CN105948503A - Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same - Google Patents

Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same Download PDF

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Publication number
CN105948503A
CN105948503A CN201610281839.6A CN201610281839A CN105948503A CN 105948503 A CN105948503 A CN 105948503A CN 201610281839 A CN201610281839 A CN 201610281839A CN 105948503 A CN105948503 A CN 105948503A
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China
Prior art keywords
glaze
wear
frit
abrasion
resistant clear
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Granted
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CN201610281839.6A
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Chinese (zh)
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CN105948503B (en
Inventor
金国庭
罗宏
程志坚
周燕
王华明
麦炳浩
李清莲
黄焱墉
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FENGCHENG DONGPENG CERAMIC Co Ltd
FOSHAN HUASHENGCHANG CERAMIC Co Ltd
Foshan Dongpeng Ceramic Co Ltd
Guangdong Dongpeng Holdings Co Ltd
Original Assignee
FENGCHENG DONGPENG CERAMIC Co Ltd
FOSHAN HUASHENGCHANG CERAMIC Co Ltd
Foshan Dongpeng Ceramic Co Ltd
Guangdong Dongpeng Holdings Co Ltd
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Priority to CN201610281839.6A priority Critical patent/CN105948503B/en
Publication of CN105948503A publication Critical patent/CN105948503A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

Abstract

The invention provides a wear-resistant transparent glaze and a method for preparing a glazed tile by utilizing the same. According to the components of the wear-resistant transparent glaze, spodumene, frit, potash feldspar, calcinedtalc, barium carbonate and zinc oxide are adopted as a fluxing agent, and the Si/Al ratio is adopted by utilizing wollastonite and kaolin. Meanwhile, the wear-resistant performance of the glaze is improved by adopting white corundum and zirconium oxide as a wear-resistant agent. The weight percentage of zirconia relative to the total weight of the raw materials of the wear-resistant transparent glaze is smaller than or equal to 0.2%. The above wear-resistant transparent glaze is applied onto the surface of a green body, and then the green body is polished after being sintered in a furnace to obtain a glazed tile product. Compared with the prior art, the wear-resistant transparent glaze is excellent in wear resistance, and can be used for preparing ceramic tiles with thin glaze layers. The decorative properties and the anti-pollution characteristics of obtained products are greatly improved. Meanwhile, the manufacturing cost of products is lower.

Description

A kind of abrasion-resistant clear glaze and the method using its preparation throwing glazed brick
Technical field
The present invention relates to architectural pottery technical field, particularly relate to a kind of abrasion-resistant clear glaze and use it to prepare The method throwing glazed brick.
Background technology
Throwing the building and ornament materials that glazed brick is a kind of top grade, it refers to have glaze layer on adobe surface, by throwing It is become the product with gloss or matte effect by light, and some of which goods use clear frit, at glaze Having texture under Ceng, texture can be realized by known various decorative means, the texture that such as cloth is formed, The texture etc. that stamp is formed.
But because current glaze wearability is a relatively hang-up of frustration industry.As floor decorative material Time, the anti-wear performance of glaze is had bigger requirement, is otherwise easy to mill flower, although this point is more existing Crystallite glass composite plate has bigger improvement, but the anti-wear performance of existing glaze is not met by demand.
To this, some enterprises are solving this problem by the mode thickening glaze layer, but along with glaze layer thickeies, for Adobe surface has the product of printed layer and has certain impact, thickeies along with glaze layer simultaneously, also increases and be manufactured into This, and because it needs rubbing down, thick glaze layer can close some bubbles, these bubbles are in rubbing down process meeting Presenting, appearance and antifouling property to end product impact, and this thickening glaze layer The problem that mode is also only capable of alleviating glaze anti-wear performance difference.
Summary of the invention
The problem proposed for background technology, the present invention provides a kind of abrasion-resistant clear glaze, by glaze Use white fused alumina to improve its anti-wear performance, use substantial amounts of spodumene as flux simultaneously, improve glaze Spreading property, and then make glaze the most smooth, solvent use zinc oxide to improve after glaze burns simultaneously Transparency, and being used in mixed way by white fused alumina and zinc oxide, solve glaze layer transparency and wearability The contradiction of energy.Possibly together with a small amount of zirconium in above-mentioned wear-resisting glaze, by zirconium to be converted into zirconic percent mass Ratio, mass percent need to be less than 0.2% in glaze for zirconium oxide, and general consumption is the 0.1-0.2% of raw materials quality. A small amount of zirconium can improve the anti-wear performance of glaze layer, is also unlikely to affect the effect of glaze layer simultaneously, the most right In needing to decorate under display glaze layer the clear frit of texture, this point is particularly important.
A kind of abrasion-resistant clear glaze, its raw material includes following component by mass percentage: 10~20% frit, 10~20% potassium feldspar, 15~40% spodumene, 5~20% burn Talcum, 8~15% brium carbonate, 10~20% wollastonite, 5~10% Kaolin, 0.5~5% white fused alumina, 5~10% zinc oxide, 0.1~0.2% zirconium oxide.
Above-mentioned frit can use known preparing ceramic clinker, and it is mainly flux effect.It is, of course, preferable to for having There is the functional frit of improved function, such as: for promoting its anti-wear performance, it is possible to use High-Alumina wear-resisting Frit, is more highly preferred to the raw material of frit and includes following component according to mass percent: 20~30% potassium feldspar, 3~6% The raw Talcum of wollastonite, 4~8%, 5~8% brium carbonate, 15~20% calcite, 18~22% quartz, 10-14% oxygen Change aluminum, 2~4% zinc oxide, 1~3% potassium carbonate, 1~2% strontium carbonate.
Frit is as a kind of flux, it is also desirable to it has higher anti-wear performance, therefore makes in this component Use larger amount of aluminium oxide, and use rare earth carbonate and zinc oxide as flux, make frit have higher Transparency and anti-wear performance, and the use of carbonate, in frit melting process can abundant aerofluxus, nothing CAB is in frit, and this is further such that grade free of pinholes is because of the defect of exhausting problem in subsequent clear glaze layer.
In the clear frit provided in the present invention, using strontium carbonate in its frit, addition is 1~2%, While not increasing the porosity of glaze layer, the wearability of clear frit can be effectively improved, improve clear frit further Toughness and hardness, and also improve the melting behaviour of high temperature cover-coat enamel, it is thus achieved that the good transparency and gloss Degree.
In order to make above-mentioned frit have more preferable using effect, its glass melting temperature in the preparation is 1450~1550 DEG C.Glass melting temperature is too low, it can be made to melt insufficient, and glass melting temperature is too high, can waste the energy.
The present invention also provides for a kind of method using the preparation of above-mentioned glaze to throw glazed brick, by above-mentioned glaze charity at base Surface, enters after kiln burns till, and carries out rubbing down processing and obtains and throw glaze brick product.
Preferably, in above method, can decorate base substrate before charity glaze, described decoration can Think any one or the combination in stamp, charity dicoration glaze, charity dry granular frit.
Preferably, in above method, stamp is ink-jet printed.
Preferably, in above method, before charity glaze, base substrate can be carried out rubbing down process.
Glazed thickness≤the 0.5mm throwing glaze tile product preferably, in above method, after rubbing down processing.Relatively Thin glaze layer, so that the decorative effect on base substrate is preferably presented, and is obtained relatively by rubbing down Thin glaze layer, can avoid bubble therein, needle pore defect, has preferable antifouling property.
Preferably, in above method, the abrading block hardness that rubbing down processing is used is higher than corundum.
Compared to the prior art, the abrasion-resistant clear glaze that the present invention provides has particularly preferred anti-wear performance, and And it can prepare the Ceramic Tiles product of thin glaze layer, have at the decoration performance of product, anti-pollution characteristic and carry more greatly Rise, and manufacturing cost is lower.
Detailed description of the invention
Below by some specific embodiments, the present invention will be described, needs following embodiment party is described Formula is exemplary only, and mostly is preferred embodiment.
Embodiment 1-10
With reference to table 1 below, table 1 below is the formula table (wt%) of the present embodiment 1-5 provided abrasion-resistant clear glaze
Table 1
Above glaze is carried out ball milling, charity on conventional ceramic brick adobe surface, the Ceramic Tiles adobe used For known adobe, glaze ball milling forms glaze slip, uses the mode drenching glaze to form about 1mm on adobe surface Glaze layer, then enter klining become, firing temperature 1200-1250 DEG C, firing period is 2.5 hours.Here need Illustrating, above in addition to glaze component, other technological process is architectural pottery and produces known mode i.e. Can, can suitably adjust at different production lines.Frit used herein above is known conventional ceramic Producing transparent middle temperature frit, its firing temperature being suitable for is 1150-1250 DEG C, certainly in different process requirements Time it can be adjusted.
After burning till, goods are carried out rubbing down processing, it is thus achieved that throw glaze brick product, test its performance.
Use the method for testing in GB/T4100-2006 that the anti-wear performance of goods glaze is tested, test knot Fruit display, anti-wear performance reaches 4 grades of requirements in standard, and in Ceramic Tiles goods famous with anti-wear performance Polished bricks remains basically stable, and goes for pedestrian's dealing ground decoration frequently and uses.
For the advantage of the present invention program is described, illustrated by two comparative examples.
Contrast enforcement 1
Embodiment 1 is selected to compare.
In this comparative example, the flux material sodium that spodumene replaces with in glaze formula component routine is long Stone, removes white fused alumina simultaneously, and the ratio of wollastonite being heightened is 15 (wt%).
Test result shows, the anti-wear performance of its glaze layer is only capable of reach in standard 3 grades.
Comparative example 2
Embodiment 3 is selected to compare
In the present embodiment, spodumene replacing with albite, result shows that the anti-wear performance of goods glaze layer has Bigger lifting, but glaze layer is second-rate, has more needle pore defect, not resistant, and flatness is poor.
Embodiment 6-8
In this is class embodiment, remaining component is consistent with embodiment 4, except that the frit used is such as The raw material of lower component prepares after 1450-1550 DEG C melted.Recipe ingredient is: 20~30% potassium feldspar, 3~6% The raw Talcum of wollastonite, 4~8%, 5~8% brium carbonate, 15~20% calcite, 18~22% quartz, 10-14% oxygen Change aluminum, 2~4% zinc oxide, 1~3% potassium carbonate, 1~2% strontium carbonate.Specifically:
Embodiment 6-8 frit component such as table 2 below (wt%)
Table 2
Test its anti-wear performance, reach 5 grades, and glaze is the most smooth, can be with rubbing down to glazed thickness 0.3mm even below.This is because frit is as a kind of flux, it is also desirable to it has higher wearability Can, in this component, therefore use larger amount of aluminium oxide, and use rare earth carbonate and zinc oxide conduct Flux, makes frit have higher transparency and an anti-wear performance, and the use of carbonate, melt at frit During can abundant aerofluxus, without CAB in frit, this is further such that needleless in subsequent clear glaze layer Holes etc. are because of the defect of exhausting problem.
In the wear-resisting glaze that series embodiment provides, using strontium carbonate in its frit, addition is 1~2%, While not increasing the porosity of glaze layer, the wearability of clear frit can be effectively improved, improve transparent further The toughness of glaze and hardness, and also improve the melting behaviour of high temperature cover-coat enamel, it is thus achieved that the good transparency and light Pool degree.
Embodiment 9
In the present embodiment, it is provided that the side of glazed brick is thrown in a kind of abrasion-resistant clear glaze preparation using embodiment 8 to provide Method, it comprises the steps:
(1) use known base substrate raw material, carry out mixing and ball milling, mist projection granulating, and compressing;
(2) it is dried green compact, carries out throwing base, and execute ground-coat enamel, then drench cosmetic cover-coat enamel;
(3) screen printing is used to carry out printing ornament;
(4) adobe of step (3) spooned state abrasion-resistant clear glaze, drench glaze amount be 360g (preparation be The brick of 800X800mm);
(5) the adobe employing oiliness after drenching glaze is oozed colored ink jet and is carried out oozing flower decoration, and high temperature burns till;
(6) adobe after burning till uses diamond module to carry out flat polish;Firing temperature is 1180 DEG C, burns The one-tenth cycle is 2.5 hours;
(7) thick, finishing polish, refines limit, it is thus achieved that ooze the throwing glaze brick product of colored effect.
In one embodiment of the invention, the adobe used itself has texture, after it is carried out rubbing down, The texture making its cloth be formed highlights further, the abrasion-resistant clear glaze of the then charity embodiment of the present invention 6 preparation Material, then enters klining, after rubbing down is processed, it is thus achieved that throwing glaze brick product, it is entered by the texture in adobe Luggage is adornd, it is thus achieved that the effect of similar stone material, and because surface covers one layer of glaze layer, reflecting feel and decoration effect Fruit is more preferably.
Certainly, decorating method can be chosen as charity dicoration glaze and (such as has the glaze of metallic luster here Material products), or the modes such as charity dry granular, stamp that carry out it decorate.
The know-why of the present invention is described above in association with specific embodiment.These describe and are intended merely to explain this The principle of invention, and limiting the scope of the invention can not be construed to by any way.Based on herein Explaining, those skilled in the art need not pay performing creative labour can associate other tool of the present invention Body embodiment, within these modes fall within protection scope of the present invention.

Claims (10)

1. an abrasion-resistant clear glaze, its use spodumene, frit, potassium feldspar, burning Talcum, brium carbonate and Zinc oxide as flux, uses wollastonite and Kaolin regulation silica alumina ratio, use white fused alumina and zirconium oxide as Anti-wear agent improves the anti-wear performance of glaze, and described zirconium oxide accounts for the quality of described abrasion-resistant clear glaze raw material gross weight Percent is less than or equal to 0.2%.
A kind of abrasion-resistant clear glaze the most according to claim 1, it is characterised in that described abrasion-resistant clear The raw material of glaze includes following component by mass percentage: 10~20% frit, 10~20% potassium feldspar, 15~40% Spodumene, 5~20% burn Talcum, 8~15% brium carbonate, 10~20% wollastonite, 5~10% Kaolin, 0.5~5% White fused alumina, 5~10% zinc oxide, 0.1~0.2% zirconium oxide.
A kind of abrasion-resistant clear glaze the most according to claim 1, it is characterised in that described frit is high The wear-resisting frit of aluminum matter.
A kind of abrasion-resistant clear glaze the most according to claim 3, it is characterised in that described High-Alumina is resistance to The raw material of mill frit includes following component according to mass percent: 20~30% potassium feldspar, 3~6% wollastonite, 4~8% raw Talcum, 5~8% brium carbonate, 15~20% calcite, 18~22% quartz, 10-14% aluminium oxide, 2~4% Zinc oxide, 1~3% potassium carbonate, 1~2% strontium carbonate.
A kind of abrasion-resistant clear glaze the most according to claim 4, it is characterised in that described High-Alumina is resistance to The glass melting temperature of mill frit is 1450~1550 DEG C.
6. one kind uses abrasion-resistant clear glaze preparation described in any one in the claims 1-5 to throw glazed brick Method, by above-mentioned abrasion-resistant clear glaze charity in billet surface, enters after kiln burns till, carries out rubbing down processing and obtain Glaze brick product must be thrown.
7. the method that glazed brick is thrown in preparation as claimed in claim 6, it is characterised in that wear-resisting in described charity The step that base substrate is carried out rubbing down process is also included before marzacotto.
8. the method that glazed brick is thrown in preparation as claimed in claim 6, it is characterised in that wear-resisting in described charity Also include the step that base substrate is decorated before marzacotto, described decoration be stamp, charity dicoration glaze, Any one or combination in charity dry granular frit.
9. the method that glazed brick is thrown in preparation as claimed in claim 8, it is characterised in that base substrate is entered described The step that base substrate is carried out rubbing down process is also included before luggage decorations.
10. the method that glazed brick is thrown in preparation as claimed in claim 6, it is characterised in that after the processing of described rubbing down Throw glaze tile product glazed thickness≤0.5mm.
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CN106495742A (en) * 2016-11-07 2017-03-15 揭阳市揭东易成陶瓷实业有限公司 Anti- wax stone bonding glaze, anti-wax stone bonding pottery and its preparation technology
CN106565089A (en) * 2016-11-03 2017-04-19 广州凯耀资产管理有限公司 Ceramic glaze and preparation method of same
CN106587621A (en) * 2016-11-11 2017-04-26 广东道氏技术股份有限公司 Diamond glaze with super abrasion resistance and three-dimensional decorative effect
CN107021634A (en) * 2017-05-24 2017-08-08 禹州市神器钧窑有限公司 A kind of red glaze of an ancient unit of weight
CN107032833A (en) * 2017-05-17 2017-08-11 佛山欧神诺陶瓷股份有限公司 A kind of on-slip brick and preparation method thereof
CN107555948A (en) * 2017-09-06 2018-01-09 福建省德化县嘉威陶瓷有限公司 A kind of abrasion-resistant ceramic product and its manufacturing process
CN107628824A (en) * 2017-09-27 2018-01-26 禹州市正玉钧窑有限公司 A kind of pottery glazing process
CN107963814A (en) * 2017-11-16 2018-04-27 蒙娜丽莎集团股份有限公司 Compound glaze, the wear-resisting porcelain Antique Imitation Tiles of compound glaze slip and the soft face of 4-8 degree
CN108975708A (en) * 2018-08-06 2018-12-11 杭州景杰陶瓷科技有限公司 A kind of high rigidity imitates the secret color glaze of Over-summer cultivation household china and its manufacture craft
CN109265005A (en) * 2018-10-26 2019-01-25 广东能强陶瓷有限公司 A kind of environmental protection sheen Ceramic Tiles and preparation method
CN109354413A (en) * 2018-12-12 2019-02-19 清远市坚瓷陶瓷有限公司 A kind of dry granular vitreous brick and preparation method thereof
CN109455936A (en) * 2019-01-07 2019-03-12 佛山市东鹏陶瓷有限公司 Silk texture and anti-skidding unglazed glaze, preparation method and the ceramic tile using it
CN109608045A (en) * 2019-02-18 2019-04-12 青田县南方陶瓷原料有限公司 A kind of wear-resisting high-hardness ceramic glaze and preparation method thereof
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CN106565089A (en) * 2016-11-03 2017-04-19 广州凯耀资产管理有限公司 Ceramic glaze and preparation method of same
CN106495742A (en) * 2016-11-07 2017-03-15 揭阳市揭东易成陶瓷实业有限公司 Anti- wax stone bonding glaze, anti-wax stone bonding pottery and its preparation technology
CN106587621A (en) * 2016-11-11 2017-04-26 广东道氏技术股份有限公司 Diamond glaze with super abrasion resistance and three-dimensional decorative effect
CN107032833B (en) * 2017-05-17 2020-03-27 佛山欧神诺陶瓷有限公司 Anti-slip brick and preparation method thereof
CN107032833A (en) * 2017-05-17 2017-08-11 佛山欧神诺陶瓷股份有限公司 A kind of on-slip brick and preparation method thereof
CN107021634A (en) * 2017-05-24 2017-08-08 禹州市神器钧窑有限公司 A kind of red glaze of an ancient unit of weight
CN107555948A (en) * 2017-09-06 2018-01-09 福建省德化县嘉威陶瓷有限公司 A kind of abrasion-resistant ceramic product and its manufacturing process
CN107555948B (en) * 2017-09-06 2020-06-02 福建省德化县嘉威陶瓷有限公司 Wear-resistant ceramic product and manufacturing process thereof
CN107628824A (en) * 2017-09-27 2018-01-26 禹州市正玉钧窑有限公司 A kind of pottery glazing process
CN107628824B (en) * 2017-09-27 2020-10-13 禹州市正玉钧窑有限公司 Jun porcelain glazing process
CN107963814A (en) * 2017-11-16 2018-04-27 蒙娜丽莎集团股份有限公司 Compound glaze, the wear-resisting porcelain Antique Imitation Tiles of compound glaze slip and the soft face of 4-8 degree
CN107963814B (en) * 2017-11-16 2021-05-07 蒙娜丽莎集团股份有限公司 Composite glaze, composite glaze slip and 4-8 degree soft surface wear-resistant porcelain archaized brick
WO2020000849A1 (en) * 2018-06-29 2020-01-02 佛山石湾鹰牌陶瓷有限公司 Wear-resistant dry particle of soft brick with waxy luster texture and soft retro ceramic brick
CN108975708A (en) * 2018-08-06 2018-12-11 杭州景杰陶瓷科技有限公司 A kind of high rigidity imitates the secret color glaze of Over-summer cultivation household china and its manufacture craft
CN109265005A (en) * 2018-10-26 2019-01-25 广东能强陶瓷有限公司 A kind of environmental protection sheen Ceramic Tiles and preparation method
CN109354413B (en) * 2018-12-12 2020-04-14 泰州市津专知识产权服务有限公司 Dry-grain glaze ceramic tile and preparation method thereof
CN109354413A (en) * 2018-12-12 2019-02-19 清远市坚瓷陶瓷有限公司 A kind of dry granular vitreous brick and preparation method thereof
CN109455936A (en) * 2019-01-07 2019-03-12 佛山市东鹏陶瓷有限公司 Silk texture and anti-skidding unglazed glaze, preparation method and the ceramic tile using it
CN109608045A (en) * 2019-02-18 2019-04-12 青田县南方陶瓷原料有限公司 A kind of wear-resisting high-hardness ceramic glaze and preparation method thereof
CN112341166A (en) * 2020-12-04 2021-02-09 淄博昊祥模具科技有限公司 Ceramic hand mold coating suitable for nitrile rubber glove production and preparation method thereof

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