CN111646776B - Wear-resistant antifouling ceramic tile with starlight diamond effect and preparation method thereof - Google Patents
Wear-resistant antifouling ceramic tile with starlight diamond effect and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of ceramic materials, and particularly relates to a wear-resistant antifouling ceramic tile with starlight diamond effect and a preparation method thereof. Comprises a blank body, a ground coat, a surface glaze, an ink spraying layer, a glue layer and a starlight glaze layer which are sequentially compounded from bottom to top; the starlight glaze layer is prepared from starlight glaze particles, and the starlight glaze particles comprise the following raw materials in parts by weight: 10-15 parts of carborundum, 5-10 parts of mullite, 3-6 parts of alumina, 20-30 parts of potash feldspar, 10-20 parts of quartz sand, 3-5 parts of zinc oxide, 3-7 parts of barium carbonate and 8-12 parts of calcined talc. The wear-resistant antifouling ceramic tile with the starlight diamond effect has the advantages of delicate glaze layer color, naturalness, good wear resistance, strong antifouling property, high strength, excellent mechanical property and shining diamond-like surface.
Description
Technical Field
The invention belongs to the technical field of ceramic materials, and particularly relates to a wear-resistant antifouling ceramic tile with starlight diamond effect and a preparation method thereof.
Background
The ceramic tile is a plate-shaped or block-shaped ceramic product produced by clay, potash feldspar, albite and other inorganic non-metallic raw materials through the processes of material mixing, ball milling, powder making, molding, sintering and the like, and is widely applied to decorating and protecting walls and floors of buildings and structures.
With the rapid development of science and technology, people's lives are changing day by day, and meanwhile, an era of pursuing fashion and showing individuality is cast, and the field of building decoration materials is not exceptional. Ceramic tiles are popular with more and more consumers due to their superior performance and decorative effect, and are widely used in people's daily life. The ceramic tile is used as the most important component of indoor decoration, and the difference of the performance directly influences the application range.
The traditional ceramic overglaze mainly takes common white glaze as a main part, although the pattern decoration is favorably realized, the prepared ceramic product can only display the decorative design pattern on the surface under the bright condition, but cannot display the original decorative effect of the product under the condition of insufficient brightness or darkness, has no new originality and development, and is not suitable for the current cultural and artistic development and the pursuit of people for innovative art.
CN104529553A discloses a glazed tile made of ceramic waste and having a surface like broken diamond sand twinkling starlight and a preparation method thereof, wherein the scheme mainly adopts that crystallized melt particles are maintained in a slightly concave-convex shape after being calcined at high temperature, and fine crystals like pyroxene and sphene can be re-precipitated after being cooled, and the crystals are fine and large in quantity and can emit twinkling starlight like broken diamond sand under the irradiation of light. However, this method has high melting cost and complicated process. At present, few researches on glaze and ceramic tiles capable of generating diamond luster effects are carried out on the market.
The existing glazed tile with the starlight flashing effect is complex in preparation process and high in cost, and the prepared glazed tile is poor in wear resistance, large in abrasion loss during use and poor in antifouling performance, so that the service life of the glazed tile is seriously influenced.
Disclosure of Invention
The purpose of the invention is: provides a wear-resistant antifouling ceramic tile with starlight diamond effect. The ceramic tile has high wear resistance, good antifouling performance and long service life; the invention also provides a preparation method thereof.
The invention relates to a wear-resistant antifouling ceramic tile with a starlight diamond effect, which comprises a blank body, a ground coat, a surface coat, an ink spraying layer, a glue layer and a starlight glaze layer which are sequentially compounded from bottom to top; the starlight glaze layer is prepared from starlight glaze particles, and the starlight glaze particles comprise the following raw materials in parts by weight: 10-15 parts of carborundum, 5-10 parts of mullite, 3-6 parts of alumina, 20-30 parts of potash feldspar, 10-20 parts of quartz sand, 3-5 parts of zinc oxide, 3-7 parts of barium carbonate and 8-12 parts of calcined talc.
Wherein:
the particle size of the starlight glaze particles after grinding is 60-250 meshes.
The green body is prepared from, by weight, 10-20 parts of potassium feldspar, 15-25 parts of albite, 5-10 parts of cryolite, 3-8 parts of brown fused alumina, 20-30 parts of kaolin, 8-12 parts of coal gangue and 5-8 parts of pitchstone.
Cryolite and coal gangue are added into the blank, so that abundant Al, Na and Si elements are provided for the blank, and rare elements such as vanadium, titanium and the like are also provided, and the cryolite and the coal gangue have synergistic effect, so that the production cost and the sintering temperature are greatly reduced, and the stability and the wear resistance of the blank are improved.
The ground glaze is prepared from 5-12 parts by weight of montmorillonite, 8-15 parts by weight of zirconium silicate, 3-12 parts by weight of bauxite, 2-3 parts by weight of talcum powder, 8-12 parts by weight of zinc oxide, 3-5 parts by weight of kaliophilite and 15-20 parts by weight of wollastonite.
The zirconium silicate and the talcum powder are added into the ground glaze, the zirconium silicate and the talcum powder have synergistic effect, the stability, the whiteness, the covering power and the lubricity of the ground glaze are improved while the hardness of the ground glaze is improved, the whiteness is further improved by adding wollastonite, the abrasion resistance of the ground glaze is also improved, and the problems that the fluidity of the ground glaze is poor and bubbles are generated during glaze pouring in the preparation process of the ground glaze are solved by adding montmorillonite into the glaze.
The overglaze is prepared from 3-5 parts of chromium carbide, 8-15 parts of soapstone, 10-24 parts of quartz, 2-3 parts of nano zinc oxide, 5-7 parts of calcite, 2-4 parts of zirconium silicate, 5-7 parts of magnesium oxide, 10-14 parts of cordierite, 20-30 parts of potassium feldspar and 15-20 parts of albite in parts by weight.
The zirconium silicate and the zinc oxide in the glaze act synergistically, so that the glaze has a remarkable fluxing function, the heat stability of a product is guaranteed, the bonding capacity of a blank and the glaze is remarkably improved, the thermal expansion coefficient of the glaze is reduced, and the glossiness, hardness and elasticity of the glaze are improved; the addition of chromium carbide improves the wear resistance, corrosion resistance and oxidation resistance of the glaze surface.
As a preferred technical scheme, the starlight glaze particles comprise the following raw materials in parts by weight: 12-13 parts of carborundum, 7-8 parts of mullite, 4-5 parts of alumina, 27-28 parts of potash feldspar, 15-17 parts of quartz sand, 3-5 parts of zinc oxide, 3-5 parts of barium carbonate and 8-10 parts of calcined talc.
The glue layer is prepared from 4-7 parts by mass of carboxymethyl cellulose, 90-94 parts by mass of glue and 0.3-0.4 part by mass of sodium tripolyphosphate.
The preparation method of the wear-resistant antifouling ceramic tile with the starlight diamond effect comprises the steps of applying base coat and surface coat on a blank body, then carrying out ink jet, and spraying glue on the base coat and the surface coat to form a glue layer; and (3) spreading the starlight glaze particles on a glue layer to form a starlight glaze layer, and finally sintering to obtain the wear-resistant antifouling ceramic tile with the starlight diamond effect.
Wherein:
as a preferred technical scheme, the preparation method of the wear-resistant antifouling ceramic tile with the starlight diamond effect comprises the following steps:
(1) pressing the green body powder into a green body, and drying at 80-250 ℃ for 40-45 min;
(2) spraying base glaze and surface glaze on the green body;
(3) spraying a required pattern on the overglaze layer by adopting an ink-jet printer to form an ink-jet layer;
(4) spraying glue on the ink spraying layer to form a glue layer;
(5) spreading starlight glaze particles on the glue layer by using a spreader to form a starlight glaze layer;
(6) sintering at 1200-1250 ℃ for 45-50min, and obtaining the wear-resistant antifouling ceramic tile with starlight diamond effect after post-treatment.
Wherein:
and (3) ball-milling the raw material of the ground glaze in the step (2) and sieving the ground glaze with a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the ground glaze is 1.5.
And (3) ball-milling the raw material of the overglaze in the step (2) and sieving the raw material by a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the overglaze is 1.5.
Compared with the prior art, the invention has the following beneficial effects:
(1) the wear-resistant antifouling ceramic tile with the starlight diamond effect has the advantages of delicate glaze layer color, naturalness, good wear resistance, strong antifouling property, high strength, excellent mechanical property and shining diamond-like surface.
(2) The preparation method of the wear-resistant antifouling ceramic tile with the starlight diamond effect is simple in preparation process, environment-friendly, low in production cost and wide in market prospect.
(3) The surface of the wear-resistant antifouling ceramic tile with the starlight diamond effect is provided with a plurality of fine granular flashing particles, the water absorption rate is 0.1-0.2%, the wear-resistant grade is 7-8 grade, the antifouling property is 7-8 grade, and the Mohs hardness is 7-8 grade.
Detailed Description
The present invention is further described below with reference to examples.
Example 1
The wear-resistant antifouling ceramic tile with the starlight diamond effect in the embodiment 1 comprises a blank body, a ground coat, a cover coat, an ink-jet layer, a glue layer and a starlight glaze layer which are sequentially compounded from bottom to top; the starlight glaze layer is prepared from starlight glaze particles, and the starlight glaze particles comprise the following raw materials in parts by weight: 15 parts of carborundum, 7 parts of mullite, 4 parts of alumina, 25 parts of potassium feldspar, 15 parts of quartz sand, 4 parts of zinc oxide, 5 parts of barium carbonate and 10 parts of calcined talc.
Wherein:
the particle size of the starlight glaze particles after grinding is 200 meshes.
The green body is prepared from 15 parts of potassium feldspar, 15 parts of albite, 7 parts of cryolite, 5 parts of brown corundum, 25 parts of kaolin, 10 parts of coal gangue and 5 parts of pitchstone by weight.
The ground glaze is prepared from 8 parts by weight of montmorillonite, 10 parts by weight of zirconium silicate, 8 parts by weight of bauxite, 2.5 parts by weight of talcum powder, 10 parts by weight of zinc oxide, 4 parts by weight of kaliophilite and 18 parts by weight of wollastonite.
The overglaze is prepared from 5 parts by weight of chromium carbide, 10 parts by weight of soapstone, 18 parts by weight of quartz, 2 parts by weight of nano zinc oxide, 5 parts by weight of calcite, 4 parts by weight of zirconium silicate, 6 parts by weight of magnesium oxide, 12 parts by weight of cordierite, 25 parts by weight of potassium feldspar and 15 parts by weight of albite.
The glue layer is prepared from 5 parts of carboxymethyl cellulose, 90 parts of glue and 0.3 part of sodium tripolyphosphate in parts by mass.
The preparation method of the abrasion-resistant and antifouling ceramic tile with starlight diamond effect described in the embodiment 1 comprises the following steps:
(1) pressing the blank powder into a blank, and drying at 100 ℃ for 40 min;
(2) spraying base glaze and surface glaze on the green body;
(3) spraying a required pattern on the overglaze layer by adopting an ink-jet printer to form an ink-jet layer;
(4) spraying glue on the ink spraying layer to form a glue layer;
(5) spreading starlight glaze particles on the glue layer by using a spreader to form a starlight glaze layer;
(6) and (3) sintering at 1200 ℃ for 50min, and performing post-treatment to obtain the wear-resistant antifouling ceramic tile with starlight diamond effect.
Wherein:
and (3) ball-milling the raw material of the ground glaze in the step (2) and sieving the ground glaze with a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the ground glaze is 1.5.
And (3) performing ball milling on the raw material of the overglaze in the step (2), sieving the raw material by using a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the overglaze is 1.5.
Example 2
The wear-resistant antifouling ceramic tile with the starlight diamond effect in the embodiment 2 comprises a blank body, a ground coat, a cover coat, an ink-jet layer, a glue layer and a starlight glaze layer which are sequentially compounded from bottom to top; the starlight glaze layer is prepared from starlight glaze particles, and the starlight glaze particles comprise the following raw materials in parts by weight: 10 parts of carborundum, 10 parts of mullite, 6 parts of alumina, 30 parts of potassium feldspar, 10 parts of quartz sand, 3 parts of zinc oxide, 7 parts of barium carbonate and 12 parts of calcined talc.
Wherein:
the particle size of the starlight glaze particles after grinding is 250 meshes.
The green body is prepared from 10 parts of potash feldspar, 20 parts of albite, 5 parts of cryolite, 3 parts of brown corundum, 30 parts of kaolin, 8 parts of coal gangue and 8 parts of pitchstone by weight.
The ground glaze is prepared from 5 parts by weight of montmorillonite, 8 parts by weight of zirconium silicate, 12 parts by weight of bauxite, 2 parts by weight of talcum powder, 12 parts by weight of zinc oxide, 3 parts by weight of kaliophilite and 15 parts by weight of wollastonite.
The overglaze is prepared from 3 parts by weight of chromium carbide, 8 parts by weight of soapstone, 10 parts by weight of quartz, 3 parts by weight of nano zinc oxide, 7 parts by weight of calcite, 2 parts by weight of zirconium silicate, 5 parts by weight of magnesium oxide, 10 parts by weight of cordierite, 20 parts by weight of potassium feldspar and 18 parts by weight of albite.
The glue layer is prepared from 5 parts of carboxymethyl cellulose, 94 parts of glue and 0.3 part of sodium tripolyphosphate in parts by mass.
The preparation method of the wear-resistant antifouling ceramic tile with starlight diamond effect in the embodiment 2 comprises the following steps:
(1) pressing the blank powder into a blank, and drying at 150 ℃ for 40 min;
(2) spraying base glaze and surface glaze on the green body;
(3) spraying a required pattern on the overglaze layer by adopting an ink-jet printer to form an ink-jet layer;
(4) spraying glue on the ink spraying layer to form a glue layer;
(5) spreading starlight glaze particles on the glue layer by using a spreader to form a starlight glaze layer;
(6) and (3) firing at 1230 ℃ for 50min, and performing post-treatment to obtain the wear-resistant antifouling ceramic tile with the starlight diamond effect.
Wherein:
and (3) ball-milling the raw material of the ground glaze in the step (2) and sieving the ground glaze with a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the ground glaze is 1.5.
And (3) ball-milling the raw material of the overglaze in the step (2) and sieving the raw material by a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the overglaze is 1.5.
Example 3
The wear-resistant antifouling ceramic tile with the starlight diamond effect in the embodiment 3 comprises a blank body, a ground coat, a cover coat, an ink-jet layer, a glue layer and a starlight glaze layer which are sequentially compounded from bottom to top; the starlight glaze layer is prepared from starlight glaze particles, and the starlight glaze particles comprise the following raw materials in parts by weight: 12 parts of carborundum, 5 parts of mullite, 5 parts of alumina, 20 parts of potassium feldspar, 20 parts of quartz sand, 5 parts of zinc oxide, 3 parts of barium carbonate and 8 parts of calcined talc.
Wherein:
the particle size of the starlight glaze particles after grinding is 150 meshes.
The green body is prepared from 20 parts of potassium feldspar, 25 parts of albite, 10 parts of cryolite, 8 parts of brown corundum, 20 parts of kaolin, 12 parts of coal gangue and 7 parts of pitchstone by weight.
The ground glaze is prepared from 12 parts by weight of montmorillonite, 15 parts by weight of zirconium silicate, 3 parts by weight of bauxite, 3 parts by weight of talcum powder, 8 parts by weight of zinc oxide, 5 parts by weight of kaliophilite and 20 parts by weight of wollastonite.
The overglaze is prepared from 4 parts by weight of chromium carbide, 15 parts by weight of soapstone, 24 parts by weight of quartz, 2.5 parts by weight of nano zinc oxide, 6 parts by weight of calcite, 3 parts by weight of zirconium silicate, 7 parts by weight of magnesium oxide, 14 parts by weight of cordierite, 30 parts by weight of potassium feldspar and 20 parts by weight of albite.
The glue layer is prepared from 7 parts by mass of carboxymethyl cellulose, 92 parts by mass of glue and 0.4 part by mass of sodium tripolyphosphate.
The preparation method of the wear-resistant antifouling ceramic tile with starlight diamond effect in the embodiment 3 comprises the following steps:
(1) pressing the blank powder into a blank, and drying at 250 ℃ for 40 min;
(2) spraying base glaze and surface glaze on the green body;
(3) spraying a required pattern on the overglaze layer by adopting an ink-jet printer to form an ink-jet layer;
(4) spraying glue on the ink spraying layer to form a glue layer;
(5) spreading starlight glaze particles on the glue layer by using a spreader to form a starlight glaze layer;
(6) and (3) firing at 1250 ℃ for 50min, and performing post-treatment to obtain the wear-resistant antifouling ceramic tile with the starlight diamond effect.
Wherein:
and (3) performing ball milling on the raw materials of the ground glaze in the step (2), sieving the ground glaze by using a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the ground glaze is 1.5.
And (3) performing ball milling on the raw material of the overglaze in the step (2), sieving the raw material by using a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the overglaze is 1.5.
Comparative example 1
The wear-resistant antifouling ceramic tile in the comparative example 1 is different from that in the example 3 in that the starlight glaze layer adopts starlight glaze particles, and the starlight glaze particles comprise the following raw materials in parts by weight: 5 parts of mullite, 5 parts of alumina, 20 parts of potassium feldspar, 20 parts of albite, 5 parts of zinc oxide, 3 parts of barium carbonate and 8 parts of calcined talc.
The composition and preparation method of the rest of the blank, ground coat, overglaze, ink-jet layer and glue layer are the same as those of example 3.
Comparative example 2
The wear-resistant antifouling ceramic tile in the comparative example 2 is different from that in the example 3 in that the blank body is lack of cryolite and is prepared from 25 parts by weight of potash feldspar, 30 parts by weight of albite, 8 parts by weight of brown corundum, 20 parts by weight of kaolin, 12 parts by weight of coal gangue and 7 parts by weight of pitchstone.
The ingredients and preparation methods of the rest of the ground coat, the overglaze, the ink-jet layer, the starlight glaze layer and the glue layer are the same as those of the example 3.
Comparative example 3
The wear-resistant antifouling ceramic tile of comparative example 3 is different from example 3 in the ground glaze component, and the ground glaze is prepared from 10 parts by weight of kaolin, 8 parts by weight of potassium feldspar, 10 parts by weight of albite, 3 parts by weight of bauxite, 3 parts by weight of talcum powder, 8 parts by weight of zinc oxide, 5 parts by weight of kaliophilite and 20 parts by weight of wollastonite.
The ingredients and preparation methods of the rest of the body, overglaze, ink-jet layer, starlight glaze layer and glue layer are the same as those of example 3.
Comparative example 4
The wear-resistant antifouling ceramic tile in comparative example 4 is different from that in example 3 in the glaze components, and the glaze is prepared from 15 parts by weight of soapstone, 24 parts by weight of quartz, 2.5 parts by weight of nano zinc oxide, 6 parts by weight of calcite, 7 parts by weight of magnesium oxide, 14 parts by weight of cordierite, 30 parts by weight of potassium feldspar and 20 parts by weight of albite.
The composition and preparation method of the rest of the blank, the ground coat, the ink-jet layer, the starlight glaze layer and the glue layer are the same as those of example 3.
The ceramic tiles prepared in examples 1-3 and comparative examples 1-4 were subjected to performance testing, the results of which are shown in Table 1 below:
| performance of | Detection standard | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 |
| Water absorption (%) | GB/T 3810-2016 | 0.10 | 0.13 | 0.12 | 0.20 | 0.23 | 0.18 | 0.17 |
| Stain resistance | GB/T 3810-2016 | Stage 8 | Stage 7 | Stage 7 | Grade 5 | Grade 5 | Grade 5 | Grade 5 |
| Wear rating | GB/T 3810-2016 | Stage 8 | Stage 7 | Stage 7 | Grade 5 | Grade 5 | Grade 5 | Grade 5 |
| Breaking Strength/N | GB/T 3810-2016 | 3108 | 2804 | 2905 | 2303 | 2287 | 2303 | 2409 |
| Mohs hardness | GB/T 3810-2016 | Stage 8 | Stage 7 | Stage 7 | Stage 7 | Stage 7 | Stage 7 | Stage 7 |
Claims (7)
1. The utility model provides a wear-resisting antifouling pottery brick with starlight diamond effect which characterized in that: comprises a blank body, a ground coat, a surface glaze, an ink spraying layer, a glue layer and a starlight glaze layer which are sequentially compounded from bottom to top; the starlight glaze layer is prepared from starlight glaze particles, and the starlight glaze particles comprise the following raw materials in parts by weight: 10-15 parts of carborundum, 5-10 parts of mullite, 3-6 parts of alumina, 20-30 parts of potash feldspar, 10-20 parts of quartz sand, 3-5 parts of zinc oxide, 3-7 parts of barium carbonate and 8-12 parts of calcined talc;
wherein:
the green body is prepared from 10-20 parts of potassium feldspar, 15-25 parts of albite, 5-10 parts of cryolite, 3-8 parts of brown fused alumina, 20-30 parts of kaolin, 8-12 parts of coal gangue and 5-8 parts of pitchstone by weight;
the ground glaze is prepared from 5-12 parts by weight of montmorillonite, 8-15 parts by weight of zirconium silicate, 3-12 parts by weight of bauxite, 2-3 parts by weight of talcum powder, 8-12 parts by weight of zinc oxide, 3-5 parts by weight of kaliophilite and 15-20 parts by weight of wollastonite;
the overglaze is prepared from 3-5 parts of chromium carbide, 8-15 parts of soapstone, 10-24 parts of quartz, 2-3 parts of nano zinc oxide, 5-7 parts of calcite, 2-4 parts of zirconium silicate, 5-7 parts of magnesium oxide, 10-14 parts of cordierite, 20-30 parts of potassium feldspar and 15-20 parts of albite in parts by weight.
2. The abrasion resistant, anti-fouling ceramic tile with starlight diamond effect of claim 1, wherein: the particle size of the ground starlight glaze particles is 60-250 meshes; the starlight glaze particles comprise the following raw materials in parts by weight: 12-13 parts of carborundum, 7-8 parts of mullite, 4-5 parts of alumina, 27-28 parts of potash feldspar, 15-17 parts of quartz sand, 3-5 parts of zinc oxide, 3-5 parts of barium carbonate and 8-10 parts of calcined talc.
3. The abrasion resistant, anti-fouling ceramic tile with starlight diamond effect of claim 1, wherein: the glue layer is prepared from 4-7 parts by mass of carboxymethyl cellulose, 90-94 parts by mass of glue and 0.3-0.4 part by mass of sodium tripolyphosphate.
4. A method for preparing a wear-resistant and anti-fouling ceramic tile with starlight diamond effect as claimed in claim 1, wherein: spraying ink after applying base coat and surface coat on the blank, and spraying glue on the base coat and the surface coat to form a glue layer; and (3) spreading the starlight glaze particles on a glue layer to form a starlight glaze layer, and finally sintering to obtain the wear-resistant antifouling ceramic tile with the starlight diamond effect.
5. The method for preparing the abrasion-resistant and anti-fouling ceramic tile with starlight diamond effect according to claim 4, wherein the method comprises the following steps: the method comprises the following steps:
(1) pressing the green body powder into a green body, and drying at 80-250 ℃ for 40-45 min;
(2) spraying base glaze and surface glaze on the green body;
(3) spraying a required pattern on the overglaze layer by adopting an ink-jet printer to form an ink-jet layer;
(4) spraying glue on the ink spraying layer to form a glue layer;
(5) spreading starlight glaze particles on the glue layer by using a spreader to form a starlight glaze layer;
(6) sintering at 1200-1250 ℃ for 45-50min, and obtaining the wear-resistant antifouling ceramic tile with starlight diamond effect after post-treatment.
6. The method for preparing abrasion-resistant and anti-fouling ceramic tile with starlight diamond effect as claimed in claim 5, wherein: and (3) performing ball milling on the raw materials of the ground glaze in the step (2), sieving the ground glaze by using a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the ground glaze is 1.5.
7. The method for preparing the abrasion-resistant and anti-fouling ceramic tile with starlight diamond effect according to claim 5, wherein the method comprises the following steps: and (3) ball-milling the raw material of the overglaze in the step (2) and sieving the raw material by a 325-mesh sieve, and then adding an aqueous solution to ensure that the specific gravity of the overglaze is 1.5.
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| CN112209618B (en) * | 2020-09-29 | 2022-09-09 | 广东金牌陶瓷有限公司 | Velvet ceramic rock plate and preparation method thereof |
| CN112321332A (en) * | 2020-11-25 | 2021-02-05 | 珠海市斗门区旭日陶瓷有限公司 | Wear-resistant brick and production process thereof |
| CN112979349B (en) * | 2021-03-24 | 2022-10-25 | 江西金唯冠建材有限公司 | Wear-resistant antifouling ceramic starlight glazed brick and preparation method thereof |
| CN113845304B (en) * | 2021-08-12 | 2023-06-09 | 广东宏宇新型材料有限公司 | Ceramic tile with starry sky decorative effect and preparation method thereof |
| CN113666729B (en) * | 2021-08-20 | 2023-04-14 | 河源市东源鹰牌陶瓷有限公司 | Preparation method of white diamond glittering diamond glaze ceramic tile |
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| CN113999055B (en) * | 2021-10-29 | 2023-04-14 | 淄博金狮王科技陶瓷集团有限公司 | Antifouling wear-resistant ceramic tile and preparation method thereof |
| CN114315332A (en) * | 2022-01-06 | 2022-04-12 | 广东中宏创展陶瓷有限公司 | Production process of skin-softening diamond luxury porcelain |
| CN114853343B (en) * | 2022-07-06 | 2022-09-16 | 新明珠集团股份有限公司 | Starlight dry particle and preparation method thereof, glazed ceramic tile with starlight effect and preparation method and application thereof |
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| CN110357426A (en) * | 2019-06-24 | 2019-10-22 | 广东能强陶瓷有限公司 | A kind of starlight glaze and preparation method thereof |
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