CN109020490A - A kind of composite permeable brick manufacturing process - Google Patents

A kind of composite permeable brick manufacturing process Download PDF

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Publication number
CN109020490A
CN109020490A CN201811036153.6A CN201811036153A CN109020490A CN 109020490 A CN109020490 A CN 109020490A CN 201811036153 A CN201811036153 A CN 201811036153A CN 109020490 A CN109020490 A CN 109020490A
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Prior art keywords
permeable brick
water
underlayment
manufacturing process
temperature
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CN201811036153.6A
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Chinese (zh)
Inventor
吴连波
徐龙
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Anqing Renchuang Juyuan Ecological Environmental Protection Science And Technology Ltd Co
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Anqing Renchuang Juyuan Ecological Environmental Protection Science And Technology Ltd Co
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Priority to CN201811036153.6A priority Critical patent/CN109020490A/en
Publication of CN109020490A publication Critical patent/CN109020490A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/444Halide containing anions, e.g. bromide, iodate, chlorite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/606Drying
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Road Paving Structures (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention provides a kind of composite permeable brick manufacturing process, including material layers and underlayment, comprising the following steps: raw material selection, raw material proportioning, mixing, compression moulding, drying, firing;It wherein is added with silica sand and drift-sand in raw material selection, segmented is fired high temperature and is sintered to material layers, and medium temperature is sintered material layers and basal layer junction, and low temperature is sintered basal layer;A kind of composite water permeable brick of the present invention, freeze-thaw resistance and ageing-resistant performance are high, and material layers main material is from a wealth of sources, and basal layer cost of material is low, can reduce the production cost of water-permeable brick.

Description

A kind of composite permeable brick manufacturing process
Technical field
The present invention relates to environmental-friendly construction material field, specially a kind of composite permeable brick manufacturing process.
Background technique
Water-permeable brick reduces rainwash, pollution and the noise in city is reduced, in people's row due to that can feed greening water Surface road is decorated in road, community, the place of garden landscape road is widely used.
Due to the proposition of national environmental protection proposal, existing environment friendly pervious brick much utilizes discarded ceramic material or sewage plant Sludge powder is produced as raw material, but is not reached requirement as the water-permeable brick freeze-thaw resistance and resistance to ag(e)ing of raw material, is made The service life of its water-permeable brick reduces;If entire permeable brick body is all made of the materials such as high molecular material or marble, granite, make The production cost for obtaining water-permeable brick increases.
Summary of the invention
It is an object of the invention to provide a kind of composite permeable brick manufacturing process, to solve water-permeable brick resistance to ag(e)ing in the prior art It is low with freeze-thaw resistance, and the problem of high production cost.
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of composite permeable brick manufacturing process, including material Matter layer and underlayment, comprising the following steps:
(1) raw material are chosen: material layers include silica sand, shraff, drift-sand, mineralizer, underlayment include cement, water ash, The poly- ammonia fiber of rigidity is glued;
(2) raw material proportioning: shraff: 70%-80%, silica sand: 8%-10%, drift-sand: 10%-15%, mineralizer: 4%-5%, water Mud: 65%-80%, water ash: 10%-30%, the poly- ammonia fiber 3%-6% of rigidity;
(3) it is mixed: shraff being added into blender: 70%-80%, silica sand: 8%-10%, drift-sand: 10%-15%, mine Agent: 4%-5% obtains material layers mixing material after stirring;Cement is added into blender: 65%-80%, water ash: 10%-30%, The poly- ammonia fiber 3%-6% of rigidity is stirred, and underlayment mixing material is obtained after stirring;
(4) compression moulding: by the base layered material injection press die after stirring, compacting obtains underlayment, by what is stirred to get Material layer material is injected on underlayment, then is molded and is made by press;
(5) dry: to be dried by molding green body of the microwave to compacting;
(6) it fires: dry base substrate is placed on to the temperature controlled side for using three-stage " high temperature-medium temperature-low temperature " in baking furnace Method is fired adobe.
Preferably, the silica sand sorting in the step (1) is 4-8mm, after the shraff is crushed by pulverizer, With the partial size of 60-90 mesh is screened, and the powder of 6-9mm is filtered out, and the drift-sand sorting is 5-8mm.
Preferably, the mineralizer main component in the step (2) is magnesium chloride.
Preferably, adhesive 3%-5%, mixing time 30-40min, the material of underlayment is added when material layer material stirs Material stirring 5-10min.
Preferably, the step (4) is pressed into basal layer green body with the pressure of 15-25MPa, with the pressure pressure of 25-40MPa Water-permeable brick green body is made.
Preferably, the step (5) is done by green body from the dry 40-60min at 160-190 DEG C is poured out in mold Dry green body.
Preferably, step (6) material layers carry out the burning of 20-30min by a definite date under 1100-1300 DEG C of environment of high temperature Knot keeps the temperature 5-10min, then is cooled to 850-1000 DEG C in 8-10min and carries out 15- by a definite date to material layers and basal layer junction The sintering of 20min keeps the temperature 12-18min, then cools to 450-550 DEG C and be sintered to basal layer, keeps the temperature 40-60min, most After naturally cool to room temperature.
Compared with prior art, beneficial effects of the present invention: water-permeable brick of the invention uses combined type, the main material of material layers Expect that shraff is the partial size of 6-9mm, the silica sand sorting of addition is 4-8mm and drift-sand sorting is 5-8mm, because silica sand is with good Good acid-resisting scouring ability and freezing-thawing resistance, and the water holding capacity of water-permeable brick can be improved in the drift-sand raw material added, Matched by the pole between reasonable arrangement different materials, be mutually embedded between size size particle materials, improves the resistance to ag(e)ing of water-permeable brick And freeze-thaw resistance, while the mineralizer chlorination magnesium component being added can inhibit the abnormal growth of shraff crystal grain, improve permeable The flexural strength of brick;Underlayment uses cement and water ash for the intensity that water-permeable brick substrate can be enhanced without sand mixed mud of raw material, The cost of water-permeable brick is also reduced simultaneously.
It is to be understood that above-mentioned general description and following specific embodiments are merely illustrative and illustrative, not The range of the invention to be advocated can be limited.
Detailed description of the invention
Following attached drawing is part of specification of the invention, depicts example embodiments of the present invention, appended attached Figure is used to illustrate the principle of the present invention together with the description of specification.
Fig. 1 is flow chart of the invention.
Specific embodiment
The existing various exemplary embodiment that the present invention will be described in detail, the detailed description are not considered as to limit of the invention System, and it is understood as the more detailed description to certain aspects of the invention, characteristic and embodiment.
Without departing substantially from the scope or spirit of the invention, the specific embodiment of description of the invention can be done more Kind improvements and changes, this will be apparent to those skilled in the art.Other realities obtained by specification of the invention Applying mode for technical personnel is apparent obtain.Present specification and embodiment are merely exemplary.
Embodiment 1, a kind of environment friendly pervious brick of the prior art, comprising the following steps:
(1) ingredient: score weighs following raw material: 50 parts of shraff, 15 parts of sewage plant sludge powder, useless brick 10 respectively by weight Part, 8 parts of clay, 1 part of rosin, 10 parts of water;
(2) it stirs: 50 parts of shraff, 15 parts of sewage plant sludge powder and 10 parts of useless brick mixings being added into blender, The speed of stirring is 30r/min, mixing time 2min, adds 8 parts of clay, and 1 part and 10 parts of water of rosin resin is continued to stir 3min, mixture, aging 1d;
(3) base: in the mixture subject mold after will be aging, green body is pressed into the pressure of 15MPa;
(4) dry: green body is poured out from mold, the dry 2h at 175 DEG C, dry base substrate;
(5) it fires: dry base substrate being placed in the furnace that heating rate is 10 DEG C/min, fired at 1050 DEG C, keep the temperature 1h, so After be cooled to room temperature, arrive environment friendly pervious brick.
Embodiment 2, please refers to attached drawing 1, a kind of composite permeable brick manufacturing process, including material layers and underlayment, including with Lower step:
(1) raw material are chosen: material layers include silica sand, shraff, drift-sand, mineralizer, underlayment include cement, water ash, The poly- ammonia fiber of rigidity is glued;
(2) raw material proportioning: shraff: 70%, silica sand: 8%, drift-sand: 10%, mineralizer: 4%, cement: 65%, water ash: 10%, The poly- ammonia fiber 3% of rigidity;
(3) it is mixed: shraff being added into blender: 70%, silica sand: 8%, drift-sand: 10%, mineralizer: 4%, bonding Agent 3%, mixing time 30min obtain material layers mixing material after stirring;Cement is added into blender: 65%, water ash: 10%, the poly- ammonia fiber 3% of rigidity is stirred, and mixing time 5min obtains underlayment mixing material after stirring;
(4) it compression moulding: by the base layered material injection press die after stirring, suppresses to obtain underlayment with the pressure of 20MPa The material layer material stirred to get is injected on underlayment green body by green body, then press molding is made again with 38MPa pressure Water adobe body;
(5) dry: water-permeable brick green body is poured out from mold, and dry 40min, obtains dry base substrate at 160 DEG C;
(6) it fires: dry base substrate is placed in baking furnace using the burning that at 1100 DEG C of high temperature material layers are carried out with 20min by a definite date Knot keeps the temperature 5min, then is cooled to 850 DEG C of sintering for scheduling to last 15min to material layers and basal layer junction in 8min, continues to drop 450 DEG C of temperature is sintered basal layer, keeps the temperature 40min, and last cooled to room temperature obtains composite water permeable brick.
Embodiment 3, please refers to attached drawing 1, a kind of composite permeable brick manufacturing process, including material layers and underlayment, including with Lower step:
(1) raw material are chosen: material layers include silica sand, shraff, drift-sand, mineralizer, underlayment include cement, water ash, The poly- ammonia fiber of rigidity is glued;
(2) raw material proportioning: shraff: 75%, silica sand: 9%, drift-sand: 13%, mineralizer: 4.5%, cement: 75%, water ash: 20%, the poly- ammonia fiber 4.5% of rigidity;
(3) it is mixed: shraff being added into blender: 75%, silica sand: 9%, drift-sand: 13%, mineralizer: 4.5%, it glues Mixture 4%, mixing time 35min obtain material layers mixing material after stirring;Cement is added into blender: 75%, water ash: 20%, the poly- ammonia fiber 4.5% of rigidity is stirred, and mixing time 8min obtains underlayment mixing material after stirring;
(4) it compression moulding: by the base layered material injection press die after stirring, suppresses to obtain underlayment with the pressure of 15MPa The material layer material stirred to get is injected on underlayment green body by green body, then press molding is made again with 38MPa pressure Water adobe body;
(5) dry: water-permeable brick green body is poured out from mold, and dry 50min, obtains dry base substrate at 175 DEG C;
(6) it fires: dry base substrate is placed in baking furnace using the burning that at 1200 DEG C of high temperature material layers are carried out with 25min by a definite date Knot keeps the temperature 8min, then is cooled to 900 DEG C of sintering for scheduling to last 18min to material layers and basal layer junction in 9min, continues to drop 500 DEG C of temperature is sintered basal layer, keeps the temperature 50min, and last cooled to room temperature obtains composite water permeable brick.
Embodiment 4, please refers to attached drawing 1, a kind of composite permeable brick manufacturing process, including material layers and underlayment, including with Lower step:
(1) raw material are chosen: material layers include silica sand, shraff, drift-sand, mineralizer, underlayment include cement, water ash, The poly- ammonia fiber of rigidity is glued;
(2) raw material proportioning: shraff: 80%, silica sand: 10%, drift-sand: 15%, mineralizer: 5%, cement: 80%, water ash: 30%, The poly- ammonia fiber 6% of rigidity;
(3) it is mixed: shraff being added into blender: 80%, silica sand: 10%, drift-sand: 15%, mineralizer: 5%, bonding Agent 5%, mixing time 40min obtain material layers mixing material after stirring;Cement is added into blender: 80%, water ash: 30%, the poly- ammonia fiber 6% of rigidity is stirred, and mixing time 10min obtains underlayment mixing material after stirring;
(4) it compression moulding: by the base layered material injection press die after stirring, suppresses to obtain underlayment with the pressure of 25MPa The material layer material stirred to get is injected on underlayment green body by green body, then press molding is made again with 40MPa pressure Water adobe body;
(5) dry: water-permeable brick green body is poured out from mold, and dry 60min, obtains dry base substrate at 190 DEG C;
(6) it fires: dry base substrate is placed in baking furnace using the burning that at 1300 DEG C of high temperature material layers are carried out with 30min by a definite date Knot keeps the temperature 10min, then is cooled to 1000 DEG C of sintering for scheduling to last 20min to material layers and basal layer junction in 10min, after Continuous 550 DEG C of cooling is sintered basal layer, keeps the temperature 60min, and last cooled to room temperature obtains composite water permeable brick.
In conclusion water-permeable brick of the invention uses combined type, the main material shraff of material layers is the grain of 6-9mm Diameter, the silica sand sorting of addition is 4-8mm and drift-sand sorting is 5-8mm, because silica sand has good acid-resisting scouring ability And freezing-thawing resistance, and the water holding capacity of water-permeable brick can be improved in the drift-sand raw material added, passes through reasonable arrangement different materials Between pole match, be mutually embedded between size size particle materials, the resistance to ag(e)ing and freeze-thaw resistance of water-permeable brick improved, using high temperature section Material layers are sintered, cementation power between mixed raw material in raising material layers, so that brick body is with higher wear-resisting strong Degree;The mineralizer chlorination magnesium component being added simultaneously can inhibit the abnormal growth of shraff crystal grain, improve the anti-folding of water-permeable brick Intensity;Underlayment uses cement and water ash that the intensity of water-permeable brick substrate can be enhanced without sand mixed mud for raw material, while also dropping The cost of low water-permeable brick.
The foregoing is merely the schematical specific embodiments of the present invention, before not departing from conceptions and principles of the invention It puts, the equivalent changes and modifications that any those skilled in the art is made should belong to the scope of protection of the invention.

Claims (7)

1. a kind of composite permeable brick manufacturing process, including material layers and underlayment, which comprises the following steps:
(1) raw material are chosen: material layers include silica sand, shraff, drift-sand, mineralizer, underlayment include cement, water ash, The poly- ammonia fiber of rigidity is glued;
(2) raw material proportioning: shraff: 70%-80%, silica sand: 8%-10%, drift-sand: 10%-15%, mineralizer: 4%-5%, water Mud: 65%-80%, water ash: 10%-30%, the poly- ammonia fiber 3%-6% of rigidity;
(3) it is mixed: shraff being added into blender: 70%-80%, silica sand: 8%-10%, drift-sand: 10%-15%, mine Agent: 4%-5% obtains material layers mixing material after stirring;Cement is added into blender: 65%-80%, water ash: 10%-30%, The poly- ammonia fiber 3%-6% of rigidity is stirred, and underlayment mixing material is obtained after stirring;
(4) compression moulding: by the base layered material injection press die after stirring, it is pressed into underlayment green body, will be stirred to get Material layer material be injected on underlayment green body, then by press molding water-permeable brick green body is made;
(5) dry: to be dried by molding green body of the microwave to compacting;
(6) it fires: dry base substrate is placed on to the temperature controlled side for using three-stage " high temperature-medium temperature-low temperature " in baking furnace Method is fired adobe.
2. a kind of composite permeable brick manufacturing process according to claim 1, which is characterized in that the silica sand sorting in the step (1) It is screened with the partial size of 60-90 mesh after the shraff is crushed by pulverizer for 4-8mm, filters out 6-9mm's Powder, the drift-sand sorting are 5-8mm.
3. a kind of composite permeable brick manufacturing process according to claim 1, which is characterized in that the mineralizer master in the step (2) Wanting ingredient is magnesium chloride.
4. a kind of composite permeable brick manufacturing process according to claim 1, which is characterized in that step (3) the material layer material stirs Adhesive 3%-5% is added when mixing, the material of mixing time 30-40min, underlayment stir 5-10min.
5. a kind of composite permeable brick manufacturing process according to claim 1, which is characterized in that the step (4) is with 15-25MPa's Pressure is pressed into basal layer green body, is pressed into water-permeable brick green body with the pressure of 25-40MPa.
6. a kind of composite permeable brick manufacturing process according to claim 1, which is characterized in that the step (5) is by green body from mold In pour out at 160-190 DEG C dry 40-60min, obtain dry base substrate.
7. a kind of composite permeable brick manufacturing process according to claim 1, which is characterized in that step (6) material layers are in high temperature The sintering of 20-30min by a definite date is carried out under 1100-1300 DEG C of environment, keeps the temperature 5-10min, then 850- is cooled in 8-10min 1000 DEG C of junctions to material layers and basal layer carry out the sintering of 15-20min by a definite date, keep the temperature 12-18min, then cool to 450-550 DEG C is sintered basal layer, keeps the temperature 40-60min, finally naturally cools to room temperature.
CN201811036153.6A 2018-09-06 2018-09-06 A kind of composite permeable brick manufacturing process Pending CN109020490A (en)

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Application publication date: 20181218