CN105948503A - Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same - Google Patents
Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same Download PDFInfo
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- CN105948503A CN105948503A CN201610281839.6A CN201610281839A CN105948503A CN 105948503 A CN105948503 A CN 105948503A CN 201610281839 A CN201610281839 A CN 201610281839A CN 105948503 A CN105948503 A CN 105948503A
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- China
- Prior art keywords
- glaze
- wear
- frit
- abrasion
- resistant
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention provides a wear-resistant transparent glaze and a method for preparing a glazed tile by utilizing the same. According to the components of the wear-resistant transparent glaze, spodumene, frit, potash feldspar, calcinedtalc, barium carbonate and zinc oxide are adopted as a fluxing agent, and the Si/Al ratio is adopted by utilizing wollastonite and kaolin. Meanwhile, the wear-resistant performance of the glaze is improved by adopting white corundum and zirconium oxide as a wear-resistant agent. The weight percentage of zirconia relative to the total weight of the raw materials of the wear-resistant transparent glaze is smaller than or equal to 0.2%. The above wear-resistant transparent glaze is applied onto the surface of a green body, and then the green body is polished after being sintered in a furnace to obtain a glazed tile product. Compared with the prior art, the wear-resistant transparent glaze is excellent in wear resistance, and can be used for preparing ceramic tiles with thin glaze layers. The decorative properties and the anti-pollution characteristics of obtained products are greatly improved. Meanwhile, the manufacturing cost of products is lower.
Description
Technical field
The present invention relates to architectural pottery technical field, particularly relate to a kind of abrasion-resistant clear glaze and use it to prepare
The method throwing glazed brick.
Background technology
Throwing the building and ornament materials that glazed brick is a kind of top grade, it refers to have glaze layer on adobe surface, by throwing
It is become the product with gloss or matte effect by light, and some of which goods use clear frit, at glaze
Having texture under Ceng, texture can be realized by known various decorative means, the texture that such as cloth is formed,
The texture etc. that stamp is formed.
But because current glaze wearability is a relatively hang-up of frustration industry.As floor decorative material
Time, the anti-wear performance of glaze is had bigger requirement, is otherwise easy to mill flower, although this point is more existing
Crystallite glass composite plate has bigger improvement, but the anti-wear performance of existing glaze is not met by demand.
To this, some enterprises are solving this problem by the mode thickening glaze layer, but along with glaze layer thickeies, for
Adobe surface has the product of printed layer and has certain impact, thickeies along with glaze layer simultaneously, also increases and be manufactured into
This, and because it needs rubbing down, thick glaze layer can close some bubbles, these bubbles are in rubbing down process meeting
Presenting, appearance and antifouling property to end product impact, and this thickening glaze layer
The problem that mode is also only capable of alleviating glaze anti-wear performance difference.
Summary of the invention
The problem proposed for background technology, the present invention provides a kind of abrasion-resistant clear glaze, by glaze
Use white fused alumina to improve its anti-wear performance, use substantial amounts of spodumene as flux simultaneously, improve glaze
Spreading property, and then make glaze the most smooth, solvent use zinc oxide to improve after glaze burns simultaneously
Transparency, and being used in mixed way by white fused alumina and zinc oxide, solve glaze layer transparency and wearability
The contradiction of energy.Possibly together with a small amount of zirconium in above-mentioned wear-resisting glaze, by zirconium to be converted into zirconic percent mass
Ratio, mass percent need to be less than 0.2% in glaze for zirconium oxide, and general consumption is the 0.1-0.2% of raw materials quality.
A small amount of zirconium can improve the anti-wear performance of glaze layer, is also unlikely to affect the effect of glaze layer simultaneously, the most right
In needing to decorate under display glaze layer the clear frit of texture, this point is particularly important.
A kind of abrasion-resistant clear glaze, its raw material includes following component by mass percentage: 10～20% frit,
10～20% potassium feldspar, 15～40% spodumene, 5～20% burn Talcum, 8～15% brium carbonate, 10～20% wollastonite,
5～10% Kaolin, 0.5～5% white fused alumina, 5～10% zinc oxide, 0.1～0.2% zirconium oxide.
Above-mentioned frit can use known preparing ceramic clinker, and it is mainly flux effect.It is, of course, preferable to for having
There is the functional frit of improved function, such as: for promoting its anti-wear performance, it is possible to use High-Alumina wear-resisting
Frit, is more highly preferred to the raw material of frit and includes following component according to mass percent: 20～30% potassium feldspar, 3～6%
The raw Talcum of wollastonite, 4～8%, 5～8% brium carbonate, 15～20% calcite, 18～22% quartz, 10-14% oxygen
Change aluminum, 2～4% zinc oxide, 1～3% potassium carbonate, 1～2% strontium carbonate.
Frit is as a kind of flux, it is also desirable to it has higher anti-wear performance, therefore makes in this component
Use larger amount of aluminium oxide, and use rare earth carbonate and zinc oxide as flux, make frit have higher
Transparency and anti-wear performance, and the use of carbonate, in frit melting process can abundant aerofluxus, nothing
CAB is in frit, and this is further such that grade free of pinholes is because of the defect of exhausting problem in subsequent clear glaze layer.
In the clear frit provided in the present invention, using strontium carbonate in its frit, addition is 1～2%,
While not increasing the porosity of glaze layer, the wearability of clear frit can be effectively improved, improve clear frit further
Toughness and hardness, and also improve the melting behaviour of high temperature cover-coat enamel, it is thus achieved that the good transparency and gloss
Degree.
In order to make above-mentioned frit have more preferable using effect, its glass melting temperature in the preparation is
1450～1550 DEG C.Glass melting temperature is too low, it can be made to melt insufficient, and glass melting temperature is too high, can waste the energy.
The present invention also provides for a kind of method using the preparation of above-mentioned glaze to throw glazed brick, by above-mentioned glaze charity at base
Surface, enters after kiln burns till, and carries out rubbing down processing and obtains and throw glaze brick product.
Preferably, in above method, can decorate base substrate before charity glaze, described decoration can
Think any one or the combination in stamp, charity dicoration glaze, charity dry granular frit.
Preferably, in above method, stamp is ink-jet printed.
Preferably, in above method, before charity glaze, base substrate can be carried out rubbing down process.
Glazed thickness≤the 0.5mm throwing glaze tile product preferably, in above method, after rubbing down processing.Relatively
Thin glaze layer, so that the decorative effect on base substrate is preferably presented, and is obtained relatively by rubbing down
Thin glaze layer, can avoid bubble therein, needle pore defect, has preferable antifouling property.
Preferably, in above method, the abrading block hardness that rubbing down processing is used is higher than corundum.
Compared to the prior art, the abrasion-resistant clear glaze that the present invention provides has particularly preferred anti-wear performance, and
And it can prepare the Ceramic Tiles product of thin glaze layer, have at the decoration performance of product, anti-pollution characteristic and carry more greatly
Rise, and manufacturing cost is lower.
Detailed description of the invention
Below by some specific embodiments, the present invention will be described, needs following embodiment party is described
Formula is exemplary only, and mostly is preferred embodiment.
Embodiment 1-10
With reference to table 1 below, table 1 below is the formula table (wt%) of the present embodiment 1-5 provided abrasion-resistant clear glaze
Table 1
Above glaze is carried out ball milling, charity on conventional ceramic brick adobe surface, the Ceramic Tiles adobe used
For known adobe, glaze ball milling forms glaze slip, uses the mode drenching glaze to form about 1mm on adobe surface
Glaze layer, then enter klining become, firing temperature 1200-1250 DEG C, firing period is 2.5 hours.Here need
Illustrating, above in addition to glaze component, other technological process is architectural pottery and produces known mode i.e.
Can, can suitably adjust at different production lines.Frit used herein above is known conventional ceramic
Producing transparent middle temperature frit, its firing temperature being suitable for is 1150-1250 DEG C, certainly in different process requirements
Time it can be adjusted.
After burning till, goods are carried out rubbing down processing, it is thus achieved that throw glaze brick product, test its performance.
Use the method for testing in GB/T4100-2006 that the anti-wear performance of goods glaze is tested, test knot
Fruit display, anti-wear performance reaches 4 grades of requirements in standard, and in Ceramic Tiles goods famous with anti-wear performance
Polished bricks remains basically stable, and goes for pedestrian's dealing ground decoration frequently and uses.
For the advantage of the present invention program is described, illustrated by two comparative examples.
Contrast enforcement 1
Embodiment 1 is selected to compare.
In this comparative example, the flux material sodium that spodumene replaces with in glaze formula component routine is long
Stone, removes white fused alumina simultaneously, and the ratio of wollastonite being heightened is 15 (wt%).
Test result shows, the anti-wear performance of its glaze layer is only capable of reach in standard 3 grades.
Comparative example 2
Embodiment 3 is selected to compare
In the present embodiment, spodumene replacing with albite, result shows that the anti-wear performance of goods glaze layer has
Bigger lifting, but glaze layer is second-rate, has more needle pore defect, not resistant, and flatness is poor.
Embodiment 6-8
In this is class embodiment, remaining component is consistent with embodiment 4, except that the frit used is such as
The raw material of lower component prepares after 1450-1550 DEG C melted.Recipe ingredient is: 20～30% potassium feldspar, 3～6%
The raw Talcum of wollastonite, 4～8%, 5～8% brium carbonate, 15～20% calcite, 18～22% quartz, 10-14% oxygen
Change aluminum, 2～4% zinc oxide, 1～3% potassium carbonate, 1～2% strontium carbonate.Specifically:
Embodiment 6-8 frit component such as table 2 below (wt%)
Table 2
Test its anti-wear performance, reach 5 grades, and glaze is the most smooth, can be with rubbing down to glazed thickness
0.3mm even below.This is because frit is as a kind of flux, it is also desirable to it has higher wearability
Can, in this component, therefore use larger amount of aluminium oxide, and use rare earth carbonate and zinc oxide conduct
Flux, makes frit have higher transparency and an anti-wear performance, and the use of carbonate, melt at frit
During can abundant aerofluxus, without CAB in frit, this is further such that needleless in subsequent clear glaze layer
Holes etc. are because of the defect of exhausting problem.
In the wear-resisting glaze that series embodiment provides, using strontium carbonate in its frit, addition is 1～2%,
While not increasing the porosity of glaze layer, the wearability of clear frit can be effectively improved, improve transparent further
The toughness of glaze and hardness, and also improve the melting behaviour of high temperature cover-coat enamel, it is thus achieved that the good transparency and light
Pool degree.
Embodiment 9
In the present embodiment, it is provided that the side of glazed brick is thrown in a kind of abrasion-resistant clear glaze preparation using embodiment 8 to provide
Method, it comprises the steps:
(1) use known base substrate raw material, carry out mixing and ball milling, mist projection granulating, and compressing；
(2) it is dried green compact, carries out throwing base, and execute ground-coat enamel, then drench cosmetic cover-coat enamel；
(3) screen printing is used to carry out printing ornament；
(4) adobe of step (3) spooned state abrasion-resistant clear glaze, drench glaze amount be 360g (preparation be
The brick of 800X800mm)；
(5) the adobe employing oiliness after drenching glaze is oozed colored ink jet and is carried out oozing flower decoration, and high temperature burns till；
(6) adobe after burning till uses diamond module to carry out flat polish；Firing temperature is 1180 DEG C, burns
The one-tenth cycle is 2.5 hours；
(7) thick, finishing polish, refines limit, it is thus achieved that ooze the throwing glaze brick product of colored effect.
In one embodiment of the invention, the adobe used itself has texture, after it is carried out rubbing down,
The texture making its cloth be formed highlights further, the abrasion-resistant clear glaze of the then charity embodiment of the present invention 6 preparation
Material, then enters klining, after rubbing down is processed, it is thus achieved that throwing glaze brick product, it is entered by the texture in adobe
Luggage is adornd, it is thus achieved that the effect of similar stone material, and because surface covers one layer of glaze layer, reflecting feel and decoration effect
Fruit is more preferably.
Certainly, decorating method can be chosen as charity dicoration glaze and (such as has the glaze of metallic luster here
Material products), or the modes such as charity dry granular, stamp that carry out it decorate.
The know-why of the present invention is described above in association with specific embodiment.These describe and are intended merely to explain this
The principle of invention, and limiting the scope of the invention can not be construed to by any way.Based on herein
Explaining, those skilled in the art need not pay performing creative labour can associate other tool of the present invention
Body embodiment, within these modes fall within protection scope of the present invention.
Claims (10)
1. an abrasion-resistant clear glaze, its use spodumene, frit, potassium feldspar, burning Talcum, brium carbonate and
Zinc oxide as flux, uses wollastonite and Kaolin regulation silica alumina ratio, use white fused alumina and zirconium oxide as
Anti-wear agent improves the anti-wear performance of glaze, and described zirconium oxide accounts for the quality of described abrasion-resistant clear glaze raw material gross weight
Percent is less than or equal to 0.2%.
A kind of abrasion-resistant clear glaze the most according to claim 1, it is characterised in that described abrasion-resistant clear
The raw material of glaze includes following component by mass percentage: 10～20% frit, 10～20% potassium feldspar, 15～40%
Spodumene, 5～20% burn Talcum, 8～15% brium carbonate, 10～20% wollastonite, 5～10% Kaolin, 0.5～5%
White fused alumina, 5～10% zinc oxide, 0.1～0.2% zirconium oxide.
A kind of abrasion-resistant clear glaze the most according to claim 1, it is characterised in that described frit is high
The wear-resisting frit of aluminum matter.
A kind of abrasion-resistant clear glaze the most according to claim 3, it is characterised in that described High-Alumina is resistance to
The raw material of mill frit includes following component according to mass percent: 20～30% potassium feldspar, 3～6% wollastonite,
4～8% raw Talcum, 5～8% brium carbonate, 15～20% calcite, 18～22% quartz, 10-14% aluminium oxide, 2～4%
Zinc oxide, 1～3% potassium carbonate, 1～2% strontium carbonate.
A kind of abrasion-resistant clear glaze the most according to claim 4, it is characterised in that described High-Alumina is resistance to
The glass melting temperature of mill frit is 1450～1550 DEG C.
6. one kind uses abrasion-resistant clear glaze preparation described in any one in the claims 1-5 to throw glazed brick
Method, by above-mentioned abrasion-resistant clear glaze charity in billet surface, enters after kiln burns till, carries out rubbing down processing and obtain
Glaze brick product must be thrown.
7. the method that glazed brick is thrown in preparation as claimed in claim 6, it is characterised in that wear-resisting in described charity
The step that base substrate is carried out rubbing down process is also included before marzacotto.
8. the method that glazed brick is thrown in preparation as claimed in claim 6, it is characterised in that wear-resisting in described charity
Also include the step that base substrate is decorated before marzacotto, described decoration be stamp, charity dicoration glaze,
Any one or combination in charity dry granular frit.
9. the method that glazed brick is thrown in preparation as claimed in claim 8, it is characterised in that base substrate is entered described
The step that base substrate is carried out rubbing down process is also included before luggage decorations.
10. the method that glazed brick is thrown in preparation as claimed in claim 6, it is characterised in that after the processing of described rubbing down
Throw glaze tile product glazed thickness≤0.5mm.
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Address after: 528031 Chancheng, Foshan District, Jiangwan, No. three, No., layer 8, layer two Applicant after: Foshan Dongpeng Ceramic Co., Ltd. Applicant after: Guangdong Dongpeng Holdings Co., Ltd. Applicant after: Fengcheng Dongpeng Ceramic Co., Ltd. Applicant after: Donghua Foshan New Material Co., Ltd. Address before: 528031 Chancheng, Foshan District, Jiangwan, No. three, No., layer 8, layer two Applicant before: Foshan Dongpeng Ceramic Co., Ltd. Applicant before: Fengcheng Dongpeng Ceramic Co., Ltd. Applicant before: Foshan Huashengchang Ceramic Co., Ltd. Applicant before: Guangdong Dongpeng Holdings Co., Ltd. |
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