CN108117413A - The manufacturing method of Ceramic Tiles and a kind of Ceramic Tiles - Google Patents
The manufacturing method of Ceramic Tiles and a kind of Ceramic Tiles Download PDFInfo
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- CN108117413A CN108117413A CN201711455510.8A CN201711455510A CN108117413A CN 108117413 A CN108117413 A CN 108117413A CN 201711455510 A CN201711455510 A CN 201711455510A CN 108117413 A CN108117413 A CN 108117413A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 239000011449 brick Substances 0.000 claims abstract description 12
- 238000007493 shaping process Methods 0.000 claims abstract description 7
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 4
- 238000010304 firing Methods 0.000 claims abstract description 4
- 239000007921 spray Substances 0.000 claims abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 4
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 3
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 238000007641 inkjet printing Methods 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 3
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 10
- 239000011435 rock Substances 0.000 description 11
- 230000000007 visual effect Effects 0.000 description 4
- 239000003973 paint Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000002969 artificial stone Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
Abstract
The present invention puies forward a kind of manufacturing method of Ceramic Tiles, including：One layer of ground glaze layer is applied on adobe surface after shaping；Ceramic ink is printed upon on the ground glaze layer by the pre-designed colour image of computer, is formed decorative pattern by ink-jet printer；It sprays layer of transparent protection glaze again on decorative pattern surface, forms pattern decorative layer；Apply transparent dry granular on brick face with dry granular machine, then apply a second part black dry granular on dry granular, form printed decor；A kind of ceramic tile that high-temperature firing and this method directly obtain, glaze layer are divided into ground glaze layer, pattern decorative layer and printed decor from bottom to up.The pattern decorative layer is divided into the transparency protected glaze being directly sprayed in the pattern layer and pattern layer on ground-coat enamel surface；The printed decor be by transparent dry granular and and the mixing of black dry granular arrange, the present invention improves dry granular application method, and sandstone stain dry granular makes its overall effect more naturally, feel is true.
Description
Technical field
The present invention relates to ceramic fabrication technique field more particularly to a kind of ceramic brick product and its manufacturing methods.
Background technology
Ceramic brick product is mainly used for interior/exterior decoration, but for the common porcelain polished bricks of society too light, too sliding, easy soil pick-up
The defects of, the dry granular glaze developed earliest by Japanese NIC Nikkens Co., Ltd. just solves the problems, such as this well.
China's patent of invention 201610899076.1, describes a kind of artificial stone sandstone at date of publication on March 8th, 2017
Ceramic Tiles, which includes the glaze layer on ceramic tile blank and the ceramic tile blank surface, it is characterized in that：The glaze layer surface print
There are stone shape striped and ink-jet gritstone figure, which includes ground glaze layer, for the first time cover coat, point glaze layer, second glaze successively
Layer, protection glaze layer and dry granular glaze layer.Technical solution disclosed in the invention is only to carrying out the thick of imitative rock texture on ceramic tile surface
Rough processing.
The problem of scheme recorded in above-mentioned patent application effectively avoids porcelain surface too light, and user easily slips.It must
The harsh feeling of imitative rock is arrived, but this scheme largely uses sandstone, the ceramic tile surface of gained or color list on adobe surface
One or colour mixture it is uniform, surface can not form natural rock texture or pattern, decorative poor.
The content of the invention
It is an object of the invention to propose a kind of manufacturing method of Ceramic Tiles, technological process controllability is high, produces
Product Visual effect is naturally true to nature, and feel is coarse true.
The technical solution adopted by the present invention is in order to achieve the above objectives：
A kind of manufacturing method of Ceramic Tiles, step include successively：
A：By ceramic brick powder lot cloth in common plane mold, shaping forms adobe, on adobe surface after shaping
Apply one layer of ground glaze layer；
B：Ceramic ink is printed upon by the ground glaze layer by the pre-designed colour image of computer by ink-jet printer
On, form decorative pattern；
C：It sprays layer of transparent protection glaze again on decorative pattern surface, forms pattern decorative layer；
D：Apply transparent dry granular on brick face with dry granular machine, then apply a second part black dry granular on dry granular, formed
Printed decor；
E：High-temperature firing.
This method forms rock patterns with printing ink, and pattern is various to be limited from material, then is covered and obtained with dry granular
Harsh hand, black sandstone can strengthen simulated effect.
Using zirconium base opaque glaze, ingredient is ground glaze layer in step A：Into powdered frit 80-88%, zirconium silicate 7-12%,
Kaolin 3-8%.Wherein it is into the chemical composition composition of powdered frit：Silica 40-52%, aluminium oxide 15-25%, three oxygen
Change two iron 0.1-0.2%, titanium dioxide 0.1-0.5%, calcium oxide 7-15%, magnesia 2-8%, potassium oxide 0.5-
5%, sodium oxide molybdena 0.5-8%, barium monoxide 0.5-6%, zinc oxide 0.5-5%, zirconium oxide 1-8%, loss on ignition 5-8%.
The preferred component of zirconium base opaque glaze is：Into powdered frit 85%, zirconium silicate 10%, kaolin 5%.
Inkjet printing pixel in the step B is set greater than or equal to 360DPI.
In step C, the transparency protected glaze thickness is 0.01-0.05mm.
The transparent dry granular is in zonal distribution, and black dry granular is distributed in Banded, and transparent dry granular interlocks with black dry granular
Mixing imposes on ceramic tile surface.
The transparent dry granular can impose on ceramic tile entirety upper surface, and the black dry granular disperses, fragmentary imposes on transparent dry
The whole upper surfaces of grain；It can also be in banding scatterplot formal distribution in dry granular upper surface.Gained ceramic tile patterns are various, and visual effect is certainly
It is so true to nature.
The manufacturing method of the present invention improves dry granular application method, increases sandstone stain dry granular, makes its overall effect more certainly
So, there is the raising of bigger in wearability and case hardness and antifouling property.
A kind of Ceramic Tiles obtained by above-mentioned manufacturing method, the glaze layer including ceramic tile blank and billet surface are special
Sign is：The glaze layer is divided into ground glaze layer, pattern decorative layer and printed decor from bottom to up.The pattern decorative layer is divided into directly
The transparency protected glaze being sprayed in the pattern layer and pattern layer on ground-coat enamel surface；The printed decor be by transparent dry granular and and it is black
The mixing of color dry granular arranges.
This ceramic tile imitates nature reason stone texture, and surface is coarse particles, and feel is true, and the addition of black dry granular imitates vision
Fruit is naturally true to nature.
Specific embodiment
With reference to specific embodiment to the detailed description of the invention：
The method of present invention manufacture Ceramic Tiles, which focuses on how to obtain, possesses natural marble decorative pattern, and visual effect is more forced
Genuine tile product, the product copy pattern, the texture of a variety of natural rocks, and can possess the coarse hand of similar natural rock
Sense.
The decorative effect of the present invention is carried out on ceramic tile base surface, and in the glazing of adobe surface, which includes directly applying
In adobe surface ground glaze layer；Texture, the pattern of imitative natural rock are made on ground glaze layer, then can add transparent guarantor on this pattern
Protect glaze.Sandstone is the common used material for making imitative Stone-ceramic brick, and it is previously obtained using transparent sandstone to impose on pattern layer in the present invention
Harsh feeling, while add some fragmentary black sands and strengthen simulated effect.
Specifically manufacturing method is：
A：By ceramic brick powder lot cloth in common plane mold, shaping forms adobe, on adobe surface after shaping
Apply one layer of ground glaze layer.
B：Ceramic ink is printed upon by the ground glaze layer by the pre-designed colour image of computer by ink-jet printer
On, form decorative pattern.
C：It sprays layer of transparent protection glaze again on decorative pattern surface, forms pattern decorative layer.
D：Apply transparent dry granular on brick face with dry granular machine, then apply a second part black dry granular on dry granular, formed
Printed decor.
E：High-temperature firing.
Using zirconium base opaque glaze, the specific formula of the glaze is ground glaze layer in step A：Into powdered frit 80-88%, silicon
Sour zirconium 7-12%, kaolin 3-8%.
Wherein it is into the chemical composition composition of powdered frit：Silica 40-52%, aluminium oxide 15-25%, di-iron trioxide
0.1-0.2%, titanium dioxide 0.1-0.5%, calcium oxide 7-15%, magnesia 2-8%, potassium oxide 0.5-5%, oxidation
Sodium 0.5-8%, barium monoxide 0.5-6%, zinc oxide 0.5-5%, zirconium oxide 1-8%, loss on ignition 5-8%.
Embodiment one
The zirconium base opaque glaze of preparation：Into powdered frit 85%, zirconium silicate 10%, kaolin 5%.
Wherein it is into powdered frit list of ingredients：
The Ceramic Tiles produced using the method for the invention, are had the following advantages：
Wear-resisting property is strong, case hardness is high, non-skid property is good, ceramic tile overall effect natural reality, and level is vertical with protrusion
Body-sensing is strong.It changes the energy consumption of polished bricks excessive feed consumption and the shortcomings of production environment easily causes pollution, international market new one will be become
For product salable
Preferably, the inkjet printing pixel in step B is set greater than or equal to 360DPI.
It preferentially selects, in step C, transparency protected glaze thickness is 0.01-0.05mm.
The printed decor of the present invention provides the surface of coarse sense of touch for ceramic tile, and transparent dry granular part can display pattern decoration
The grain pattern of display, but the color of general rock surface can't substantially uniformity, the rock surface through really polishing can show as
Different stains or other color spots are poured deeply, black dry granular is added in this manufacturing method, makes ceramic tile surface more like real rock.
How black dry granular is distributed on ceramic tile cuts much ice to the decorative effect of ceramic tile, and three kinds of present invention offer is transparent
The method of administration of dry granular and black dry granular generates the glaze paint of three kinds of different decorative effects therefrom.
(1) in step D the transparent dry granular be in zonal distribution, black dry granular in Banded be distributed, transparent dry granular and
What black dry granular staggeredly mixed imposes on ceramic tile surface.
(2) the transparent dry granular covering ceramic tile entirety upper surface in step D, black dry granular disperses, fragmentary is distributed in
Transparent dry granular surface on the whole.
(3) the transparent dry granular covering ceramic tile entirety upper surface, black dry granular are in banding scatterplot form point in step D
Cloth is on transparent dry granular.
Dry granular glaze belongs to mat glaze series, in the prior art, is chiefly used in making the ceramic tile glaze of surface irregularity, main mesh
Be that ceramic tile is made to have unglazed, anti-skidding using effect.The mentality of designing direction setting of the present invention makes the picture on surface of ceramic tile more
Various, visual effect is naturally true to nature, creates the ceramic tile of imitative variety classes nature stone face texture.It further developed dry granular use
New approaches.
The transparent dry grain-by-grain seed selection that the present invention uses is 0.1-1mm with grain size；It is 0.05-0.3mm's that black dry granular, which selects grain size,
Dry granular.
Through experiment, transparent dry grain-by-grain seed selection 0.6-1mm, black dry granular selects 0.08-0.18mm, and obtained ceramic tile surface is recessed
Convex apparent, the figure peace three-dimensional sense of glaze paint performance is strong.Transparent dry grain-by-grain seed selection 0.1-0.5mm, black dry granular select 0.08-0.1mm, institute
Ceramic tile surface obtained is concave-convex apparent, and glaze paint shows as the low reflective sense of low light transmission, close to rock texture.
Using during dry granular can on a small quantity, multiple applications, constantly adjust the use of local transparent dry granular, black dry granular in application
Amount ensures that ceramic tile surface is smooth.
A kind of Ceramic Tiles are obtained by above-mentioned manufacturing method, the glaze layer including ceramic tile blank and billet surface is described
Glaze layer is divided into ground glaze layer, pattern decorative layer and printed decor from bottom to up, wherein, the pattern decorative layer, which is divided into, directly to be sprayed
In the transparency protected glaze in the pattern layer and pattern layer on ground-coat enamel surface；The printed decor be by transparent dry granular and and black do
Grain mixing arranges.
The pattern image vegetarian refreshments of the ceramic tile is 360DPI；The ceramic tile ground glaze layer uses zirconium base opaque glaze；Glaze Composition is preferably：
Into powdered frit 85%, zirconium silicate 10%, kaolin 5%.
The present invention is distilled on the basis of dry granular glazed tile, improves dry granular application method, increases sandstone stain dry granular,
Make its overall effect more naturally, having rapid progress in wear-resisting ceramic tile performance and ceramic tile general levels effect.
Claims (9)
1. a kind of manufacturing method of Ceramic Tiles, step include successively：
A：By ceramic brick powder lot cloth in common plane mold, shaping forms adobe, and one is applied on adobe surface after shaping
Layer ground glaze layer；
B：Ceramic ink is pressed by the pre-designed colour image of computer by ink-jet printer, is printed upon on the ground glaze layer,
Form decorative pattern；
C：It sprays layer of transparent protection glaze again on decorative pattern surface, forms pattern decorative layer；
D：Apply transparent dry granular on brick face with dry granular machine, then apply a second part black dry granular on dry granular, form stamp
Decorative layer；
E：High-temperature firing.
2. the manufacturing method of Ceramic Tiles as described in claim 1, it is characterized in that：Ground glaze layer in step A uses zirconium base opaque glaze,
Its ingredient is：Into powdered frit 80-88%, zirconium silicate 7-12%, kaolin 3-8%, wherein the chemical composition into powdered frit forms
For：Silica 40-52%, aluminium oxide 15-25%, di-iron trioxide 0.1-0.2%, titanium dioxide 0.1-0.5%, oxygen
Change calcium 7-15%, magnesia 2-8%, potassium oxide 0.5-5%, sodium oxide molybdena 0.5-8%, barium monoxide 0.5-6%, zinc oxide
0.5-5%, zirconium oxide 1-8%, loss on ignition 5-8%.
3. the manufacturing method of Ceramic Tiles as claimed in claim 2, it is characterized in that：The preferred component of zirconium base opaque glaze is：Into powdered frit
85%, zirconium silicate 10%, kaolin 5%.
4. the manufacturing method of Ceramic Tiles as described in claim 1, it is characterized in that：Inkjet printing pixel in the step B is set
To be greater than or equal to 360DPI.
5. the manufacturing method of Ceramic Tiles as described in claim 1, it is characterized in that：In step C, the transparency protected glaze thickness is
0.01-0.05mm。
6. the manufacturing method of Ceramic Tiles as described in claim 1, it is characterized in that：The transparent dry granular is in banding point in step D
Cloth, black dry granular are distributed in Banded, and transparent dry granular imposes on ceramic tile surface with what black dry granular staggeredly mixed.
7. the manufacturing method of Ceramic Tiles as described in claim 1, it is characterized in that：The transparent dry granular covering ceramic tile in step D
Whole upper surface, black dry granular disperses, fragmentary is distributed in transparent dry granular surface on the whole.
8. the manufacturing method of Ceramic Tiles as described in claim 1, it is characterized in that：The transparent dry granular covering ceramic tile in step D
Whole upper surface, black dry granular are to be in banding scatterplot formal distribution on transparent dry granular.
9. the manufacturing method as described in any of the above-described claim, a kind of Ceramic Tiles obtained, including ceramic tile blank and base
The glaze layer in body surface face, it is characterized in that：The glaze layer is divided into ground glaze layer, pattern decorative layer and printed decor from bottom to up, described
Pattern decorative layer is divided into the transparency protected glaze being directly sprayed in the pattern layer and pattern layer on ground-coat enamel surface；The printed decor
For by transparent dry granular and and black dry granular mixing arrange.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711455510.8A CN108117413A (en) | 2017-12-28 | 2017-12-28 | The manufacturing method of Ceramic Tiles and a kind of Ceramic Tiles |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711455510.8A CN108117413A (en) | 2017-12-28 | 2017-12-28 | The manufacturing method of Ceramic Tiles and a kind of Ceramic Tiles |
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| CN108117413A true CN108117413A (en) | 2018-06-05 |
Family
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| CN201711455510.8A Pending CN108117413A (en) | 2017-12-28 | 2017-12-28 | The manufacturing method of Ceramic Tiles and a kind of Ceramic Tiles |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109574632A (en) * | 2019-01-23 | 2019-04-05 | 信益陶瓷(中国)有限公司 | A kind of the polychrome Imitation Rock Porcelain Tiles and manufacturing method of substitution mould flower production concave-convex surface effect |
| CN109795017A (en) * | 2019-03-29 | 2019-05-24 | 东莞市唯美陶瓷工业园有限公司 | Stablize the preparation method of brindled brick |
| CN111516131A (en) * | 2020-07-06 | 2020-08-11 | 广东博德精工建材有限公司 | Preparation method of porcelain archaized brick |
| CN111875414A (en) * | 2020-06-30 | 2020-11-03 | 蒙娜丽莎集团股份有限公司 | High solar light reflectivity ceramic plate and preparation method thereof |
| CN113698190A (en) * | 2021-03-16 | 2021-11-26 | 亚细亚建筑材料股份有限公司 | Preparation process of dry-grain half-polished brick |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111875414A (en) * | 2020-06-30 | 2020-11-03 | 蒙娜丽莎集团股份有限公司 | High solar light reflectivity ceramic plate and preparation method thereof |
| CN111516131A (en) * | 2020-07-06 | 2020-08-11 | 广东博德精工建材有限公司 | Preparation method of porcelain archaized brick |
| CN113698190A (en) * | 2021-03-16 | 2021-11-26 | 亚细亚建筑材料股份有限公司 | Preparation process of dry-grain half-polished brick |
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Application publication date: 20180605 |