CN108083769A - A kind of sintering brick permeable to water produced using ceramic particle and preparation method thereof - Google Patents
A kind of sintering brick permeable to water produced using ceramic particle and preparation method thereof Download PDFInfo
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- CN108083769A CN108083769A CN201711401270.3A CN201711401270A CN108083769A CN 108083769 A CN108083769 A CN 108083769A CN 201711401270 A CN201711401270 A CN 201711401270A CN 108083769 A CN108083769 A CN 108083769A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1315—Non-ceramic binders
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/6303—Inorganic additives
- C04B35/6316—Binders based on silicon compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63444—Nitrogen-containing polymers, e.g. polyacrylamides, polyacrylonitriles, polyvinylpyrrolidone [PVP], polyethylenimine [PEI]
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/636—Polysaccharides or derivatives thereof
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- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0038—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by superficial sintering or bonding of particulate matter
- C04B38/0041—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by superficial sintering or bonding of particulate matter the particulate matter having preselected particle sizes
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
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Abstract
The invention discloses a kind of sintering brick permeable to water produced using ceramic particle, including fabric and bottom material, wherein, primary raw material of the bottom material in terms of mass parts is as follows：Ceramic 80 100 parts of particle bonds 3 12 parts of base-material, 3 12 parts of liquid glue；Primary raw material of the fabric in terms of mass parts is as follows：Ceramic 0 30 parts of particle bonds 04 parts of base-material, 04 parts of liquid glue, 04 parts of colorant；The cohesive base-material is bentonite, the one or more in clay；The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.Correspondingly, the invention discloses a kind of preparation methods of the sintering brick permeable to water produced using ceramic particle.The use of ceramic particle is primary raw material, the intensity height of water-permeable brick obtained, frost resistance are strong, excellent water permeability using the present invention.
Description
Technical field
The present invention relates to water-permeable brick technical field more particularly to a kind of sintering brick permeable to water produced using ceramic particle and its
Preparation method.
Background technology
Water-permeable brick is to alleviate urban waterlogging, while keeping moisture, safeguards balance of city ecosystem structure sponge city and grand
The century environment-friendly building materials new product being born again.It using useless ceramic tile (useless polished bricks, useless glazed tile, useless tile etc.), ceramic particle,
The solid wastes such as slag are primary raw material, are equipped with shaping assistant, add suitable binding agent, are molded through cloth twice, and high temperature is burnt
Into being green product.
Water-permeable brick can consume a large amount of useless ceramic tiles (solid wastes such as ceramic particle or slag), this is not only solved at this stage
The processing problem of solid waste, also substantially reduces the pollution to environment.The ceramic water-permeable brick produced can be directly used in city
City is built, and is turned waste into wealth.Therefore, there is apparent social effect.
Water-permeable brick is divided into sintering class water-permeable brick and coagulation great soil group water-permeable brick, wherein sintering class water-permeable brick is needed by high temperature
It burns till, and coagulation great soil group water-permeable brick needs not move through high temperature firing.
The prior art 1 is the patent of invention of 101955349 B of Publication No. CN, and it discloses a kind of water-permeable brick, water-permeable bricks
Using ceramic waste residue powder, cullet powder, useless porcelain fragment powder, the useless mud powder in municipal administration basis, calcium oxide, calcium sulfate, swelling
Soil, talcum powder, cinder powder, useless pure plant powder and water are raw material, stir and use mechanical oscillation extrusion forming in after moist shape
For water-permeable brick lower floor brick, then with secondary material distributing machine one layer of fine flour material (main component is uniformly distributed on the top of water-permeable brick lower floor brick
For waste ceramic fragment powder, bentonite, water), ceramic waste residue sintering pervious environment protection is then manufactured under the pressure of 25~30MPa
Adobe is spontaneously dried.The feeding tunnel oven of the ceramic waste residue pervious environment protection adobe after natural drying will be molded again to roast
It burns, temperature control is fired into the range of 1150~1200 DEG C.In said program, the useless body refuse fine powder in municipal administration basis and bentonite are
Binding agent.In the prior art 1, the addition of waste ceramic fragment powder is 20-30 parts, and bentonitic addition is 5-8 parts, municipal administration
The addition of the useless mud powder in basis is 20-30 parts, that is to say, that the addition of waste ceramic fragment powder is about 20-30 parts, glues
The addition of knot agent is about 25-38 parts.The addition of waste ceramic fragment powder is less, and consumption of binder is more, and described viscous
The ultimate load of knot agent is relatively low, causes the blank strength after shaping low.
The predominantly useless polished bricks of the raw material of water-permeable brick disclosed in the prior art 2, the formula of raw material are：Useless ceramic tile 10-
40 parts, 66-130 parts of binding agent, wherein, binding agent includes 60-90 parts of bentonite, 5-20 parts of frit (glass dust etc.), carboxymethyl
1-20 parts of sodium cellulosate.In the prior art, the addition of useless ceramic tile is few, and consumption of binder is extremely more.And the pole of the binding agent
Limit load load is relatively low, generally in 64.8N or so, causes the blank strength after shaping low.
In addition, the technological process of existing water-permeable brick is complex, production process is more, and time-consuming, of high cost, technological process
Figure is as shown in Figure 1.Referring to Fig. 1, the binding agent of existing water-permeable brick needs individual ball milling, still, ball milling process operations time
Long, ball-grinding machine is bulky, takes up a large area, and will so considerably increase the production cost of water-permeable brick.
The content of the invention
The technical problems to be solved by the invention are, provide a kind of sintering brick permeable to water produced using ceramic particle, institute
The intensity of stating water-permeable brick is high, frost resistance is strong, excellent water permeability.
In order to solve the above technical problem, the present invention provides a kind of sintering brick permeable to water produced using ceramic particle, bags
Fabric and bottom material are included, wherein, primary raw material of the bottom material in terms of mass parts is as follows：
Ceramic particle 80-100 parts
Bond 3-12 parts of base-material
3-12 parts of liquid glue；
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
As the improvement of said program, including fabric and bottom material, wherein, primary raw material of the bottom material in terms of mass parts is such as
Under：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.As upper
State the improvement of scheme, the polyacrylamide solution is Sodium Polyacrylate, polyvinyl pyridine salt, one kind in polyethyleneimine or
It is a variety of.
As the improvement of said program, the clay is kaolin, the one or more in black mud, Municipal sludge.
As the improvement of said program, the shraff is domestic ceramics particle, bathroom ceramics particle, the art pottery are broken
One or more in material.
As the improvement of said program, the dosage weight ratio of the bottom material and fabric is 70-100:0-30.
As the improvement of said program, the ceramic particle of the fabric includes：
4-20 mesh ceramics particles 100wt%.
As the improvement of said program, the ceramic particle of the bottom material includes：
4-20 mesh ceramics particles 20-50wt%
12-40 mesh ceramics particles 20-50wt%
40 mesh ceramics particle 0-60wt% of ＜.
Correspondingly, the preparation method of the sintering brick permeable to water produced the present invention also provides a kind of ceramic particle of use, including：
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and stir
Uniformly, bottom material is obtained；By the ceramic particle after sieving, dispensing is carried out by formula, adds in and bonds base-material, liquid glue and color
Material, and stir evenly, obtain fabric；
(4) fabric after stirring and bottom material are obtained into green body through cloth twice and compression moulding；
(5) green body in kiln through and firing, obtain finished product.
As the improvement of said program, in the compression moulding step, the pressure of press is 1500-2000T；
In the firing step, the temperature of firing is 1100-1220 DEG C.
Implement the present invention, have the advantages that：
The present invention is primary raw material using ceramic particle, and the water-permeable brick that the amount ratio of ceramic particle is common is much higher, pottery
The dosage ＞ 85% of porcelain particle can largely consume ceramic particle, achieve the purpose that height recycle solid waste, change give up into
Treasured, environmental protection and energy saving.
The binding agent includes bonding base-material and liquid glue, and it can be bentonite, kaolin, black mud or city to bond base-material
One or more in municipal sludge, binding agent of the present invention innovatively add in liquid glue, considerably increase binding agent first
Ultimate load, the ultimate load of binding agent of the present invention are up to 150.8N, improve the blank strength of water-permeable brick；Secondly, the present invention
Binding agent so that green body is easily molded, simplifies molding process, reduces molding difficulty；Finally, binding agent of the present invention is easy to operate,
Simple batch mixing is only needed, the step of without being pre-mixed ball milling, simplifies process, reduces cost.
The preparation method of water-permeable brick of the present invention is crushed including raw material, sieved, the stirring of dispensing, batch mixing, compression moulding, firing etc.
Step, the present invention simplify process, reduce cost, shorten the production time, and pass through made from above-mentioned preparation method thoroughly without ball milling
Water brick, intensity height, excellent water permeability, frost resistance are strong.
Description of the drawings
Fig. 1 is the process flow chart of the existing sintering brick permeable to water produced using ceramic particle；
Fig. 2 is the process flow chart for the sintering brick permeable to water that the present invention is produced using ceramic particle.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, the present invention is made into one below in conjunction with attached drawing
It is described in detail on step ground.
The present invention provides a kind of sintering brick permeable to water produced using ceramic particle, including fabric and bottom material, the bottom material
Dosage weight ratio with fabric is 70-100:0-30.Preferably, the dosage weight ratio of the bottom material and fabric is 80-90:10-
20.When fabric mixture is 0, water-permeable brick only includes bottom, and all-body tile is made.When water-permeable brick needs color, water-permeable brick
Including surface layer and bottom, the dosage weight ratio of bottom material mixture and fabric mixture is 70-99.9:0.1-30.
Wherein, primary raw material of the bottom material in terms of mass parts is as follows：
Ceramic particle 80-100 parts
Bond 3-12 parts of base-material
3-12 parts of liquid glue；
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
Ceramics particle is essentially available for landfill at present or balcony is stacked, and occupies substantial amounts of soil, and by high-temperature firing
The extremely difficult weathering of ceramic particle crossed, not good treating method.
The water-permeable brick that the amount ratio of ceramics particle of the invention is common is much higher, the dosage ＞ 85% of ceramic particle, can be with
A large amount of ceramic particles of consumption, achieve the purpose that height recycles solid waste, turn waste into wealth, environmental protection and energy saving.
The present invention selects specific binding agent, is formed by bonding base-material and liquid glue, wherein, base-material is bonded with plastic
Property, it can help to be molded and enhance blank strength, liquid glue can make the combination of ceramic particle and bonding base-material more close.The two
Cooperation, it can be ensured that the intensity and good firing property that water-permeable brick has had in process of production.
Specifically, the intensity of water-permeable brick of the present invention mainly refers to two stages respectively：After one stage is press-molding
Shaping strength (mainly ensures molding blank not cracky before firing), and one is that product intensity after burning till (mainly produces
The final performance of product, product using when can bear great pressure, such as vehicle can be forced up directly).This hair
Prescribed liquid glue is mainly used for ensureing the processability and shaping strength of formula；Bond the base-material mainly energy after high temperature sintering
It is enough that cementation is played between particle and particle, it is for ensureing the intensity of final products.
As the preferred embodiment of the present invention, primary raw material of the bottom material in terms of mass parts is as follows：
Ceramic particle 90-96 parts
Bond 5-8 parts of base-material
5-8 parts of liquid glue；
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
Frit is additionally added as the present invention more preferably embodiment, the binding agent, i.e.
Primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
After the present invention adds in frit, product strength can be improved and reduce the firing temperature of water-permeable brick.
In any of the above-described formula, the polyacrylamide solution is preferably Sodium Polyacrylate, polyvinyl pyridine salt, poly- second
One or more in alkene imines.The present invention selects the macromolecules such as Sodium Polyacrylate, polyvinyl pyridine salt, polyethyleneimine organic
Binding agent so that liquid glue can fully wrap up the surface of water-permeable brick ceramics particle particle, improve the intensity of water-permeable brick.
The clay is kaolin, the one or more in black mud, Municipal sludge.List of the invention can use swollen
Profit soil, can also use the clays such as kaolin, black mud, Municipal sludge, substantially increases the convenience of application, raw material sources
It is abundant.
For binding agent in the case where adding in equivalent, the performance comparison of binding agent of the present invention and existing binding agent is as follows：
| Binding agent | Test green body size (mm) | Ultimate load (N) | Cost |
| The existing binding agent in market | 80×40×15 | 62-65 | 7.92 yuan/square |
| Binding agent of the present invention | 80×40×15 | 150-160 | 3.2 yuan/square |
Binding agent of the present invention innovatively adds in liquid glue, considerably increases the ultimate load of binding agent first, the present invention
The ultimate load of binding agent is up to 150.8N, improves the blank strength of water-permeable brick；Secondly, binding agent of the present invention so that green body is easy
Shaping simplifies molding process, reduces molding difficulty；Finally, binding agent of the present invention is easy to operate, and only the simple batch mixing of need is
Can, the step of without being pre-mixed ball milling, simplify process, reduce cost.
Further, the present invention use ceramic particle the shraff is domestic ceramics particle, bathroom as primary raw material
One or more in ceramic particle, art pottery particle.Preferably, the shraff is domestic ceramics particle, bathroom is made pottery
Any one in porcelain particle, art pottery particle.
In order to improve the intensity of water-permeable brick, the processability of water-permeable brick green body is improved, the ceramics particle selects specific
Blending powder, it is specific as follows：
Ceramic particle in the fabric mixture includes：
4-20 mesh ceramics particles 100wt%.
Ceramic particle in the fabric mixture selects the ceramic particle of 4-20 mesh, and this grain composition contributes to finished product
Hole is formed, reaches permeable effect, and obtains good appearance property and comfort level.
If fabric particle is too big, one side finished surface is too coarse, be not suitable for square brick use, people go to above or
Person's bicycle rides over influences comfort level above, and on the other hand, the flatness on adobe surface can be poor, and especially marginal position is uneven
Whole, paving comes out aesthetics and adaptation is poor.
Ceramic particle in the bottom material mixture includes：
4-20 mesh ceramics particles 20-50wt%
12-40 mesh ceramics particles 20-50wt%
40 mesh ceramics particle 0-60wt% of ＜.
Ceramic particle in the bottom material mixture selects 4-20 mesh, the ceramic particle of 40 mesh of 12-40 mesh and ＜, and
The ceramic particle of 40 mesh of 4-20 mesh, 12-40 mesh and ＜ mixes according to a certain ratio, and this grain composition contributes to finished product to form hole
Hole reaches permeable effect.And it can also be allowed as far as possible in the case where meeting product final strength and break off next material all bases
Instinct is finished, and does not leave clout, cost-effective, avoids wasting.
Correspondingly, as shown in Fig. 2, the present invention also provides a kind of preparation sides of the sintering brick permeable to water produced using ceramic particle
Method, including：
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and stir
Uniformly, bottom material is obtained；By the ceramic particle after sieving, dispensing is carried out by formula, adds in and bonds base-material, liquid glue and color
Material, and stir evenly, obtain fabric；
(4) fabric after stirring and bottom material are obtained into green body through cloth twice and compression moulding；
In the compression moulding step, the pressure of press is 1500-2000T.Preferably, the pressure of press is 1600-
1800T。
(5) green body in kiln through and firing, obtain finished product.
In the firing step, the temperature of firing is 1100-1220 DEG C.Preferably, the temperature of firing is 1180-1200
℃。
Water-permeable brick produced by the present invention and existing water-permeable brick, performance comparison are as follows：
It should be noted that compression strength of the present invention passes through under conditions of being 27 DEG C of temperature, humidity 53%
YQ027SHT4305 microcomputer controlled electro-hydraulic servo testing machines measure, and the specimen sample specification of the water-permeable brick is as follows：Long 68mm, width
64mm.The examination criteria reference standard JG/T 376-2012 of frost resistance are carried out.
From the foregoing, it will be observed that compared with prior art, compression strength of the invention, which has, to be obviously improved, coefficient of permeability there has also been
Significantly improve, and frost resistance might as well, wherein, after 25 Frozen-thawed cycleds, mass loss is few, loss of strength is few.
With specific embodiment, the present invention is further explained below
Embodiment 1
(1) it is formulated：Including fabric and bottom material, wherein, primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is bentonite, and the liquid glue is silicon sol solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, and the liquid glue is silicon sol solution；
(2) preparation method
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and is stirred equal
It is even, obtain bottom material；By the ceramic particle after sieving, dispensing is carried out by formula, adds in and bonds base-material, liquid glue and colorant,
And stir evenly, obtain fabric；
(4) by the fabric after stirring and bottom material through cloth twice and compression moulding, the pressure of press is 1500T, obtains base
Body；
(5) green body in kiln through and firing, the temperature of firing is 1100 DEG C, obtains finished product.
Embodiment 2
(1) it is formulated：Including fabric and bottom material, wherein, primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is kaolin, and the liquid glue is Sodium Polyacrylate；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is black mud, and the liquid glue is polyvinyl pyridine salt；
(2) preparation method
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and is stirred equal
It is even, obtain bottom material；By the ceramic particle after sieving, dispensing is carried out by formula, adds in and bonds base-material, liquid glue and colorant,
And stir evenly, obtain fabric；
(4) by the fabric after stirring and bottom material through cloth twice and compression moulding, the pressure of press is 1800T, obtains base
Body；
(5) green body in kiln through and firing, the temperature of firing is 1180 DEG C, obtains finished product.
Embodiment 3
(1) it is formulated：Including fabric and bottom material, wherein, primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is Municipal sludge, and the liquid glue is guar gum solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is Municipal sludge, and the liquid glue is guar gum solution；
(2) preparation method
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and is stirred equal
It is even, obtain bottom material；By the ceramic particle after sieving, dispensing is carried out by formula, adds in and bonds base-material, liquid glue and colorant,
And stir evenly, obtain fabric；
(4) by the fabric after stirring and bottom material through cloth twice and compression moulding, the pressure of press is 1900T, obtains base
Body；
(5) green body in kiln through and firing, the temperature of firing is 1200 DEG C, obtains finished product.
Embodiment 4
(1) it is formulated：Including fabric and bottom material, wherein, primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is bentonite, and the liquid glue is silicon sol solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, and the liquid glue is polyethyleneimine.
(2) preparation method
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and is stirred equal
It is even, obtain bottom material；By the ceramic particle after sieving, dispensing is carried out by formula, adds in and bonds base-material, liquid glue and colorant,
And stir evenly, obtain fabric；
(4) by the fabric after stirring and bottom material through cloth twice and compression moulding, the pressure of press is 1900T, obtains base
Body；
(5) green body in kiln through and firing, the temperature of firing is 1210 DEG C, obtains finished product.
Embodiment 5
(1) it is formulated：Including bottom material, wherein, primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is bentonite, and the liquid glue is Sodium Polyacrylate；
(2) preparation method
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and is stirred equal
It is even, obtain bottom material；
(4) by the bottom material after stirring through cloth and compression moulding, the pressure of press is 2000T, obtains green body；
(5) green body in kiln through and firing, the temperature of firing is 1220 DEG C, obtains finished product.
Embodiment 1-5 is done into technology detection, it is as a result as follows：
From the foregoing, it will be observed that sintering brick permeable to water of the present invention, compression strength >=55MPa, coefficient of permeability >=4.2*10-2, and 25 jellies
Melt cycle after mass loss and compression strength loss rate it is all very small, it was demonstrated that frost resistance is good.
In conclusion implementing the present invention, have the advantages that：
The present invention is primary raw material using ceramic particle, and the water-permeable brick that the amount ratio of ceramic particle is common is much higher, pottery
The dosage ＞ 85% of porcelain particle can largely consume the ceramics such as red granite, Luoyuan, quartz, porcelain stone, potassium feldspar or albite
Particle, achieve the purpose that height recycle solid waste, turn waste into wealth, environmental protection and energy saving.
The binding agent includes bonding base-material and liquid glue, and it can be bentonite, kaolin, black mud or city to bond base-material
One or more in municipal sludge, binding agent of the present invention innovatively add in liquid glue, considerably increase binding agent first
Ultimate load, the ultimate load of binding agent of the present invention are up to 150.8N, improve the blank strength of water-permeable brick；Secondly, the present invention
Binding agent so that green body is easily molded, simplifies molding process, reduces molding difficulty；Finally, binding agent of the present invention is easy to operate,
Simple batch mixing is only needed, the step of without being pre-mixed ball milling, simplifies process, reduces cost.
The preparation method of water-permeable brick of the present invention is crushed including raw material, sieved, the stirring of dispensing, batch mixing, compression moulding, firing etc.
Step, the present invention simplify process, reduce cost, shorten the production time, and pass through made from above-mentioned preparation method thoroughly without ball milling
Water brick, intensity height, excellent water permeability, frost resistance are strong.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected
The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, those of ordinary skill in the art should
Understand, technical scheme can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention
And scope.
Claims (10)
1. a kind of sintering brick permeable to water produced using ceramic particle, which is characterized in that including fabric and bottom material, wherein, the bottom
Expect that the primary raw material in terms of mass parts is as follows：
Ceramic particle 80-100 parts
Bond 3-12 parts of base-material
3-12 parts of liquid glue；
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
2. the sintering brick permeable to water as described in claim 1 produced using ceramic particle, which is characterized in that including fabric and bottom
Material, wherein, primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, the one or more in clay；
The liquid glue is silicon sol solution, polyacrylamide solution, the one or more of guar gum solution.
3. the sintering brick permeable to water produced such as claim 1-2 any one of them using ceramic particle, which is characterized in that described poly-
Acrylamide solution is Sodium Polyacrylate, the one or more in polyvinyl pyridine salt, polyethyleneimine.
4. the sintering brick permeable to water produced such as claim 1-2 any one of them using ceramic particle, which is characterized in that described viscous
Soil is kaolin, the one or more in black mud, Municipal sludge.
5. the sintering brick permeable to water produced such as claim 1-2 any one of them using ceramic particle, which is characterized in that the pottery
Porcelain waste material is domestic ceramics particle, the one or more in bathroom ceramics particle, art pottery particle.
6. the sintering brick permeable to water produced such as claim 1-2 any one of them using ceramic particle, which is characterized in that the bottom
The dosage weight ratio of material and fabric is 70-100:0-30.
7. the sintering brick permeable to water as described in claim 1 produced using ceramic particle, which is characterized in that the ceramics of the fabric
Particle includes：
4-20 mesh ceramics particles 100wt%.
8. the sintering brick permeable to water as described in claim 1 produced using ceramic particle, which is characterized in that the ceramics of the bottom material
Particle includes：
4-20 mesh ceramics particles 20-50wt%
12-40 mesh ceramics particles 20-50wt%
40 mesh ceramics particle 0-60wt% of ＜.
9. a kind of preparation method of sintering brick permeable to water produced using ceramic particle as described in claim 1-8, feature are existed
In, including：
(1) ceramic particle is crushed；
(2) broken ceramic particle is crossed to the sieve of different pore size, obtains the particle of variable grain degree；
(3) by the ceramic particle after sieving, dispensing is carried out by backing material formula, adds in and bonds base-material, liquid glue, and stirred evenly,
Obtain bottom material；By the ceramic particle after sieving, dispensing is carried out by formula, adds in and bonds base-material, liquid glue and colorant, and stir
It mixes uniformly, obtains fabric；
(4) fabric after stirring and bottom material are obtained into green body through cloth twice and compression moulding；
(5) green body in kiln through and firing, obtain finished product.
10. the preparation method of the sintering brick permeable to water as claimed in claim 9 produced using ceramic particle, which is characterized in that institute
It states in compression moulding step, the pressure of press is 1500-2000T；
In the firing step, the temperature of firing is 1100-1220 DEG C.
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| CN201711401270.3A CN108083769A (en) | 2017-12-22 | 2017-12-22 | A kind of sintering brick permeable to water produced using ceramic particle and preparation method thereof |
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| CN201711401270.3A CN108083769A (en) | 2017-12-22 | 2017-12-22 | A kind of sintering brick permeable to water produced using ceramic particle and preparation method thereof |
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| CN109020490A (en) * | 2018-09-06 | 2018-12-18 | 安庆仁创聚源生态环保科技有限公司 | A kind of composite permeable brick manufacturing process |
| CN109824345A (en) * | 2019-01-29 | 2019-05-31 | 唐山燕山钢铁有限公司 | Using vessel slag and lithium tailing as the preparation method of the ceramic water-permeable brick of raw material |
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| CN110981422A (en) * | 2019-12-19 | 2020-04-10 | 佛山生态海绵城市科技发展有限公司 | Glass waste residue ceramic water permeable brick and preparation process thereof |
| CN115368113A (en) * | 2022-09-29 | 2022-11-22 | 湖南华联瓷业股份有限公司 | Method for recycling waste porcelain |
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| CN109824345A (en) * | 2019-01-29 | 2019-05-31 | 唐山燕山钢铁有限公司 | Using vessel slag and lithium tailing as the preparation method of the ceramic water-permeable brick of raw material |
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| CN115368113A (en) * | 2022-09-29 | 2022-11-22 | 湖南华联瓷业股份有限公司 | Method for recycling waste porcelain |
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Application publication date: 20180529 |