CN115043649B - Integral ceramic tile with spinel-like effect and preparation method thereof - Google Patents
Integral ceramic tile with spinel-like effect and preparation method thereof Download PDFInfo
- Publication number
- CN115043649B CN115043649B CN202210665423.XA CN202210665423A CN115043649B CN 115043649 B CN115043649 B CN 115043649B CN 202210665423 A CN202210665423 A CN 202210665423A CN 115043649 B CN115043649 B CN 115043649B
- Authority
- CN
- China
- Prior art keywords
- parts
- ceramic tile
- spinel
- blank
- effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3215—Barium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/606—Drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The application provides a whole ceramic tile with a spinel-like effect and a preparation method thereof, and relates to the technical field of building ceramics. The preparation method of the whole ceramic tile comprises the following steps: adopting a fixed-point texture material distribution component station mode to perform positioning material distribution on blanks and penetrating materials in a preset proportion to form preset textures, and pressing the blanks into blanks; and (3) distributing protective glaze on the green body, and firing to obtain the whole ceramic tile. The utility model discloses a utilize the spinel effect of penetrating material self to and blank self is little to the characteristic of adobe surface color development influence, and the blank surface of formation can demonstrate the texture change of the spinel effect of similar natural stone material, does not need ground coat and overglaze, can not produce the exhaust reaction and lead to the product surface to appear defects such as extensive pinhole, bubble or concave edge, fried brick when firing, and the rethread protection glaze protects the texture effect that the blank formed.
Description
Technical Field
The application relates to the technical field of building ceramics, in particular to a whole ceramic tile with a spinel-like effect and a preparation method thereof.
Background
The existing polished tiles, glazed tiles and other ceramic tile products are basically plane products, and even if the products have three-dimensional decorative effect, the products obviously float on the surface of the ceramic tile products, so that the texture decorative effect is relatively simple. In particular, for some tiles imitating natural stone, the pattern texture effect is dead and stiff, and is obviously not suitable for decorating specific occasions or individual places, and the required tile texture and visual effect are obviously not provided by the products. Therefore, the prior art has not yet been improved and improved in terms of the effect of the ceramic tile to simulate the natural stone surface.
Disclosure of Invention
The purpose of the application is to provide a whole ceramic tile with a crystal-like effect, which is similar to natural stone, and a preparation method thereof.
In order to achieve the above object, the technical scheme of the present application is as follows:
the application provides a preparation method of a whole ceramic tile with a spinel effect, which comprises the following steps:
adopting a fixed-point texture material distribution component station mode to perform positioning material distribution on blanks and penetrating materials in a preset proportion to form preset textures, and pressing the blanks into blanks;
applying protective glaze on the green body, and firing to obtain the whole ceramic tile;
the chemical composition of the blank comprises the following components in percentage by mass 2 65-72％，Al 2 O 3 15-20％，CaO0.2-1％，MgO1-2％，Na 2 O1-2％，K 2 3-6% of O and 8-10.5% of burning loss;
the chemical composition of the permeable material comprises the following components in percentage by mass 2 45-55％，Al 2 O 3 10-15％，CaO8-12％，MgO3-7％，Na 2 O1-2％，K 2 1-2% of O, 6-10% of BaO, 3-5% of ZnO and 7.5-9.5% of burning loss.
Preferably, the raw material components of the blank comprise the following components in parts by mass: 20-25 parts of mud, 15-19 parts of kaolin, 15-20 parts of potassium feldspar, 8-12 parts of albite, 20-25 parts of sand, 3-5 parts of talcum and 2-4 parts of recycled brick powder;
the permeable material comprises the following raw material components in parts by mass: 15-30 parts of potassium feldspar, 5-20 parts of albite, 8-12 parts of kaolin, 6-15 parts of calcined kaolin, 6-10 parts of barium carbonate, 13-18 parts of calcite, 6-10 parts of dolomite, 2-6 parts of calcined talcum, 3-5 parts of zinc oxide and 1.5-2.5 parts of aluminum oxide;
the permeable material is dry particles obtained by firing and crushing the permeable material raw material.
Preferably, before the positioning cloth is carried out, the blank with different colors and different forms and the permeable cloth are respectively prepared;
the different colors include at least one of a bulk color, red, blue, brown, yellow, gray, green, cyan, and black;
the different forms comprise powdery materials with the particle size of 100-200 meshes and irregular blocky particles with the particle size of 3-30 mm.
Preferably, before the protective glaze is applied, a decorative layer is further required to be arranged on the surface of the blank body, and the decorative layer comprises an ink layer and/or a functional layer;
preferably, the ink layer is obtained by positioning jet printing ink on the surface of the blank, and the pattern texture formed by the ink layer corresponds to the preset texture of the blank;
preferably, the ink includes color ink or dip function ink.
Preferably, the functional layer comprises a dry grain layer or a mica sheet layer;
preferably, the dry particle layer is obtained by positioning and spraying glue on the surface of the blank body or the surface of the ink layer and distributing dry particles, and the dry particles comprise colored dry particles or flash dry particles;
preferably, the mica sheet layer is obtained by applying mica sheets on the surface of the blank body or the surface of the ink layer.
Preferably, after the green body is pressed, the green body is further subjected to primary drying;
after the cloth is coated with the protective glaze, the cloth is also required to be dried for the second time.
Preferably, the temperature of the first drying is 120-200 ℃ and the time is 15-20 min;
preferably, the temperature of the second drying is 120-200 ℃ and the time is 30-50 min.
Preferably, before the positioning of the cloth, the method further comprises: and distributing the blank to obtain a base blank layer, and distributing the positioning cloth on the base blank layer.
Preferably, the sintering temperature is 1130-1220 ℃ and the sintering time is 45-70 min.
The application also provides a whole ceramic tile with a spinel-like effect, which is prepared by using the preparation method.
The beneficial effects of this application:
in the preparation method of the whole ceramic tile with the spinel effect, the spinel effect of the permeable material and the characteristic that the blank has small influence on the color development of the surface of the green brick are utilized, and after the permeable material and the blank are mixed to form a green body, the texture change similar to the spinel effect of natural stone can be displayed on the surface of the green body. And the two materials can be perfectly fused together without applying ground coat and overglaze on the fired green body, so that defects of pinholes, bubbles or concave edges, brick explosion and the like with large area are avoided on the surface of a product due to exhaust reaction during firing, and the texture effect formed by the green body is protected by the protective glaze, so that the transparent feeling and effect similar to the texture of crystal stone can be intuitively seen through the brick surface. Meanwhile, the firing loss of the blank and the firing of the transparent material is also different to a certain extent, the surface of the finally fired blank can form a certain concave-convex sense, and the transparent sense of the transparent material itself is combined to prepare the transparent ceramic tile with the three-dimensional concave-convex sense and the spinel-like effect.
The whole ceramic tile with the crystal-like stone effect is similar to natural stone in texture and visual effect, and has high surface hardness and excellent wear resistance and corrosion resistance.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are needed in the embodiments will be briefly described below, it being understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope of the present invention.
FIG. 1 is a physical view of the ceramic tile prepared in example 1;
FIG. 2 is a physical view of the ceramic tile prepared in example 2;
FIG. 3 is a physical view of the ceramic tile prepared in example 3;
FIG. 4 is a physical view of the ceramic tile prepared in example 4.
Detailed Description
The term as used herein:
"prepared from … …" is synonymous with "comprising". The terms "comprising," "including," "having," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, step, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, step, method, article, or apparatus.
The conjunction "consisting of … …" excludes any unspecified element, step or component. If used in a claim, such phrase will cause the claim to be closed, such that it does not include materials other than those described, except for conventional impurities associated therewith. When the phrase "consisting of … …" appears in a clause of the claim body, rather than immediately following the subject, it is limited to only the elements described in that clause; other elements are not excluded from the stated claims as a whole.
When an equivalent, concentration, or other value or parameter is expressed as a range, preferred range, or a range bounded by a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when ranges of "1 to 5" are disclosed, the described ranges should be construed to include ranges of "1 to 4", "1 to 3", "1 to 2 and 4 to 5", "1 to 3 and 5", and the like. When a numerical range is described herein, unless otherwise indicated, the range is intended to include its endpoints and all integers and fractions within the range.
In these examples, the parts and percentages are by mass unless otherwise indicated.
"parts by mass" means a basic unit of measurement showing the mass ratio of a plurality of components, and 1 part may be any unit mass, for example, 1g may be expressed, 2.689g may be expressed, and the like. If we say that the mass part of the a component is a part and the mass part of the B component is B part, the ratio a of the mass of the a component to the mass of the B component is represented as: b. alternatively, the mass of the A component is aK, and the mass of the B component is bK (K is an arbitrary number and represents a multiple factor). It is not misunderstood that the sum of the parts by mass of all the components is not limited to 100 parts, unlike the parts by mass.
"and/or" is used to indicate that one or both of the illustrated cases may occur, e.g., a and/or B include (a and B) and (a or B).
The application provides a preparation method of a whole ceramic tile with a spinel effect, which comprises the following steps: adopting a fixed-point texture material distribution component station mode to perform positioning material distribution on blanks and penetrating materials in a preset proportion to form preset textures, and pressing the blanks into blanks; and (3) distributing protective glaze on the green body, and firing to obtain the whole ceramic tile.
Wherein the chemical composition of the blank in the blank comprises the following components in percentage by mass 2 65-72%, for example, may be 65%, 66%, 67%, 68%, 69%, 70%, 71%, 72% or any value between 65% -72%, al 2 O 3 15-20%, for example 15%, 16%, 17%, 18%, 19%, 20% or any value between 15 and 20%, caO0.2-1%, for example 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1% or any value between 0.2 and 1%, mgO1-2%, for example 1%, 1.2%, 1.4%, 1.6%, 1.8%, 2% or any value between 1 and 2%, na 2 O1-2%, for example, may be 1%, 1.1%, 1.3%, 1.5%, 1.7%, 1.9%, 2% or any value between 1-2%, K 2 O3-6%, for example, may be 3%, 3.5%, 4%, 4.5%, 5%, 5.5%, 6% or any value between 3-6%, with a burn loss of 8-10.5%.
The chemical composition of the permeable material in the green body comprises SiO by mass percent 2 45-55%, for example 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52%, 53%, 54%, 55% or any value between 45-55%, al 2 O 3 10-15%, for example, 10%, 11%, 12%, 13%, 14%, 15% or any value between 10 and 15%, 8-12% CaO, for example, 8%, 9%, 10%, 11%, 12% or any value between 8 and 12%, mgO3-7%, for example, 3%, 4%, 5%, 6%, 7% or any value between 3 and 7%, na 2 O1-2%, for example, may be 1%, 1.2%, 1.4%, 1.6%, 1.8%, 2% or any value between 1-2%, K 2 O1-2%, for example 1%, 1.2%, 1.4%, 1.6%, 1.8%, 2% or any value between 1-2%, baO6-10%, for example 6%, 7%, 8%, 9%, 10% or 6-10%The ZnO content may be 3-5%, for example, 3%, 3.5%, 4%, 4.5%, 5% or 3-5%, and the burning loss may be 7.5-9.5%.
The blank comprises the following raw material components in parts by mass: 20-25 parts of mud, 15-19 parts of kaolin, 15-20 parts of potassium feldspar, 8-12 parts of albite, 20-25 parts of sand, 3-5 parts of talcum and 2-4 parts of recycled brick powder; the transparent material comprises the following raw material components in parts by mass: 15-30 parts of potassium feldspar, 5-20 parts of albite, 8-12 parts of kaolin, 6-15 parts of calcined kaolin, 6-10 parts of barium carbonate, 13-18 parts of calcite, 6-10 parts of dolomite, 2-6 parts of calcined talcum, 3-5 parts of zinc oxide and 1.5-2.5 parts of aluminum oxide.
The mud in the blank of the application can purchase the relevant raw materials with the silicon dioxide content of 45-65% and the aluminum oxide content of 24-30%, and the sand can purchase the relevant raw materials with the silicon dioxide content of 64-75% and the aluminum oxide content of 18-25%, for example, mud and sand produced in Guangxi Guttice county or mud and sand produced in Jiangxi Jingdian county. The recycled brick powder in the blank is a material obtained by recycling and crushing products with flaws or breakage in the production, sales and other stages of ceramic bricks produced by the company.
The main chemical components of the potassium feldspar in the blank and the penetrating material comprise: siO (SiO) 2 60-70％，Al 2 O 3 10-17％，CaO0.2-1％，Na 2 O2-3％，K 2 10-15% of O; the main chemical components of the albite comprise: siO (SiO) 2 68-75％，Al 2 O 3 15-20％，CaO0.2-1％，Na 2 O8-11％，K 2 O0-1%; the main chemical components of the kaolin comprise: siO (SiO) 2 53-57％，Al 2 O 3 28-32％，CaO0.1-0.3％，MgO0.1-0.3％，Na 2 O0.2-0.5％，K 2 O2-6％。
The blank and the penetrating material of the application have a part of SiO after firing 2 With Al 2 O 3 The netlike mullite crystal is generated by reaction to form a powder skeleton, so that the mechanical strength and the chemical stability of the ceramic green brick are improved. Another part of SiO 2 In the raw materials such as feldspar and the likeThe alkali metal and alkaline earth metal oxides form glassy substances, increase the viscosity of the liquid phase and fill the green body.
Al 2 O 3 Can improve the firing temperature, whiteness, chemical stability and thermal stability of the green bricks, and if the content is too small, such as less than 15 percent, the green bricks are easy to deform at high temperature.
K 2 O plays a role of fluxing, and has higher chemical stability, elasticity and thermal stability than Na 2 O is good, and the melting range is wider, so that the green brick has certain light transmittance. While Na is 2 O, caO, znO also acts as a fluxing agent, where ZnO also has the effect of improving color development.
MgO can reduce the sintering temperature and the ceramization temperature of the ceramic blank, and increase the bending strength and the fracture toughness of the blank. BaO is mainly used for extinction.
In the preparation of the blank, the blank raw materials are mixed according to the mass parts, then mixed with 0.15 mass part of sodium carboxymethyl cellulose, 0.35 mass part of sodium tripolyphosphate and 38 mass parts of water to prepare glaze slip, and the glaze slip is fully ground and then dried to prepare the blank. Wherein, the sodium carboxymethyl cellulose can adjust the viscosity of the glaze slip and lead the glaze slip to be in a stable dispersion state; the sodium tripolyphosphate can adjust the viscosity of the glaze slip and improve the thixotropic property of the glaze slip.
In an alternative embodiment, the blank and the permeable material of different colors and different forms are prepared separately before the cloth. Wherein the different colors include a bulk color and at least one of red, blue, brown, yellow, gray, green, cyan, and black; the different forms comprise powdery materials with the particle size of 100-200 meshes and irregular blocky particles with the particle size of 3-30 mm.
When blanks or penetrating materials with different colors are prepared, different pigments are mainly added into blank raw materials or penetrating materials for regulation, and the adding proportion of the pigments is that 0.01-3.5 parts of pigments are added into every 100 parts of blank raw materials or penetrating materials by mass.
Specifically, iron oxide or cobalt oxide can be added into a blank or a permeable raw material, and the effect of red color can be presented after firing; cobalt oxide is selected to be added into the raw materials, and the blue effect can be presented after firing; praseodymium oxide is selected and added into the raw materials, and the yellow effect can be obtained after firing; cobalt oxide is selected to be added into the raw materials, and the black effect can be obtained after firing.
When blanks with different forms are prepared, glaze slurry forming the blanks can be subjected to powder spraying and granulation to prepare 100-200-mesh powdery material; mixing the powder materials, pressing and crushing, and selecting the block materials with the size of 3mm-30mm from the crushed materials to obtain irregular block particles.
For preparing the transparent materials with different forms, the raw material components of the transparent materials are required to be mixed and then sent into a high-temperature furnace for firing, transparent frits are formed after cooling, and the transparent frits are crushed and then the powdery materials and irregular block-shaped particles with the required sizes are selected.
It should be noted that, before the blank is distributed, the blank distribution can be adjusted according to the product requirement, for example, a method of positioning the cloth can be selected, the blank is distributed at a fixed position, and then the blank is distributed at other positions; or mixing the transparent materials with different forms with the blank to form mixed materials with different proportions, wherein the transparent materials are distributed at certain specific positions to form mixed materials with higher proportion, and the transparent materials are distributed at other positions to form mixed materials with lower proportion; or the transparent materials with different colors and the blank materials can be selected for matching and distributing. Generally, when the whole green body is distributed, the material penetrating quality ratio is not higher than 60% of the whole green body.
When the blank and the blank are fired together, the defects of exhaust reaction, pinholes on the surface of a product and the like are avoided, because the expansion coefficients of the blank and the blank are relatively stable, the difference is not large, the expansion coefficient of a blank layer formed by the blank at 100 ℃ is about 5.61, and the expansion coefficient of the blank is 4.86.
In an alternative embodiment, a decorative layer is also provided on the surface of the blank, before the protective glaze is applied, said decorative layer comprising an ink layer and/or a functional layer.
In a preferred embodiment, the ink layer may be obtained by positioning inkjet ink on the surface of the blank, where the pattern texture formed by the ink layer corresponds to the preset texture of the blank.
It should be noted that the positioning jet printing ink is a texture formed by combining a blank in a blank body and a penetrating positioning cloth, so that the positioning jet printing position of the ink layer is designed, and the texture formed by the ink layer and the texture of the blank body layer are combined to form a more vivid texture effect. The ink layer thickness of the present application is generally set to 0.05-0.1mm.
The ink layer can be prepared by adopting a digital jet printing mode. For ordinary ink-jet printing, the ink-jet printing diagram is preset according to the effect diagram, the pattern is quite dead and stiff, the ink-jet printing pattern in the application is disassembled according to the effect diagram, the effect is changeable, the whole brick does not need to be printed, only part of positions need to be printed, and the effect is more similar to the effect of stone random textures.
In order to diversify the effect of the prepared ceramic tile, besides the common color ink forming textures of different colors, the application can also position and use sinking functional ink for spray printing, and the ceramic tile with more obvious stereoscopic concave-convex effect is prepared.
In a preferred embodiment, the functional layer comprises a dry grain layer or a mica flake layer;
the dry particle layer is obtained by positioning and spraying glue on the surface of the green body or the surface of the ink layer and distributing dry particles, and the dry particles comprise colored dry particles or flash dry particles. Similarly, the positioning effect of the dry particle layer is also to be correspondingly designed by combining the texture effect of the blank.
The thickness of the dry particle layer prepared by the method is 1.5-3.0mm. The arrangement of the dry particle layer can improve the stereoscopic concave-convex sense of the ceramic tile, and especially when a plurality of flash or color dry particles are used, the self effect of the dry particles can be utilized to prepare the ceramic tile with stereoscopic concave-convex sense with different visual effects.
In addition, the dry particles can be directly distributed on the surface of the blank body or on the surface of the ink layer instead of being distributed, and different decorative effects can be realized by utilizing the mica sheets. The mica sheet can be distributed by using a roller or a belt to control the falling distribution.
In an alternative embodiment, after the green body is pressed, the green body is subjected to a first drying; after the cloth is coated with the protective glaze, the cloth is also required to be dried for the second time.
Preferably, the temperature at which the first drying is carried out is 120℃to 200℃and may be, for example, 120℃150℃170℃200℃or any value between 120 and 200 ℃; the time for the first drying is 15min-20min, for example, 15min, 18min, 20min or any value between 15-20 min.
Preferably, the temperature of the second drying is 120 ℃ to 200 ℃, for example, can be 120 ℃, 150 ℃, 170 ℃, 200 ℃ or any value between 120 ℃ and 200 ℃; the second drying time is 30min-50min, for example, 30min, 40min, 50min or any value between 30-50 min.
In an alternative embodiment, the method further comprises, before positioning the cloth: and (3) distributing the blank to obtain a base blank layer, and independently distributing the positioning cloth on the base blank layer. Therefore, the preparation cost of the blank body can be greatly reduced, and the texture effect presented on the surface of the blank body is not influenced.
When the protective glaze is applied, the protective glaze slurry commonly used in ceramic bricks is selected for spraying, and the thickness of the formed protective glaze layer is 0.1-0.5mm. When preparing the protective glaze slip, the raw material components comprise: zinc: 8-12 parts of quartz: 22-28 parts of barium: 12-18 parts of feldspar: 18-26 parts of burned soil: 10-18 parts of water washing soil: 6-12 parts of sodium carboxymethyl cellulose: 0.15 part of sodium tripolyphosphate: 0.35 parts of water: 38 parts.
In an alternative embodiment, the temperature at which the dried ceramic tile is fired may be any value from 1130 ℃ to 1220 ℃, such as 1130 ℃, 1150 ℃, 1170 ℃, 1200 ℃, 1220 ℃ or 1130-1220 ℃ and the firing time may be from 45min to 70min, such as 45min, 50min, 60min, 70min or any value from 45-70 min.
After the ceramic tile is sintered and cooled, polishing is not needed, and a semi-polishing or full-polishing mode can be selected to obtain a finished product of the whole ceramic tile with the spinel-like effect.
According to the ceramic tile product, through the pre-designed blank and the material distribution effect of the penetrating material, and the decoration of some ink, dry particles, mica and the like, various ceramic tile products of different types can be prepared.
Embodiments of the present invention will be described in detail below with reference to specific examples, but it will be understood by those skilled in the art that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention. The specific conditions are not noted in the examples and are carried out according to conventional conditions or conditions recommended by the manufacturer. The reagents or apparatus used were conventional products commercially available without the manufacturer's attention.
Example 1
The embodiment provides a whole ceramic tile with a spinel-like effect, and the specific preparation method comprises the following steps:
(1) Respectively preparing blanks and penetrating materials with various colors, wherein the blanks and the penetrating materials respectively need 100-200 meshes of powder and 3mm, 10mm, 20mm and 30mm of irregular block-shaped particles.
(2) And respectively loading the transparent materials and the blanks with different colors and different sizes into different hoppers, positioning the cloth to form preset textures through the preset textures by using a cloth machine, and then conveying the whole blank layer into a press die frame to be punched into a blank body.
(3) And (3) conveying the pressed green body into a drying kiln for drying, wherein the drying temperature is 150 ℃ and the drying time is 15min.
(4) And directly carrying out digital spray printing by using color ink without adding an underglaze and an overglaze on the surface of the dried green body to obtain an ink pattern layer.
(5) After the ink pattern layer is obtained, the protective glaze slurry is continuously sprayed, and then the ink pattern layer is sent into a drying kiln for drying, wherein the drying temperature is 150 ℃ and the drying time is 30min.
(6) And (3) sending the dried brick body into a firing kiln for firing, wherein the firing temperature is 1200 ℃, the firing time is 60 minutes, and polishing treatment is carried out after cooling.
A concrete physical photograph of the ceramic tile is shown in FIG. 1.
Example 2
The concrete preparation method of the ceramic tile of the embodiment is the same as that of the embodiment 1, except that a dry particle layer is further arranged between the steps (4) and (5), specifically: and selecting preset positions on the ink pattern layer, applying glue, and respectively positioning transparent dry particles and flash dry particles at different preset positions.
A concrete physical photograph of the ceramic tile is shown in FIG. 2. The transparent dry particles and the flash dry particles are distributed, so that the surface of the fired ceramic tile realizes obvious three-dimensional concave-convex effect.
Example 3
The ceramic tile of this example was prepared in the same manner as in example 1, except that the ink having the sagging function was used in step (4).
A concrete physical photograph of the ceramic tile is shown in FIG. 3. By using the sinking ink, the surface of the ceramic tile after firing presents a certain three-dimensional concave-convex texture.
Example 4
The concrete preparation method of the ceramic tile of the embodiment is the same as that of the embodiment 1, except that mica sheets are added between the steps (4) and (5), specifically: a mica sheet is applied at predetermined locations on the ink pattern layer.
A concrete physical photograph of the ceramic tile is shown in FIG. 4.
As the transparent material is added in the green body, the finally manufactured product is compared with the common polished tile, and the product has more transparent feel and is more similar to stone than the texture of the polished tile; compared with the microcrystalline stone, the product effect of the stone is close to that of the microcrystalline stone, but the controllable variability is more, the extensibility is more close to that of the stone, and the stone is not uniform in pattern like the microcrystalline stone.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present invention, and not for limiting the same; although the invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some or all of the technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit of the invention.
Furthermore, those skilled in the art will appreciate that while some embodiments herein include some features but not others included in other embodiments, combinations of features of different embodiments are meant to be within the scope of the invention and form different embodiments. For example, in the claims below, any of the claimed embodiments may be used in any combination. The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.
Claims (12)
1. A method for preparing a monolithic ceramic tile with a spinel-like effect, comprising:
adopting a fixed-point texture material distribution component station mode to perform positioning material distribution on blanks and penetrating materials in a preset proportion to form preset textures, and pressing the blanks into blanks;
applying protective glaze on the green body, and firing to obtain the whole ceramic tile;
the chemical composition of the blank comprises the following components in percentage by mass 2 65-72％，Al 2 O 3 15-20％，CaO0.2-1％，MgO1-2％，Na 2 O1-2％，K 2 3-6% of O and 8-10.5% of burning loss;
the chemical composition of the permeable material comprises the following components in percentage by mass 2 45-55％，Al 2 O 3 10-15％，CaO8-12％，MgO3-7％，Na 2 O1-2％，K 2 1-2% of O, 6-10% of BaO, 3-5% of ZnO and 7.5-9.5% of burning loss;
the blank comprises the following raw material components in parts by mass: 20-25 parts of mud, 15-19 parts of kaolin, 15-20 parts of potassium feldspar, 8-12 parts of albite, 20-25 parts of sand, 3-5 parts of talcum and 2-4 parts of recycled brick powder;
the permeable material comprises the following raw material components in parts by mass: 15-30 parts of potassium feldspar, 5-20 parts of albite, 8-12 parts of kaolin, 6-15 parts of calcined kaolin, 6-10 parts of barium carbonate, 13-18 parts of calcite, 6-10 parts of dolomite, 2-6 parts of calcined talcum, 3-5 parts of zinc oxide and 1.5-2.5 parts of aluminum oxide;
the preparation method of the blank comprises the following steps: mixing the raw materials of the blank, mixing with 0.15 mass part of sodium carboxymethyl cellulose, 0.35 mass part of sodium tripolyphosphate and 38 mass parts of water to prepare glaze slurry, fully grinding, and drying the glaze slurry to prepare the blank;
the permeable material is dry granules obtained by firing and crushing the permeable material raw material, and the preparation method of the permeable material comprises the following steps: and mixing the raw material components of the transparent material, sending the mixture into a high-temperature furnace for firing, cooling to form transparent frit, and crushing the transparent frit.
2. The method for producing a monolithic ceramic tile having a spinel effect according to claim 1, wherein said blanks and said penetrating materials of different colors and different morphologies are respectively produced before said positioning cloth is carried out;
the different colors include at least one of a bulk color, red, blue, brown, yellow, gray, green, cyan, and black;
the different forms comprise powdery materials with the particle size of 100-200 meshes and irregular blocky particles with the particle size of 3-30 mm.
3. The method for producing a monolithic ceramic tile having a spinel-like effect according to claim 1, wherein a decorative layer is further provided on the surface of the green body before the protective glaze is applied, the decorative layer including an ink layer and/or a functional layer.
4. The method for preparing a monolithic ceramic tile with a spinel effect according to claim 3, wherein the ink layer is obtained by positioning inkjet ink on the surface of the green body, and the pattern texture formed by the ink layer corresponds to the preset texture of the green body;
the ink includes color ink or dip function ink.
5. A method of producing monolithic ceramic tiles having a spinel-like effect as claimed in claim 3, wherein said functional layer comprises a dry grain layer or a mica sheet layer.
6. The method for preparing the whole ceramic tile with the spinel effect according to claim 5, wherein the dry grain layer is obtained by positioning and spraying glue on the surface of the green body or the surface of the ink layer and distributing dry grains, and the dry grains comprise colored dry grains or flash dry grains;
the mica sheet layer is obtained by distributing mica sheets on the surface of the blank body or the surface of the ink layer.
7. The method for producing a monolithic ceramic tile having a spinel effect according to claim 1, wherein said green body is subjected to a first drying after said green body is pressed;
after the cloth is coated with the protective glaze, the cloth is also required to be dried for the second time.
8. The method for preparing a monolithic ceramic tile having a spinel effect as claimed in claim 7, wherein the first drying is performed at a temperature of 120 ℃ to 200 ℃ for 15min to 20min.
9. The method for preparing a monolithic ceramic tile having a spinel effect as claimed in claim 7, wherein the second drying is performed at a temperature of 120 ℃ to 200 ℃ for 30min to 50min.
10. The method for preparing a monolithic ceramic tile having a spinel effect according to claim 1, further comprising, prior to performing said positioning cloth: and distributing the blank to obtain a base blank layer, and distributing the positioning cloth on the base blank layer.
11. The method for preparing a monolithic ceramic tile having a spinel effect as claimed in any one of claims 1 to 10, wherein the firing temperature is 1130 ℃ to 1220 ℃ for 45min to 70min.
12. A monolithic ceramic tile having a spinel-like effect, characterized in that it is prepared by the preparation method according to any one of claims 1 to 11.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210665423.XA CN115043649B (en) | 2022-06-13 | 2022-06-13 | Integral ceramic tile with spinel-like effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210665423.XA CN115043649B (en) | 2022-06-13 | 2022-06-13 | Integral ceramic tile with spinel-like effect and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115043649A CN115043649A (en) | 2022-09-13 |
| CN115043649B true CN115043649B (en) | 2023-05-12 |
Family
ID=83162371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210665423.XA Active CN115043649B (en) | 2022-06-13 | 2022-06-13 | Integral ceramic tile with spinel-like effect and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115043649B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113248285A (en) * | 2021-06-28 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Dry particle decorative ceramic tile and preparation method thereof |
| WO2021189822A1 (en) * | 2020-03-23 | 2021-09-30 | 广东欧文莱陶瓷有限公司 | Fine carving ceramic tile and production process thereof |
| WO2021218132A1 (en) * | 2020-04-30 | 2021-11-04 | 佛山市陶莹新型材料有限公司 | 3d dazzling ceramic tile and preparation method therefor |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0931773B1 (en) * | 1997-11-27 | 2003-03-26 | Ferro (Italia) s.r.l. | Ceramic tile and glaze for use thereon |
| CN1231425C (en) * | 2002-01-10 | 2005-12-14 | 梁自好 | Method for producing large size composite jade crystal stone by roll channel kiln |
| EP1638904A1 (en) * | 2003-03-13 | 2006-03-29 | Jan Prochazka | Manufacturing of photocatalytic, antibacterial, selfcleaning and optically non-interfering surfaces on tiles and glazed ceramic products |
| CN103922712B (en) * | 2014-04-04 | 2015-09-23 | 佛山市三水宏源陶瓷企业有限公司 | The brilliant jade ceramic tile single firing process of crystallite |
| CN106365612B (en) * | 2016-08-30 | 2019-02-22 | 淄博狮王陶瓷有限公司 | The natural-like stone ceramic tile and its manufacturing method of a kind of color, sharpness of border |
| CN106431502A (en) * | 2016-09-03 | 2017-02-22 | 佛山市高明贝斯特陶瓷有限公司 | Production process of tile with natural jade texture |
| DE102017222447A1 (en) * | 2016-12-14 | 2018-06-14 | Ceramtec-Etec Gmbh | Transparent composite material |
| CN107915479B (en) * | 2017-11-06 | 2020-06-12 | 蒙娜丽莎集团股份有限公司 | Porcelain whole-body archaized brick and preparation method thereof |
| CN109796224B (en) * | 2019-03-01 | 2021-03-02 | 江西和美陶瓷有限公司 | Ink-jet dry particle decorative ceramic tile and manufacturing method thereof |
| CN110498675B (en) * | 2019-09-12 | 2022-04-19 | 清远市简一陶瓷有限公司 | High-whiteness light-transmitting marble tile blank and preparation method thereof |
| CN112225451A (en) * | 2020-10-27 | 2021-01-15 | 佛山欧神诺陶瓷有限公司 | Polished porcelain tile and preparation method thereof |
| CN112456802B (en) * | 2021-01-27 | 2021-06-25 | 佛山市道氏科技有限公司 | Giant crystal particles capable of forming crystal flowers, dry particle combination, particles for ceramics, ceramics and preparation method of ceramics |
| CN113999054B (en) * | 2021-10-12 | 2022-12-02 | 广东清远蒙娜丽莎建陶有限公司 | Crystal-drilled marble porcelain tile and preparation method thereof |
| CN114507013A (en) * | 2022-04-18 | 2022-05-17 | 佛山市东鹏陶瓷发展有限公司 | Transparent wear-resistant frit and preparation method thereof, and glazed brick and preparation method thereof |
-
2022
- 2022-06-13 CN CN202210665423.XA patent/CN115043649B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021189822A1 (en) * | 2020-03-23 | 2021-09-30 | 广东欧文莱陶瓷有限公司 | Fine carving ceramic tile and production process thereof |
| WO2021218132A1 (en) * | 2020-04-30 | 2021-11-04 | 佛山市陶莹新型材料有限公司 | 3d dazzling ceramic tile and preparation method therefor |
| CN113248285A (en) * | 2021-06-28 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Dry particle decorative ceramic tile and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115043649A (en) | 2022-09-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110759641B (en) | Crystal flower dry grain glaze and positioning crystal flower ceramic tile prepared from crystal flower dry grain glaze | |
| CN110746117B (en) | Colored seeding glaze and positioning crystal ceramic tile prepared by using colored seeding glaze | |
| CN110845227B (en) | Positioning crystal-patterned light-transmitting ceramic tile and preparation method thereof | |
| CN109455933B (en) | Crystalline glaze and ceramic tile prepared from same | |
| CN110776256B (en) | White radial crystal flower dry grain glaze, light-transmitting ceramic tile and preparation method thereof | |
| CN106986540B (en) | Formula for making sunken and peeled marble glaze | |
| CN109279920A (en) | A kind of wear-resisting antiskid brick and preparation method thereof | |
| CN106518029A (en) | Preparation method for marble ceramic tile with metallic luster sunken textures | |
| CN105198217B (en) | It is a kind of to be used for throwing vitreous brick production entirely, beneficial to the ground-coat enamel of ceramic ink color development | |
| CN105016787B (en) | Scrim fancy glaze face brick manufactured with polishing slag and preparation method thereof | |
| CN100360462C (en) | Glaze coloured decoration daily use poocelain and its production method | |
| CN111943724A (en) | Method for manufacturing matt transparent glazed ceramic chip | |
| CN105330158A (en) | Glaze of brunet ceramic and preparation method of glaze | |
| CN110903033B (en) | Crystal nucleating agent and positioning crystal pattern ceramic tile prepared by using same | |
| CN110835234B (en) | Colored chrysanthemum-shaped crystal flower glaze, chrysanthemum-shaped crystal flower light-transmitting ceramic tile and preparation method thereof | |
| CN110885189A (en) | Zirconium-free mutton tallow glaze and positioning crystal pattern ceramic tile prepared from same | |
| CN109279919A (en) | A kind of water mill essence stone brick and preparation method thereof | |
| CN105218170B (en) | A kind of high-hardness, wearable exempts to polish iron microcrystalline glass in series ceramic clad plate and preparation method thereof | |
| CN112723870A (en) | Ceramic rock plate with color jade effect and preparation method thereof | |
| CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
| CN108484123A (en) | A kind of Ceramic Tiles and preparation method thereof of high additive metallurgical steel slag waste material | |
| CN107417102A (en) | Low temperature transmutation plum blossom glaze porcelain and its preparation technology | |
| CN110845252B (en) | Special blank large-particle combined digital cloth archaized brick and preparation method thereof | |
| CN110903080B (en) | Special blank large particle combined digital cloth ink-jet infiltration polished brick and preparation method thereof | |
| CN114890822A (en) | Ceramic rock plate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |