel glaze slip, protection glaze glaze slip, overglaze glaze slip, ink-jet ink and glitter particles slurry are prepared respectively;
Ground coat enamel glaze slurry formula: 54 parts of potassium feldspar, 14.5 parts of calcined alumina, 7 parts of kaolin, 9 parts of kaolin are burnt, quartz 14
Part, 5 parts of calcination of talc, 5 parts of wollastonite, 9 parts of zirconium silicate;Ground coat enamel glaze slip chemical component are as follows: SiO258.04%, Al2O3
28.54%, Fe2O30.15%, TiO20.15%, CaO 0.85%, MgO 0.81%, K2O 5.7%, Na2O 0.8%,
ZrO 22.36%;Surplus is impurity.325 mesh screen residue of ground coat enamel is 0.52%, specific gravity 1.84g/mL, and flow velocity is 32 seconds.
Protect glaze glaze slurry formula are as follows: 29 parts of potassium feldspar, 18 parts of kaolin of burning, 4.5 parts of calcining zinc oxide, 18 parts of barium carbonate,
8 parts of calcinated talc powder, 7 parts of calcined alumina;Protect the chemical component of glaze glaze slip are as follows: SiO244.85%, Al2O3
21.04%, Fe2O30.28%, TiO20.33%, CaO 0.56%, MgO 2.58%, K2O 3.8%, Na2O 1.22%,
ZnO 4.25%, BaO 16.85%, surplus are impurity;The fineness of protection glaze glaze slip is that 325 meshes tail over 0.42%, and specific gravity is
1.56g/mL。
Overglaze glaze slurry formula are as follows: 24 parts of albite, 10 parts of calcined alumina, 5 parts of dolomite, 2.5 parts of calcining zinc oxide, silicon
11.5 parts of lime stone, 26 parts of additive;
Wherein, additive component are as follows: SiO247.32%, Al2O319.25%, Fe2O30.62%, TiO20.18%,
CaO 15.99%, MgO 4.2%, K2O 0.5%, Na2O 0.25%, ZnO 5.8%, BaO 5.24%, surplus are impurity;Face
Glaze glaze slip chemical component are as follows: SiO251.45%, Al2O324.21%, Fe2O30.26%, TiO20.32%, CaO
2.55%, MgO 0.6%, K2O 0.9%, Na2O 1.9%, ZnO 6%, BaO 8%, surplus are impurity;325 mesh of overglaze glaze slip
Tailing over is 0.45%, specific gravity 1.57g/mL.
Glitter particles slurry formula are as follows: 0.9 part of mica sheet, 55 parts of water, wetting agent 43, wherein wetting agent is glycerol and second two
The mixture of alcohol, glycerol: ethylene glycol=1:1;The specific gravity of glitter particles slurry is 1.07g/mL, flow velocity 22s.
(2) use bell jar leaching ground coat enamel glaze slip to form ground glaze layer in the billet surface of drying;
Ground coat enamel glaze slip glaze volume is 400g/m2。
(3) glaze glaze slip is protected in the billet surface silk-screen printing to form protection glaze glaze layer;
The glaze volume for protecting glaze glaze slip is 160g/m2。
(4) ink-jet ink printed decoration pattern is used in the protection glaze glaze layer;When printing, green body temperature is 58 DEG C.
(5) green body that step (3) obtains is placed 5 minutes so that decorative pattern penetrates into protection glaze glaze layer;
(6) silk-screen printing is used in the billet surface overglaze glaze slip, and will using glaze method is got rid of to form cover coat twice
Metallic slurry is embedded in cover coat;
Overglaze glaze slip glaze volume is 255g/m2;The applied amount of glitter particles slurry is 68g/m2。
(7) green body that step (6) obtains is dried;
Green body water absorption rate≤0.5% after drying
(8) wear-resisting antiskid brick is obtained after being burnt into the green body that step (7) obtains at 1180 DEG C;Firing period is 55 points
Clock.
Wear-resisting antiskid brick in embodiment 1-3 is detected, wherein tested using the method in GB/T 3810.3-2006
Its water absorption rate and the modulus of rupture test its surface abrasion resistance using the method in GB/T3810.6-2006;Using GB/T
Test method in 3810.14-2006 tests its anti-pollution characteristic;Its skid resistance is tested using the method in GB/T 4100-2015
Can, using Moh's hardness scale test surfaces Mohs' hardness.Itself the result is as follows:
Wearability | Mohs' hardness | Water absorption rate | The modulus of rupture | Coefficient of friction | |
Embodiment 1 | 5 grades | 7 | 0.1% | 45MPa | 0.8 |
Embodiment 2 | 5 grades | 7.5 | 0.09% | 48MPa | 0.85 |
Embodiment 3 | 5 grades | 8 | 0.03% | 55MPa | 1.0 |
To sum up, water absorption rate≤0.1% of wear-resisting antiskid brick prepared by the present invention, the modulus of rupture >=45MPa, coefficient of friction >=
0.8,8 wearability is 5 grades, surface Mohs' hardness >=7;Ceramic tile in the present invention has good wearability and non-skid property.
The foregoing is merely preferred embodiments of the invention, are not intended to limit the invention, all in spirit of the invention
With any modification affected within principle, equivalent replacement and improvement etc. be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of preparation method of wear-resisting antiskid brick characterized by comprising
(1) green body, ground coat enamel glaze slip, protection glaze glaze slip, overglaze glaze slip and ink-jet ink are prepared respectively;
(2) ground coat enamel glaze slip is applied to form ground glaze layer in the billet surface of drying;
(3) protection glaze glaze slip is applied in the billet surface to form protection glaze glaze layer;
(4) ink-jet ink printed decoration pattern is used in the protection glaze glaze layer;
(5) green body that step (4) obtains is placed into preset time so that decorative pattern penetrates into protection glaze glaze layer;
(6) the billet surface apply at least twice overglaze glaze slip to form cover coat;
(7) green body that step (6) obtains is dried;
(8) green body of drying is burnt into, obtains wear-resisting antiskid brick finished product.
2. the preparation method of wear-resisting antiskid brick as described in claim 1, which is characterized in that the protection glaze glaze slip is by following heavy
The raw material of amount part is prepared: 25-30 parts of potassium feldspar, kaolin 15-20 parts of burning, and 3-5 parts of calcining zinc oxide, barium carbonate 15-18
Part, 7-10 parts of calcinated talc powder, 6-10 parts of calcined alumina;
The chemical component of the protection glaze glaze slip are as follows: SiO242-45%, Al2O321-25%, Fe2O30.2-0.3%, TiO2
0.3-0.5%, CaO 0.5-0.8%, MgO 2-5%, K2O 2.5-4%, Na2O 0.8-1.5%, ZnO 3-5%, BaO 15-
17%, surplus is impurity.
3. the preparation method of wear-resisting antiskid brick as claimed in claim 2, which is characterized in that the overglaze glaze slip is by following weight
The raw material of part is made: 18-25 parts of albite, 7-10 parts of calcined alumina, and 2-4 parts of calcining zinc oxide, 5-7 parts of dolomite, silicon ash
8-12 parts of stone, 25-30 parts of additive;
The chemical component of the overglaze glaze slip are as follows: SiO251-55%, Al2O322-25%, Fe2O30.1-0.3%, TiO2
0.15-0.3%, CaO 1.5-3%, MgO 0.5-0.9%, K2O 0.5-1.0%, Na2O 1.5-3.0%, ZnO 5-7%,
BaO 7-9%, surplus are impurity;
The additive component are as follows: SiO245-48%, Al2O318-20%, Fe2O30.6-0.8%, TiO2 0.15-
0.3%, CaO 14-16%, MgO 4-8%, K2O 0.5-1.0%, Na2O 0.2-0.5%, ZnO 5-10%, BaO 5-
7.5%, surplus is impurity.
4. the preparation method of wear-resisting antiskid brick as claimed in claim 2 or claim 3, which is characterized in that step (3) is adopted with step (6)
The protection glaze and the overglaze are applied with the mode of silk-screen printing.
5. the preparation method of wear-resisting antiskid brick as described in claim 1, which is characterized in that the step (1) further includes preparing
Glitter particles slurry;Step (6) further includes that the glitter particles slurry is applied on cover coat;The applied amount of glitter particles slurry is
65-70g/m2。
6. the preparation method of wear-resisting antiskid brick as claimed in claim 5, which is characterized in that the glitter particles slurry is by following heavy
The raw material of amount part is prepared: 0.1-5 parts of mica sheet, 20-60 parts of water, 20-60 parts of wetting agent;The specific gravity of the glitter particles slurry
For 1.01-1.1g/mL, flow velocity is 15-25 seconds.
7. the preparation method of wear-resisting antiskid brick as described in claim 1, which is characterized in that the ground coat enamel glaze slip is by following weight
The raw material of part is prepared: 50-55 parts of potassium feldspar, 12-15 parts of calcined alumina, 8-12 parts of kaolin, kaolin 5-7 parts is burnt,
It is 12-15 parts quartzy, 3-5 parts of calcination of talc, 3-5 parts of wollastonite, 5-10 parts of zirconium silicate;
The chemical component of the ground coat enamel glaze slip are as follows: SiO255-59%, Al2O325-30%, Fe2O30.1-0.2%, TiO2
0.15-0.2%, CaO 0.7-0.9%, MgO 0.6-0.9%, K2O 5.5-7.5%, Na2O 0.5-1.5%, ZrO2 8-
12%, surplus is impurity.
8. the preparation method of wear-resisting antiskid brick as described in claim 1, which is characterized in that in step (2), ground coat enamel glaze slip is applied
Glaze amount is 350-420g/m2;In step (3), the glaze volume of protection glaze glaze slip is 150-160g/m2;In step (6), overglaze glaze slip
Glaze volume be 240-260g/m2。
9. the preparation method of wear-resisting antiskid brick as claimed in claim 8, which is characterized in that the fineness of the ground coat enamel glaze slip is
325 meshes tail over as 0.5-0.9%, specific gravity 1.83-1.85g/ml, and flow velocity is 30-35 seconds;
The fineness of the protection glaze glaze slip is that 325 meshes tail over as 0.4-0.8%, specific gravity 1.55-1.60g/ml;
The fineness of the overglaze glaze slip is that 325 meshes tail over as 0.4-0.8%, specific gravity 1.55-1.60g/ml.
10. a kind of wear-resisting antiskid brick, which is characterized in that it uses the described in any item preparation methods of claim 1-9 to be such as made.
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Application publication date: 20190129 |