CN115043649A - Full-body ceramic tile with spar-like effect and preparation method thereof - Google Patents
Full-body ceramic tile with spar-like effect and preparation method thereof Download PDFInfo
- Publication number
- CN115043649A CN115043649A CN202210665423.XA CN202210665423A CN115043649A CN 115043649 A CN115043649 A CN 115043649A CN 202210665423 A CN202210665423 A CN 202210665423A CN 115043649 A CN115043649 A CN 115043649A
- Authority
- CN
- China
- Prior art keywords
- blank
- parts
- ceramic tile
- effect
- full
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3215—Barium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/606—Drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The application provides a full-body ceramic tile with a spinel-like effect and a preparation method thereof, and relates to the technical field of building ceramics. The preparation method of the full-body ceramic tile comprises the following steps: adopting a fixed-point texture material distribution component station mode, forming preset textures on the blank and the transparent material in a preset proportion through material distribution positioning, and pressing the preset textures into a blank; and (3) spreading protective glaze on the green body, and sintering to obtain the full-body ceramic tile. This application utilizes the class spar effect of penetrating material self to and blank self influences little characteristic to adobe surface color development, and the blank surface that forms can demonstrate the texture change of the quartzite effect in the similar natural stone material, does not need ground coat and overglaze, can not produce exhaust reaction and lead to defects such as pinhole, bubble or concave edge, brick explosion of large tracts of land appear on the product surface during firing, and the texture effect that the rethread protection glaze protected the blank and formed.
Description
Technical Field
The application relates to the technical field of architectural ceramics, in particular to a full-body ceramic tile with a spar-like effect and a preparation method thereof.
Background
The existing ceramic tile products such as polished tiles, glazed tiles and the like are basically plane products, even if some products with three-dimensional decorative feelings exist, the products obviously only float on the surfaces of the ceramic tile products, and the texture decorative effect is simpler. Especially, for some ceramic tiles imitating natural stone, the pattern texture effect is rigid, and the ceramic tiles are obviously not suitable for decorating some specific occasions or some individual places, and the required ceramic tile texture and visual effect are obviously not provided by the products. Therefore, the prior art needs to be improved and improved in terms of the effect of ceramic tiles imitating the surface of natural stone.
Disclosure of Invention
The application aims to provide a full-body ceramic tile which is close to natural stone and has a spar-like effect and a preparation method thereof.
In order to achieve the above purpose, the technical scheme of the application is as follows:
the application provides a preparation method of a full-body ceramic tile with a spinel-like effect, which comprises the following steps:
adopting a fixed-point texture material distribution component station mode, forming preset textures on the blank and the transparent material in a preset proportion, and pressing the preset textures into a blank;
spreading protective glaze on the green body, and sintering to obtain the whole ceramic tile;
the chemical composition of the blank comprises SiO in percentage by mass 2 65-72％，Al 2 O 3 15-20％，CaO0.2-1％，MgO1-2％，Na 2 O1-2％，K 2 O3-6%, loss of heat 8-10.5%;
the chemical composition of the permeable material comprises SiO in percentage by mass 2 45-55％，Al 2 O 3 10-15％，CaO8-12％，MgO3-7％，Na 2 O1-2％，K 2 O1-2%, BaO 6-10%, ZnO 3-5%, and loss of ignition 7.5-9.5%.
Preferably, the blank comprises the following raw material components in parts by weight: 20-25 parts of mud, 15-19 parts of kaolin, 15-20 parts of potassium feldspar, 8-12 parts of albite, 20-25 parts of sand, 3-5 parts of talc and 2-4 parts of recycled brick powder;
the permeable material comprises the following raw material components in parts by mass: 15-30 parts of potash feldspar, 5-20 parts of albite, 8-12 parts of kaolin, 6-15 parts of calcined kaolin, 6-10 parts of barium carbonate, 13-18 parts of calcite, 6-10 parts of dolomite, 2-6 parts of calcined talc, 3-5 parts of zinc oxide and 1.5-2.5 parts of alumina;
the permeable material is dry particles obtained by burning and crushing the permeable material raw materials.
Preferably, before the positioning cloth is carried out, the blanks with different colors and different forms and the transparent cloth are respectively prepared;
the different colors include a body color and at least one of red, blue, brown, yellow, gray, green, cyan, and black;
the different forms comprise powder materials with the grain diameter of 100 meshes to 200 meshes and irregular block-shaped granular materials with the grain diameter of 3mm to 30 mm.
Preferably, before the protective glaze is applied, a decorative layer is required to be arranged on the surface of the blank body, and the decorative layer comprises an ink layer and/or a functional layer;
preferably, the ink layer is obtained by positioning and spray-printing ink on the surface of the blank, and the pattern texture formed by the ink layer corresponds to the preset texture of the blank;
preferably, the ink includes a color ink or a sinking function ink.
Preferably, the functional layer comprises a layer of dry particles or a mica sheet layer;
preferably, the dry particle layer is obtained by positioning and spraying glue on the surface of the green body or the surface of the ink layer and applying dry particles, wherein the dry particles comprise colored dry particles or glittering dry particles;
preferably, the mica sheet layer is obtained by coating mica sheets on the surface of the blank body or the surface of the ink layer.
Preferably, after the green body is pressed, the green body is dried for the first time;
and after the protective glaze is applied, secondary drying is needed.
Preferably, the temperature of the first drying is 120-200 ℃, and the time is 15-20 min;
preferably, the temperature of the second drying is 120-200 ℃, and the time is 30-50 min.
Preferably, before the positioning cloth, the method further comprises: and distributing the blank to obtain a bottom blank layer, and distributing the positioning material on the bottom blank layer.
Preferably, the sintering temperature is 1130-1220 ℃, and the time is 45-70 min.
The application also provides a full-body ceramic tile with a spar-like effect, and the full-body ceramic tile is prepared by using the preparation method.
The beneficial effect of this application:
according to the preparation method of the full-body ceramic tile with the spinel-like effect, the spinel-like effect of the transparent material and the characteristic that the blank has small influence on the surface color of the tile blank are utilized, and after the transparent material and the blank are mixed to form the blank, the texture change similar to the spinel-like effect in natural stone can be presented on the surface of the blank. And the base glaze and the cover glaze do not need to be applied to the fired blank, the two materials can be perfectly fused together, the defects of large-area pinholes, bubbles or concave edges, brick blasting and the like on the surface of a product caused by exhaust reaction can not be generated during firing, and the texture effect formed by the protection glaze on the blank body can be directly seen through the brick surface to have the texture and effect similar to that of the crystal stone. Meanwhile, the loss after the blank and the transparent material are sintered are different to a certain extent, the surface of the finally sintered blank can form a certain concave-convex feeling, and the transparent feeling of the crystal-like stone of the transparent material is combined to prepare the whole ceramic tile with the three-dimensional concave-convex feeling and the crystal-like effect.
The whole ceramic tile with the spar-like effect is close to natural stone in texture and visual effect, and is high in surface hardness, and excellent in wear resistance and corrosion resistance.
Drawings
To more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are required to be used in the embodiments will be briefly described below, and it should be understood that the following drawings only illustrate some embodiments of the present invention, and therefore should not be considered as limiting the scope of the present invention.
FIG. 1 is a pictorial representation of a ceramic tile made in accordance with example 1;
FIG. 2 is a pictorial representation of a ceramic tile prepared in accordance with example 2;
FIG. 3 is a pictorial representation of a ceramic tile made in accordance with example 3;
FIG. 4 is a pictorial representation of the ceramic tiles prepared in example 4.
Detailed Description
The terms as used herein:
"prepared from … …" is synonymous with "comprising". The terms "comprises," "comprising," "includes," "including," "has," "having," "contains," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.
The conjunction "consisting of … …" excludes any unspecified elements, steps or components. If used in a claim, the phrase is intended to claim as closed, meaning that it does not contain materials other than those described, except for the conventional impurities associated therewith. When the phrase "consisting of … …" appears in a clause of the subject matter of the claims rather than immediately after the subject matter, it defines only the elements described in the clause; other elements are not excluded from the claims as a whole.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or as a range of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when the range "1 ~ 5" is disclosed, the ranges described should be construed to include the ranges "1 ~ 4", "1 ~ 3", "1 ~ 2 and 4 ~ 5", "1 ~ 3 and 5", and the like. When a range of values is described herein, unless otherwise stated, the range is intended to include the endpoints thereof and all integers and fractions within the range.
In these examples, the parts and percentages are by mass unless otherwise indicated.
"part by mass" means a basic unit of measure indicating a mass ratio of a plurality of components, and 1 part may represent any unit mass, for example, 1g or 2.689 g. If we say that the part by mass of the component A is a part by mass and the part by mass of the component B is B part by mass, the ratio of the part by mass of the component A to the part by mass of the component B is a: b. alternatively, the mass of the A component is aK and the mass of the B component is bK (K is an arbitrary number, and represents a multiple factor). It is unmistakable that, unlike the parts by mass, the sum of the parts by mass of all the components is not limited to 100 parts.
"and/or" is used to indicate that one or both of the illustrated conditions may occur, e.g., a and/or B includes (a and B) and (a or B).
The application provides a preparation method of a full-body ceramic tile with a spinel-like effect, which comprises the following steps: adopting a fixed-point texture material distribution component station mode, forming preset textures on the blank and the transparent material in a preset proportion, and pressing the preset textures into a blank; and (3) spreading protective glaze on the green body, and sintering to obtain the full-body ceramic tile.
Wherein the chemical composition of the blank in the blank body comprises SiO in percentage by mass 2 65-72%, for example 65%, 66%, 67%, 68%, 69%, 70%, 71%, 72% or any value between 65-72%, Al 2 O 3 15-20%, for example 15%, 16%, 17%, 18%, 19%, 20% or any value between 15-20%, CaO0.2-1%, for example 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1% or any value between 0.2-1%, MgO 1-2%, for example 1%, 1.2%, 1.4%, 1.6%, 1.8%, 2% or any value between 1-2%, Na 2 O1-2%, for example, may be 1%, 1.1%, 1.3%, 1.5%, 1.7%, 1.9%, 2%, or any value between 1-2%, K 2 O3-6%, for example, may be 3%, 3.5%, 4%, 4.5%, 5%, 5.5%,6% or any value between 3-6%, loss on ignition 8-10.5%.
The chemical composition of the transparent material in the blank comprises SiO in percentage by mass 2 45-55%, for example 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52%, 53%, 54%, 55% or any value between 45-55%, Al 2 O 3 10-15%, for example 10%, 11%, 12%, 13%, 14%, 15% or any value between 10-15%, CaO 8-12%, for example 8%, 9%, 10%, 11%, 12% or any value between 8-12%, MgO 3-7%, for example 3%, 4%, 5%, 6%, 7% or any value between 3-7%, Na 2 O1-2%, for example, may be 1%, 1.2%, 1.4%, 1.6%, 1.8%, 2%, or any value between 1-2%, K 2 O1-2%, for example, can be 1%, 1.2%, 1.4%, 1.6%, 1.8%, 2%, or any value between 1-2%, BaO 6-10%, for example, can be 6%, 7%, 8%, 9%, 10%, or any value between 6-10%, ZnO 3-5%, for example, can be 3%, 3.5%, 4%, 4.5%, 5%, or any value between 3-5%, loss on ignition 7.5-9.5%.
The blank comprises the following raw material components in parts by weight: 20-25 parts of mud, 15-19 parts of kaolin, 15-20 parts of potassium feldspar, 8-12 parts of albite, 20-25 parts of sand, 3-5 parts of talc and 2-4 parts of recycled brick powder; the transparent material comprises the following raw material components in parts by mass: 15-30 parts of potash feldspar, 5-20 parts of albite, 8-12 parts of kaolin, 6-15 parts of calcined kaolin, 6-10 parts of barium carbonate, 13-18 parts of calcite, 6-10 parts of dolomite, 2-6 parts of calcined talc, 3-5 parts of zinc oxide and 1.5-2.5 parts of alumina.
It should be noted that, the mud in the blank of the present application may be purchased from raw materials having a silica content of 45-65% by mass and an alumina content of 24-30% by mass, and the sand may be purchased from raw materials having a silica content of 64-75% by mass and an alumina content of 18-25% by mass, for example, mud and sand produced in the prefecture of Guangxi rattan, or mud and sand produced in the Jingdezhen of Jiangxi province. The recycled brick powder in the blank is a material obtained by recycling and crushing defective or damaged products produced by the company in the production, sale and other stages.
The main chemical components of the blank and the potassium feldspar in the transparent material comprise: SiO 2 2 60-70％，Al 2 O 3 10-17％，CaO0.2-1％，Na 2 O2-3％，K 2 O10-15%; the albite mainly comprises the following chemical components: SiO 2 2 68-75％，Al 2 O 3 15-20％，CaO0.2-1％，Na 2 O8-11％，K 2 O0-1%; the main chemical components of kaolin comprise: SiO 2 2 53-57％，Al 2 O 3 28-32％，CaO0.1-0.3％，MgO0.1-0.3％，Na 2 O0.2-0.5％，K 2 O2-6％。
The blank and the permeable material of the application have a part of SiO after being fired 2 With Al 2 O 3 The reticular mullite crystal generated by the reaction becomes a powder framework, and the mechanical strength and the chemical stability of the ceramic green brick are improved. Another part of SiO 2 Forming a glassy substance with alkali metal and alkaline earth metal oxides in feldspar and other raw materials, increasing the viscosity of a liquid phase and filling the liquid phase into a blank.
Al 2 O 3 Can improve the firing temperature, whiteness, chemical stability and thermal stability of the green brick, and if the content of the green brick is too low, such as less than 15 percent, the green brick is easy to deform at high temperature.
K 2 O plays a role of fluxing, and has chemical stability, elasticity and thermal stability which are all higher than those of Na 2 O is good, the melting range is wide, and the green brick has certain light transmittance. And Na 2 O, CaO and ZnO also play a role in fluxing, wherein ZnO also has a role in improving color development.
MgO can reduce the sintering temperature and the vitrification temperature of the ceramic body and increase the bending strength and the fracture toughness of the body. BaO is mainly used for extinction.
When preparing a blank, mixing the blank raw materials in parts by mass, mixing with 0.15 part by mass of sodium carboxymethyl cellulose, 0.35 part by mass of sodium tripolyphosphate and 38 parts by mass of water to prepare a glaze slurry, fully grinding, and drying the glaze slurry to prepare the blank. Wherein, the sodium carboxymethyl cellulose can adjust the viscosity of the glaze slip and ensure that the glaze slip is in a stable dispersion state; and the sodium tripolyphosphate can adjust the viscosity of the glaze slip and improve the thixotropy of the glaze slip.
In an alternative embodiment, the blank and the permeable material are prepared separately in different colors and in different forms before the cloth. Wherein the different colors include a body color and at least one of red, blue, brown, yellow, gray, green, cyan, and black; the different forms comprise powder materials with the grain diameter of 100 meshes to 200 meshes and irregular block-shaped granular materials with the grain diameter of 3mm to 30 mm.
When preparing blanks or permeable materials with different colors, the blank materials or permeable materials are mainly regulated and controlled by adding different coloring materials, and the adding proportion of the coloring materials is that 0.01 to 3.5 parts of coloring materials are added in each 100 parts by mass of the blank materials or the permeable materials.
Specifically, iron oxide or cobalt oxide can be added into the blank or the material, and the red effect can be shown after the firing; cobalt oxide is selected and added into the raw materials, and the blue effect can be shown after firing; praseodymium oxide is selected to be added into the raw materials, and a yellow effect can be obtained after the raw materials are fired; cobalt oxide is selected to be added into the raw materials, and a black effect can be obtained after firing.
When preparing blanks with different shapes, the glaze slip forming the blanks can be subjected to powder spraying granulation to prepare powder materials with 100-200 meshes; mixing the powdery materials, pressing, crushing, and selecting block materials with size of 3-30 mm to obtain irregular block granule.
For preparing the transparent materials with different forms, the raw material components of the transparent materials are mixed and then sent into a high-temperature furnace for firing, transparent frits are formed after cooling, and after the transparent frits are crushed, powdery materials and irregular massive granular materials with required sizes are selected.
Before the blank is distributed, the distribution of the blank can be adjusted according to the product requirements, for example, a method for positioning the distribution can be selected, the blank is thoroughly distributed at a fixed position, and then the blank is distributed at other positions; or mixing the penetrating materials and the blanks in different forms to form mixed materials in different proportions, wherein the mixed materials with higher penetrating material proportion are distributed at certain specific positions, and the mixed materials with lower penetrating material proportion are distributed at other positions; or the transparent material and the blank material with different colors can be selected for matching cloth. Generally, when the whole blank is distributed, the mass ratio of the penetrating material is not higher than 60% of the mass of the whole blank.
When the permeable material and the blank are fired together, defects such as exhaust pinholes on the surface of a product caused by exhaust reaction and the like cannot be generated, because the expansion coefficients of the blank and the permeable material are relatively stable and have small difference, the expansion coefficient of a blank layer formed by the blank at 100 ℃ is about 5.61, and the expansion coefficient of the permeable material is 4.86.
In an alternative embodiment, before applying the protective glaze, it is also necessary to provide a decorative layer on the surface of the blank, the decorative layer comprising an ink layer and/or a functional layer.
In a preferred embodiment, the ink layer may be obtained by positioning and spraying ink on the surface of the blank, and the pattern texture formed by the ink layer corresponds to the preset texture of the blank.
It should be noted that the positioning and spray-printing ink is a texture formed by combining a blank in a blank and a permeable positioning cloth, and the position of the ink layer for positioning and spray-printing is designed, so that after the texture formed by the ink layer is combined with the texture of the blank layer, a more vivid texture effect is formed. The thickness of the ink layer of the present application is generally set to 0.05 to 0.1 mm.
The ink layer can be prepared in a digital jet printing mode. To ordinary ink-jet printing, generally all focus on predetermineeing the inkjet printing picture according to the effect picture, the pattern is very rigid, and the ink printing pattern in this application is disassembled according to the effect picture, and the effect is changeable, need not spout the printing whole brick, only need spout the printing partial position can, be closer to the effect of the random texture of stone material more.
In order to diversify the effect of the prepared ceramic tile, besides the common color ink forms textures with different colors, the ink can be used for jet printing by positioning the sinking functional ink, and the ceramic tile with more obvious stereoscopic concave-convex feeling is prepared.
In a preferred embodiment, the functional layer comprises a layer of dry particles or a mica sheet;
the dry particle layer is obtained by positioning, spraying and printing glue on the surface of the blank or the surface of the ink layer and applying dry particles, wherein the dry particles comprise colored dry particles or glittering dry particles. Similarly, the positioning effect of the dry particle layer needs to be designed correspondingly with the texture effect of the blank.
The thickness of the dry particle layer prepared by the method is 1.5-3.0 mm. The arrangement of the dry particle layer can improve the three-dimensional concave-convex feeling of the ceramic tile, and particularly when some flashing or colored dry particles are used, the effect of the dry particles can be utilized to prepare the ceramic tile with the three-dimensional concave-convex feeling and different visual effects.
In addition, in the application, the mica sheets can be directly distributed on the surface of the blank instead of distributing dry particles, or the mica sheets can be distributed on the surface of the ink layer, and different decorative effects can be realized by using the mica sheets. The mica sheet can be distributed in a roller mode or a belt-controlled falling mode.
In an alternative embodiment, after the green body is pressed, the green body is dried for the first time; and after the protective glaze is applied, secondary drying is needed.
Preferably, the first drying is carried out at a temperature of 120 ℃ to 200 ℃, for example, at any value between 120 ℃, 150 ℃, 170 ℃, 200 ℃ or 120 ℃ to 200 ℃; the first drying time is 15min-20min, such as 15min, 18min, 20min or any value between 15-20 min.
Preferably, the temperature of the second drying is 120-200 ℃, for example, it can be any value between 120 ℃, 150 ℃, 170 ℃, 200 ℃ or 120-200 ℃; the time for the second drying is 30min-50min, for example, 30min, 40min, 50min or any value between 30-50 min.
In an optional embodiment, before positioning the cloth, the method further comprises: and distributing the blank to obtain a bottom blank layer, and independently distributing the positioning material on the bottom blank layer. Therefore, the preparation cost of the blank can be greatly reduced, and the texture effect presented on the surface of the blank is not influenced.
When the protective glaze is applied, the protective glaze slurry commonly used in ceramic tiles is selected and sprayed, and the thickness of the formed protective glaze layer is 0.1-0.5 mm. When preparing the protective glaze slip, the raw material components comprise: zinc: 8-12 parts of quartz: 22-28 parts of barium: 12-18 parts of feldspar: 18-26 parts of calcined soil: 10-18 parts of water-washed soil: 6-12 parts of sodium carboxymethyl cellulose: 0.15 part, sodium tripolyphosphate: 0.35 part, water: 38 parts of the raw materials.
In an alternative embodiment, the temperature of the dried ceramic tile is 1130-1220 ℃, for example, 1130 ℃, 1150 ℃, 1170 ℃, 1200 ℃, 1220 ℃ or 1130-1220 ℃, and the firing time is 45-70min, for example, 45min, 50min, 60min, 70min or 45-70 min.
The ceramic tile can be fired and cooled without polishing, and a semi-polishing or full-polishing mode can be selected to obtain a whole ceramic tile product with the spinel-like effect.
According to the method, various ceramic tile products of different types can be prepared by predesigned blank and material distribution effect and decoration of ink, dry particles, mica and the like.
Embodiments of the present invention will be described in detail below with reference to specific examples, but those skilled in the art will appreciate that the following examples are only illustrative of the present invention and should not be construed as limiting the scope of the present invention. The examples, in which specific conditions are not specified, were carried out according to conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
Example 1
The embodiment provides a full-body ceramic tile with a spinel-like effect, and the specific preparation method comprises the following steps:
(1) preparing a blank and a permeable material with various colors respectively, wherein the blank and the permeable material respectively need 100-200 meshes of powder and irregular block-shaped granular materials with the particle sizes of 3mm, 10mm, 20mm and 30 mm.
(2) And respectively loading the transparent materials and the blanks with different colors and different sizes into different hoppers, positioning and distributing the materials by using a distributing machine through preset textures to form the preset textures, then sending the whole blank layer into a press die frame, and stamping to obtain a blank.
(3) And (3) conveying the pressed blank into a drying kiln for drying at the drying temperature of 150 ℃ for 15 min.
(4) And (3) directly carrying out digital spray printing by using color ink to obtain an ink pattern layer without adding a ground coat and a cover coat on the surface of the dried blank.
(5) And after the ink pattern layer is obtained, continuously spraying protective glaze slip, and then sending the protective glaze slip into a drying kiln for drying at the drying temperature of 150 ℃ for 30 min.
(6) And (3) feeding the dried brick body into a firing kiln for firing at 1200 ℃ for 60min, and carrying out polishing treatment after cooling.
The concrete photo of the ceramic tile is shown in figure 1.
Example 2
The specific preparation method of the ceramic tile of the embodiment is the same as that of embodiment 1, except that a dry particle layer is further arranged between steps (4) and (5), specifically: and selecting a preset position on the ink pattern layer, applying glue, and respectively positioning and applying the transparent dry particles and the glitter dry particles at different preset positions.
The concrete photo of the ceramic tile is shown in figure 2. Because the transparent dry particles and the flash dry particles are distributed, the surface of the fired ceramic tile realizes obvious three-dimensional concave-convex effect.
Example 3
The ceramic tile of this example was produced in the same manner as in example 1, except that the ink having a sagging function was used in step (4).
The concrete photo of the ceramic tile is shown in figure 3. By using the sinking ink, the surface of the ceramic tile after firing presents a certain three-dimensional concave-convex texture.
Example 4
The specific preparation method of the ceramic tile of the embodiment is the same as that of embodiment 1, except that a mica sheet is added between steps (4) and (5), specifically: a mica sheet is applied at a predetermined position on the ink pattern layer.
The concrete photo of the ceramic tile is shown in figure 4.
As the blank body of the ceramic tile is added with the transparent material, compared with the common polished tile, the finally prepared product has more transparent feeling and is closer to the stone material than the texture of the polished tile; compared with microlite, the product effect of this application is close to microlite, but controllable variability is more, and the extensibility is more close to the stone material, and the decorative pattern is even like microlite.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and these modifications or substitutions do not depart from the spirit of the corresponding technical solutions of the embodiments of the present invention.
Furthermore, those skilled in the art will appreciate that while some embodiments herein include some features included in other embodiments, rather than other features, combinations of features of different embodiments are meant to be within the scope of the invention and form different embodiments. For example, in the claims above, any of the claimed embodiments may be used in any combination. The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person skilled in the art.
Claims (10)
1. The preparation method of the full-body ceramic tile with the spinel-like effect is characterized by comprising the following steps of:
adopting a fixed-point texture material distribution component station mode, forming preset textures on the blank and the transparent material in a preset proportion through material distribution positioning, and pressing the preset textures into a blank;
spreading protective glaze on the green body, and sintering to obtain the whole ceramic tile;
the chemical composition of the blank comprises SiO in percentage by mass 2 65-72％，Al 2 O 3 15-20％，CaO0.2-1％，MgO1-2％，Na 2 O1-2％，K 2 O3-6%, loss of heat 8-10.5%;
the chemical composition of the permeable material comprises SiO in percentage by mass 2 45-55％，Al 2 O 3 10-15％，CaO8-12％，MgO3-7％，Na 2 O1-2％，K 2 O1-2%, BaO 6-10%, ZnO 3-5%, and loss of ignition 7.5-9.5%.
2. The method for preparing the full-body ceramic tile with the spinel-like effect according to claim 1, wherein the raw material components of the blank comprise, by mass: 20-25 parts of mud, 15-19 parts of kaolin, 15-20 parts of potassium feldspar, 8-12 parts of albite, 20-25 parts of sand, 3-5 parts of talc and 2-4 parts of recycled brick powder;
the permeable material comprises the following raw material components in parts by mass: 15-30 parts of potash feldspar, 5-20 parts of albite, 8-12 parts of kaolin, 6-15 parts of calcined kaolin, 6-10 parts of barium carbonate, 13-18 parts of calcite, 6-10 parts of dolomite, 2-6 parts of calcined talc, 3-5 parts of zinc oxide and 1.5-2.5 parts of alumina.
3. The method for preparing the full-body ceramic tile with the spinel-like effect as claimed in claim 1, wherein, before the positioning and material distribution, the blank and the permeable material with different colors and different forms are respectively prepared;
the different colors include a body color and at least one of red, blue, brown, yellow, gray, green, cyan, and black;
the different forms comprise powder materials with the grain diameter of 100 meshes to 200 meshes and irregular block-shaped granular materials with the grain diameter of 3mm to 30 mm.
4. The method for preparing the full-body ceramic tile with the spinel-like effect as claimed in claim 1, wherein before the protective glaze is applied, a decorative layer is required to be arranged on the surface of the body, and the decorative layer comprises an ink layer and/or a functional layer;
preferably, the ink layer is obtained by positioning and spray-printing ink on the surface of the blank, and the pattern texture formed by the ink layer corresponds to the preset texture of the blank;
preferably, the ink comprises a colored ink or a sinking function ink.
5. The method for preparing a monolithic ceramic tile with a spinel-like effect as claimed in claim 4, wherein said functional layer comprises a layer of dry particles or a layer of mica platelets;
preferably, the dry particle layer is obtained by positioning and spraying glue on the surface of the green body or the surface of the ink layer and applying dry particles, wherein the dry particles comprise colored dry particles or glittering dry particles;
preferably, the mica sheet layer is obtained by coating mica sheets on the surface of the green body or the surface of the ink layer.
6. The method for preparing the full-body ceramic tile with the spinel-like effect according to claim 1, wherein after the ceramic tile is pressed into a green body, the green body is dried for the first time;
and after the protective glaze is applied, secondary drying is needed.
7. The method for preparing the full-body ceramic tile with the spinel-like effect according to claim 6, wherein the temperature for the first drying is 120-200 ℃ and the time is 15-20 min;
preferably, the temperature of the second drying is 120-200 ℃, and the time is 30-50 min.
8. The method for preparing a full-body ceramic tile with a spinel-like effect as claimed in claim 1, wherein before the positioning and distributing, the method further comprises: and distributing the blank to obtain a bottom blank layer, and distributing the positioning material on the bottom blank layer.
9. The method for preparing the full-body ceramic tile with the spinel-like effect according to any one of claims 1 to 8, wherein the firing temperature is 1130 ℃ to 1220 ℃ and the firing time is 45min to 70 min.
10. A full body ceramic tile with a spinel-like effect, prepared by the method of any one of claims 1-9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210665423.XA CN115043649B (en) | 2022-06-13 | 2022-06-13 | Integral ceramic tile with spinel-like effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210665423.XA CN115043649B (en) | 2022-06-13 | 2022-06-13 | Integral ceramic tile with spinel-like effect and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115043649A true CN115043649A (en) | 2022-09-13 |
| CN115043649B CN115043649B (en) | 2023-05-12 |
Family
ID=83162371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210665423.XA Active CN115043649B (en) | 2022-06-13 | 2022-06-13 | Integral ceramic tile with spinel-like effect and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115043649B (en) |
Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174608B1 (en) * | 1997-11-27 | 2001-01-16 | Ferro (Italia) Srl | Ceramic tile and glaze for use thereon |
| CN1358683A (en) * | 2002-01-10 | 2002-07-17 | 梁自好 | Method for producing large size composite jade crystal stone by roll channel kiln |
| US20070275168A1 (en) * | 2003-03-13 | 2007-11-29 | Jan Prochazka | Manufacturing of Photocatalytic, Antibacterial, Selfcleaning and Optically Non-Interfering Sufaces on Tiles and Glazed Ceramic Products |
| CN103922712A (en) * | 2014-04-04 | 2014-07-16 | 佛山市三水宏源陶瓷企业有限公司 | Once-firing process of microcrystalline jade ceramic tile |
| CN106365612A (en) * | 2016-08-30 | 2017-02-01 | 淄博狮王陶瓷有限公司 | Natural stone imitated ceramic tile with clear color, luster and boundary and manufacturing method of natural stone imitated ceramic tile |
| CN106431502A (en) * | 2016-09-03 | 2017-02-22 | 佛山市高明贝斯特陶瓷有限公司 | Production process of tile with natural jade texture |
| CN107915479A (en) * | 2017-11-06 | 2018-04-17 | 蒙娜丽莎集团股份有限公司 | A kind of ceramic surface archaizing brick and preparation method thereof |
| US20190322591A1 (en) * | 2016-12-14 | 2019-10-24 | Ceramtec-Etec Gmbh | Transparent Composite Material |
| CN110498675A (en) * | 2019-09-12 | 2019-11-26 | 清远市简一陶瓷有限公司 | A kind of high white light transmission Dali stone ceramic tile blank and preparation method thereof |
| CN112225451A (en) * | 2020-10-27 | 2021-01-15 | 佛山欧神诺陶瓷有限公司 | Polished porcelain tile and preparation method thereof |
| CN112456802A (en) * | 2021-01-27 | 2021-03-09 | 佛山市道氏科技有限公司 | Giant crystal particles capable of forming crystal flowers, dry particle combination, particles for ceramics, ceramics and preparation method of ceramics |
| CN113248285A (en) * | 2021-06-28 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Dry particle decorative ceramic tile and preparation method thereof |
| WO2021189822A1 (en) * | 2020-03-23 | 2021-09-30 | 广东欧文莱陶瓷有限公司 | Fine carving ceramic tile and production process thereof |
| US20210340071A1 (en) * | 2019-03-01 | 2021-11-04 | Dongguan City Wonderful Ceramics Industrial Park Co., Ltd. | Method for manufacturing ceramic tiles decorated with dry particle inks |
| WO2021218132A1 (en) * | 2020-04-30 | 2021-11-04 | 佛山市陶莹新型材料有限公司 | 3d dazzling ceramic tile and preparation method therefor |
| CN113999054A (en) * | 2021-10-12 | 2022-02-01 | 广东清远蒙娜丽莎建陶有限公司 | Crystal-drilled marble porcelain tile and preparation method thereof |
| CN114507013A (en) * | 2022-04-18 | 2022-05-17 | 佛山市东鹏陶瓷发展有限公司 | Transparent wear-resistant frit and preparation method thereof, and glazed brick and preparation method thereof |
-
2022
- 2022-06-13 CN CN202210665423.XA patent/CN115043649B/en active Active
Patent Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174608B1 (en) * | 1997-11-27 | 2001-01-16 | Ferro (Italia) Srl | Ceramic tile and glaze for use thereon |
| CN1358683A (en) * | 2002-01-10 | 2002-07-17 | 梁自好 | Method for producing large size composite jade crystal stone by roll channel kiln |
| US20070275168A1 (en) * | 2003-03-13 | 2007-11-29 | Jan Prochazka | Manufacturing of Photocatalytic, Antibacterial, Selfcleaning and Optically Non-Interfering Sufaces on Tiles and Glazed Ceramic Products |
| CN103922712A (en) * | 2014-04-04 | 2014-07-16 | 佛山市三水宏源陶瓷企业有限公司 | Once-firing process of microcrystalline jade ceramic tile |
| CN106365612A (en) * | 2016-08-30 | 2017-02-01 | 淄博狮王陶瓷有限公司 | Natural stone imitated ceramic tile with clear color, luster and boundary and manufacturing method of natural stone imitated ceramic tile |
| CN106431502A (en) * | 2016-09-03 | 2017-02-22 | 佛山市高明贝斯特陶瓷有限公司 | Production process of tile with natural jade texture |
| US20190322591A1 (en) * | 2016-12-14 | 2019-10-24 | Ceramtec-Etec Gmbh | Transparent Composite Material |
| CN107915479A (en) * | 2017-11-06 | 2018-04-17 | 蒙娜丽莎集团股份有限公司 | A kind of ceramic surface archaizing brick and preparation method thereof |
| US20210340071A1 (en) * | 2019-03-01 | 2021-11-04 | Dongguan City Wonderful Ceramics Industrial Park Co., Ltd. | Method for manufacturing ceramic tiles decorated with dry particle inks |
| CN110498675A (en) * | 2019-09-12 | 2019-11-26 | 清远市简一陶瓷有限公司 | A kind of high white light transmission Dali stone ceramic tile blank and preparation method thereof |
| WO2021189822A1 (en) * | 2020-03-23 | 2021-09-30 | 广东欧文莱陶瓷有限公司 | Fine carving ceramic tile and production process thereof |
| WO2021218132A1 (en) * | 2020-04-30 | 2021-11-04 | 佛山市陶莹新型材料有限公司 | 3d dazzling ceramic tile and preparation method therefor |
| CN112225451A (en) * | 2020-10-27 | 2021-01-15 | 佛山欧神诺陶瓷有限公司 | Polished porcelain tile and preparation method thereof |
| CN112456802A (en) * | 2021-01-27 | 2021-03-09 | 佛山市道氏科技有限公司 | Giant crystal particles capable of forming crystal flowers, dry particle combination, particles for ceramics, ceramics and preparation method of ceramics |
| CN113248285A (en) * | 2021-06-28 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Dry particle decorative ceramic tile and preparation method thereof |
| CN113999054A (en) * | 2021-10-12 | 2022-02-01 | 广东清远蒙娜丽莎建陶有限公司 | Crystal-drilled marble porcelain tile and preparation method thereof |
| CN114507013A (en) * | 2022-04-18 | 2022-05-17 | 佛山市东鹏陶瓷发展有限公司 | Transparent wear-resistant frit and preparation method thereof, and glazed brick and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115043649B (en) | 2023-05-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106277793B (en) | A kind of glaze of high temperature gold colored glaze face brick, brick and preparation method thereof | |
| CN110746117B (en) | Colored seeding glaze and positioning crystal ceramic tile prepared by using colored seeding glaze | |
| CN112499971B (en) | Crystal flash dry particle, crystal flash ceramic tile and preparation method thereof | |
| CN110759641B (en) | Crystal flower dry grain glaze and positioning crystal flower ceramic tile prepared from crystal flower dry grain glaze | |
| CN106518029B (en) | A kind of marble Ceramic Tiles preparation method with metallic luster recess texture | |
| CN106986540B (en) | Formula for making sunken and peeled marble glaze | |
| CN110790506A (en) | Granular double-layer reaction glaze and preparation method thereof | |
| CN111253072A (en) | Ceramic glaze with good wear resistance and high hardness and preparation method thereof | |
| CN112723870B (en) | Ceramic rock plate with color jade effect and preparation method thereof | |
| CN111943724A (en) | Method for manufacturing matt transparent glazed ceramic chip | |
| CN110845227A (en) | Positioning crystal-patterned light-transmitting ceramic tile and preparation method thereof | |
| CN110776256A (en) | White radial crystal flower dry grain glaze, light-transmitting ceramic tile and preparation method thereof | |
| CN110835234B (en) | Colored chrysanthemum-shaped crystal flower glaze, chrysanthemum-shaped crystal flower light-transmitting ceramic tile and preparation method thereof | |
| CN105924229A (en) | Glaze for thousand-bead multi-color glazed tile and thousand-bead multi-color glazed tile, and preparation methods thereof | |
| CN100360462C (en) | Glaze coloured decoration daily use poocelain and its production method | |
| CN109279919A (en) | A kind of water mill essence stone brick and preparation method thereof | |
| CN110903033B (en) | Crystal nucleating agent and positioning crystal pattern ceramic tile prepared by using same | |
| CN105776861A (en) | Bright red nanometer glaze slip for ceramic sanitary wares as well as preparation method and application of bright red nanometer glaze slip | |
| CN105218170B (en) | A kind of high-hardness, wearable exempts to polish iron microcrystalline glass in series ceramic clad plate and preparation method thereof | |
| CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
| CN107417102A (en) | Low temperature transmutation plum blossom glaze porcelain and its preparation technology | |
| CN108484123A (en) | A kind of Ceramic Tiles and preparation method thereof of high additive metallurgical steel slag waste material | |
| CN113305994B (en) | Method for micro-carving artistic picture on surface of ceramic product | |
| CN110862230B (en) | Dry ice crack nucleating agent particles, ice crack crystal flower light-transmitting ceramic tile and preparation method thereof | |
| CN103497006B (en) | A kind of Polished crystal tile with ice crack shape and manufacture method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |