CN116354697A - High-hardness wear-resistant ceramic tile and preparation method thereof - Google Patents
High-hardness wear-resistant ceramic tile and preparation method thereof Download PDFInfo
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- CN116354697A CN116354697A CN202310360318.XA CN202310360318A CN116354697A CN 116354697 A CN116354697 A CN 116354697A CN 202310360318 A CN202310360318 A CN 202310360318A CN 116354697 A CN116354697 A CN 116354697A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title abstract description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 74
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 66
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 41
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 41
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000011787 zinc oxide Substances 0.000 claims abstract description 37
- 239000002994 raw material Substances 0.000 claims abstract description 32
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 29
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 29
- 239000006004 Quartz sand Substances 0.000 claims abstract description 25
- 239000010459 dolomite Substances 0.000 claims abstract description 21
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims abstract description 14
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910033181 TiB2 Inorganic materials 0.000 claims abstract description 13
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010434 nepheline Substances 0.000 claims abstract description 13
- 229910052664 nepheline Inorganic materials 0.000 claims abstract description 13
- 238000005498 polishing Methods 0.000 claims abstract description 13
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 238000007639 printing Methods 0.000 claims abstract description 9
- 235000019983 sodium metaphosphate Nutrition 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 44
- 238000002156 mixing Methods 0.000 claims description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
- 239000010456 wollastonite Substances 0.000 claims description 20
- 229910052882 wollastonite Inorganic materials 0.000 claims description 20
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 20
- 229910001570 bauxite Inorganic materials 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 16
- 238000000227 grinding Methods 0.000 claims description 16
- 239000010453 quartz Substances 0.000 claims description 16
- 229910021532 Calcite Inorganic materials 0.000 claims description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 12
- 239000001506 calcium phosphate Substances 0.000 claims description 12
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 12
- 235000011010 calcium phosphates Nutrition 0.000 claims description 12
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052637 diopside Inorganic materials 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 229910052744 lithium Inorganic materials 0.000 claims description 12
- 229910052573 porcelain Inorganic materials 0.000 claims description 12
- 239000004576 sand Substances 0.000 claims description 12
- 239000004575 stone Substances 0.000 claims description 12
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 12
- 229910052845 zircon Inorganic materials 0.000 claims description 12
- 235000019738 Limestone Nutrition 0.000 claims description 8
- 229910052878 cordierite Inorganic materials 0.000 claims description 8
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000006028 limestone Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 229920000609 methyl cellulose Polymers 0.000 claims description 8
- 239000001923 methylcellulose Substances 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000000454 talc Substances 0.000 claims description 8
- 235000012222 talc Nutrition 0.000 claims description 8
- 229910052623 talc Inorganic materials 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 210000001161 mammalian embryo Anatomy 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 2
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/16—Lean materials, e.g. grog, quartz
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention relates to a high-hardness wear-resistant ceramic tile and a preparation method thereof, belonging to the technical field of ceramic tile manufacturing and processing, and comprising a green body layer, a surface glaze layer, a transparent glaze layer and a high-hardness wear-resistant glaze polishing layer: the high-hardness wear-resistant glaze polishing layer comprises wear-resistant glaze particles, a dispersing agent, water, printing paste and sodium metaphosphate; the wear-resistant glaze particles consist of the following raw materials: potassium feldspar, kaolin, nepheline, dolomite, calcined alumina, quartz sand, talcum powder, magnesium borate whisker, diatomite, titanium diboride, barium carbonate, magnesium oxide and zinc oxide. The invention provides a high-hardness wear-resistant ceramic tile and a preparation method thereof, which greatly improve the hardness and wear resistance of the glazed surface of the ceramic tile, and have the advantages of simplicity, easiness in implementation, wide sources of raw materials, simple preparation process, long service life and wide market prospect.
Description
Technical Field
The invention relates to a high-hardness wear-resistant ceramic tile and a preparation method thereof, belonging to the technical field of ceramic tile manufacturing and processing.
Background
The ceramic tile is a platy or blocky ceramic product which is prepared by mixing clay and other inorganic nonmetallic raw materials according to a certain proportion, extruding and forming the raw materials, and firing the raw materials, and is used for decorating and protecting the wall surfaces and the ground surfaces of buildings and structures; the ceramic tile is divided into extrusion molding ceramic tile and dry pressing molding ceramic tile according to the molding method, wherein the extrusion molding ceramic tile adopts an extrusion process in the production process, the proportioned raw materials are made into wet mud balls, the wet mud balls are correspondingly extruded according to the processing requirements, and then the wet mud balls are fired, so that the ceramic tile used in daily life is obtained.
At present, the ceramic tile on the market is generally insufficient in surface wear resistance, is easy to scratch and abrade, thereby influencing the beauty and grade of the product and further influencing the use effect.
Disclosure of Invention
In view of the above, the invention provides a high-hardness wear-resistant ceramic tile and a preparation method thereof, which greatly improve the hardness and wear resistance of the glazed surface of the ceramic tile, and have the advantages of simplicity, easiness in implementation, wide sources of raw materials, simple preparation process, long service life and wide market prospect.
The invention provides a high-hardness wear-resistant ceramic tile and a preparation method thereof, wherein the high-hardness wear-resistant ceramic tile comprises a green body layer, a surface glaze layer, a transparent glaze layer and a high-hardness wear-resistant glaze polishing layer:
the high-hardness wear-resistant glaze polishing layer comprises wear-resistant glaze particles, a dispersing agent, water, printing paste and sodium metaphosphate;
the wear-resistant glaze particles consist of the following raw materials:
15-30 parts of potassium feldspar, 20-35 parts of kaolin, 12-25 parts of nepheline, 5-15 parts of dolomite, 10-28 parts of calcined alumina, 15-35 parts of quartz sand, 8-12 parts of talcum powder, 5-12 parts of magnesium borate whisker, 15-25 parts of diatomite, 5-12 parts of titanium diboride, 8-15 parts of barium carbonate, 5-10 parts of magnesium oxide and 7-15 parts of zinc oxide;
the blank layer is composed of the following raw materials: 20-35 parts of kaolin, 10-25 parts of wollastonite, 15-25 parts of calcite, 8-20 parts of lithium porcelain stone, 10-18 parts of diopside, 12-25 parts of zircon sand, 5-10 parts of iron ore, 10-28 parts of bauxite, 12-20 parts of quartz sand and 5-12 parts of calcium phosphate.
Preferably, the wear-resistant glaze particles consist of the following raw materials:
15 parts of potassium feldspar, 20 parts of kaolin, 12 parts of nepheline, 5 parts of dolomite, 10 parts of calcined alumina, 15 parts of quartz sand, 8 parts of talcum powder, 5 parts of magnesium borate whisker, 15 parts of diatomite, 5 parts of titanium diboride, 8 parts of barium carbonate, 5 parts of magnesium oxide and 7 parts of zinc oxide;
preferably, the blank layer is composed of the following raw materials: 20 parts of kaolin, 10 parts of wollastonite, 15 parts of calcite, 8 parts of lithium porcelain stone, 10 parts of diopside, 12 parts of zircon sand, 5 parts of iron ore, 10 parts of bauxite, 12 parts of quartz sand and 5 parts of calcium phosphate.
Preferably, the wear-resistant glaze particles consist of the following raw materials: 30 parts of potassium feldspar, 35 parts of kaolin, 25 parts of nepheline, 15 parts of dolomite, 28 parts of calcined alumina, 35 parts of quartz sand, 12 parts of talcum powder, 12 parts of magnesium borate whisker, 25 parts of diatomite, 12 parts of titanium diboride, 15 parts of barium carbonate, 10 parts of magnesium oxide and 15 parts of zinc oxide;
preferably, the blank layer is composed of the following raw materials: 35 parts of kaolin, 25 parts of wollastonite, 25 parts of calcite, 20 parts of lithium porcelain stone, 18 parts of diopside, 25 parts of zircon sand, 10 parts of iron ore, 28 parts of bauxite, 20 parts of quartz sand and 12 parts of calcium phosphate.
Preferably, the overglaze layer is composed of the following raw materials: 15-20 parts of potassium feldspar, 8-15 parts of cordierite, 15-25 parts of high bauxite, 8-20 parts of kaolin, 10-15 parts of quartz, 5-12 parts of wollastonite, 3-8 parts of zinc oxide, 12-25 parts of zirconium silicate, 2-5 parts of methylcellulose, 8-12 parts of calcined talcum and 3-8 parts of titanium dioxide.
Preferably, the transparent glaze layer is composed of the following raw materials: 12-25 parts of potassium feldspar, 8-15 parts of limestone, 10-18 parts of barium carbonate, 3-8 parts of zinc oxide, 12-20 parts of kaolin, 5-12 parts of zinc oxide, 7-15 parts of barium carbonate, 10-15 parts of quartz, 3-10 parts of dolomite and 5-8 parts of barium sulfate.
Preferably, the method specifically comprises the following steps:
1) Ball milling and mixing kaolin, wollastonite, calcite, lithium porcelain stone, diopside, zircon sand, iron ore, bauxite, quartz sand and calcium phosphate uniformly to obtain a first mixture;
2) Continuously stirring the first mixture for 45-60min under the irradiation power of 30-45kw and the rotation speed of 450-600r/min, stamping, forming and drying to obtain a blank;
3) Fully mixing and grinding potassium feldspar, cordierite, high bauxite, kaolin, quartz, wollastonite, zinc oxide, zirconium silicate, methylcellulose, calcined talcum and titanium dioxide to obtain a second mixture;
4) Wetting the blank with water, and uniformly mixing and applying the second mixture to the blank;
5) Fully mixing and grinding potassium feldspar, limestone, barium carbonate, zinc oxide, kaolin, zinc oxide, barium carbonate, quartz 1, dolomite and barium sulfate to obtain a third mixture.
6) Uniformly mixing the third mixture and applying the mixture to the embryo body;
7) Mixing potassium feldspar, kaolin, nepheline, dolomite, calcined alumina, quartz sand, talcum powder, magnesium borate whisker, diatomite, titanium diboride, barium carbonate, magnesium oxide and zinc oxide, and grinding for the first time to obtain a fourth mixture;
8) Adding a dispersing agent into the fourth mixture for carrying out second superfine grinding to obtain a fifth mixture;
9) Adding water, printing paste and sodium metaphosphate into the fifth mixture, and stirring in a high-speed dispersing machine to obtain slurry;
10 Uniformly applying the slurry on the blank body, and calcining at high temperature in a kiln to obtain a high-hardness wear-resistant ceramic tile finished product.
The invention has the beneficial effects that:
the invention provides a high-hardness wear-resistant ceramic tile and a preparation method thereof, which greatly improve the hardness and wear resistance of the glazed surface of the ceramic tile, and have the advantages of simplicity, easiness in implementation, wide sources of raw materials, simple preparation process, long service life and wide market prospect.
Detailed Description
Preferred embodiments of the present invention are described in detail below.
Embodiment one:
the invention provides a high-hardness wear-resistant ceramic tile and a preparation method thereof, wherein the high-hardness wear-resistant ceramic tile comprises the following components: the high-hardness wear-resistant glaze polishing layer comprises a blank layer, a surface glaze layer, a transparent glaze layer and a high-hardness wear-resistant glaze polishing layer;
the high-hardness wear-resistant glaze polishing layer comprises wear-resistant glaze particles, a dispersing agent, water, printing paste and sodium metaphosphate
The wear-resistant glaze particles consist of the following raw materials:
15 parts of potassium feldspar, 20 parts of kaolin, 12 parts of nepheline, 5 parts of dolomite, 10 parts of calcined alumina, 15 parts of quartz sand, 8 parts of talcum powder, 5 parts of magnesium borate whisker, 15 parts of diatomite, 5 parts of titanium diboride, 8 parts of barium carbonate, 5 parts of magnesium oxide and 7 parts of zinc oxide;
the green body layer of the invention is composed of the following raw materials: 20 parts of kaolin, 10 parts of wollastonite, 15 parts of calcite, 8 parts of lithium porcelain stone, 10 parts of diopside, 12 parts of zircon sand, 5 parts of iron ore, 10 parts of bauxite, 12 parts of quartz sand and 5 parts of calcium phosphate.
The surface glaze layer of the invention is composed of the following raw materials:
15 parts of potassium feldspar, 8 parts of cordierite, 15 parts of high alumina, 8 parts of kaolin, 10 parts of quartz, 5 parts of wollastonite, 3 parts of zinc oxide, 12 parts of zirconium silicate, 2 parts of methylcellulose, 8 parts of calcined talcum and 3 parts of titanium dioxide.
The transparent glaze layer in the invention is composed of the following raw materials:
12 parts of potassium feldspar, 8 parts of limestone, 10 parts of barium carbonate, 3 parts of zinc oxide, 12 parts of kaolin, 5 parts of zinc oxide, 7 parts of barium carbonate, 10 parts of quartz, 3 parts of dolomite and 5 parts of barium sulfate.
The method specifically comprises the following steps:
1) Ball milling and mixing kaolin, wollastonite, calcite, lithium porcelain stone, diopside, zircon sand, iron ore, bauxite, quartz sand and calcium phosphate uniformly to obtain a first mixture;
2) Continuously stirring the first mixture for 45-60min under the irradiation power of 30-45kw and the rotation speed of 450-600r/min, stamping, forming and drying to obtain a blank;
3) Fully mixing and grinding potassium feldspar, cordierite, high bauxite, kaolin, quartz, wollastonite, zinc oxide, zirconium silicate, methylcellulose, calcined talcum and titanium dioxide to obtain a second mixture;
4) Wetting the blank with water, and uniformly mixing and applying the second mixture to the blank;
5) Fully mixing and grinding potassium feldspar, limestone, barium carbonate, zinc oxide, kaolin, zinc oxide, barium carbonate, quartz 1, dolomite and barium sulfate to obtain a third mixture.
6) Uniformly mixing the third mixture and applying the mixture to the embryo body;
7) Mixing potassium feldspar, kaolin, nepheline, dolomite, calcined alumina, quartz sand, talcum powder, magnesium borate whisker, diatomite, titanium diboride, barium carbonate, magnesium oxide and zinc oxide, and grinding for the first time to obtain a fourth mixture;
8) Adding a dispersing agent into the fourth mixture for carrying out second superfine grinding to obtain a fifth mixture;
9) Adding water, printing paste and sodium metaphosphate into the fifth mixture, and stirring in a high-speed dispersing machine to obtain slurry;
10 Uniformly applying the slurry on the blank body, and calcining at high temperature in a kiln to obtain a high-hardness wear-resistant ceramic tile finished product.
Embodiment two:
the invention provides a high-hardness wear-resistant ceramic tile and a preparation method thereof, wherein the high-hardness wear-resistant ceramic tile comprises the following components: the high-hardness wear-resistant glaze polishing layer comprises a blank layer, a surface glaze layer, a transparent glaze layer and a high-hardness wear-resistant glaze polishing layer;
the high-hardness wear-resistant glaze polishing layer comprises wear-resistant glaze particles, a dispersing agent, water, printing paste and sodium metaphosphate
The wear-resistant glaze particles consist of the following raw materials:
30 parts of potassium feldspar, 35 parts of kaolin, 25 parts of nepheline, 15 parts of dolomite, 28 parts of calcined alumina, 35 parts of quartz sand, 12 parts of talcum powder, 12 parts of magnesium borate whisker, 25 parts of diatomite, 12 parts of titanium diboride, 15 parts of barium carbonate, 10 parts of magnesium oxide and 15 parts of zinc oxide;
the green body layer of the invention is composed of the following raw materials: 35 parts of kaolin, 25 parts of wollastonite, 25 parts of calcite, 20 parts of lithium porcelain stone, 18 parts of diopside, 25 parts of zircon sand, 10 parts of iron ore, 28 parts of bauxite, 20 parts of quartz sand and 12 parts of calcium phosphate.
The surface glaze layer of the invention is composed of the following raw materials:
20 parts of potassium feldspar, 15 parts of cordierite, 25 parts of high alumina, 20 parts of kaolin, 15 parts of quartz, 12 parts of wollastonite, 8 parts of zinc oxide, 25 parts of zirconium silicate, 5 parts of methylcellulose, 12 parts of calcined talc and 8 parts of titanium dioxide.
The transparent glaze layer in the invention is composed of the following raw materials:
25 parts of potassium feldspar, 15 parts of limestone, 18 parts of barium carbonate, 8 parts of zinc oxide, 20 parts of kaolin, 12 parts of zinc oxide, 15 parts of barium carbonate, 15 parts of quartz, 10 parts of dolomite and 8 parts of barium sulfate.
The method specifically comprises the following steps:
1) Ball milling and mixing kaolin, wollastonite, calcite, lithium porcelain stone, diopside, zircon sand, iron ore, bauxite, quartz sand and calcium phosphate uniformly to obtain a first mixture;
2) Continuously stirring the first mixture for 45-60min under the irradiation power of 30-45kw and the rotation speed of 450-600r/min, stamping, forming and drying to obtain a blank;
3) Fully mixing and grinding potassium feldspar, cordierite, high bauxite, kaolin, quartz, wollastonite, zinc oxide, zirconium silicate, methylcellulose, calcined talcum and titanium dioxide to obtain a second mixture;
4) Wetting the blank with water, and uniformly mixing and applying the second mixture to the blank;
5) Fully mixing and grinding potassium feldspar, limestone, barium carbonate, zinc oxide, kaolin, zinc oxide, barium carbonate, quartz 1, dolomite and barium sulfate to obtain a third mixture.
6) Uniformly mixing the third mixture and applying the mixture to the embryo body;
7) Mixing potassium feldspar, kaolin, nepheline, dolomite, calcined alumina, quartz sand, talcum powder, magnesium borate whisker, diatomite, titanium diboride, barium carbonate, magnesium oxide and zinc oxide, and grinding for the first time to obtain a fourth mixture;
8) Adding a dispersing agent into the fourth mixture for carrying out second superfine grinding to obtain a fifth mixture;
9) Adding water, printing paste and sodium metaphosphate into the fifth mixture, and stirring in a high-speed dispersing machine to obtain slurry;
10 Uniformly applying the slurry on the blank body, and calcining at high temperature in a kiln to obtain a high-hardness wear-resistant ceramic tile finished product.
The invention and its embodiments have been described above without limitation, and the actual construction is not limited thereto. In summary, if one of ordinary skill in the art is informed by this disclosure, a structural manner and an embodiment similar to the technical solution should not be creatively devised without departing from the gist of the present invention.
Claims (6)
1. A high hardness wear resistant ceramic tile comprising: the high-hardness wear-resistant glaze polishing layer comprises a blank layer, a surface glaze layer, a transparent glaze layer and a high-hardness wear-resistant glaze polishing layer;
the high-hardness wear-resistant glaze polishing layer comprises wear-resistant glaze particles, a dispersing agent, water, printing paste and sodium metaphosphate;
the wear-resistant glaze particles consist of the following raw materials:
15-30 parts of potassium feldspar, 20-35 parts of kaolin, 12-25 parts of nepheline, 5-15 parts of dolomite, 10-28 parts of calcined alumina, 15-35 parts of quartz sand, 8-12 parts of talcum powder, 5-12 parts of magnesium borate whisker, 15-25 parts of diatomite, 5-12 parts of titanium diboride, 8-15 parts of barium carbonate, 5-10 parts of magnesium oxide and 7-15 parts of zinc oxide;
the blank layer is composed of the following raw materials: 20-35 parts of kaolin, 10-25 parts of wollastonite, 15-25 parts of calcite, 8-20 parts of lithium porcelain stone, 10-18 parts of diopside, 12-25 parts of zircon sand, 5-10 parts of iron ore, 10-28 parts of bauxite, 12-20 parts of quartz sand and 5-12 parts of calcium phosphate.
2. The high hardness wear resistant ceramic tile as set forth in claim 1, wherein: the wear-resistant glaze particles consist of the following raw materials:
15 parts of potassium feldspar, 20 parts of kaolin, 12 parts of nepheline, 5 parts of dolomite, 10 parts of calcined alumina, 15 parts of quartz sand, 8 parts of talcum powder, 5 parts of magnesium borate whisker, 15 parts of diatomite, 5 parts of titanium diboride, 8 parts of barium carbonate, 5 parts of magnesium oxide and 7 parts of zinc oxide;
the blank layer is composed of the following raw materials: 20 parts of kaolin, 10 parts of wollastonite, 15 parts of calcite, 8 parts of lithium porcelain stone, 10 parts of diopside, 12 parts of zircon sand, 5 parts of iron ore, 10 parts of bauxite, 12 parts of quartz sand and 5 parts of calcium phosphate.
3. The high hardness wear resistant ceramic tile as set forth in claim 1, wherein: the wear-resistant glaze particles consist of the following raw materials:
30 parts of potassium feldspar, 35 parts of kaolin, 25 parts of nepheline, 15 parts of dolomite, 28 parts of calcined alumina, 35 parts of quartz sand, 12 parts of talcum powder, 12 parts of magnesium borate whisker, 25 parts of diatomite, 12 parts of titanium diboride, 15 parts of barium carbonate, 10 parts of magnesium oxide and 15 parts of zinc oxide;
the blank layer is composed of the following raw materials: 35 parts of kaolin, 25 parts of wollastonite, 25 parts of calcite, 20 parts of lithium porcelain stone, 18 parts of diopside, 25 parts of zircon sand, 10 parts of iron ore, 28 parts of bauxite, 20 parts of quartz sand and 12 parts of calcium phosphate.
4. The high hardness wear resistant ceramic tile as set forth in claim 1, wherein: the overglaze layer is composed of the following raw materials:
15-20 parts of potassium feldspar, 8-15 parts of cordierite, 15-25 parts of high bauxite, 8-20 parts of kaolin, 10-15 parts of quartz, 5-12 parts of wollastonite, 3-8 parts of zinc oxide, 12-25 parts of zirconium silicate, 2-5 parts of methylcellulose, 8-12 parts of calcined talcum and 3-8 parts of titanium dioxide.
5. The high hardness wear resistant ceramic tile as set forth in claim 1, wherein: the transparent glaze layer is composed of the following raw materials:
12-25 parts of potassium feldspar, 8-15 parts of limestone, 10-18 parts of barium carbonate, 3-8 parts of zinc oxide, 12-20 parts of kaolin, 5-12 parts of zinc oxide, 7-15 parts of barium carbonate, 10-15 parts of quartz, 3-10 parts of dolomite and 5-8 parts of barium sulfate.
6. The method for preparing the high-hardness wear-resistant ceramic tile according to claim 1, wherein the method comprises the following steps: the method specifically comprises the following steps:
1) Ball milling and mixing kaolin, wollastonite, calcite, lithium porcelain stone, diopside, zircon sand, iron ore, bauxite, quartz sand and calcium phosphate uniformly to obtain a first mixture;
2) Continuously stirring the first mixture for 45-60min under the irradiation power of 30-45kw and the rotation speed of 450-600r/min, stamping, forming and drying to obtain a blank;
3) Fully mixing and grinding potassium feldspar, cordierite, high bauxite, kaolin, quartz, wollastonite, zinc oxide, zirconium silicate, methylcellulose, calcined talcum and titanium dioxide to obtain a second mixture;
4) Wetting the blank with water, and uniformly mixing and applying the second mixture to the blank;
5) Fully mixing and grinding potassium feldspar, limestone, barium carbonate, zinc oxide, kaolin, zinc oxide, barium carbonate, quartz 1, dolomite and barium sulfate to obtain a third mixture.
6) Uniformly mixing the third mixture and applying the mixture to the embryo body;
7) Mixing potassium feldspar, kaolin, nepheline, dolomite, calcined alumina, quartz sand, talcum powder, magnesium borate whisker, diatomite, titanium diboride, barium carbonate, magnesium oxide and zinc oxide, and grinding for the first time to obtain a fourth mixture;
8) Adding a dispersing agent into the fourth mixture for carrying out second superfine grinding to obtain a fifth mixture;
9) Adding water, printing paste and sodium metaphosphate into the fifth mixture, and stirring in a high-speed dispersing machine to obtain slurry;
10 Uniformly applying the slurry on the blank body, and calcining at high temperature in a kiln to obtain a high-hardness wear-resistant ceramic tile finished product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116854486A (en) * | 2023-07-06 | 2023-10-10 | 河南蚂蚁新材料有限公司 | Composite ceramic chute and preparation method and application thereof |
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| CN112010633A (en) * | 2020-09-10 | 2020-12-01 | 淄博峰霞陶瓷有限公司 | Preparation method of wear-resistant anti-skid ceramic tile |
| CN114920541A (en) * | 2022-05-28 | 2022-08-19 | 河北浩锐陶瓷制品有限公司 | High-wear-resistance ceramic material for ceramic tiles, preparation method of high-wear-resistance ceramic material and high-wear-resistance ceramic tiles |
| CN115583845A (en) * | 2022-10-24 | 2023-01-10 | 广东简一(集团)陶瓷有限公司 | High-hardness high-wear-resistance embossed ceramic tile and preparation method thereof |
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| CN111995437A (en) * | 2020-09-10 | 2020-11-27 | 淄博峰霞陶瓷有限公司 | Super wear-resistant anti-skid ceramic tile and preparation method thereof |
| CN112010633A (en) * | 2020-09-10 | 2020-12-01 | 淄博峰霞陶瓷有限公司 | Preparation method of wear-resistant anti-skid ceramic tile |
| CN114920541A (en) * | 2022-05-28 | 2022-08-19 | 河北浩锐陶瓷制品有限公司 | High-wear-resistance ceramic material for ceramic tiles, preparation method of high-wear-resistance ceramic material and high-wear-resistance ceramic tiles |
| CN115583845A (en) * | 2022-10-24 | 2023-01-10 | 广东简一(集团)陶瓷有限公司 | High-hardness high-wear-resistance embossed ceramic tile and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116854486A (en) * | 2023-07-06 | 2023-10-10 | 河南蚂蚁新材料有限公司 | Composite ceramic chute and preparation method and application thereof |
| CN116854486B (en) * | 2023-07-06 | 2024-02-27 | 河南蚂蚁新材料有限公司 | Composite ceramic chute and preparation method and application thereof |
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