CN103819085A - Glaze simulated stone glass for construction walls and floor surfaces - Google Patents
Glaze simulated stone glass for construction walls and floor surfaces Download PDFInfo
- Publication number
- CN103819085A CN103819085A CN201410082533.9A CN201410082533A CN103819085A CN 103819085 A CN103819085 A CN 103819085A CN 201410082533 A CN201410082533 A CN 201410082533A CN 103819085 A CN103819085 A CN 103819085A
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- Prior art keywords
- parts
- oxide
- glaze
- calcium
- aluminum
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Links
- 239000011521 glass Substances 0.000 title claims abstract description 96
- 239000004575 stone Substances 0.000 title abstract description 11
- 238000010276 construction Methods 0.000 title abstract 4
- -1 9 ~ 10 parts Chemical compound 0.000 claims description 97
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 60
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 59
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 57
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 40
- 239000000292 calcium oxide Substances 0.000 claims description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 36
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 35
- 239000000395 magnesium oxide Substances 0.000 claims description 34
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 34
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 34
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 32
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 32
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 31
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 30
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 30
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 30
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 30
- 229910052737 gold Inorganic materials 0.000 claims description 30
- 239000010931 gold Substances 0.000 claims description 30
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 30
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 30
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 30
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 29
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 29
- 229910052810 boron oxide Inorganic materials 0.000 claims description 29
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 29
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 29
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 29
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 29
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 29
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 29
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 29
- 239000011787 zinc oxide Substances 0.000 claims description 29
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 28
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 18
- 238000000137 annealing Methods 0.000 claims description 18
- GHLITDDQOMIBFS-UHFFFAOYSA-H cerium(3+);tricarbonate Chemical compound [Ce+3].[Ce+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O GHLITDDQOMIBFS-UHFFFAOYSA-H 0.000 claims description 18
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 18
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 18
- 229910052726 zirconium Inorganic materials 0.000 claims description 18
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 17
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 16
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- 238000005245 sintering Methods 0.000 claims description 16
- 238000000465 moulding Methods 0.000 claims description 15
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 12
- MOWNZPNSYMGTMD-UHFFFAOYSA-N oxidoboron Chemical class O=[B] MOWNZPNSYMGTMD-UHFFFAOYSA-N 0.000 claims description 12
- 238000002425 crystallisation Methods 0.000 claims description 10
- 229960003280 cupric chloride Drugs 0.000 claims description 9
- 230000008025 crystallization Effects 0.000 claims description 6
- 239000007858 starting material Substances 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims 3
- 239000003086 colorant Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 description 43
- 238000001816 cooling Methods 0.000 description 24
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 239000002245 particle Substances 0.000 description 17
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 238000010792 warming Methods 0.000 description 7
- 238000005352 clarification Methods 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 150000003841 chloride salts Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002241 glass-ceramic Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910017119 AlPO Inorganic materials 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229910016655 EuF 3 Inorganic materials 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 230000006353 environmental stress Effects 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910003771 Gold(I) chloride Inorganic materials 0.000 description 1
- 239000006125 LAS system Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 239000006063 cullet Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 229940077441 fluorapatite Drugs 0.000 description 1
- 229910052587 fluorapatite Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses glaze simulated stone glass for construction walls and floor surfaces. The glaze simulated stone glass comprises glaze and frit, wherein the frit comprises LAS/BAS and other necessary components; the glaze comprises LAS/BAS, a coloring agent and other necessary components. As the glaze simulated stone glass for construction walls and floor surfaces is lower in coefficient of thermal expansion, so that the glaze simulated stone glass is not easy to crack when being paved on the wall and the floor, is high in hardness and good in wearing resistance, and can be used for a long time; the intensity of the glaze simulated stone glass for construction walls and floor surfaces also satisfies the requirement.
Description
Technical field
The present invention relates to stone-pseudo glass, relate in particular to a kind of glaze stone-pseudo glass for building wall ground.
Background technology
Devitrified glass, between glass and pottery, can, for making building wall ground, be excellent constructional ornamental material.In order further to optimize the outward appearance of glass or devitrified glass, be convenient to clean simultaneously, can be at its surface coverage one deck glaze.
01127483.2 discloses a kind of production process of glazed devitrified glass tile, and its glaze consists of the following composition: SiO
247-57%, CaO14-17%, Al
2o
37-11%, MgO1-5%, Na
2o0.2-1%, TiO
210-12%, Fe
2o
37.7-10%, BaO0.2-10%; The weight percent of adobe raw material consists of: cullet 30-40%, sandstone 40-50%, clay 20-30%, binding agent 2-3%.This case discloses the preparation technology of ornamental brick.
201080060684.4 relate to a kind of enamel composition for devitrified glass, and said composition comprises paint box matrix, and its matrix contains SiO
245-65%, Al
2o
30-13%, B
2o
323-55%, Na
2o 0-10%, K
2o 0-10%, Li
2o 0-10%.The inhomogeneous meeting of thermal expansivity causes be full of cracks, and this case can address this problem.
201010152488.1 relate to colored decorating plate made of composite fly ash microcrystalline glass, are come by ash glass-Ceramics pellet and microcrystalline glass glaze sintering, and wherein ash glass-Ceramics pellet is by flyash, SiO
2, CaO, BaCO
3, MgO, B
2o
3found and form Deng raw material; Microcrystalline glass glaze is by Al
2o
3, SiO
2, CaO, Na
2cO
3or K
2cO
3, B
2o
3found and form with raw materials such as tinting materials.This case also discloses the method for double sintering glazing.
201110097680.X relates to a kind of preparation method of aventurine fluoride-free opal glass: the silicon-dioxide of 65～75 parts, the aluminum oxide of 0.5～2.0 part, the calcium oxide of 8.0～12.0 parts, the magnesium oxide of 2.0～5.0 parts, the sodium oxide of 9～15 parts, the Vanadium Pentoxide in FLAKES of 1～5 part, the boron oxide of 0.5～1 part, the zinc oxide of 0.5～1.5 part, the zirconium white of 0.5～1 part, the bismuth oxide of 0.5～1 part and the cerous carbonate of 0.2～0.5 part.This glass has certain transmittance, is white in color translucent.
201110287900.5 relate to a kind of transparent glass-ceramics that contains fluorapatite crystal, are made up of: SiO the component of following molar percentage
225.9～45%, AlPO
412～36%, Al
2o
36～19%, CaO15～30%, CaF
212～24%, Eu
2o
30～2%, EuF
30～2%, Yb
2o
30～5%, YbF
30～5%, CeO
20～2%, CeF
30～2%; Wherein, described Eu
2o
3, EuF
3, CeO
2and CeF
3total amount be no less than 0.1%; Yb
2o
3and YbF
3total amount be no less than 0.2%.Xln ratio in this devitrified glass is low, has higher specific refractory power.
Glaze devitrified glass has glazing type material and bed material composition at least, and glaze should be wear-resisting, and bed material should resistance to compression.But consistent in order to guarantee thermal expansivity, component and preparation technology should not distinguish too large.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of stone-pseudo glass, its have low-refraction, high strength, high rigidity etc. performance, replace stone material to make high-grade imitative stone furniture.
A kind of glaze stone-pseudo glass, is characterized in that, formed by glaze and frit, and mass percent meter,
Described frit consists of the following composition: 33 ~ 36 parts of silicon oxide, 9 ~ 10 parts, calcium oxide, 10 ~ 12 parts, magnesium oxide, 8 ~ 12 parts, aluminum oxide, 8 ~ 10 parts of aluminum phosphates, 5 ~ 6 parts, Calcium Fluoride (Fluorspan), 0.1 ~ 2 part of potassium oxide, 0.01 ~ 0.1 part of sodium oxide, 0.01 ~ 0.016 part of gold perchloride, 0.01 ~ 0.1 part, copper sulfate, 1 ~ 3 part of boron oxide, 5 ~ 6 parts of zirconium whites, 5 ~ 6 parts of Lithium Oxide 98mins, 0.1 ~ 3 part of bismuth oxide, 1 ~ 3 part of titanium oxide, 1 ~ 3 part, barium oxide, 1 ~ 1.5 part of weisspiessglanz, 1 ~ 1.9 part of Vanadium Pentoxide in FLAKES, 1 ~ 1.5 part of lanthanum trioxide, 1 ~ 1.5 part of cerous carbonate, 0.01 ~ 0.04 part, zinc oxide, 0 ~ 0.1 part of ferric oxide,
Described glaze consists of the following composition: 33 ~ 36 parts of silicon oxide, 9 ~ 10 parts, calcium oxide, 10 ~ 12 parts, magnesium oxide, 11 ~ 12 parts, aluminum oxide, 8 ~ 10 parts of aluminum phosphates, 2 ~ 4 parts, Calcium Fluoride (Fluorspan), 0.01 ~ 0.1 part of sodium oxide, 0.01 ~ 0.016 part of gold perchloride, 0.01 ~ 0.1 part, copper sulfate, 1 ~ 3 part of boron oxide, 5 ~ 6 parts of zirconium whites, 5 ~ 6 parts of Lithium Oxide 98mins, 0.1 ~ 3 part of bismuth oxide, 1 ~ 3 part of titanium oxide, 1 ~ 3 part, barium oxide, 1 ~ 1.5 part of weisspiessglanz, 1 ~ 1.9 part of Vanadium Pentoxide in FLAKES, 1 ~ 1.5 part of lanthanum trioxide, 1 ~ 1.5 part of cerous carbonate, 0.01 ~ 0.04 part, zinc oxide, 1 ~ 8 part of ferric oxide, 0.1 ~ 3 part of cupric chloride.
Preferably, described magnesian content is 1.2 times of calcium oxide, and the content of described silicon oxide is 3.7 times of calcium oxide.The ratio outbalance of silicon oxide, magnesium oxide and calcium oxide in the present invention, under this ratio, devitrified glass is low in the viscosity of molten state, and the product intensity of making is high.In addition, under this ratio, recrystallization temperature line is sharp-pointed, is easy to nucleus moulding, and this is also that prior art is inaccessiable, is the application's further improvement.
Preferably, described frit consists of the following composition: 33.3 parts of silicon oxide, 9 parts, calcium oxide, 10.8 parts, magnesium oxide, 9 parts, aluminum oxide, 10 parts of aluminum phosphates, 5.2 parts, Calcium Fluoride (Fluorspan), 1 part of potassium oxide, 0.05 part of sodium oxide, 0.012 part of gold perchloride, 0.08 part, copper sulfate, 2 parts of boron oxides, 6 parts of zirconium whites, 5 parts of Lithium Oxide 98mins, 1 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.4 parts of weisspiessglanzs, 1.2 parts of Vanadium Pentoxide in FLAKESs, 1.4 parts of lanthanum trioxides, 1.4 parts of cerous carbonates, 1 part, zinc oxide, 0.05 part of ferric oxide;
Described glaze consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 11 parts, aluminum oxide, 9 parts of aluminum phosphates, 3 parts, Calcium Fluoride (Fluorspan), 0.03 part of sodium oxide, 0.015 part of gold perchloride, 1 part, copper sulfate, 1.5 parts of boron oxides, 5 parts of zirconium whites, 5 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.03 part, zinc oxide, 5 parts of ferric oxide, 1.5 parts of cupric chlorides.
Preferably, described frit consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 10 parts, aluminum oxide, 9 parts of aluminum phosphates, 5.6 parts, Calcium Fluoride (Fluorspan), 1.5 parts of potassium oxides, 0.08 part of sodium oxide, 0.014 part of gold perchloride, 0.05 part, copper sulfate, 2.5 parts of boron oxides, 5 parts of zirconium whites, 6 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.035 part, zinc oxide, 0.01 part of ferric oxide;
Described glaze consists of the following composition: 33.3 parts of silicon oxide, 9 parts, calcium oxide, 10.8 parts, magnesium oxide, 11.8 parts, aluminum oxide, 10 parts of aluminum phosphates, 3.5 parts, Calcium Fluoride (Fluorspan), 0.05 part of sodium oxide, 0.012 part of gold perchloride, 0.08 part, copper sulfate, 2 parts of boron oxides, 6 parts of zirconium whites, 5 parts of Lithium Oxide 98mins, 1 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.4 parts of weisspiessglanzs, 1.2 parts of Vanadium Pentoxide in FLAKESs, 1.4 parts of lanthanum trioxides, 1.4 parts of cerous carbonates, 1 part, zinc oxide, 3 parts of ferric oxide, 2 parts of cupric chlorides.
Preferably, described frit consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 11 parts, aluminum oxide, 9 parts of aluminum phosphates, 5.8 parts, Calcium Fluoride (Fluorspan), 0.1 part of potassium oxide, 0.03 part of sodium oxide, 0.015 part of gold perchloride, 1 part, copper sulfate, 1.5 parts of boron oxides, 5 parts of zirconium whites, 6 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.03 part, zinc oxide, 0.03 part of ferric oxide;
Described glaze consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 12 parts, aluminum oxide, 9 parts of aluminum phosphates, 2.5 parts, Calcium Fluoride (Fluorspan), 0.08 part of sodium oxide, 0.014 part of gold perchloride, 0.05 part, copper sulfate, 2.5 parts of boron oxides, 5 parts of zirconium whites, 6 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.035 part, zinc oxide, 7 parts of ferric oxide, 2.8 parts of cupric chlorides.
The present invention does not limit the preparation method of glaze stone-pseudo glass, can adopt existing crystallization method and sintering process.
A preparation method for glaze stone-pseudo glass, is characterized in that,
Configure on request frit, by this frit fusing, after annealing, make substrate;
Configure on request glaze, this glaze is worn into the particle that homogeneous diameter is less than 1mm, the glaze of milled is brushed on described substrate, by the substrate sintering brushing, after annealing, make glaze stone-pseudo glass.
Preferably, configure on request raw material, starting material are passed into melting end, fusing after mixing, form melten glass liquid, then glass metal is passed into cooling end, homogenizing in cooling end, clarification, discharge bubble, then glass metal is drained into forming part, moulding is annealed again, makes stone-pseudo glass.Wherein in described forming part, the temperature with 1320 ℃ to 1400 ℃ is incubated, and the time that glass metal is preserved in forming part is 1 to 10 hour.
Described melt temperature is 1500 ℃ to 1700 ℃, and forming part cooling rate is 5 to 10 ℃/min.Annealing temperature is 500 to 800 ℃, and cooling rate is 1 to 10 ℃/min.
A preparation method for glaze stone-pseudo glass, is characterized in that,
Configure on request frit, by this frit fusing, after annealing, make substrate;
Configure on request glaze, by this glaze fusing, after annealing, make glaze;
Respectively glaze and frit are ground into the particle that homogeneous diameter is less than 1mm,
First spread one deck frit particle, repave one deck frit particles, after annealing, make glaze stone-pseudo glass.
A kind of glaze floor tile, is characterized in that, is made up of described glaze stone-pseudo glass.
A kind of glaze inner wall decoration brick, is characterized in that, is made up of described glaze stone-pseudo glass.
A kind of glaze exterior wall decorating tile, is characterized in that, is made up of described glaze stone-pseudo glass.
A kind of glaze decorating bar, is characterized in that, is made up of described glaze stone-pseudo glass.
A kind of door and window is decorated guardrail, it is characterized in that, is made up of described glaze stone-pseudo glass.
Glaze stone-pseudo glass of the present invention has lower thermal expansivity, is layered on wall ground not easy to crackly, and hardness is high, and wear resistance is good, can life-time service.Intensity also meets the demands.
Embodiment
A kind of glaze stone-pseudo glass, is made up of glaze and frit, mass percent meter,
Described frit consists of the following composition: 33 ~ 36 parts of silicon oxide, 9 ~ 10 parts, calcium oxide, 10 ~ 12 parts, magnesium oxide, 8 ~ 12 parts, aluminum oxide, 8 ~ 10 parts of aluminum phosphates, 5 ~ 6 parts, Calcium Fluoride (Fluorspan), 0.1 ~ 2 part of potassium oxide, 0.01 ~ 0.1 part of sodium oxide, 0.01 ~ 0.016 part of gold perchloride, 0.01 ~ 0.1 part, copper sulfate, 1 ~ 3 part of boron oxide, 5 ~ 6 parts of zirconium whites, 5 ~ 6 parts of Lithium Oxide 98mins, 0.1 ~ 3 part of bismuth oxide, 1 ~ 3 part of titanium oxide, 1 ~ 3 part, barium oxide, 1 ~ 1.5 part of weisspiessglanz, 1 ~ 1.9 part of Vanadium Pentoxide in FLAKES, 1 ~ 1.5 part of lanthanum trioxide, 1 ~ 1.5 part of cerous carbonate, 0.01 ~ 0.04 part, zinc oxide, 0 ~ 0.1 part of ferric oxide,
Described glaze consists of the following composition: 33 ~ 36 parts of silicon oxide, 9 ~ 10 parts, calcium oxide, 10 ~ 12 parts, magnesium oxide, 11 ~ 12 parts, aluminum oxide, 8 ~ 10 parts of aluminum phosphates, 2 ~ 4 parts, Calcium Fluoride (Fluorspan), 0.01 ~ 0.1 part of sodium oxide, 0.01 ~ 0.016 part of gold perchloride, 0.01 ~ 0.1 part, copper sulfate, 1 ~ 3 part of boron oxide, 5 ~ 6 parts of zirconium whites, 5 ~ 6 parts of Lithium Oxide 98mins, 0.1 ~ 3 part of bismuth oxide, 1 ~ 3 part of titanium oxide, 1 ~ 3 part, barium oxide, 1 ~ 1.5 part of weisspiessglanz, 1 ~ 1.9 part of Vanadium Pentoxide in FLAKES, 1 ~ 1.5 part of lanthanum trioxide, 1 ~ 1.5 part of cerous carbonate, 0.01 ~ 0.04 part, zinc oxide, 1 ~ 8 part of ferric oxide, 0.1 ~ 3 part of cupric chloride.
In frit, silicon oxide (SiO
2) be main component, can reduce the thermal expansivity of glass, improve hardness, the physical strength etc. of devitrified glass.Hardness and intensity are very important factors of furniture.Calcium oxide (CaO) can increase physical strength, improves crystalline stability, mechanical best performance in the time that itself and the mass ratio of magnesium oxide and silicon oxide are 1:1.2:3.7.Magnesium oxide (MgO) can improve physical strength, is easy to calcium oxide and silicon oxide and forms high strength crystallization skeleton, and the specific proportions of magnesium silico-calcium can form eutectic, improves intensity, reduces melt viscosity.Aluminum oxide (Al
2o
3) can improve bulk strength and hardness, in general, alumina content is higher, and intensity is higher, but aluminum oxide is crossed multipair viscosity and thermal expansivity is disadvantageous.The coefficient of expansion of imitation stone material is too high, easily causes door and window and desktop etc. locate protuberance or occur crack, is unfavorable for long-time use.Aluminum phosphate (AlPO
4) can change transmittance, make material whiting or increase white point.Calcium Fluoride (Fluorspan) (CaF
2) can improve the quantity of crystal, improve folding strength, but too much viscosity is large, reduce glossiness.Potassium oxide (K
2o) can, for fluxing, form crystal simultaneously.Sodium oxide (Na
2o) similar with the effect of potassium oxide, but sodium oxide is larger to intensity effect.Gold perchloride (AuCl
3) absorption that improved visible ray within the scope of 500 to 600nm, blocking green, pyrolytic decomposition is that gold monochloride can improve crystal grain in addition, chlorine contributes to get rid of bubble.Gold perchloride is too much unsuitable, otherwise takes on a red color.Copper sulfate (CuSO
4) can desalinate the cyan of ferro element, make integral stone-imitation effect better.Boron oxide (B
2o
3) can reduce thermal expansivity, reduce crystal grain.Zirconium white (ZrO
2) can improve water tolerance, improve amount of crystals simultaneously.Lithium Oxide 98min (Li
2o) can improve hardness and density and be conducive to reduce thermal expansivity, forming LAS system.Bismuth oxide (Bi
2o
3) raising mechanical property and density.Titanium oxide (TiO
2) can reduce transmittance, improve color and luster.Barium oxide (BaO) can improve mechanical property, but is unfavorable for the coefficient of expansion, forms BAS system.Weisspiessglanz (Sb
2o
3) be conducive to get rid of bubble, improve overall density, improve mechanical property.Vanadium Pentoxide in FLAKES (V
2o
5) can be painted, reduce transmittance, improve imitative stone effect, can also reduce thermal expansivity.Lanthanum trioxide (La
2o
3) can improve gloss, improve the mechanical property of glass.Cerous carbonate (Ce
2(CO
3)
3) can stablize ferro element, reduce bubble simultaneously.In this application, adopt the carbonate of cerium to be better than the carbonate of lanthanum.Zinc oxide (ZnO) can improve crystal mass.Ferric oxide (Fe
2o
3) can make glass green.
In glaze, for guaranteeing its coefficient of expansion, adopt and the similar component of frit, but also different.For example, in order to improve hardness, glaze contains more aluminum oxide, cancels potassium oxide simultaneously.In order to give glass coloring, ferric oxide, cupric chloride (CuCl are added
2).
The present invention does not limit the preparation method of this glaze stone-pseudo glass, and it can adopt the method for crystallization-printing-sintering, can adopt the method for grinding-moulding-sintering yet.
A kind of preparation method's (crystallization method) of glaze stone-pseudo glass, comprises the following steps: configure on request frit, by this frit fusing, make substrate after annealing.Configure on request glaze, this glaze is worn into the particle that homogeneous diameter is less than 1mm.The glaze of milled is brushed on described substrate, by the substrate sintering brushing, after annealing, made glaze stone-pseudo glass.
Particularly, frit is passed into melting end, fusing after mixing, forms melten glass liquid, and melt temperature is 1500 ℃ to 1700 ℃.Then glass metal is passed into cooling end, homogenizing in cooling end, clarification, discharge bubble, then glass metal is drained into forming part, after moulding, take out substrate, wherein in described forming part, the temperature with 1320 ℃ to 1400 ℃ is incubated, and the time that glass metal is preserved in forming part is 1 to 10 hour.After cooling, after moulding, take out substrate.The insulating process of forming part is conducive to the growth of nucleus.In crystallisation process, raw material may be bonded in die cavity, need to destroy die cavity, so die cavity can adopt lower-cost heat-stable ceramic, or adopts tin molding chamber.The temperature of controlling die cavity can adopt molybdenum electrode.Preferably 5 to 10 ℃/min of cooling rate in forming part.After glaze brush is on substrate, sintering temperature is 1000 ℃ to 1200 ℃.Temperature rise rate is 6 to 8 ℃/min.Be incubated 1 to 5 hour, the moulding of temperature-fall period reference substrate.
A kind of preparation method's (sintering process) of glaze stone-pseudo glass, comprises the following steps: configure on request frit, by this frit fusing, make substrate after annealing.Configure on request glaze, by this glaze fusing, after annealing, make glaze; Respectively glaze and frit are ground into the particle that homogeneous diameter is less than 1mm; First spread one deck frit particle, repave one deck frit particles, after annealing, make glaze stone-pseudo glass.Its design parameter control can be referring to the preparation process of above-mentioned crystallization method, and the content of not addressing is referring to prior art.
embodiment mono-
A kind of glaze stone-pseudo glass, it is composited by substrate and glaze, and described substrate is made up of frit, and glaze is made up of glaze.The thickness of described substrate is 50mm, and the thickness of glaze is 2mm.Described frit consists of the following composition: silicon oxide 33.3Kg, calcium oxide 9Kg, magnesium oxide 10.8Kg, aluminum oxide 9Kg, aluminum phosphate 10Kg, Calcium Fluoride (Fluorspan) 5.2Kg, potassium oxide 1Kg, sodium oxide 0.05Kg, gold perchloride 0.012Kg, copper sulfate 0.08Kg, boron oxide 2Kg, zirconium white 6Kg, Lithium Oxide 98min 5 Kg, bismuth oxide 1Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.4Kg, Vanadium Pentoxide in FLAKES 1.2Kg, lanthanum trioxide 1.4Kg, cerous carbonate 1.4Kg, zinc oxide 1Kg, ferric oxide 0.05Kg,
Described glaze consists of the following composition: silicon oxide 35Kg, calcium oxide 9.46Kg, magnesium oxide 11.35Kg, aluminum oxide 11Kg, aluminum phosphate 9Kg, Calcium Fluoride (Fluorspan) 3Kg, sodium oxide 0.03Kg, gold perchloride 0.015Kg, copper sulfate 1Kg, boron oxide 1.5Kg, zirconium white 5Kg, Lithium Oxide 98min 5 Kg, bismuth oxide 0.2Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.2Kg, Vanadium Pentoxide in FLAKES 1.6Kg, lanthanum trioxide 1.2Kg, cerous carbonate 1.2Kg, zinc oxide 0.03Kg, ferric oxide 5Kg, cupric chloride 1.5Kg.
The preparation method of glaze stone-pseudo glass: frit is passed into melting end, fusing after mixing, form melten glass liquid, then glass metal is passed into cooling end, homogenizing in cooling end, clarification, discharge bubble, then glass metal is drained into forming part, after moulding, take out substrate, wherein in described forming part, the temperature with 1320 ℃ to 1350 ℃ is incubated, and the time that glass metal is preserved in forming part is 1 to 6 hour.The speed cooling of 5 to 10 ℃/min, takes out substrate after moulding.Glaze is ground into the particle that homogeneous diameter is less than 1mm, glaze is brushed on substrate, temperature rise rate is 6 to 8 ℃/min, and sintering temperature is 1000 ℃ to 1200 ℃, is incubated after 1 to 3 hour.The speed cooling of 5 to 10 ℃/min, takes out glaze stone-pseudo glass.
embodiment bis-
A kind of glaze stone-pseudo glass, it is composited by substrate and glaze, and described substrate is made up of frit, and glaze is made up of glaze.The thickness of described substrate is 100mm, and the thickness of glaze is 10mm.Described frit consists of the following composition: silicon oxide 35Kg, calcium oxide 9.46Kg, magnesium oxide 11.35Kg, aluminum oxide 10Kg, aluminum phosphate 9Kg, Calcium Fluoride (Fluorspan) 5.6Kg, potassium oxide 1.5Kg, sodium oxide 0.08Kg, gold perchloride 0.014Kg, copper sulfate 0.05Kg, boron oxide 2.5Kg, zirconium white 5Kg, Lithium Oxide 98min 5. 5Kg, bismuth oxide 0.2Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.2Kg, Vanadium Pentoxide in FLAKES 1.6Kg, lanthanum trioxide 1.2Kg, cerous carbonate 1.2Kg, zinc oxide 0.035Kg, ferric oxide 0.01Kg,
Described glaze consists of the following composition: silicon oxide 33.3Kg, calcium oxide 9Kg, magnesium oxide 10.8Kg, aluminum oxide 11.8Kg, aluminum phosphate 10Kg, Calcium Fluoride (Fluorspan) 3.5Kg, sodium oxide 0.05Kg, gold perchloride 0.012Kg, copper sulfate 0.08Kg, boron oxide 2Kg, zirconium white 6Kg, Lithium Oxide 98min 5. 5Kg, bismuth oxide 1Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.4Kg, Vanadium Pentoxide in FLAKES 1.2Kg, lanthanum trioxide 1.4Kg, cerous carbonate 1.4Kg, zinc oxide 1Kg, ferric oxide 3Kg, cupric chloride 2Kg.
The preparation method of glaze stone-pseudo glass: frit is passed into melting end, fusing after mixing, form melten glass liquid, then glass metal is passed into cooling end, homogenizing in cooling end, clarification, discharge bubble, then glass metal is drained into forming part, after moulding, take out substrate, wherein in described forming part, the temperature with 1300 ℃ to 1500 ℃ is incubated, and the time that glass metal is preserved in forming part is 8 to 10 hours.The speed cooling of 5 to 10 ℃/min, takes out substrate after moulding.Glaze is ground into the particle that homogeneous diameter is less than 1mm, glaze is brushed on substrate, temperature rise rate is 6 to 8 ℃/min, and sintering temperature is 1100 ℃ to 1200 ℃, is incubated after 3 hours.The speed cooling of 8 to 10 ℃/min, takes out glaze stone-pseudo glass.
embodiment tri-
A kind of glaze stone-pseudo glass, it is composited by substrate and glaze, and described substrate is made up of frit, and glaze is made up of glaze.The thickness of described substrate is 20mm, and the thickness of glaze is 2mm.Described frit consists of the following composition: silicon oxide 35Kg, calcium oxide 9.46Kg, magnesium oxide 11.35Kg, aluminum oxide 11Kg, aluminum phosphate 9Kg, Calcium Fluoride (Fluorspan) 5.8Kg, potassium oxide 0.1Kg, sodium oxide 0.03Kg, gold perchloride 0.015Kg, copper sulfate 1Kg, boron oxide 1.5Kg, zirconium white 5Kg, Lithium Oxide 98min 5. 5Kg, bismuth oxide 0.2Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.2Kg, Vanadium Pentoxide in FLAKES 1.6Kg, lanthanum trioxide 1.2Kg, cerous carbonate 1.2Kg, zinc oxide 0.03Kg, ferric oxide 0.03Kg,
Described glaze consists of the following composition: silicon oxide 35Kg, calcium oxide 9.46Kg, magnesium oxide 11.35Kg, aluminum oxide 12Kg, aluminum phosphate 9Kg, Calcium Fluoride (Fluorspan) 2.5Kg, sodium oxide 0.08Kg, gold perchloride 0.014Kg, copper sulfate 0.05Kg, boron oxide 2.5Kg, zirconium white 5Kg, Lithium Oxide 98min 5. 5Kg, bismuth oxide 0.2Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.2Kg, Vanadium Pentoxide in FLAKES 1.6Kg, lanthanum trioxide 1.2Kg, cerous carbonate 1.2Kg, zinc oxide 0.035Kg, ferric oxide 7Kg, cupric chloride 2.8Kg.
The preparation method of glaze stone-pseudo glass: frit is passed into melting end, fusing after mixing, form melten glass liquid, then glass metal is passed into cooling end, homogenizing in cooling end, clarification, discharge bubble, then glass metal is drained into forming part, after moulding, take out substrate, wherein in described forming part, the temperature with 1300 ℃ to 1500 ℃ is incubated, and the time that glass metal is preserved in forming part is 8 to 10 hours.The speed cooling of 5 to 10 ℃/min, takes out substrate after moulding.Glaze is ground into the particle that homogeneous diameter is less than 1mm, glaze is brushed on substrate, temperature rise rate is 6 to 8 ℃/min, and sintering temperature is 1100 ℃ to 1200 ℃, is incubated after 3 hours.The speed cooling of 8 to 10 ℃/min, takes out glaze stone-pseudo glass.
embodiment tetra-
A kind of glaze stone-pseudo glass, it is composited by substrate and glaze, and described substrate is made up of frit, and glaze is made up of glaze.The thickness of described substrate is 20mm, and the thickness of glaze is 2mm.Described frit consists of the following composition: silicon oxide 33Kg, calcium oxide 9Kg, magnesium oxide 12Kg, aluminum oxide 11Kg, aluminum phosphate 9Kg, Calcium Fluoride (Fluorspan) 5.8Kg, potassium oxide 0.1Kg, sodium oxide 0.03Kg, gold perchloride 0.015Kg, copper sulfate 1Kg, boron oxide 1.5Kg, zirconium white 5Kg, Lithium Oxide 98min 6Kg, bismuth oxide 0.2Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.2Kg, Vanadium Pentoxide in FLAKES 1.6Kg, lanthanum trioxide 1.2Kg, cerous carbonate 1.2Kg, zinc oxide 0.03Kg, ferric oxide 0Kg,
Described glaze consists of the following composition: silicon oxide 35Kg, calcium oxide 9.46Kg, magnesium oxide 11.35Kg, aluminum oxide 12Kg, aluminum phosphate 9Kg, Calcium Fluoride (Fluorspan) 2.5Kg, sodium oxide 0.08Kg, gold perchloride 0.014Kg, copper sulfate 0.05Kg, boron oxide 2.5Kg, zirconium white 5Kg, Lithium Oxide 98min 6Kg, bismuth oxide 0.2Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.2Kg, Vanadium Pentoxide in FLAKES 1.6Kg, lanthanum trioxide 1.2Kg, cerous carbonate 1.2Kg, zinc oxide 0.035Kg, ferric oxide 7Kg, cupric chloride 2.8Kg.
Configure on request frit, by this frit fusing, after annealing, make substrate.Configure on request glaze, by this glaze fusing, after annealing, make glaze; Respectively glaze and frit are ground into the particle that homogeneous diameter is less than 1mm; First spread one deck frit particle, repave one deck frit particles, after annealing, make glaze stone-pseudo glass.Particularly:
Can adopt more specifically sintering process to prepare this devitrified glass, to obtaining more preferably data, comprise the following steps:
Mix: get on request raw material, mix.
Grind: raw material is ground, require all particle diameters to be less than 1mm, mean diameter is 0.5 to 0.6mm;
Compression moulding: raw material is packed into the container of pre-burning to 350 ℃, pressurize 8min under 55MPa, in pressing process, envrionment temperature is 350 ℃, unloads and is pressed into idiosome;
Intensification coring: environmental stress 20MPa, be warming up to 630 ℃ with the speed of 4.5 ℃/min, insulation 40min, then be warming up to 1150 ℃ with the speed of 14 ℃/min, be incubated 3.5 hours;
Cooling crystallization: environmental stress 15MPa, be down to 850 ℃ with the speed of 9 ℃/min, be incubated 3.5 hours, then make devitrified glass after being down to normal temperature with the speed of 3.2 ℃/min;
Second annealing: be warming up to 650 ℃, be incubated 1 hour, then with the near normal temperature of speed of 0.65 ℃/min, make substrate.
Glaze is ground into the particle that homogeneous diameter is less than 1mm, glaze is brushed on substrate, temperature rise rate is 6 to 8 ℃/min, and sintering temperature is 1000 ℃ to 1200 ℃, is incubated after 1 to 3 hour.The speed cooling of 5 to 10 ℃/min, takes out glaze stone-pseudo glass.
embodiment five
A kind of glaze stone-pseudo glass, it is composited by substrate and glaze, and described substrate is made up of frit, and glaze is made up of glaze.The thickness of described substrate is 50mm, and the thickness of glaze is 2mm.Described frit consists of the following composition: silicon oxide 36Kg, calcium oxide 11Kg, magnesium oxide 10Kg, aluminum oxide 9Kg, aluminum phosphate 10Kg, Calcium Fluoride (Fluorspan) 5.2Kg, potassium oxide 1Kg, sodium oxide 0.05Kg, gold perchloride 0.012Kg, copper sulfate 0.08Kg, boron oxide 2Kg, zirconium white 6Kg, Lithium Oxide 98min 6Kg, bismuth oxide 1Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.4Kg, Vanadium Pentoxide in FLAKES 1.2Kg, lanthanum trioxide 1.4Kg, cerous carbonate 1.4Kg, zinc oxide 1Kg, ferric oxide 0.05Kg,
Described glaze consists of the following composition: silicon oxide 35Kg, calcium oxide 9.46Kg, magnesium oxide 11.35Kg, aluminum oxide 11Kg, aluminum phosphate 9Kg, Calcium Fluoride (Fluorspan) 3Kg, sodium oxide 0.03Kg, gold perchloride 0.015Kg, copper sulfate 1Kg, boron oxide 1.5Kg, zirconium white 5Kg, Lithium Oxide 98min 5Kg, bismuth oxide 0.2Kg, titanium oxide 2Kg, barium oxide 2Kg, weisspiessglanz 1.2Kg, Vanadium Pentoxide in FLAKES 1.6Kg, lanthanum trioxide 1.2Kg, cerous carbonate 1.2Kg, zinc oxide 0.03Kg, ferric oxide 5Kg, cupric chloride 1.5Kg.
Can adopt more specifically crystallization legal system for this devitrified glass, to obtaining more preferably data, to comprise the following steps:
Mix: get on request raw material, mix.
Fusing: be melted to molten state, homogenizing, clarification, discharge bubble, make glass metal within the scope of 1500 ℃ to 1550 ℃, then be down to 1360 ℃ with the speed of 8.6 ℃/min, is incubated 7 hours.
Calendering: glass metal is poured in the container of pre-burning to 1150 ℃, by glass metal compression moulding, in calender line, envrionment temperature is 1150 ℃, and the calendering time is 2min.
Cooling moulding: be down to 850 ℃ with the speed of 13 ℃/min, be incubated 3.6 hours, then make vitreum after being down to normal temperature with the speed of 3.2 ℃/min.
Intensification coring: be warming up to 610 ℃ with the speed of 4.5 ℃/min, be incubated 1 to 3 hour, then be warming up to 830 ℃ with the speed of 2.6 ℃/min, be incubated 1.5 hours.
Crystallization: be warming up to 1030 ℃ with the speed of 2.5 ℃/min, be incubated 0.8 hour, near 25 ℃ with the speed of 0.4 ℃/min, make microcrystallite body.
Second annealing: be warming up to 650 ℃, be incubated 1 hour, then with the near normal temperature of speed of 0.63 ℃/min, make substrate.
Glaze is ground into the particle that homogeneous diameter is less than 1mm, glaze is brushed on substrate, temperature rise rate is 6 to 8 ℃/min, and sintering temperature is 1000 ℃ to 1200 ℃, is incubated after 1 to 3 hour.The speed cooling of 5 to 10 ℃/min, takes out glaze stone-pseudo glass.
This preparation method describes in detail in other application documents.
Following table is the parameter of the substrate prepared of various embodiments of the present invention, and similarly, hardness increases each parameter of glaze.Each parameter is average or the representative value of how each product, does not represent that all products are all within the scope of this.The significant parameter of glaze is identical with substrate, but intensity and hardness are slightly high, and transmittance is lower slightly.Prior art one is taken from certain commercially available devitrified glass, and prior art two is commercially available immitation stone plate.Thermal expansivity reference--the observed value of 20 to 60 ℃, this is to consider the general residing envrionment temperature of furniture, is considered as linear expansion within the scope of this.
| Performance | Embodiment mono- | Embodiment bis- | Embodiment tri- | Embodiment tetra- | Embodiment five | Prior art one | Prior art two |
| Ultimate compression strength (MPa) | 300~400 | 300~400 | 300~400 | 300~400 | 300~400 | 100~400 | 130 |
| Folding strength (MPa) | 60~120 | 60~120 | 60~120 | 100~120 | 100~120 | 80 | 55 |
| Thermal expansivity (10 -7） | 40~60 | 40~70 | 40~70 | 40~60 | 40~60 | 40~70 | 150~350 |
| Hardness (Kg/mm 2） | 500~700 | 500~700 | 500~700 | 500~700 | 500~700 | 500 | 100~700 |
| Water-intake rate | Be less than 0.1% | Be less than 0.1% | Be less than 0.1% | Be less than 0.1% | Be less than 0.1% | 0.1% | 0.3%~5% |
| Transmission of visible light | Be less than 30% | Be less than 30% | Be less than 30% | Be less than 30% | Be less than 30% | 40%~95% | Opaque |
| Thermal conductivity (W/mK) | Be less than 0.2 | Be less than 0.2 | Be less than 0.2 | Be less than 0.2 | Be less than 0.2 | Do not record | Do not record |
| Bulking factor | Be less than 0.07% | Be less than 0.07% | Be less than 0.07% | Be less than 0.07% | Be less than 0.07% | Do not record | Do not record |
Be more than embodiment, the application's protection domain is as the criterion with the protection domain of claim.
Claims (7)
1. a glaze stone-pseudo glass, is characterized in that, formed by glaze and frit, and mass percent meter,
Described frit consists of the following composition: 33 ~ 36 parts of silicon oxide, 9 ~ 10 parts, calcium oxide, 10 ~ 12 parts, magnesium oxide, 8 ~ 12 parts, aluminum oxide, 8 ~ 10 parts of aluminum phosphates, 5 ~ 6 parts, Calcium Fluoride (Fluorspan), 0.1 ~ 2 part of potassium oxide, 0.01 ~ 0.1 part of sodium oxide, 0.01 ~ 0.016 part of gold perchloride, 0.01 ~ 0.1 part, copper sulfate, 1 ~ 3 part of boron oxide, 5 ~ 6 parts of zirconium whites, 5 ~ 6 parts of Lithium Oxide 98mins, 0.1 ~ 3 part of bismuth oxide, 1 ~ 3 part of titanium oxide, 1 ~ 3 part, barium oxide, 1 ~ 1.5 part of weisspiessglanz, 1 ~ 1.9 part of Vanadium Pentoxide in FLAKES, 1 ~ 1.5 part of lanthanum trioxide, 1 ~ 1.5 part of cerous carbonate, 0.01 ~ 0.04 part, zinc oxide, 0 ~ 0.1 part of ferric oxide,
Described glaze consists of the following composition: 33 ~ 36 parts of silicon oxide, 9 ~ 10 parts, calcium oxide, 10 ~ 12 parts, magnesium oxide, 11 ~ 12 parts, aluminum oxide, 8 ~ 10 parts of aluminum phosphates, 2 ~ 4 parts, Calcium Fluoride (Fluorspan), 0.01 ~ 0.1 part of sodium oxide, 0.01 ~ 0.016 part of gold perchloride, 0.01 ~ 0.1 part, copper sulfate, 1 ~ 3 part of boron oxide, 5 ~ 6 parts of zirconium whites, 5 ~ 6 parts of Lithium Oxide 98mins, 0.1 ~ 3 part of bismuth oxide, 1 ~ 3 part of titanium oxide, 1 ~ 3 part, barium oxide, 1 ~ 1.5 part of weisspiessglanz, 1 ~ 1.9 part of Vanadium Pentoxide in FLAKES, 1 ~ 1.5 part of lanthanum trioxide, 1 ~ 1.5 part of cerous carbonate, 0.01 ~ 0.04 part, zinc oxide, 1 ~ 8 part of ferric oxide, 0.1 ~ 3 part of cupric chloride.
2. glaze stone-pseudo glass according to claim 1, is characterized in that, described magnesian content is 1.2 times of calcium oxide, and the content of described silicon oxide is 3.7 times of calcium oxide.
3. glaze stone-pseudo glass according to claim 1, it is characterized in that, described frit consists of the following composition: 33.3 parts of silicon oxide, 9 parts, calcium oxide, 10.8 parts, magnesium oxide, 9 parts, aluminum oxide, 10 parts of aluminum phosphates, 5.2 parts, Calcium Fluoride (Fluorspan), 1 part of potassium oxide, 0.05 part of sodium oxide, 0.012 part of gold perchloride, 0.08 part, copper sulfate, 2 parts of boron oxides, 6 parts of zirconium whites, 5 parts of Lithium Oxide 98mins, 1 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.4 parts of weisspiessglanzs, 1.2 parts of Vanadium Pentoxide in FLAKESs, 1.4 parts of lanthanum trioxides, 1.4 parts of cerous carbonates, 1 part, zinc oxide, 0.05 part of ferric oxide,
Described glaze consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 11 parts, aluminum oxide, 9 parts of aluminum phosphates, 3 parts, Calcium Fluoride (Fluorspan), 0.03 part of sodium oxide, 0.015 part of gold perchloride, 1 part, copper sulfate, 1.5 parts of boron oxides, 5 parts of zirconium whites, 5 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.03 part, zinc oxide, 5 parts of ferric oxide, 1.5 parts of cupric chlorides.
4. glaze stone-pseudo glass according to claim 1, it is characterized in that, described frit consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 10 parts, aluminum oxide, 9 parts of aluminum phosphates, 5.6 parts, Calcium Fluoride (Fluorspan), 1.5 parts of potassium oxides, 0.08 part of sodium oxide, 0.014 part of gold perchloride, 0.05 part, copper sulfate, 2.5 parts of boron oxides, 5 parts of zirconium whites, 6 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.035 part, zinc oxide, 0.01 part of ferric oxide,
Described glaze consists of the following composition: 33.3 parts of silicon oxide, 9 parts, calcium oxide, 10.8 parts, magnesium oxide, 11.8 parts, aluminum oxide, 10 parts of aluminum phosphates, 3.5 parts, Calcium Fluoride (Fluorspan), 0.05 part of sodium oxide, 0.012 part of gold perchloride, 0.08 part, copper sulfate, 2 parts of boron oxides, 6 parts of zirconium whites, 5 parts of Lithium Oxide 98mins, 1 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.4 parts of weisspiessglanzs, 1.2 parts of Vanadium Pentoxide in FLAKESs, 1.4 parts of lanthanum trioxides, 1.4 parts of cerous carbonates, 1 part, zinc oxide, 3 parts of ferric oxide, 2 parts of cupric chlorides.
5. glaze stone-pseudo glass according to claim 1, it is characterized in that, described frit consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 11 parts, aluminum oxide, 9 parts of aluminum phosphates, 5.8 parts, Calcium Fluoride (Fluorspan), 0.1 part of potassium oxide, 0.03 part of sodium oxide, 0.015 part of gold perchloride, 1 part, copper sulfate, 1.5 parts of boron oxides, 5 parts of zirconium whites, 6 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.03 part, zinc oxide, 0.03 part of ferric oxide,
Described glaze consists of the following composition: 35 parts of silicon oxide, 9.46 parts, calcium oxide, 11.35 parts, magnesium oxide, 12 parts, aluminum oxide, 9 parts of aluminum phosphates, 2.5 parts, Calcium Fluoride (Fluorspan), 0.08 part of sodium oxide, 0.014 part of gold perchloride, 0.05 part, copper sulfate, 2.5 parts of boron oxides, 5 parts of zirconium whites, 6 parts of Lithium Oxide 98mins, 0.2 part of bismuth oxide, 2 parts of titanium oxide, 2 parts, barium oxide, 1.2 parts of weisspiessglanzs, 1.6 parts of Vanadium Pentoxide in FLAKESs, 1.2 parts of lanthanum trioxides, 1.2 parts of cerous carbonates, 0.035 part, zinc oxide, 7 parts of ferric oxide, 2.8 parts of cupric chlorides.
6. a preparation method for glaze stone-pseudo glass, is characterized in that, proportioning configuration starting material according to claim 1, after fusing crystallization, then annealing makes frit, then on frit moulding glaze.
7. a preparation method for glaze stone-pseudo glass, is characterized in that, proportioning configuration starting material according to claim 1, after sintering crystallization, then annealing makes frit, then on frit moulding glaze.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410082533.9A CN103819085B (en) | 2014-03-08 | 2014-03-08 | A kind of glaze stone-pseudo glass for building wall ground |
| CN201510730235.0A CN105236735A (en) | 2014-03-08 | 2014-03-08 | Glazed decorative brick for external wall and preparation method for glazed decorative brick |
| CN201510730335.3A CN105271718A (en) | 2014-03-08 | 2014-03-08 | Method for preparing glazed decorative strip |
| CN201510730220.4A CN105236739A (en) | 2014-03-08 | 2014-03-08 | Glazed floor brick and preparation method therefor |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410082533.9A CN103819085B (en) | 2014-03-08 | 2014-03-08 | A kind of glaze stone-pseudo glass for building wall ground |
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| CN201510730220.4A Division CN105236739A (en) | 2014-03-08 | 2014-03-08 | Glazed floor brick and preparation method therefor |
| CN201510730335.3A Division CN105271718A (en) | 2014-03-08 | 2014-03-08 | Method for preparing glazed decorative strip |
| CN201510730235.0A Division CN105236735A (en) | 2014-03-08 | 2014-03-08 | Glazed decorative brick for external wall and preparation method for glazed decorative brick |
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| CN103819085B CN103819085B (en) | 2016-09-07 |
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| CN201410082533.9A Expired - Fee Related CN103819085B (en) | 2014-03-08 | 2014-03-08 | A kind of glaze stone-pseudo glass for building wall ground |
| CN201510730220.4A Pending CN105236739A (en) | 2014-03-08 | 2014-03-08 | Glazed floor brick and preparation method therefor |
| CN201510730235.0A Pending CN105236735A (en) | 2014-03-08 | 2014-03-08 | Glazed decorative brick for external wall and preparation method for glazed decorative brick |
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| CN201510730235.0A Pending CN105236735A (en) | 2014-03-08 | 2014-03-08 | Glazed decorative brick for external wall and preparation method for glazed decorative brick |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104789222A (en) * | 2015-03-20 | 2015-07-22 | 淄博泰如工业新材料有限公司 | Special energy source luminescent material and production process thereof |
| CN105693088A (en) * | 2016-03-04 | 2016-06-22 | 苏州圣谱拉新材料科技有限公司 | Explosion-proof glass material and preparation method thereof |
| CN111606565A (en) * | 2020-07-06 | 2020-09-01 | 陈羿州 | Ceramic glaze with anti-skid matte effect |
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| CN106082958A (en) * | 2016-06-22 | 2016-11-09 | 徐晓 | A kind of preparation method of low grade fever's glazed tiles additive |
| CN107880594B (en) * | 2017-10-31 | 2020-04-07 | 湖南镭目科技有限公司 | Coating for auxiliary electrode of top-blown converter phosphorus determination sensor and top-blown converter phosphorus determination sensor |
| CN109020490A (en) * | 2018-09-06 | 2018-12-18 | 安庆仁创聚源生态环保科技有限公司 | A kind of composite permeable brick manufacturing process |
| CN115772004A (en) * | 2022-12-19 | 2023-03-10 | 东莞南玻太阳能玻璃有限公司 | Photovoltaic glaze, photovoltaic back plate glass, preparation method of photovoltaic back plate glass and double-glass photovoltaic module |
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| JPS5655569A (en) * | 1979-10-11 | 1981-05-16 | Ngk Spark Plug Co Ltd | Enameled steel plate |
| CN1810693A (en) * | 2005-01-24 | 2006-08-02 | 肖特股份公司 | Lead-free and cadmium-free glass for glazing, enameling and decoration of glasses or glass-ceramics |
| US20110091668A1 (en) * | 2008-10-20 | 2011-04-21 | Lamberson Lisa A | Antimony-free glass, antimony-free frit and a glass package that is hermetically sealed with the frit |
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- 2014-03-08 CN CN201510730335.3A patent/CN105271718A/en active Pending
- 2014-03-08 CN CN201410082533.9A patent/CN103819085B/en not_active Expired - Fee Related
- 2014-03-08 CN CN201510730220.4A patent/CN105236739A/en active Pending
- 2014-03-08 CN CN201510730235.0A patent/CN105236735A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5655569A (en) * | 1979-10-11 | 1981-05-16 | Ngk Spark Plug Co Ltd | Enameled steel plate |
| CN1810693A (en) * | 2005-01-24 | 2006-08-02 | 肖特股份公司 | Lead-free and cadmium-free glass for glazing, enameling and decoration of glasses or glass-ceramics |
| US20110091668A1 (en) * | 2008-10-20 | 2011-04-21 | Lamberson Lisa A | Antimony-free glass, antimony-free frit and a glass package that is hermetically sealed with the frit |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104789222A (en) * | 2015-03-20 | 2015-07-22 | 淄博泰如工业新材料有限公司 | Special energy source luminescent material and production process thereof |
| CN105693088A (en) * | 2016-03-04 | 2016-06-22 | 苏州圣谱拉新材料科技有限公司 | Explosion-proof glass material and preparation method thereof |
| CN111606565A (en) * | 2020-07-06 | 2020-09-01 | 陈羿州 | Ceramic glaze with anti-skid matte effect |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105236735A (en) | 2016-01-13 |
| CN105236739A (en) | 2016-01-13 |
| CN105271718A (en) | 2016-01-27 |
| CN103819085B (en) | 2016-09-07 |
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