CN105218003A - A kind of outdoor ceramic permeable brick and preparation method thereof - Google Patents
A kind of outdoor ceramic permeable brick and preparation method thereof Download PDFInfo
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- CN105218003A CN105218003A CN201410288833.2A CN201410288833A CN105218003A CN 105218003 A CN105218003 A CN 105218003A CN 201410288833 A CN201410288833 A CN 201410288833A CN 105218003 A CN105218003 A CN 105218003A
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Abstract
A kind of outdoor ceramic permeable brick, comprise bed material and surface layer, the composition of bed material and weight content are: be broken into and be greater than 0 and be less than 200 object ceramic waste material particle: 90-95wt%, tackiness agent: 5-10wt%, described tackiness agent is wilkinite; Surface layer is greater than 0 and is less than 200 object ceramic waste material particle and tackiness agents for coloured being broken into of band, or colorant and be broken into and be greater than the mixture that 0 is less than 200 object ceramic waste material particles and tackiness agent, facing weights is 20% of bed material weight, and described colorant is ceramic industry common pigments.
Description
Technical field
What the present invention relates to is a kind of outdoor ceramic permeable brick and production method thereof, concretely, what the present invention relates to is that one utilizes the renewable resource materials such as ceramic waste product and industrial residue, by being processed into specific granularity, with special combination agent and mineral dye at high temperature calcine outdoor ceramic permeable brick and production method.
Background technology
China is the concurrent country of an arid, flood, the draining contradiction of the water conservation of arid area and area of heavy rainfull is abnormal outstanding, many cities and towns by reinforced concrete building, Large Infrastructure Projects, various fluid-tight place and road cover, while these fluid-tight places and road surface have recovery electric heating system, lack respiratory and infiltration of rainwater, to make rational planning for surface rain runoff approach, at utmost reduce rainwash, multiple infiltration measure is adopted to increase the infiltration capacity of rainwater, therefore, a large amount of employing various place of dank material making and road surface.
Along with the fast development of social economy and ceramic industry, ceramic industry waste material is increasing, it is not only exerted heavy pressures on to urban environment, but also limits the development of urban economy and the Sustainable development of ceramic industry, so the treatment and utilization of ceramic industry waste material is extremely important.At present, the treatment and utilization degree of China's ceramic industry waste material is lower, funds shortage, causes a large amount of waste residue to tie up arable land, water and air is polluted.The particularly high speed development of nearly 20 years, ceramics is along with the increase of output, the quantity of waste material gets more and more, according to incomplete statistics: only Foshan Ceramic producing region, the annual production of various ceramic waste material is more than 4,000,000 tons, and the annual production of national ceramic waste material is estimated at about 1,000 ten thousand tons, through the ceramic waste product that more than 1000 degree high-temperature firings are crossed, its hardness is even also large than stone, and more than one thousand years all weathering is not, so a large amount of ceramic waste materiaves has not been the soluble problem of simple landfill, and along with the growing and social progress of economy, environment has become the focus that people pay close attention to, the accumulation of ceramic waste material ties up soil, affect the dust content of local air, and the landfill labor intensive material resources of ceramic waste material, also polluted underground water matter, how to turn waste into wealth, change waste material is resource, become the task of top priority of science and technology and environmental administration.
Summary of the invention
Main purpose of the present invention is to provide a kind of outdoor ceramic permeable brick; This water-permeable brick is main raw material with ceramic waste material, and add suitable tackiness agent and form through sintering, the more existing water-permeable brick of its cost reduces greatly, and good water permeability, intensity meets national standard.
Another object of the present invention is to provide a kind of production method of producing described outdoor ceramic permeable brick; This production method adopts waste ceramic brick and suitable tackiness agent to sinter, and method is simple, and cost is low.
To achieve these goals, the technical solution used in the present invention is: a kind of outdoor ceramic permeable brick, comprises bed material and surface layer,
The composition of bed material and weight content are:
Be broken into and be greater than the ceramic waste material that 0 is less than 200 order particles: 90-95wt%,
Tackiness agent: 5-10wt%,
Described tackiness agent is: wilkinite.
Described outdoor ceramic permeable brick also comprises a toning surface layer, described toning surface layer is that coloured being broken into of band is greater than ceramic waste material and the tackiness agent that 0 is less than 200 order particles, or colorant and be broken into and be greater than 0 and be less than the ceramic waste material of 200 order particles and the mixture of tackiness agent, toning facing weights is 20% of bed material weight, and bed material described here is exactly the gross weight of the mixture of above-mentioned composition and content.Described colorant is ceramic industry common pigments.
Preferred described wilkinite was the wilkinite of 150-300 mesh sieve.
The preferred bed material of the present invention consists of:
Be broken into and be greater than 0 and be less than 100 object ceramic waste material particle: 95wt%
Tackiness agent: 5wt%,
Preferably be broken into and be greater than 0 and be less than 100 object ceramic waste material particles; More preferably 8-30 object ceramic waste material particle.
Waste ceramic brick described in the present invention is preferably the graded particie that ceramic waste material fragmentation is sieved afterwards, wherein be greater than 0 to be less than 8 object granule contents and to be greater than zero and to be less than 5wt%, 8 orders---30 order granule contents are 85 ~ 90%, are greater than the content that 30 orders are less than 100 order particles and are greater than 5% composite grain being less than 15%.Adopt mixing-classifying particle of the present invention, outdoor ceramic permeable brick of the present invention can be made to have excellent water suction, permeability, the use of graded particie, consistency and the avidity of raw material can also be improved, improve the intensity of product, inhale water-permeable.
More preferably 8 orders---in 30 order particles, comprise 8 orders of 65-75wt%---12 order particles, and 12 orders that are greater than of 25-35wt% are less than or equal to 30 order particles.
The waste material that ceramic waste material of the present invention can adopt production ceramic tile in prior art to produce, such as: what ceramic generated after roasting burns till waste material, mainly burns till waste product and the damage in the production processes such as storage and carrying and the waste ceramic brick that causes; And the saggar utilized during polychannel tunnel kiln baked article.Because saggar repeatedly bears room temperature, the thermal stresses effect of high temperature room temperature and the carrying, collision etc. filled in alms bowl process are easy to damage and become saggar waste residue.
These waste materials, through high temperature sintering, have intensity high, and Particle Phase capacitive is good, after high temperature sintering, make outdoor ceramic permeable brick of the present invention have good permeable, ventilation property and excellent mechanical property.
In prior art, ceramic tile blank is only limitted to usually to the comprehensive utilization of waste ceramic brick.As the waste material burnt till through high temperature for waste ceramic brick, useless saggar and useless kiln furnitures and so on, through grinding and processing again, be milled to particle diameter at below 5mm, then added in the ratio of 3w% in the batching of ceramic tile or Western-style tile for ceramic tile blank.Limited for utilizing of waste ceramic brick like this, the ceramic tile cost produced is high, and is unfavorable for the pollution problem thoroughly solving pottery.
The present inventor finds through research, adopt formula of the present invention and composition thereof, when not adding the feldspar and other raw material that ceramic tile commonly uses, can produce the outdoor ceramic permeable brick meeting national standard completely, the cost of this outdoor ceramic permeable brick is significantly less than existing outdoor water-permeable brick.
The preparation method of outdoor ceramic permeable brick of the present invention comprises the steps:
(1) ceramic waste material is broken into is greater than 0 and is less than 200 object particles;
(2) in above-mentioned ceramic waste material particle, add the water of tackiness agent and 3-5wt% in proportion, obtain viscous mixt;
(3) said mixture is added in mould, with press at 90-110pa/mm
2pressure make the shape of water-permeable brick;
(4) burn till at the temperature of 1160 ~ 1220 degree.
Firing time is: tunnel furnace 26-29 hour.
Above-mentioned preparation method also comprises and adds water into mud to by mineral dye, first adds fabric mud in a mold, then adds mixture mud and become through tunnel klining.Preferred described tackiness agent was the tackiness agent of 150 ~ 300 mesh sieve screenings.
The present invention preferably consists of:
Waste ceramic brick is broken into and is greater than 0 and is less than 200 object particle: 95wt%,
Tackiness agent: 5wt%,
It is sieve after ceramic waste material fragmentation that preferably described waste ceramic brick is broken into 8-30 object particle, be greater than 0 to be less than 8 object granule contents and to be greater than zero and to be less than 5%, 8 order ~ 30 order granule contents are 85 ~ 90%, are greater than the content that 30 orders are less than 100 order particles and are greater than 5% composite grain being less than 15%.
Select wilkinite to be tackiness agent in the present invention, wilkinite is the clay pit based on montmorillonite, and montmorillonite isomorph is grown, cation replacement high-valence cationic at a low price, make structural sheet produce unnecessary negative charge, brilliant the exchangeable cationic type between layer compensate for unnecessary negative charge, keeps electric neutrality.Montmorillonite chemical composition is mainly SiO
2, Al
2o
3, Fe
2o
3mgOCaO etc., its plasticity-is fabulous, and cohesive force is strong, specific surface is very big, with waste ceramic raw material, there is good consistency and cohesiveness, under high-temperature calcination, it forms good phase with waste ceramic raw material, thus obtains high strength and has the outdoor floor tile of good infiltration, water-permeable.Simultaneously due to the present invention with waste ceramic raw material for main raw material, the waste ceramic raw material through high-temperature calcination does not absorb water, and has greatly saved the consumption of water, save energy in preparation process.
The present invention be mainly for ceramic waste material regeneration with regulate the climate and improve underground water storage function, outdoor ceramic permeable brick of the present invention in use, when efficiently solving rainy, the excessive ponding in ground causes rainwater to stay defect into Jiang Hai in a large number, help the earth water storage, purify large surface layer air, regulate the climate and reduce advantages such as " urban heat land effects ".Square, shopping mall, garden, community, public works etc. can be widely used in, and the environmental protection effect of cycling and reutilization can be reached, fully demonstrate the fine harmony of man and nature, also make contribution for society solves industrial waste pollution.Square, shopping mall, garden, community, public works etc. can be widely used in, outdoor ceramic permeable brick of the present invention (also known as porcelain brick), being controlled by outdoor ceramic permeable brick water-intake rate within 0.5% is E≤0.5%, makes traditional outdoor ceramic permeable brick product have qualitative leap.Due to its special composition, its every square metre can be permeated rainwater 0.01m per second
3.
Outdoor ceramic permeable brick of the present invention, has following feature:
1, improve the growth conditions of floor vegetation and regulate the eubiosis;
2, alleviate water exhaust system burden, prevent urban river flooding, alleviate the pollution of public waters;
3, groundwater resource are protected;
4, improve the condition of pavement, alleviate the sliding force on road surface and the circulation of rainwater;
5, the pollution of ceramic refuse to environment is solved;
6, color is various, beautifies the environment.
Main raw material(s) of the present invention is the renewable resource material such as ceramic waste product and treated industrial residue, by being processed into specific granularity, with special combination agent with or add that mineral dye at high temperature calcines further.The present invention is described in detail below in conjunction with specific embodiment.
Embodiment
Embodiment 1
Ceramic waste material is broken into and is greater than 0 and is less than 200 object particles, in 90 kilograms, above-mentioned particulate ceramic waste material, add granularity is 150 object wilkinite 10 kilograms, and add 5 kg of water stir obtain viscous mixt, said mixture is added in mould, with press at 100pa/mm
2pressure make water-permeable brick, after the demoulding, at the temperature of 1160-1220 degree, burn till 28 hours.
Embodiment 2
Ceramic waste material is broken into be greater than 0 be less than 100 object particles after sieve, get this particle 95 kilograms, wherein be greater than 0 and be less than 8 object ceramic waste material particles 0.95 kilogram (1%), 8 order ~ 30 object ceramic waste material particle 81 kilograms (85%), be greater than 30 orders and be less than 100 order ceramic waste material particle 13.05 kilograms (14%) mixing, adding granularity is wherein 300 object wilkinite 5 kilograms, and add 3 kg of water stir obtain mixture mud, said mixture is added in mould, with press at 90pa/mm
2pressure make water-permeable brick, at the temperature of 1220 degree, burn till 26 hours after the demoulding, obtain outdoor ceramic permeable brick.
Embodiment 3
Ceramic waste material is broken into be greater than 0 be less than 100 object particles after sieve, get this particle 92 kilograms, wherein be greater than 8 and be less than 30 object ceramic waste material particles 3.68 kilograms (4%), 8 order ~ 30 object ceramic waste material particle 82.8 kilograms (90%), be greater than 30 orders and be less than 100 order ceramic waste material particle 5.52 kilograms (6%) mixing, adding granularity is wherein 8 kilograms, 200 object wilkinite tackiness agent, and add 4 kg of water stir obtain mixture, said mixture is added in mould, with press at 110pa/mm
2pressure make water-permeable brick, after the demoulding, at the temperature of 1160 degree, burn till 29 hours, obtain outdoor ceramic permeable brick.
Embodiment 4
The ceramic waste material particle of embodiment 1 and tackiness agent is adopted to make mixture as primer, particle reads 8-30 order in detail, separately getting appropriate pigment mixes as mixing colours surface material with the said mixture of 20% weight, said mixture and surface material are added in mould respectively, adopts the compacting of the method for embodiment 1, be fired into outdoor ceramic permeable brick.
Embodiment 5
The ceramic waste material particle of embodiment 3 and tackiness agent is adopted to make mixture as primer, separately get appropriate pigment and mix as surface material with the said mixture of 20% weight, said mixture and surface material are added in mould respectively, adopts the compacting of the method for embodiment 3, be fired into outdoor ceramic permeable brick.Its ultimate compression strength 65MPa, folding strength 8800N, wear resistance 15mm, water-retentivity 1.9g/cm
2, coefficient of permeability 1.5 × 10
-2, frost resistance 8.1%
Outdoor ceramic permeable brick of the present invention is owing to adopting ceramic waste material particle, and itself and pigment have better consistency and adsorptivity, and the pigment added is firm, nondiscoloration.
Claims (5)
1. outdoor ceramic permeable brick and preparation method thereof, comprises bed material and surface layer, and the composition of bed material and weight content are: be broken into and be greater than 0 and be less than 200 object ceramic waste material particle: 90-95wt%, tackiness agent: 5-10wt%, described tackiness agent is wilkinite; Surface layer is greater than 0 and is less than 200 object ceramic waste material particle and tackiness agents for coloured being broken into of band, or colorant and be broken into and be greater than the mixture that 0 is less than 200 object ceramic waste material particles and tackiness agent, facing weights is 20% of bed material weight, and described colorant is ceramic industry common pigments.
2. a kind of outdoor ceramic permeable brick according to claim 1, described wilkinite was the wilkinite of 150-300 mesh sieve.
3. a kind of outdoor ceramic permeable brick according to claim 1, described ceramic waste material grain breakage one-tenth is greater than 0 and is less than 100 orders.
4. a kind of outdoor ceramic permeable brick according to claim 1, described ceramic waste material grain breakage becomes 8-30 order.
5. a kind of outdoor ceramic permeable brick according to claim 3, described ceramic waste material particle is sieve after ceramic waste material fragmentation to be less than 8 object granule contents and to be greater than zero for being greater than 0 and to be less than 5wt%, 8 order ~ 30 order granule contents are 85 ~ 90wt%, are greater than content that 30 orders are less than 100 order particles and are greater than the composite grain that 5wt% is less than 15wt%.
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| CN201410288833.2A CN105218003A (en) | 2014-06-26 | 2014-06-26 | A kind of outdoor ceramic permeable brick and preparation method thereof |
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| CN201410288833.2A CN105218003A (en) | 2014-06-26 | 2014-06-26 | A kind of outdoor ceramic permeable brick and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106007787A (en) * | 2016-05-16 | 2016-10-12 | 咸阳陶瓷研究设计院 | Environment-friendly inorganic spongy water storage material and preparation method thereof |
| CN107188597A (en) * | 2017-06-27 | 2017-09-22 | 王建军 | Method and the application of retaining brick are made using building waste |
| CN107244888A (en) * | 2017-06-09 | 2017-10-13 | 山东绿澄新材料科技有限公司 | The method that water-permeable brick ceramic matrix is produced using waste ceramic mud |
| CN107347397A (en) * | 2017-06-27 | 2017-11-17 | 王建军 | The method that water saving lawn is planted using building waste |
| CN108083769A (en) * | 2017-12-22 | 2018-05-29 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water produced using ceramic particle and preparation method thereof |
| CN108178610A (en) * | 2018-03-02 | 2018-06-19 | 陈姗 | A kind of building brick |
| CN108191393A (en) * | 2017-12-22 | 2018-06-22 | 广东科达洁能股份有限公司 | It is a kind of to use full sintering brick permeable to water thrown glaze ceramics particle and produced and preparation method thereof |
| CN108218394A (en) * | 2017-12-22 | 2018-06-29 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water produced using useless internal wall brick and preparation method thereof |
| CN108249889A (en) * | 2017-12-22 | 2018-07-06 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water produced using Antique Imitation Tiles particle and preparation method thereof |
| CN108558358A (en) * | 2017-12-22 | 2018-09-21 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water and preparation method thereof being not easy to plug |
| CN108585788A (en) * | 2017-12-22 | 2018-09-28 | 广东科达洁能股份有限公司 | It is a kind of to use the sintering brick permeable to water and preparation method thereof for smelting tailing production |
| CN111960829A (en) * | 2019-06-03 | 2020-11-20 | 成都工业学院 | Ceramic material capable of absorbing water and permeating water and preparation method thereof |
| CN113816723A (en) * | 2021-11-10 | 2021-12-21 | 内蒙古科技大学 | Solid waste base binding agent for sintered water permeable brick and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106007787A (en) * | 2016-05-16 | 2016-10-12 | 咸阳陶瓷研究设计院 | Environment-friendly inorganic spongy water storage material and preparation method thereof |
| CN107244888A (en) * | 2017-06-09 | 2017-10-13 | 山东绿澄新材料科技有限公司 | The method that water-permeable brick ceramic matrix is produced using waste ceramic mud |
| CN107188597A (en) * | 2017-06-27 | 2017-09-22 | 王建军 | Method and the application of retaining brick are made using building waste |
| CN107347397A (en) * | 2017-06-27 | 2017-11-17 | 王建军 | The method that water saving lawn is planted using building waste |
| CN107347397B (en) * | 2017-06-27 | 2020-04-28 | 王建军 | Method for planting water-saving lawn by using construction waste |
| CN108191393A (en) * | 2017-12-22 | 2018-06-22 | 广东科达洁能股份有限公司 | It is a kind of to use full sintering brick permeable to water thrown glaze ceramics particle and produced and preparation method thereof |
| CN108218394A (en) * | 2017-12-22 | 2018-06-29 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water produced using useless internal wall brick and preparation method thereof |
| CN108249889A (en) * | 2017-12-22 | 2018-07-06 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water produced using Antique Imitation Tiles particle and preparation method thereof |
| CN108558358A (en) * | 2017-12-22 | 2018-09-21 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water and preparation method thereof being not easy to plug |
| CN108585788A (en) * | 2017-12-22 | 2018-09-28 | 广东科达洁能股份有限公司 | It is a kind of to use the sintering brick permeable to water and preparation method thereof for smelting tailing production |
| WO2019119824A1 (en) * | 2017-12-22 | 2019-06-27 | 广东科达洁能股份有限公司 | Non-clogging sintered water-permeable brick and preparation method therefor |
| CN108083769A (en) * | 2017-12-22 | 2018-05-29 | 广东科达洁能股份有限公司 | A kind of sintering brick permeable to water produced using ceramic particle and preparation method thereof |
| CN108178610A (en) * | 2018-03-02 | 2018-06-19 | 陈姗 | A kind of building brick |
| CN111960829A (en) * | 2019-06-03 | 2020-11-20 | 成都工业学院 | Ceramic material capable of absorbing water and permeating water and preparation method thereof |
| CN113816723A (en) * | 2021-11-10 | 2021-12-21 | 内蒙古科技大学 | Solid waste base binding agent for sintered water permeable brick and preparation method thereof |
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