CN111606565A - Ceramic glaze with anti-skid matte effect - Google Patents
Ceramic glaze with anti-skid matte effect Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/0072—Heat treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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Abstract
The invention discloses a ceramic glaze with an anti-skid effect, which comprises the following raw materials in percentage by mass: nano SiO235-50% of nano Y2O3‑Sb2O3‑ZrO215-20% of complex phase material and K2O 5～10%、Na2The ceramic glaze disclosed by the invention can integrally protect the smooth and exquisite style characteristics of ceramics, does not influence the appearance of color, improves the friction coefficient of the surface of the ceramics while achieving a good decorative effect, plays a role in skid resistance, and is very suitable for ceramic crafts.
Description
Technical Field
The invention belongs to the field of ceramic decorative materials, and particularly relates to a ceramic glaze with an anti-skidding matte effect and a preparation method thereof.
Background
The ceramic is an art form which appears at the earliest in the human civilization history, and the ceramic history of China is long, and the manufacturing technology and the art creation of the ceramic reach high levels until the development is so far, and the ceramic is well known because of having high art value.
Ceramic artware is an art variety integrating functions of viewing, playing, using, collecting and the like, however, as the ceramic surface is smooth and fragile in texture, and is easily polluted by dust and oil stains in the using process, the ceramic artware is easily slipped and broken when being used for viewing or playing porcelain, and in recent years, technologists are constantly dedicated to finding oil stain-proof and anti-slip process manufacturing methods.
The existing anti-slip process is mainly applied to building ceramics such as ceramic tiles, for example, anti-slip agents are coated on the surface of finished floor tiles to improve the friction coefficient of the surface of a tile body, but an anti-slip layer formed by the anti-slip agents is gradually worn along with the prolonging of the service time, so that the anti-slip process is not suitable for ceramic crafts, and the anti-slip agents applied to the surface of the ceramic crafts are easy to damage the color of the surface of the ceramic crafts, and some anti-slip agents are even corrosive, so that the artistic expression of the ceramic crafts is influenced. The other anti-slip process applied to the building ceramic is to manufacture the surface of a brick body into a structure with uneven relief to realize anti-slip, but if the structure with uneven relief is applied to the ceramic artware, the characters or the paintings on the surface of the ceramic artware can be unclear, the overall style becomes rough, and the characteristics of fine and smooth gloss on the surface of the ceramic artware are lost, so that the overall decorative effect of the ceramic artware is damaged, and the attractiveness is influenced.
Disclosure of Invention
The invention aims to provide a ceramic glaze with an anti-skid effect, which is different from the existing anti-skid coating, can not form a remarkable concave-convex effect, can integrally protect the smooth and exquisite style characteristics of ceramics, does not influence the appearance of color, improves the friction coefficient of the surface of the ceramics while achieving a good decorative effect, plays a role in skid resistance, and is very suitable for ceramic crafts.
The purpose of the invention is realized by the following technical scheme:
the invention provides a ceramic glaze with an anti-skid effect, which comprises the following raw materials in percentage by mass: nano SiO235-50% of nano Y2O3-Sb2O3-ZrO215-20% of complex phase material and K2O 5～10%、Na2O10～15%、BaO5～10%、MgO2～5%、ZnO 5～10%；
Wherein the nano Y2O3-Sb2O3-ZrO2The preparation method of the complex phase material comprises the following steps:
will Y2O3And Sb2O3Uniformly mixing, adding a hydrochloric acid solution, and slowly adding ZrO at a stirring speed of 300-500 r/min2Obtaining mixed liquid, strongly stirring for 10-14 h at the stirring speed, filtering, washing filter residue for 3 times by using sodium hydroxide solution, and then washing by using water5 times, placing the mixture in a ball mill, taking water as a dispersion medium, carrying out wet ball milling for 16-20 hours to obtain mixed powder, drying the mixed powder at 120 ℃, then placing the dried mixed powder at 1250-1500 ℃ for calcining for 10-12 hours to obtain a multiphase material, and carrying out superfine grinding on the multiphase material to obtain the nano multiphase material, wherein Y is Y2O3、Sb2O3And ZrO2The mass ratio of (A) to (B) is 2-3: 0.5-1: 5-8.
In a preferred embodiment of the present invention, the hydrochloric acid solution has a pH of 1 and the sodium hydroxide solution has a pH of 8.
As a preferred embodiment of the present invention, said Y is2O3、Sb2O3And ZrO2The mass ratio of (A) to (B) is 2.5:0.8: 6.
As a preferred embodiment of the invention, the ceramic glaze can also be added with a color-based material.
As a preferred embodiment of the invention, the ceramic glaze is composed of the following raw materials in percentage by mass: nano SiO242% nano Y2O3-Sb2O3-ZrO2Multiple phase material 18%, K2O 6.5%、Na2O 12.5%、BaO 7.5%、MgO4.5%、ZnO 9%。
As a preferred embodiment of the invention, the ceramic glaze can also be added with a color-based material.
The invention also provides a preparation method of the ceramic glaze with the anti-skid effect, which comprises the following steps: weighing the raw materials according to the formula, mixing, crushing, sieving with a 200-mesh sieve, adding water, ball-milling to mix uniformly, and preparing glaze with the concentration of 32-35%.
The invention also provides an application method of the ceramic glaze with the anti-skid effect, which comprises the following steps: glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.0-2.5h, 1000-1250 ℃, firing is 3-3.5h, and then naturally cooling.
The invention has the beneficial effects that:
(1) the ceramic glaze prepared by the invention contains Y2O3-Sb2O3-ZrO2Complex phase materials, their use in glazesThe raw materials have good compatibility, can form crystals in a chimeric state with other raw materials, and form tiny, uniform and stable bulges in the firing process, wherein the bulges are bulges with a microscopic nano structure, the intervals are uniform and regular, the appearance expressive force of a ceramic finished product cannot be influenced visually, and the decorative effect and style of the surface of the ceramic cannot be influenced. (2) The ceramic glaze prepared by the invention is simple to use, does not need to change the manufacturing process of the existing ceramic process, and only can replace the ceramic glaze; and the formed nanoscale convex structure is durable, and the anti-skid effect is durable because the convex structure is generated in the ceramic sintering process and is not easy to wear like a coating.
(3) The ceramic glaze prepared by the invention forms the nano convex structure, and the surface of the fired ceramic forms light diffuse reflection due to the nano convex structure, so that a soft matte effect is formed, and the visual effect is softer.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below in conjunction with the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All embodiments obtained by a person of ordinary skill in the art based on the embodiments of the present invention without any creative efforts shall fall within the protection scope of the present invention.
Example 1
The ceramic glaze is prepared according to the following formula and method.
Preparing raw materials according to mass percent: nano SiO250% nano Y2O3-Sb2O3-ZrO215% of complex phase material, K2O5%、Na2O 15%、BaO 5%、MgO 5%、ZnO 5 %；
Wherein the nano Y2O3-Sb2O3-ZrO2The preparation method of the complex phase material comprises the following steps:
will Y2O3And Sb2O3Mixing, adding hydrochloric acid solution with pH of 1, stirringZrO is slowly added at the stirring speed of 500r/min2Obtaining mixed liquor, strongly stirring for 10h at the stirring speed, filtering, washing filter residue for 3 times by using a sodium hydroxide solution with the pH value of 8, then washing for 5 times by using water, placing the mixture in a ball mill, using water as a dispersion medium, carrying out wet ball milling for 20h to obtain mixed powder, drying the mixed powder at 120 ℃, then placing the dried mixed powder at 1250 ℃ for calcining for 12h to obtain a multiphase material, and carrying out superfine grinding on the multiphase material to obtain the nano multiphase material, wherein Y is2O3、Sb2O3And ZrO2The mass ratio of (A) to (B) is 2:1: 5.
Weighing the raw materials according to a formula, adding a red color base material containing iron oxide red, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball-milling to uniformly mix to prepare a glaze material with the concentration of 32%. Glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.5 hours, 1000 ℃, firing is 3.5 hours, and then natural cooling is carried out.
Example 2
The ceramic glaze is prepared according to the following formula and method.
Preparing raw materials according to mass percent: nano SiO235% of nano Y2O3-Sb2O3-ZrO2Composite material 20%, K2O10%、Na2O 10%、BaO10%、MgO5%、ZnO 10%；
Wherein the nano Y2O3-Sb2O3-ZrO2The preparation method of the complex phase material comprises the following steps:
will Y2O3And Sb2O3Uniformly mixing, adding hydrochloric acid solution with the pH value of 1, slowly adding ZrO2 at the stirring speed of 300r/min to obtain mixed solution, strongly stirring at the stirring speed for 14h, filtering, washing filter residues with sodium hydroxide solution with the pH value of 8 for 3 times, then washing with water for 5 times, placing in a ball mill, using water as a dispersion medium, carrying out wet ball milling for 16h to obtain mixed powder, drying the mixed powder at 120 ℃, then placing at 1500 ℃ for calcining for 10h to obtain a multiphase material, and carrying out superfine grinding on the multiphase material to obtain the nano multiphase material, wherein Y is Y2O3、Sb2O3And ZrO2The mass ratio of (A) to (B) is 3:0.5: 8.
Weighing the raw materials according to a formula, adding a red color base material containing iron oxide red, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball-milling to uniformly mix to prepare a glaze material with the concentration of 32%. Glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.5 hours, 1000 ℃, firing is 3.5 hours, and then natural cooling is carried out.
Example 3
The ceramic glaze is prepared according to the following formula and method.
Preparing raw materials according to mass percent: nano SiO242% nano Y2O3-Sb2O3-ZrO2Multiple phase material 18%, K2O6.5%、Na2O 12.5%、BaO 7.5%、MgO 4.5%、ZnO 9%；
Wherein the nano Y2O3-Sb2O3-ZrO2The preparation method of the complex phase material comprises the following steps:
will Y2O3And Sb2O3Uniformly mixing, adding hydrochloric acid solution with the pH value of 1, slowly adding ZrO2 at the stirring speed of 350r/min to obtain mixed solution, strongly stirring at the stirring speed for 14h, filtering, washing filter residues with sodium hydroxide solution with the pH value of 8 for 3 times, then washing with water for 5 times, placing in a ball mill, using water as a dispersion medium, carrying out wet ball milling for 16h to obtain mixed powder, drying the mixed powder at 120 ℃, then placing at 1500 ℃ for calcining for 10h to obtain a multiphase material, and carrying out superfine grinding on the multiphase material to obtain the nano multiphase material, wherein Y is Y2O3、Sb2O3And ZrO2The mass ratio of (A) to (B) is 2.5:0.8: 6.
Weighing the raw materials according to a formula, adding a red color base material containing iron oxide red, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball-milling to uniformly mix to prepare a glaze material with the concentration of 32%. Glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.5 hours, 1000 ℃, firing is 3.5 hours, and then natural cooling is carried out.
Comparative example 1
The ceramic glaze is prepared according to the following formula and method.
Preparing raw materials according to mass percent: nano SiO242% nano Y2O3-ZrO2Multiple phase material 18%, K2O 6.5%、Na2O 12.5%、BaO 7.5%、MgO 4.5%、ZnO 9%；
Wherein the nano Y2O3-ZrO2The preparation method of the complex phase material comprises the following steps:
will Y2O3Adding hydrochloric acid solution with the pH value of 1, slowly adding ZrO2 at the stirring speed of 350r/min to obtain mixed solution, strongly stirring for 14h at the stirring speed, filtering, washing filter residue with sodium hydroxide solution with the pH value of 8 for 3 times, then washing with water for 5 times, placing in a ball mill, taking water as a dispersion medium, carrying out wet ball milling for 16h to obtain mixed powder, drying the mixed powder at 120 ℃, then placing at 1500 ℃ for calcining for 10h to obtain a multiphase material, and carrying out superfine grinding on the multiphase material to obtain the nano multiphase material, wherein Y is2O3And ZrO2The mass ratio of (A) to (B) is 2.5: 6.
Weighing the raw materials according to a formula, adding a red color base material containing iron oxide red, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball-milling to uniformly mix to prepare a glaze material with the concentration of 32%. Glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.5 hours, 1000 ℃, firing is 3.5 hours, and then natural cooling is carried out.
Comparative example 2
The ceramic glaze is prepared according to the following formula and method.
Preparing raw materials according to mass percent: nano SiO242% of nano Sb2O3-ZrO2Multiple phase material 18%, K2O 6.5%、Na2O 12.5%、BaO 7.5%、MgO 4.5%、ZnO 9%；
Wherein the nano Sb2O3-ZrO2The preparation method of the complex phase material comprises the following steps:
sb2O3Adding hydrochloric acid solution with pH value of 1, slowly adding ZrO2 at stirring speed of 350r/min to obtain mixed solution, strongly stirring at the stirring speed for 14 hr,filtering, washing filter residues with a sodium hydroxide solution with the pH value of 8 for 3 times, then washing with water for 5 times, placing in a ball mill, taking water as a dispersion medium, carrying out wet ball milling for 16 hours to obtain mixed powder, drying the mixed powder at 120 ℃, then placing at 1500 ℃ for calcining for 10 hours to obtain a multiphase material, and carrying out superfine grinding on the multiphase material to obtain the nano multiphase material, wherein the Sb is Sb2O3And ZrO2The mass ratio of (A) to (B) is 0.8: 6.
Weighing the raw materials according to a formula, adding a red color base material containing iron oxide red, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball-milling to uniformly mix to prepare a glaze material with the concentration of 32%. Glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.5 hours, 1000 ℃, firing is 3.5 hours, and then natural cooling is carried out.
Comparative example 3
The ceramic glaze is prepared according to the following formula and method.
Preparing raw materials according to mass percent: nano SiO242% nano ZrO218%、K2O 6.5%、Na2O 12.5%、BaO7.5%、MgO 4.5%、ZnO 9%；
Weighing the raw materials according to a formula, adding a red color base material containing iron oxide red, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball-milling to uniformly mix to prepare a glaze material with the concentration of 32%. Glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.5 hours, 1000 ℃, firing is 3.5 hours, and then natural cooling is carried out.
Comparative example 4
The ceramic glaze is prepared according to the following formula and method.
33 parts of potash feldspar, 9 parts of double flying powder, 6 parts of barium carbonate, 27 parts of frit, 6 parts of air-knife kaolin, 11 parts of silicon micropowder, 3 parts of white corundum, 5 parts of zinc oxide and 14 parts of calcined talc.
Adding water into the raw materials for ball milling, adding water accounting for 45% of the total mass of the glaze during ball injection, wherein the ball milling time is 8 hours, the ball milling fineness is 0.5% of the screen allowance of a ten-thousand-hole screen, and after ball discharge, adjusting the flow rate of 100ml of slurry to 250s and the specific gravity to 1.70 to obtain the glaze. Glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 1170 ℃, firing for 110min, and then naturally cooling.
Comparative example 5
The ceramic glaze is prepared according to the following formula and method.
Preparing raw materials according to mass percent: SiO 2229.3%、Al2O313.1%、K2O 13.1%、Na2O 16.4%、CaO5.2%、BaO 4.2%、MgO 2.4%、ZnO 2.1%；
Weighing the raw materials according to the formula, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball milling to mix uniformly to prepare glaze with the concentration of 32%. The prepared glaze is glazed on the blank body, the glaze firing temperature is 1100 ℃, the firing is carried out for 3.5h, and then the blank body is naturally cooled.
Comparative example 6
The ceramic glaze is prepared according to the following formula and method.
20 parts of wear-resistant anti-slip material and 80 parts of basic glaze; wherein the wear-resistant anti-slip material consists of 20 percent of silicon nitride, 30 percent of silicon carbide and 50 percent of nano titanium dioxide; the basic glaze consists of 61% of silicon dioxide, 8% of aluminum oxide, 15% of calcium oxide, 5% of zinc oxide, 2% of sodium oxide, 4% of potassium oxide, 1% of magnesium oxide, 1% of barium oxide and 3% of boron trioxide.
Weighing the raw materials according to the formula, mixing, crushing, sieving with a 200-mesh sieve, adding water, and ball milling to mix uniformly to prepare glaze with the concentration of 32%. Glazing the prepared glaze on the blank body, firing the glaze at 1050 ℃ for 3.5h, and then naturally cooling.
Comparative example 7
The ceramic glaze is prepared according to the following formula and method.
61 parts of silicon dioxide, 16 parts of aluminum oxide, 1 part of magnesium oxide, 3.5 parts of sodium oxide, 1 part of potassium oxide, 12.2 parts of zinc oxide, 2.6 parts of lithium oxide, 0.3 part of titanium dioxide and 2.4 parts of antimony trioxide.
Weighing the raw materials according to the formula, placing the raw materials in a ball mill for ball milling and uniformly mixing, then sieving by a 60-mesh sieve, then heating for 2 hours at 1550 ℃, then performing water quenching, placing in the ball mill for ball milling, sieving by a 200-mesh sieve, and preparing glaze with the concentration of 32%. Glazing the prepared glaze on the blank body, firing the glaze at 1200 ℃ for 3.5h, and then naturally cooling.
To compare the results of the test examples, the above examples and comparative examples were applied with the same thickness. The ceramics prepared in the respective test examples were compared in friction coefficient and appearance form, and the results are shown in the following table.
| Test examples | Coefficient of friction | Appearance of the product |
| Example 1 | 0.42 | No crack, no coarse pore and no macro concave-convex structure |
| Example 2 | 0.45 | No crack, no coarse pore and no macro concave-convex structure |
| Example 3 | 0.48 | No crack, no coarse pore and no macro concave-convex structure |
| Comparative example 1 | 0.44 | Has cracks, no coarse pores and no macro concave-convex structure |
| Comparative example 2 | 0.56 | Has cracks, coarse pores and macro concave-convex structure |
| Comparative example 3 | 0.33 | No crack, no coarse pore and no macro concave-convex structure |
| Comparative example 4 | 0.72 | No crack, large pore and macro concave-convex structure |
| Comparative example 5 | 0.68 | No crack, large pore and macro concave-convex structure |
| Comparative example 6 | 0.65 | Has cracks, coarse pores and macro concave-convex structure |
| Comparative example 7 | 0.81 | No crack, large pore and macro concave-convex structure |
While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
Claims (8)
1. The ceramic glaze with the anti-skid effect is characterized by comprising the following raw materials in percentage by mass:nano SiO235-50% of nano Y2O3-Sb2O3-ZrO215-20% of complex phase material and K2O 5～10%、Na2O10～15%、BaO5～10%、MgO2～5%、ZnO 5～10%；
Wherein the nano Y2O3-Sb2O3-ZrO2The preparation method of the complex phase material comprises the following steps:
will Y2O3And Sb2O3Uniformly mixing, adding a hydrochloric acid solution, and slowly adding ZrO at a stirring speed of 300-500 r/min2Obtaining mixed liquor, strongly stirring the mixed liquor for 10 to 14 hours at the stirring speed, filtering the mixed liquor, washing filter residues for 3 times by using a sodium hydroxide solution, then washing the filter residues for 5 times by using water, placing the washed filter residues into a ball mill, carrying out wet ball milling for 16 to 20 hours by using water as a dispersion medium to obtain mixed powder, drying the mixed powder at 120 ℃, then placing the dried mixed powder into a ball mill for calcining for 10 to 12 hours at 1250 to 1500 ℃ to obtain a multiphase material, and carrying out superfine grinding on the multiphase material to obtain the nano multiphase material, wherein Y is2O3、Sb2O3And ZrO2The mass ratio of (A) to (B) is 2-3: 0.5-1: 5-8.
2. The ceramic glaze with anti-slip effect according to claim 1, wherein the hydrochloric acid solution has a pH of 1 and the sodium hydroxide solution has a pH of 8.
3. Ceramic glaze with anti-slip effect according to claim 1, characterized in that said Y is2O3、Sb2O3And ZrO2The mass ratio of (A) to (B) is 2.5:0.8: 6.
4. The ceramic glaze with anti-slip effect as claimed in claim 1, wherein a color-based material is further added to the ceramic glaze.
5. The ceramic glaze with anti-slip effect according to claim 1, wherein the ceramic glaze consists of the following raw materials in percentage by mass: nano SiO242% nano Y2O3-Sb2O3-ZrO2Multiple phase material 18%, K2O 6.5%、Na2O12.5%、BaO 7.5%、MgO 4.5%、ZnO 9%。
6. The ceramic glaze with anti-slip effect as claimed in claim 5, wherein a color-based material is further added to the ceramic glaze.
7. The non-slip ceramic glaze according to any one of claims 1 to 6, wherein the ceramic glaze is prepared by a method comprising: weighing the raw materials according to the formula, mixing, crushing, sieving with a 200-mesh sieve, adding water, ball-milling to mix uniformly, and preparing glaze with the concentration of 32-35%.
8. The application method of the ceramic glaze with the anti-skid effect according to claim 7 is as follows: glazing the prepared glaze on the blank body, wherein the glaze firing temperature is 800 ℃, firing is 2.0-2.5h, 1000-1250 ℃, firing is 3-3.5h, and then naturally cooling.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112759262A (en) * | 2021-03-05 | 2021-05-07 | 德化县嘉翔工艺品有限公司 | Wear-resistant diamond transparent glaze, wear-resistant diamond transparent glaze ceramic product and preparation method thereof |
| CN114656147A (en) * | 2022-04-06 | 2022-06-24 | 浙江睿达电器有限公司 | Stainless steel matt enamel nano material and method for manufacturing nano stainless steel matt enamel |
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| CN114656147A (en) * | 2022-04-06 | 2022-06-24 | 浙江睿达电器有限公司 | Stainless steel matt enamel nano material and method for manufacturing nano stainless steel matt enamel |
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