CN111574245A - 3D (three-dimensional) dazzling ceramic tile and preparation method thereof - Google Patents
3D (three-dimensional) dazzling ceramic tile and preparation method thereof Download PDFInfo
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- CN111574245A CN111574245A CN202010366889.0A CN202010366889A CN111574245A CN 111574245 A CN111574245 A CN 111574245A CN 202010366889 A CN202010366889 A CN 202010366889A CN 111574245 A CN111574245 A CN 111574245A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title claims description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 74
- 230000001681 protective effect Effects 0.000 claims abstract description 57
- 239000011787 zinc oxide Substances 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 27
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 27
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 27
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 27
- 239000010459 dolomite Substances 0.000 claims abstract description 27
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 27
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000010453 quartz Substances 0.000 claims abstract description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052656 albite Inorganic materials 0.000 claims abstract description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000454 talc Substances 0.000 claims abstract description 9
- 229910052623 talc Inorganic materials 0.000 claims abstract description 9
- 239000010456 wollastonite Substances 0.000 claims abstract description 9
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 9
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 36
- 239000002994 raw material Substances 0.000 claims description 34
- 238000010304 firing Methods 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 21
- 235000019738 Limestone Nutrition 0.000 claims description 18
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 18
- 239000004327 boric acid Substances 0.000 claims description 18
- 230000004313 glare Effects 0.000 claims description 18
- 230000005484 gravity Effects 0.000 claims description 18
- 239000006028 limestone Substances 0.000 claims description 18
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 18
- 238000010791 quenching Methods 0.000 claims description 16
- 230000000171 quenching effect Effects 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 15
- 238000005507 spraying Methods 0.000 claims description 15
- 239000001506 calcium phosphate Substances 0.000 claims description 11
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 11
- 235000011010 calcium phosphates Nutrition 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 11
- 238000000498 ball milling Methods 0.000 claims description 9
- 238000000748 compression moulding Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 claims description 9
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 9
- 238000007641 inkjet printing Methods 0.000 claims description 8
- 238000005245 sintering Methods 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000011449 brick Substances 0.000 claims 1
- 230000000149 penetrating effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 17
- 238000010521 absorption reaction Methods 0.000 abstract description 16
- 239000000976 ink Substances 0.000 description 45
- 239000000047 product Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 15
- 230000006872 improvement Effects 0.000 description 9
- 230000009286 beneficial effect Effects 0.000 description 7
- 238000005034 decoration Methods 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000009044 synergistic interaction Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Abstract
The invention discloses a 3D stereoscopic dazzling ceramic tile which sequentially comprises a blank layer, a dazzling surface glaze layer, an ink-jet pattern texture layer, a functional ink layer and a transparent protective glaze layer from bottom to top, wherein the dazzling surface glaze layer comprises 35-40 parts of albite, 12-15 parts of kaolin, 11-15 parts of barium carbonate, 1-2 parts of zinc oxide, 16-20 parts of quartz, 2-4 parts of alumina, 5-6 parts of calcined kaolin and 0.5-12 parts of ink-jet frits, and the transparent protective glaze layer comprises 12-15 parts of potassium feldspar, 18-24 parts of albite, 12-13 parts of kaolin, 8-12 parts of calcined talc, 3-5 parts of wollastonite, 22-26 parts of barium carbonate, 10-14 parts of dolomite, 4-6 parts of zinc oxide, 1-2 parts of alumina and 2-6 parts of transparent high-brightness frits. The invention enables the ceramic tile product to present obvious 3D stereoscopic effect and can adapt to different water absorption rates, thereby greatly widening the application range of the ceramic tile with 3D stereoscopic dazzling light.
Description
Technical Field
The invention relates to the field of architectural ceramics, in particular to a functional ceramic tile and a preparation method thereof.
Background
With the increasing living standard of people, more and more functional ceramic tiles are widely applied to various occasions in daily life by people. The ceramic tile with the carved and sunken patterns and textures is very popular among people due to the unique decorative effect. The existing ceramic tiles are generally realized in two ways, one way is to form a ceramic tile blank body with corresponding concave-convex textures by using a mold with concave-convex textures so as to endow the ceramic tile with a three-dimensional pattern decoration effect, and the other way is to coat carved ink or sunken ink on a decoration layer of the ceramic tile blank body so that the decoration pattern of the decoration layer has a certain concave-convex effect. However, the first method limits the variety of decorative effects due to the inconvenience of replacement of the mold, and the second method leaves room for improvement in the stereoscopic effect due to the poor performance of the functional ink.
Disclosure of Invention
The invention aims to provide a 3D stereoscopic dazzling ceramic tile and a preparation method thereof aiming at the defects of the prior art, wherein the 3D stereoscopic dazzling ceramic tile has a remarkable 3D stereoscopic dazzling effect, can form various decorative special effects, and can be adapted to ceramic tiles with different water absorption rates.
The technical scheme adopted by the invention is as follows: A3D stereoscopic dazzling ceramic tile sequentially comprises a blank layer, a dazzling overglaze layer, an ink-jet pattern texture layer, a functional ink layer and a transparent protective glaze layer from bottom to top, wherein raw material components of the dazzling overglaze in the dazzling overglaze layer comprise, by weight, 35-40 parts of albite, 12-15 parts of kaolin, 11-15 parts of barium carbonate, 1-2 parts of zinc oxide, 16-20 parts of quartz, 2-4 parts of alumina, 5-6 parts of calcined kaolin and 0.5-12 parts of ink-jet frits, and raw material components of the transparent protective glaze in the transparent protective glaze layer comprise, by weight, 12-15 parts of potassium feldspar, 18-24 parts of albite, 12-13 parts of kaolin, 8-12 parts of calcined talc, 3-5 parts of wollastonite, 22-26 parts of barium carbonate, 10-14 parts of dolomite, 4-6 parts of zinc oxide, 1-2 parts of alumina and 2-10 parts of transparent high-brightness frits.
Specifically, the dazzling overglaze provides a good color development foundation for the ink-jet pattern texture layer through a special formula design, solves the problem that the color development of the traditional overglaze is not good, and is beneficial to the perfect presentation of various ink-jet pattern textures. The transparent protective glaze is beneficial to the synergy of functional ink through the special formula design, so that the pattern texture is more three-dimensional, and the transparent protective glaze has the functions of protecting the pattern, namely preventing fouling and resisting wear. Therefore, the dazzling overglaze and the transparent protective glaze in the invention generate 3D stereoscopic effect by the synergistic action with the functional ink layer, for example, the concave-convex effect of stone lines, vein lines or stereoscopic patterns of the imitated natural stone material can show the dazzling visual effect of finely carved and 3D stereoscopic, and simultaneously the defect of poor film-forming performance of the existing functional ink is also synergistically overcome.
In addition, the formula of the transparent protective glaze can be adapted to ceramic tiles with different water absorption rates, and the addition amount of the high-brightness transparent frit can be adjusted to be adapted to the ceramic tiles with different absorption rates, so that good combination of blank glaze is realized, and the application range of the ceramic tiles is greatly expanded. Specifically, when the water absorption of the green body layer is greater than 6%, the adding proportion of the high-brightness transparent frit in the transparent protective glaze formula is about 10%; when the water absorption of the green body layer is 1-6%, the adding proportion of the high-brightness transparent frit in the transparent protective glaze formula is about 4%; when the water absorption of the green body layer is less than 1%, the addition ratio of the high-brightness transparent frit in the transparent protective glaze formula is about 2%.
The dazzling overglaze and the transparent protective glaze are both prepared by adopting the conventional preparation process of ceramic glaze.
As a further improvement of the above aspect, the functional ink of the functional ink layer is selected from one of a bleeding ink, a glossy ink, a stripping ink, and a metal ink. Specifically, the diversity of the functional inks in the invention is due to the special improvement of both the glaring overglaze and the transparent protective glaze, that is, both the glaring overglaze and the transparent protective glaze have good adaptability, and both the glaring overglaze and the transparent protective glaze have good adaptability to various functional inks in the market.
As a further improvement of the scheme, the ink-jet frit comprises, by weight, 28-36% of quartz, 18-24% of potassium feldspar, 2.5-3% of zirconium silicate, 3.5-5% of calcium borate, 9.6-10.2% of limestone, 7-9% of dolomite, 1.8-3.4% of calcium phosphate, 7-8% of zinc oxide, 4.4-6.5% of boric acid and 2-3.2% of potassium carbonate. Specifically, the inkjet frit mainly provides good whiteness for the glaring overglaze, and meanwhile, the inkjet frit can generate rainbow pearl gloss in subsequent processing by introducing the calcium phosphate with a specific proportion, so that the overglaze is endowed with a glaring function. Further, according to the research, the comprehensive performance of the formula of the ink-jet frit is better when the ink-jet frit comprises 34.68% of quartz, 22.15% of potassium feldspar, 3% of zirconium silicate, 5.98% of calcium borate, 10.12% of limestone, 7.3% of dolomite, 2.35% of calcium phosphate, 7.13% of zinc oxide, 4.64% of boric acid and 2.65% of potassium carbonate by weight percentage of raw materials. Specifically, the inkjet frit mainly provides good whiteness for the glaring overglaze, and meanwhile, the inkjet frit can generate rainbow pearl gloss in subsequent processing by introducing the calcium phosphate with a specific proportion, so that the overglaze is endowed with a glaring function. The preparation method of the ink-jet frit comprises the steps of mixing the raw material components by a mixer for 20-30 min, placing the mixture in a frit furnace, sintering at 1540 ℃, and then quenching with water and cooling.
As a further improvement of the scheme, the transparent high-brightness frit comprises, by weight, 35-40% of quartz, 7-8% of zinc oxide, 19-21% of limestone, 5-6% of dolomite, 1.8-2.1% of potassium carbonate, 1-1.3% of barium carbonate, 25-30% of potassium feldspar and 0.6-1.2% of boric acid. In particular, the special formula amount of the zinc oxide is beneficial to assisting the color development and strengthening the 3D stereoscopic dazzling effect of the functional ink. Further, according to research, the transparent high-brightness frit formulation has better comprehensive performance when the transparent high-brightness frit comprises 38.82% of quartz, 7.17% of zinc oxide, 19.17% of limestone, 5% of dolomite, 2% of potassium carbonate, 1.17% of barium carbonate, 25.67% of potassium feldspar and 1% of boric acid in percentage by weight of raw materials. The preparation method of the transparent high-brightness frit comprises the steps of mixing the raw material components by a mixer for 20-30 min, placing the mixture in a frit furnace, sintering at the high temperature of 1480 ℃, and then quenching with water to obtain the transparent high-brightness frit.
The other technical scheme adopted by the invention is as follows: the preparation method of the 3D stereoscopic dazzling ceramic tile comprises the following process steps:
1) taking common ceramic blanks, mixing uniformly, and performing ball milling, drying and compression molding to obtain a blank layer;
2) coating the glaring overglaze on the body layer in a glaze pouring mode to form a glaring overglaze layer;
3) carrying out ink-jet printing on pattern textures and functional ink on the dazzling glaze layer in sequence to form an ink-jet pattern texture layer and a functional ink layer in sequence;
4) spraying transparent protective glaze on the functional ink layer at high pressure to form a transparent protective glaze layer, and sintering in a kiln at high temperature to obtain the final product.
Specifically, the common ceramic blank in the present invention is an existing common ceramic blank, and is not described herein again.
As a further improvement of the scheme, the glazing specific gravity of the pouring glaze in the step 2) is 1.8-1.82 g/cm3. Particularly, the control of the glazing amount of the glazing is beneficial to the film forming uniformity of the coating.
As a further improvement of the scheme, the glazing specific gravity of the high-pressure spraying in the step 4) is 1.45-1.55 g/cm3. Particularly, the control of the spraying glazing amount is beneficial to the film forming uniformity of the coating film.
As a further improvement of the scheme, the sintering temperature of the one-time high-temperature sintering in the step 4) is 1020-1150 ℃.
The invention has the beneficial effects that:
according to the invention, by adjusting the formulas of the dazzling overglaze and the transparent protective glaze and simultaneously realizing synergistic interaction with the functional ink, the ceramic tile product sintered at high temperature shows a remarkable 3D (three-dimensional) effect, and can be adapted to ceramic tiles with different water absorption rates, so that the application range of the 3D dazzling ceramic tile is greatly widened.
The preparation method disclosed by the invention is simple in process flow, strong in controllability and beneficial to large-scale industrial production.
Detailed Description
The present invention is specifically described below with reference to examples in order to facilitate understanding of the present invention by those skilled in the art. It should be particularly noted that the examples are given solely for the purpose of illustration and are not to be construed as limitations on the scope of the invention, as non-essential improvements and modifications to the invention may occur to those skilled in the art, which fall within the scope of the invention as defined by the appended claims. Meanwhile, the raw materials mentioned below are not specified in detail and are all commercial products; the process steps or preparation methods not mentioned in detail are all process steps or preparation methods known to the person skilled in the art.
Example 1
A3D stereoscopic dazzling ceramic tile sequentially comprises a blank layer, a dazzling overglaze layer, an ink-jet pattern texture layer, a stripping glaze ink layer and a transparent protective glaze layer from bottom to top.
The raw material components of the glare overglaze in the glare overglaze layer comprise 35 parts of albite, 15 parts of kaolin, 11 parts of barium carbonate, 2 parts of zinc oxide, 16 parts of quartz, 4 parts of alumina, 5 parts of calcined kaolin and 10 parts of inkjet frit by weight; the transparent protective glaze in the transparent protective glaze layer comprises the following raw materials, by weight, 15 parts of potassium feldspar, 18 parts of albite, 13 parts of kaolin, 8 parts of calcined talc, 5 parts of wollastonite, 22 parts of barium carbonate, 14 parts of dolomite, 4 parts of zinc oxide, 2 parts of alumina and 11 parts of transparent high-brightness frit.
The ink-jet frit comprises, by weight, 34.68% of quartz, 22.15% of potassium feldspar, 3% of zirconium silicate, 5.98% of calcium borate, 10.12% of limestone, 7.3% of dolomite, 2.35% of calcium phosphate, 7.13% of zinc oxide, 4.64% of boric acid and 2.65% of potassium carbonate, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1540 ℃, and then quenching with water and cooling.
The transparent high-brightness frit comprises, by weight, 38.82% of quartz, 7.17% of zinc oxide, 19.17% of limestone, 5% of dolomite, 2% of potassium carbonate, 1.17% of barium carbonate, 25.67% of potassium feldspar and 1% of boric acid, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1480 ℃, quenching with water and cooling.
The preparation method comprises the following steps:
1) mixing common ceramic blanks uniformly, and performing ball milling, drying and compression molding to obtain a blank layer with the water absorption rate of more than 6%;
2) coating the glaze layer with the glaring overglaze in a glaze spraying mode, and controlling the glazing specific gravity to be 1.8g/cm3Forming a dazzling glaze layer;
3) carrying out ink-jet printing on pattern textures and functional ink on the dazzling glaze layer in sequence to form an ink-jet pattern texture layer and a functional ink layer in sequence;
4) spraying transparent protective glaze on the functional ink layer at high pressure, wherein the specific gravity of the glaze is 1.55g/cm3And a transparent protective glaze layer is formed, and the mixture is put into a kiln for one-time high-temperature firing at 1020 ℃ to obtain a finished product of the example 1.
The common ceramic blank in this embodiment is a common ceramic tile blank commercially available.
Comparative example 1
A ceramic tile with decorative effect is composed of a blank layer, a surface glaze layer, an ink-jet pattern texture layer, a stripped glaze ink layer and a transparent protective glaze layer from bottom to top.
The transparent protective glaze in the transparent protective glaze layer comprises the following raw materials, by weight, 15 parts of potassium feldspar, 18 parts of albite, 13 parts of kaolin, 8 parts of calcined talc, 5 parts of wollastonite, 22 parts of barium carbonate, 14 parts of dolomite, 4 parts of zinc oxide, 2 parts of alumina and 11 parts of transparent high-brightness frit.
The transparent high-brightness frit comprises, by weight, 38.82% of quartz, 7.17% of zinc oxide, 19.17% of limestone, 5% of dolomite, 2% of potassium carbonate, 1.17% of barium carbonate, 25.67% of potassium feldspar and 1% of boric acid, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1480 ℃, quenching with water and cooling.
The overglaze layer is formed by applying ordinary ceramic tile overglaze cloth, the overglaze layer can be selected from commercially available ordinary ceramic tile overglaze, and the ceramic tile overglaze in the comparative example is purchased from a Zibobos golden glaze factory with the product model number of 5625.
The preparation method comprises the following steps:
1) mixing common ceramic blanks uniformly, and performing ball milling, drying and compression molding to obtain a blank layer with the water absorption rate of more than 6%;
2) coating the surface glaze of the ceramic tile on the body layer by adopting a glaze pouring mode, and controlling the glazing specific gravity to be 1.8g/cm3Forming a surface glaze layer;
3) sequentially carrying out ink-jet printing on pattern textures and functional ink on the overglaze layer to sequentially form an ink-jet pattern texture layer and a functional ink layer;
4) spraying transparent protective glaze on the functional ink layer at high pressure, wherein the specific gravity of the glaze is 1.55g/cm3Forming a transparent protective glaze layer, putting the transparent protective glaze layer into a kiln for one-time high-temperature firing, and controlling the firing temperature to be 1020 to obtain a finished product of the comparative example 1.
The general ceramic blank described in this comparative example was the same as the general ceramic blank in example 1.
Comparative example 2
A ceramic tile with decorative effect is composed of a blank layer, a glaring surface glaze layer, an ink-jet pattern texture layer, a stripped glaze ink layer and a transparent surface glaze layer from bottom to top.
The raw material components of the glare overglaze in the glare overglaze layer comprise, by weight, 35 parts of albite, 15 parts of kaolin, 11 parts of barium carbonate, 2 parts of zinc oxide, 16 parts of quartz, 4 parts of alumina, 5 parts of calcined kaolin and 10 parts of inkjet frit.
The ink-jet frit comprises, by weight, 34.68% of quartz, 22.15% of potassium feldspar, 3% of zirconium silicate, 5.98% of calcium borate, 10.12% of limestone, 7.3% of dolomite, 2.35% of calcium phosphate, 7.13% of zinc oxide, 4.64% of boric acid and 2.65% of potassium carbonate, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1540 ℃, and then quenching with water and cooling.
The transparent overglaze layer is formed by applying a common ceramic tile transparent overglaze cloth, the common ceramic tile transparent overglaze can be selected from commercially available common ceramic tile transparent overglazes, and the ceramic tile transparent overglaze in the comparative example is purchased from a Zibobos golden glaze factory with the product model number of 5625.
The preparation method comprises the following steps:
1) mixing common ceramic blanks uniformly, and performing ball milling, drying and compression molding to obtain a blank layer with the water absorption rate of more than 6%;
2) coating the glaze layer with the glaring overglaze in a glaze spraying mode, and controlling the glazing specific gravity to be 1.8g/cm3Forming a dazzling glaze layer;
3) carrying out ink-jet printing on pattern textures and functional ink on the dazzling glaze layer in sequence to form an ink-jet pattern texture layer and a functional ink layer in sequence;
4) spraying ceramic tile transparent overglaze on the functional ink layer at high pressure, wherein the glazing specific gravity is 1.55g/cm3Forming a transparent overglaze layer, putting the overglaze layer into a kiln for one-time high-temperature firing, and controlling the firing temperature to be 1020 ℃ to obtain a finished product of comparative example 2.
The general ceramic blank described in this comparative example was the same as the general ceramic blank in example 1.
Comparative example 3
A ceramic tile with decorative effect is composed of a body layer, a glaring surface glaze layer, an ink-jet pattern texture layer and a transparent protective glaze layer from bottom to top.
The raw material components of the glare overglaze in the glare overglaze layer comprise 35 parts of albite, 15 parts of kaolin, 11 parts of barium carbonate, 2 parts of zinc oxide, 16 parts of quartz, 4 parts of alumina, 5 parts of calcined kaolin and 10 parts of inkjet frit by weight; the transparent protective glaze in the transparent protective glaze layer comprises the following raw materials, by weight, 15 parts of potassium feldspar, 18 parts of albite, 13 parts of kaolin, 8 parts of calcined talc, 5 parts of wollastonite, 22 parts of barium carbonate, 14 parts of dolomite, 4 parts of zinc oxide, 2 parts of alumina and 11 parts of transparent high-brightness frit.
The ink-jet frit comprises, by weight, 34.68% of quartz, 22.15% of potassium feldspar, 3% of zirconium silicate, 5.98% of calcium borate, 10.12% of limestone, 7.3% of dolomite, 2.35% of calcium phosphate, 7.13% of zinc oxide, 4.64% of boric acid and 2.65% of potassium carbonate, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1540 ℃, and then quenching with water and cooling.
The transparent high-brightness frit comprises, by weight, 38.82% of quartz, 7.17% of zinc oxide, 19.17% of limestone, 5% of dolomite, 2% of potassium carbonate, 1.17% of barium carbonate, 25.67% of potassium feldspar and 1% of boric acid, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1480 ℃, quenching with water and cooling.
The preparation method comprises the following steps:
1) mixing common ceramic blanks uniformly, and performing ball milling, drying and compression molding to obtain a blank layer with the water absorption rate of more than 6%;
2) coating the glaze layer with the glaring overglaze in a glaze spraying mode, and controlling the glazing specific gravity to be 1.8g/cm3Forming a dazzling glaze layer;
3) spraying transparent protective glaze on the glaring glaze layer at high pressure, wherein the glazing specific gravity is 1.55g/cm3Forming a transparent protective glaze layer, putting the transparent protective glaze layer into a kiln for one-time high-temperature firing, and controlling the firing temperature to be 1020 ℃ to obtain a finished product of the comparative example 3.
The general ceramic blank described in this comparative example was the same as the general ceramic blank in example 1.
Example 2
A3D stereoscopic dazzling ceramic tile sequentially comprises a blank layer, a dazzling glaze layer, an ink-jet pattern texture layer, a pattern-permeating ink layer and a transparent protective glaze layer from bottom to top.
The raw material components of the glare overglaze in the glare overglaze layer comprise, by weight, 40 parts of albite, 12 parts of kaolin, 15 parts of barium carbonate, 1 part of zinc oxide, 20 parts of quartz, 2 parts of alumina, 6 parts of calcined kaolin and 0.5 part of inkjet frit; the raw material components of the transparent protective glaze in the transparent protective glaze layer comprise, by weight, 12 parts of potassium feldspar, 24 parts of albite, 12 parts of kaolin, 12 parts of calcined talc, 3 parts of wollastonite, 26 parts of barium carbonate, 10 parts of dolomite, 6 parts of zinc oxide, 1 part of alumina and 6 parts of transparent high-brightness frit.
The ink-jet frit comprises, by weight, 34.68% of quartz, 22.15% of potassium feldspar, 3% of zirconium silicate, 5.98% of calcium borate, 10.12% of limestone, 7.3% of dolomite, 2.35% of calcium phosphate, 7.13% of zinc oxide, 4.64% of boric acid and 2.65% of potassium carbonate, and is prepared by mixing the raw material components by a mixer for 20min, placing the mixture in a frit furnace, firing at a high temperature of 1540 ℃, and then quenching with water and cooling.
The transparent high-brightness frit comprises, by weight, 38.82% of quartz, 7.17% of zinc oxide, 19.17% of limestone, 5% of dolomite, 2% of potassium carbonate, 1.17% of barium carbonate, 25.67% of potassium feldspar and 1% of boric acid, and is prepared by mixing the raw material components for 20min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1480 ℃, quenching with water and cooling.
The preparation method comprises the following steps:
1) uniformly mixing common ceramic blanks, and performing ball milling, drying and compression molding to obtain a blank layer with the water absorption rate of 1-6%;
2) coating the glaze layer with the glaring overglaze in a glaze pouring mode, and controlling the glazing specific gravity to be 1.82g/cm3Forming a dazzling glaze layer;
3) carrying out ink-jet printing on pattern textures and functional ink on the dazzling glaze layer in sequence to form an ink-jet pattern texture layer and a functional ink layer in sequence;
4) spraying transparent protective glaze on the functional ink layer at high pressure, wherein the specific gravity of the glaze is 1.45g/cm3And a transparent protective glaze layer is formed, and the mixture is put into a kiln for one-time high-temperature firing, wherein the firing temperature is controlled to be 1120 ℃, and a finished product of the example 2 is obtained.
The common ceramic blank described in this example is a commercially available common stone tile blank.
Example 3
A3D stereoscopic dazzling ceramic tile sequentially comprises a blank layer, a dazzling glaze layer, an ink-jet pattern texture layer, a bright ink layer and a transparent protective glaze layer from bottom to top.
The raw material components of the glare overglaze in the glare overglaze layer comprise 38 parts of albite, 14 parts of kaolin, 12 parts of barium carbonate, 1.5 parts of zinc oxide, 18 parts of quartz, 3 parts of alumina, 5.5 parts of calcined kaolin and 6 parts of inkjet frit in parts by weight; the raw material components of the transparent protective glaze in the transparent protective glaze layer comprise, by weight, 13 parts of potassium feldspar, 20 parts of albite, 12.5 parts of kaolin, 10 parts of calcined talc, 4 parts of wollastonite, 25 parts of barium carbonate, 12 parts of dolomite, 5 parts of zinc oxide, 1.5 parts of alumina and 11.5 parts of transparent high-brightness frit.
The ink-jet frit comprises, by weight, 34.68% of quartz, 22.15% of potassium feldspar, 3% of zirconium silicate, 5.98% of calcium borate, 10.12% of limestone, 7.3% of dolomite, 2.35% of calcium phosphate, 7.13% of zinc oxide, 4.64% of boric acid and 2.65% of potassium carbonate, and is prepared by mixing the raw material components with a mixer for 25min, placing the mixture in a frit furnace, firing at a high temperature of 1540 ℃, and then quenching with water and cooling.
The transparent high-brightness frit comprises, by weight, 38.82% of quartz, 7.17% of zinc oxide, 19.17% of limestone, 5% of dolomite, 2% of potassium carbonate, 1.17% of barium carbonate, 25.67% of potassium feldspar and 1% of boric acid, and is prepared by mixing the raw material components for 25min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1480 ℃, quenching with water and cooling.
The preparation method comprises the following steps:
1) mixing common ceramic blanks uniformly, and performing ball milling, drying and compression molding to obtain a blank layer with the water absorption rate of more than 6%;
2) coating the glaze layer with the glaring overglaze in a glaze pouring mode, and controlling the glazing specific gravity to be 1.81g/cm3Forming a dazzling glaze layer;
3) carrying out ink-jet printing on pattern textures and functional ink on the dazzling glaze layer in sequence to form an ink-jet pattern texture layer and a functional ink layer in sequence;
4) spraying transparent protective glaze on the functional ink layer at high pressure, wherein the specific gravity of the glaze is 1.5g/cm3And a transparent protective glaze layer is formed, and the mixture is put into a kiln for one-time high-temperature firing at 1020 ℃ to obtain a finished product of example 3.
The common ceramic blank in this embodiment is a common ceramic tile blank commercially available.
Example 4
A3D stereoscopic dazzling ceramic tile sequentially comprises a blank layer, a dazzling overglaze layer, an ink-jet pattern texture layer, a stripping glaze ink layer and a transparent protective glaze layer from bottom to top.
The raw material components of the glare overglaze in the glare overglaze layer comprise 38 parts of albite, 12 parts of kaolin, 12 parts of barium carbonate, 2 parts of zinc oxide, 16 parts of quartz, 3 parts of alumina, 6 parts of calcined kaolin and 8 parts of inkjet frit by weight; the transparent protective glaze in the transparent protective glaze layer comprises 14 parts of potassium feldspar, 22 parts of albite, 12 parts of kaolin, 9 parts of calcined talc, 5 parts of wollastonite, 23 parts of barium carbonate, 12 parts of dolomite, 4 parts of zinc oxide, 2 parts of alumina and 2.5 parts of transparent high-brightness frit according to parts by weight.
The ink-jet frit comprises, by weight, 34.68% of quartz, 22.15% of potassium feldspar, 3% of zirconium silicate, 5.98% of calcium borate, 10.12% of limestone, 7.3% of dolomite, 2.35% of calcium phosphate, 7.13% of zinc oxide, 4.64% of boric acid and 2.65% of potassium carbonate, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1540 ℃, and then quenching with water and cooling.
The transparent high-brightness frit comprises, by weight, 38.82% of quartz, 7.17% of zinc oxide, 19.17% of limestone, 5% of dolomite, 2% of potassium carbonate, 1.17% of barium carbonate, 25.67% of potassium feldspar and 1% of boric acid, and is prepared by mixing the raw material components for 30min by a mixer, placing the mixture in a frit furnace, firing at a high temperature of 1480 ℃, quenching with water and cooling.
The preparation method comprises the following steps:
1) mixing common ceramic blanks uniformly, and performing ball milling, drying and compression molding to obtain a blank layer with the water absorption rate of below 1%;
2) coating the glaze layer with the glaring overglaze in a glaze pouring mode, and controlling the glazing specific gravity to be 1.82g/cm3Forming a dazzling glaze layer;
3) carrying out ink-jet printing on pattern textures and functional ink on the dazzling glaze layer in sequence to form an ink-jet pattern texture layer and a functional ink layer in sequence;
4) spraying transparent protective glaze on the functional ink layer at high pressure, wherein the specific gravity of the glaze is 1.48g/cm3And a transparent protective glaze layer is formed, and the mixture is put into a kiln for one-time high-temperature firing at the firing temperature of 1150 ℃ to obtain a finished product of the example 4.
The common ceramic blank described in this example is a commercially available common ceramic tile blank.
Example 4: performance detection
The products obtained in examples 1-4 and comparative examples 1-3 were subjected to related performance tests, and the product performance test data are shown in table 1 below. According to the product performance test data in table 1, the formula of the dazzling glaze and the formula of the transparent protective glaze are adjusted, and the formula and the functional ink are synergistic, so that the ceramic tile product after high-temperature firing has an obvious 3D (three-dimensional) effect, has good glaze compressive strength, brightness, antifouling performance and the like, can be adapted to ceramic tiles with different water absorption rates, and the application range of the 3D dazzling ceramic tile is greatly widened.
TABLE 1 product Performance test results
| Test specimen | Compressive strength of glaze | Lightness of light | Antifouling property | 3D (three-dimensional) dazzling effect |
| Example 1 | 35MPa | 85° | Conforms to GB/T3810.14 | Is provided with |
| Comparative example 1 | 28MPa | 75° | Conforms to GB/T3810.14 | Is free of |
| Comparative example 2 | 30MPa | 78° | Not conforming to GB/T3810.14 | Is free of |
| Comparative example 3 | 27MPa | 74° | Conforms to GB/T3810.14 | Is free of |
| Example 2 | 33MPa | 82° | Conforms to GB/T3810.14 | Is provided with |
| Example 3 | 34MPa | 81° | Conforms to GB/T3810.14 | Is provided with |
| Example 4 | 35MPa | 84° | Conforms to GB/T3810.14 | Is provided with |
The above embodiments are preferred embodiments of the present invention, and all similar processes and equivalent variations to those of the present invention should fall within the scope of the present invention.
Claims (10)
1. The utility model provides a three-dimensional glazed ceramic brick that dazzles of 3D which characterized in that: the glaze comprises a blank layer, a glaring glaze layer, an ink-jet pattern texture layer, a functional ink layer and a transparent protective glaze layer from bottom to top in sequence, wherein raw material components of the glaring glaze layer in the glaring glaze layer comprise, by weight, 35-40 parts of albite, 12-15 parts of kaolin, 11-15 parts of barium carbonate, 1-2 parts of zinc oxide, 16-20 parts of quartz, 2-4 parts of alumina, 5-6 parts of calcined kaolin and 0.5-12 parts of ink-jet frits, and raw material components of the transparent protective glaze layer in the transparent protective glaze layer comprise, by weight, 12-15 parts of potassium feldspar, 18-24 parts of albite, 12-13 parts of kaolin, 8-12 parts of calcined talc, 3-5 parts of wollastonite, 22-26 parts of barium carbonate, 10-14 parts of dolomite, 4-6 parts of zinc oxide, 1-2 parts of alumina and 2-6 parts of transparent frits.
2. The 3D glare ceramic tile of claim 1, wherein: the functional ink of the functional ink layer is selected from one of pattern penetrating ink, bright ink, stripping glaze ink and metal ink.
3. The 3D glare ceramic tile of claim 1, wherein: the ink-jet frit comprises, by weight, 28-36% of quartz, 18-24% of potassium feldspar, 2.5-3% of zirconium silicate, 3.5-5% of calcium borate, 9.6-10.2% of limestone, 7-9% of dolomite, 1.8-3.4% of calcium phosphate, 7-8% of zinc oxide, 4.4-6.5% of boric acid and 2-3.2% of potassium carbonate.
4. The 3D glare ceramic tile of claim 3, wherein: the preparation method of the ink-jet frit comprises the steps of mixing raw material components of the ink-jet frit for 20-30 min by using a mixer, placing the mixture in a frit furnace, sintering at a high temperature of 1540 ℃, and then quenching with water and cooling.
5. The 3D glare ceramic tile of claim 1, wherein: the transparent high-brightness frit comprises, by weight, 35-40% of quartz, 7-8% of zinc oxide, 19-21% of limestone, 5-6% of dolomite, 1.8-2.1% of potassium carbonate, 1-1.3% of barium carbonate, 25-30% of potassium feldspar and 0.6-1.2% of boric acid.
6. The 3D glare ceramic tile of claim 5, wherein: the preparation method of the transparent high-brightness frit comprises the steps of mixing raw material components of the transparent high-brightness frit for 20-30 min by using a mixer, placing the mixture in a frit furnace, sintering at the high temperature of 1480 ℃, and then quenching with water and cooling.
7. The preparation method of the 3D stereoscopic glare ceramic tile according to any one of claims 1 to 6, characterized by comprising the following process steps:
1) taking common ceramic blanks, mixing uniformly, and performing ball milling, drying and compression molding to obtain a blank layer;
2) coating the glaring overglaze on the body layer in a glaze pouring mode to form a glaring overglaze layer;
3) carrying out ink-jet printing on pattern textures and functional ink on the dazzling glaze layer in sequence to form an ink-jet pattern texture layer and a functional ink layer in sequence;
4) spraying transparent protective glaze on the functional ink layer at high pressure to form a transparent protective glaze layer, and sintering in a kiln at high temperature to obtain the final product.
8. The method for preparing 3D stereoscopic dazzling ceramic tile according to claim 1, characterized in that: step 2) glazing specific gravity of the sprayed glaze is 1.8-1.82 g/cm3。
9. The method for preparing 3D stereoscopic dazzling ceramic tile according to claim 1, characterized in that: step 4) the specific gravity of the high-pressure spraying glazing is 1.45-1.55 g/cm3。
10. The method for preparing 3D stereoscopic dazzling ceramic tile according to claim 1, characterized in that: and 4) the firing temperature of the one-time high-temperature firing is 1020-1150 ℃.
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| CN111574245B (en) | 2021-05-04 |
| WO2021218132A1 (en) | 2021-11-04 |
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Denomination of invention: A 3D three-dimensional dazzling ceramic tile and its preparation method Effective date of registration: 20231204 Granted publication date: 20210504 Pledgee: Foshan Rural Commercial Bank Co.,Ltd. Lanshi Branch Pledgor: FOSHAN TAOYING NEW MATERIAL CO.,LTD. Registration number: Y2023980069216 |
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