CN109627052B - Ceramic tile with three-dimensional decoration effect and preparation method thereof - Google Patents

Ceramic tile with three-dimensional decoration effect and preparation method thereof Download PDF

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Publication number
CN109627052B
CN109627052B CN201910038346.3A CN201910038346A CN109627052B CN 109627052 B CN109627052 B CN 109627052B CN 201910038346 A CN201910038346 A CN 201910038346A CN 109627052 B CN109627052 B CN 109627052B
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China
Prior art keywords
layer
ceramic tile
glaze
pattern layer
pattern
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CN201910038346.3A
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CN109627052A (en
Inventor
柯善军
马超
田维
倪成林
吴洋
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GUANGXI OUSHENNUO CERAMIC Co.,Ltd.
Foshan Oceano Ceramics Co Ltd
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Guangxi Oushennuo Ceramic Co ltd
Foshan Oceano Ceramics Co Ltd
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Priority to CN201910038346.3A priority Critical patent/CN109627052B/en
Publication of CN109627052A publication Critical patent/CN109627052A/en
Priority to PCT/CN2019/097544 priority patent/WO2020147291A1/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Finishing Walls (AREA)

Abstract

The invention discloses a ceramic tile with a three-dimensional decorative effect, which sequentially comprises a blank layer, a ground glaze layer, a background pattern layer, a transparent glaze layer, a texture pattern layer and a glaze polishing layer from bottom to top, wherein the pattern textures of the background pattern layer and the texture pattern layer are from the same original image. According to the invention, the ceramic tile pattern texture from the same original image is subjected to ink-jet printing on different layer structures of the ceramic tile, so that the three-dimensional effect of the ceramic tile decorative pattern texture is effectively improved, and the three-dimensional decorative effect is clear. The preparation method has simple process and strong operability, and is beneficial to large-scale industrial production and application.

Description

Ceramic tile with three-dimensional decoration effect and preparation method thereof
Technical Field
The invention relates to the field of architectural ceramics, in particular to a ceramic tile with a three-dimensional decorative effect.
Background
The building ceramic tile is a building decoration material, occupies a considerable proportion in building decoration, is popular with consumers due to rich colors and surface textures, and improves the living standard of substances. The aesthetic level of people is also continuously improved, the architectural ceramic product with pure color development and vivid texture effect is often more favored by consumers, but the pattern of the traditional ceramic tile is usually improved on a single-layer plane and cannot effectively express the three-dimensional effect. With the application of ceramic ink-jet printing technology, the decoration of ceramic tiles is developed into digital non-contact printing from the original screen printing and roller printing. The screen printing and the roller printing have the problem of difficult alignment, and the ink-jet printing can be accurately positioned. Therefore, the ink-jet printing decoration technology can separate and superpose the decoration layers of the ceramic tiles at any level. However, the three-dimensional decoration effect of the existing inkjet printing ceramic tile still needs to be improved.
Disclosure of Invention
The invention aims to provide a ceramic tile with a three-dimensional decoration effect and a preparation method of the ceramic tile, aiming at the defects of the prior art.
The technical scheme adopted by the invention is as follows: the ceramic tile with the three-dimensional decoration effect sequentially comprises a body layer, a ground glaze layer, a background pattern layer, a transparent glaze layer, a texture pattern layer and a glaze polishing layer from bottom to top, wherein pattern textures of the background pattern layer and the texture pattern layer are derived from the same original image.
As a further improvement of the scheme, the transparent glaze layer has the chemical composition of 58.23 percent of SiO in percentage by mass213.16% of Al2O30.05% of Fe2O30.12% of TiO25.13% CaO, 6.79% MgO, 5.04% K2O, 2.78% of Na2O, 2.72% ZnO, 1.46% BaO, 3.27% SrO and 1.25% loss on ignition.
As a further improvement of the scheme, the thickness of the transparent glaze layer is 0.2-0.4 mm.
The preparation method of the ceramic tile with the three-dimensional decorative effect comprises the following process steps:
1) pressing and molding ceramic tile green body powder to obtain a green body layer, and applying a ground coat on the green body layer to obtain a ground coat layer;
2) processing the ceramic tile pattern texture original image through image processing software, and separating line patterns or specific pattern areas of the original image into independent images to form a background pattern layer and a texture pattern layer;
3) ink-jet printing the background pattern layer obtained in the step 2) on the bottom oil layer obtained in the step 1);
4) applying a transparent glaze cloth on the background pattern layer to obtain a transparent glaze layer;
5) ink-jet printing the textured pattern layer of step 2) on the transparent layer;
6) and (4) glazing the texture pattern layer to obtain a glazed layer, and firing, cutting and polishing to obtain a finished product.
As a further improvement of the above scheme, in the step 1), the ground coat is applied by means of glaze spraying or glaze spraying.
As a further improvement of the above scheme, in the step 4), a glaze spraying manner is adopted to apply the transparent glaze.
As a further improvement of the scheme, the highest firing temperature in the step 6) is 1180-1230 ℃, and the firing time is 55-65 min.
The invention has the beneficial effects that:
according to the invention, the ceramic tile pattern texture from the same original image is subjected to ink-jet printing on different layer structures of the ceramic tile, so that the three-dimensional effect of the ceramic tile decorative pattern texture is effectively improved, and the three-dimensional decorative effect is clear.
The preparation method has simple process and strong operability, and is beneficial to large-scale industrial production and application.
Detailed Description
The present invention is specifically described below with reference to examples in order to facilitate understanding of the present invention by those skilled in the art. It should be particularly noted that the examples are given solely for the purpose of illustration and are not to be construed as limitations on the scope of the invention, as non-essential improvements and modifications to the invention may occur to those skilled in the art, which fall within the scope of the invention as defined by the appended claims. Meanwhile, the raw materials mentioned below are not specified in detail and are all commercial products; the process steps or preparation methods not mentioned in detail are all process steps or preparation methods known to the person skilled in the art.
Example 1
A ceramic tile with three-dimensional decoration effect sequentially comprises a body layer, a ground glaze layer, a background pattern layer, a transparent glaze layer, a texture pattern layer and a glaze polishing layer from bottom to top.
And the pattern textures of the background pattern layer and the texture pattern layer are derived from the same original image. The transparent glaze layer comprises 58.23 mass percent of SiO213.16% of Al2O30.05% of Fe2O30.12% of TiO25.13% CaO, 6.79% MgO, 5.04% K2O, 2.78% of Na2O, 2.72 percent of ZnO and 1.46 percent ofBaO, 3.27% SrO and 1.25% loss on ignition. The thickness of the transparent glaze layer is 0.2 mm.
The preparation method comprises the following steps:
1) pressing and molding ceramic tile green body powder to obtain a green body layer, and applying a ground glaze on the green body layer in a glaze spraying mode to obtain a ground glaze layer;
2) processing the ceramic tile pattern texture original image through image processing software, and separating line patterns or specific pattern areas of the original image into independent images to form a background pattern layer and a texture pattern layer;
3) ink-jet printing the background pattern layer obtained in the step 2) on the bottom oil layer obtained in the step 1);
4) applying a transparent glaze cloth on the background pattern layer in a glaze pouring mode to obtain a transparent glaze layer;
5) ink-jet printing the textured pattern layer of step 2) on the transparent layer;
6) and (3) glazing the texture pattern layer to obtain a glazed layer, firing at 1180 ℃ for 65min, cutting and polishing to obtain the finished product of the embodiment 1.
Example 2
A ceramic tile with three-dimensional decoration effect sequentially comprises a body layer, a ground glaze layer, a background pattern layer, a transparent glaze layer, a texture pattern layer and a glaze polishing layer from bottom to top.
And the pattern textures of the background pattern layer and the texture pattern layer are derived from the same original image. The transparent glaze layer comprises 58.23 mass percent of SiO213.16% of Al2O30.05% of Fe2O30.12% of TiO25.13% CaO, 6.79% MgO, 5.04% K2O, 2.78% of Na2O, 2.72% ZnO, 1.46% BaO, 3.27% SrO and 1.25% loss on ignition. The thickness of the transparent glaze layer is 0.4 mm.
The preparation method comprises the following steps:
1) pressing and molding ceramic tile green body powder to obtain a green body layer, and applying a ground coat on the green body layer in a glaze spraying manner to obtain a ground coat layer;
2) processing the ceramic tile pattern texture original image through image processing software, and separating line patterns or specific pattern areas of the original image into independent images to form a background pattern layer and a texture pattern layer;
3) ink-jet printing the background pattern layer obtained in the step 2) on the bottom oil layer obtained in the step 1);
4) applying a transparent glaze cloth on the background pattern layer in a glaze pouring mode to obtain a transparent glaze layer;
5) ink-jet printing the textured pattern layer of step 2) on the transparent layer;
6) and (3) glazing the texture pattern layer to obtain a glazed layer, firing at 1230 ℃ for 55min, cutting and polishing to obtain the finished product of the example 2.
Example 3
A ceramic tile with three-dimensional decoration effect sequentially comprises a body layer, a ground glaze layer, a background pattern layer, a transparent glaze layer, a texture pattern layer and a glaze polishing layer from bottom to top.
And the pattern textures of the background pattern layer and the texture pattern layer are derived from the same original image. The transparent glaze layer comprises 58.23 mass percent of SiO213.16% of Al2O30.05% of Fe2O30.12% of TiO25.13% CaO, 6.79% MgO, 5.04% K2O, 2.78% of Na2O, 2.72% ZnO, 1.46% BaO, 3.27% SrO and 1.25% loss on ignition. The thickness of the transparent glaze layer is 0.3 mm.
The preparation method comprises the following steps:
1) pressing and molding ceramic tile green body powder to obtain a green body layer, and applying a ground coat on the green body layer in a glaze spraying manner to obtain a ground coat layer;
2) processing the ceramic tile pattern texture original image through image processing software, and separating line patterns or specific pattern areas of the original image into independent images to form a background pattern layer and a texture pattern layer;
3) ink-jet printing the background pattern layer obtained in the step 2) on the bottom oil layer obtained in the step 1);
4) applying a transparent glaze cloth on the background pattern layer in a glaze pouring mode to obtain a transparent glaze layer;
5) ink-jet printing the textured pattern layer of step 2) on the transparent layer;
6) and (3) glazing the texture pattern layer to obtain a glazed layer, firing at 1200 ℃ for 60min, cutting and polishing to obtain the finished product of the embodiment 3.
The above embodiments are preferred embodiments of the present invention, and all similar processes and equivalent variations to those of the present invention should fall within the scope of the present invention.

Claims (4)

1. A ceramic tile with three-dimensional decoration effect is characterized in that: the glaze-free artificial leather comprises a body layer, a ground glaze layer, a background pattern layer, a transparent glaze layer, a texture pattern layer and a glaze-polished layer from bottom to top in sequence, wherein the pattern textures of the background pattern layer and the texture pattern layer are from the same original image;
the transparent glaze layer comprises 58.23 mass percent of SiO213.16% of Al2O30.05% of Fe2O30.12% of TiO25.13% CaO, 6.79% MgO, 5.04% K2O, 2.78% of Na2O, 2.72% ZnO, 1.46% BaO, 3.27% SrO and 1.25% loss on ignition; the thickness of the transparent glaze layer is 0.2-0.4 mm;
the preparation method of the ceramic tile with the three-dimensional decoration effect comprises the following process steps:
1) pressing and molding ceramic tile green body powder to obtain a green body layer, and applying a ground coat on the green body layer to obtain a ground coat layer;
2) processing the ceramic tile decorative pattern texture original image through image processing software, and separating line patterns or specific pattern areas of the original image into independent images to form a background pattern layer and a texture pattern layer;
3) ink-jet printing the background pattern layer obtained in the step 2) on the bottom oil layer obtained in the step 1);
4) applying a transparent glaze cloth on the background pattern layer to obtain a transparent glaze layer;
5) ink-jet printing the textured pattern layer of step 2) on the transparent layer;
6) and (4) glazing the texture pattern layer to obtain a glazed layer, and firing, cutting and polishing to obtain a finished product.
2. The ceramic tile with three-dimensional decorative effect as claimed in claim 1, wherein: and (2) applying the ground coat in the step 1) in a glaze spraying or glaze spraying manner.
3. The ceramic tile with three-dimensional decorative effect as claimed in claim 1, wherein: and 4) applying transparent glaze in a glaze spraying mode in the step 4).
4. The ceramic tile with three-dimensional decorative effect as claimed in claim 1, wherein: the highest firing temperature in the step 6) is 1180-1230 ℃, and the firing time is 55-65 min.
CN201910038346.3A 2019-01-16 2019-01-16 Ceramic tile with three-dimensional decoration effect and preparation method thereof Active CN109627052B (en)

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PCT/CN2019/097544 WO2020147291A1 (en) 2019-01-16 2019-07-24 Ceramic tile having stereoscopic decoration effect and preparation method therefor

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Publication number Priority date Publication date Assignee Title
CN109627052B (en) * 2019-01-16 2021-07-13 佛山欧神诺陶瓷有限公司 Ceramic tile with three-dimensional decoration effect and preparation method thereof
CN110981552B (en) * 2019-12-17 2021-12-17 佛山欧神诺陶瓷有限公司 Cera flava-imitated ceramic tile and preparation method thereof
CN110981553B (en) * 2019-12-17 2021-12-17 佛山欧神诺陶瓷有限公司 Transparent amber-like ceramic tile and preparation method thereof
CN111087254B (en) * 2020-03-23 2020-12-01 广东欧文莱陶瓷有限公司 Ceramic tile, frit for manufacturing ceramic tile and preparation method of frit
CN113216445B (en) * 2021-04-23 2022-05-20 广东职业技术学院 Thermochromic ceramic background wall and preparation method and application thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005121048A1 (en) * 2004-06-11 2005-12-22 Masahiro Kubuki Tile with two-dimensional code and process for producing the same
CN105418162A (en) * 2015-12-14 2016-03-23 东莞市唯美陶瓷工业园有限公司 Whole-body polished porcelain tile having three-dimensional stone texture and production method of tile
CN106522499A (en) * 2016-10-18 2017-03-22 蒙娜丽莎集团股份有限公司 Archaized brick with 3D decorative effect and preparation method thereof
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WO2020147291A1 (en) 2020-07-23

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