Summary of the invention
The object of the invention provides a kind of sintering pervious environment protection brick that uses ceramic waste residue, cullet, useless ceramics, the useless mud in basis, cinder, useless plant etc. as raw material production just for the problem that solves above-mentioned existence; Thereby solved the pollution that ceramic waste residue waste material, cullet, useless basic mud and cinder produce environment; Solved the resource recycling of ceramic waste residue, cullet, useless basic mud, cinder and useless plant again; Turn waste into wealth; Change evil and be benefit, realized that the resource benign cycle of solid waste utilizes.
The present invention also provides the method for manufacture of ceramic waste residue sintering pervious environment protection brick.
The objective of the invention is to realize by following technical proposal.
The sintering pervious environment protection brick that the ceramic waste residue of a kind of usefulness is produced is made up of upper strata brick and lower floor's brick, and lower floor's brick is processed by the following weight proportion raw material:
The upper strata brick is processed by the following weight proportion raw material:
20~30 parts of waste ceramic fragment powders
5~8 parts of wilkinites
3~4 parts in water
Described ceramic waste residue powder is to produce the throw out that abrasive dust, abrasive particle, brick bits and waste water that the waste material that produces in the ceramic process and ceramic produce in the deep processing polishing process obtains through WWT and the inorganic flocculating agent of interpolation, remove scrap metal through sorting, fragmentation, magnetic separation after, again through drying, rolling abrasive dust, to process fineness after sieving be 30 purpose powders;
Described cullet powder is cullet fragment, cullet bottle, the building that in the assorting room of handling domestic refuse, sorts out and fits up the cullet that produces, through processing the powder that particle diameter is 1mm after fragmentation, pulverizing, sorting, magnetic separation, drying, rolling abrasive dust, the screening;
Described waste ceramic fragment powder is the waste ceramic fragment that the useless ceramic tile that produces in the fitment process, useless snitaryware, commercial location and house decoration produce, and is 120 purpose powders through processing fineness after fragmentation, pulverizing, sorting, magnetic separation, drying, abrasive dust, the screening;
The useless mud powder in described municipal administration basis is the useless mud of discharging in the urban construction construction, the useless mud that the urban architecture engineering produces in the construction process that digs basis and underground parking, is 120 purpose powders through processing fineness after sorting, fragmentation, pulverizing, sorting, magnetic separation, drying, rolling abrasive dust, the screening;
Described cinder powder is a domestic refuse through the furnace bottom waste residue of discharging behind the burning electricity generation, remove scrap metal through sorting, pulverizing, magnetic separation after, behind drying, rolling sub-sieve, process the powder that particle diameter is 2mm again.
Described useless pure plant powder is waste wood, leaf, branch, the wood chip discarded plant that in the assorting room of handling domestic refuse, sorts out, through processing the powder that particle diameter is 2mm behind pulverizing, sorting, drying, the rolling sub-sieve.
The method of manufacture of the sintering pervious environment protection brick that the ceramic waste residue of described a kind of usefulness is produced, it is undertaken by following step:
(a) with the ceramic waste residue powder of 30~40 weight parts; The cullet powder of 20~30 weight parts; The useless body refuse powder in municipal administration basis of 20~30 weight parts; The cinder powder of 15~25 weight parts; The useless pure plant powder of 5~8 weight parts; The quicklime of 10~15 weight parts; The calcium sulfate of 5~8 weight parts; The water of the talcum powder of 4~6 weight parts and 12~25 weight parts is raw material; Adopt double-shaft mixing agitator to stir to be that to use the mechanical vibration extrusion molding behind the moist shape be lower floor's brick of permeable brick; Again with the waste ceramic fragment powder of 20~30 weight parts; The water of the wilkinite of 5~8 weight parts and 3~4 weight parts mixes the back and is uniformly distributed with one deck fine flour material with the secondary material distributing machine on the top of lower floor's brick of permeable brick; Under the pressure of 25~30Mpa, make the ceramic waste residue sintering pervious environment protection adobe of moulding then; Carry out seasoning
(b) send the ceramic waste residue pervious environment protection adobe of moulding after seasoning to tunnel again and carry out roasting, temperature is controlled at and is fired into ceramic waste residue sintering pervious environment protection brick product in 1150~1200 ℃ of scopes.
Its powder particle diameter of described quicklime and calcium sulfate is-0.2mm.
It is the main raw material of pervious environment protection brick that the present invention adopts ceramic waste residue, cullet, useless porcelain fragment, the useless body refuse in municipal administration basis; Wear into the upper strata lining of fine powder as the pervious environment protection brick with the waste ceramic fragment, selecting quicklime powder and calcium sulfate powder for use is the gelling material of pervious environment protection brick; Selecting useless body refuse fine powder in municipal administration basis and wilkinite for use is tackiness agent; Talcum powder is a fusing assistant; Cullet is ventilating agent and toughener; Improve and improve the performance of ceramic waste residue pervious environment protection brick, make the sintering pervious environment protection brick of ceramic waste residue production have durability index such as good water-permeable, ventilation property, water-retentivity, freeze-thaw resistance and increase substantially.The specification of quality of these over-all properties may command pottery waste residue pervious environment protection bricks.Above-mentioned multiple additives has advantages such as dispersiveness is strong, process stabilizing.Be convenient to produce and have good heat-resisting and permanent stability; Can strengthen the ultimate compression strength of the sintering pervious environment protection brick of ceramic waste residue production.
It is the internal combustion raw material of sintering pervious environment protection brick that the present invention selects cinder powder and useless pure plant powder for use, is because cinder itself contains a certain amount of fixed carbon and volatile matter, is generally 20%~30%, and its thermal value is at 1300~2200KJ/kg; It is higher to add that useless plant contains organic material, all can burn, and after burning, will produce a large amount of small pores, has good water-permeable and water-retentivity.Be save energy, protect environment again, meet the technical requirements of national energy-saving and emission-reduction, development low-carbon economy.In addition; Cinder also contains chemical ingredientss such as a large amount of silicon-dioxide, aluminium sesquioxide, red oxide of iron, quicklime; In the moulding process of pervious environment protection brick, has the potential hydration activity; It can with calcium hydroxide attack at normal temperatures, generate more stable hydrated calcium silicate and drated calcium aluminate.One deck hydrated product in cinder and useless pure plant powder and the formation of other spikes surface gets up cinder powder and other spike gluings, forms the material with certain physical and mechanical property intensity.Help the moulding of ceramic waste residue sintering pervious environment protection adobe.
The method of manufacture of the sintering pervious environment protection brick that the ceramic waste residue of a kind of usefulness of the present invention is produced; Be to be raw material with ceramic waste residue powder, cullet powder, the useless body refuse powder in municipal administration basis, cinder powder, useless pure plant powder, quicklime, calcium sulfate, talcum powder and water; Adopt double-shaft mixing agitator to stir to be that to use the mechanical vibration extrusion molding behind the moist shape be lower floor's brick of permeable brick; Again with waste ceramic fragment powder; Wilkinite and water mix the back and are uniformly distributed with one deck fine flour material with the secondary material distributing machine on the top of permeable brick lower floor brick; Under the pressure of 25~30Mpa, make the ceramic waste residue sintering pervious environment protection adobe of moulding then; Carry out seasoning; Send the ceramic waste residue pervious environment protection adobe of moulding after seasoning to tunnel again and carry out roasting, temperature is controlled at and is fired into ceramic waste residue sintering pervious environment protection brick product in 1150~1200 ℃ of scopes, thereby has solved the treatment and disposal problem of ceramic waste residue, cullet, useless porcelain fragment, municipal administration basis useless body refuse, cinder and useless plant; Realized the resource utilization recycle of ceramic waste residue, cullet, useless porcelain fragment, municipal administration basis useless body refuse, cinder and useless plant, to reduce pollution to physical environment.
Also can be made into the vegetation brick of different size with raw material of the present invention.
Utilize ceramic waste residue for the sintering pervious environment protection brick of main material production as a kind of new city floor decorative material, be a kind of environment protection ecologic building materials geared to the 21st century.It has good water-permeable and water-retentivity, and rainy day, the rainwater on ground can in time be penetrated into undergroundly, avoided street ponding, helps pedestrian's walking, vehicular traffic, reduces exhaust gas emission.Simultaneously, can make urban groundwater in time obtain replenishing of rainwater, avoid the city excessively to take and sink because of underground water; Stop producing moisture evaporation behind the rain, help regulating the urban surface temperature and humidity, reduce atmospheric pollution, reduce tropical island effect; In addition, because the singularity of this permeable brick is multi-cellular structure, it has absorption of noise, alleviates the function of city noise pollution; Its surface hardness is high, and ultimate compression strength is big, and color is various, and different modeling applicable to the laying on walkway, mall, park, square, has the function of beautifying the environment, protect environment.Help the protection of urban atmosphere adjusting and groundwater resource, help building the ecocity of Sustainable development.
According to the invention technology to produce a sintered ceramic waste production permeable green bricks, construction materials by the State under the relevant quality inspection department inspection, the technical indicators have reached the state building standards.
Building materials research institute building material product quality test center detected result is following through Guangdong Province:
The sintering pervious environment protection brick that the ceramic waste residue of a kind of usefulness is produced detects: according to Guangzhou capital construction commission file: (2002) No. 15 literary compositions of fringe building and JC/T945-2005 " the People's Republic of China's building material industry " (permeable brick) standard.Specification: 200 * 100 * 60mm.
A) ultimate compression strength: MV is 35.3Mpa, monolithic minimum value: 32.5Mpa,
B) folding strength: MV is 22.5Mpa, monolithic minimum value: 18.3Mpa,
C) wear resistance: mill hole length is 25mm,
D) water-retentivity: water retention is 1.8g/cm
2,
E) coefficient of permeability: permeability rate is (15 ℃)>=3.5x10
-2Cm/s,
F) radioactivity: internal radiation: 0.5, external radiation exposure: 0.6, be superior to national standard.Test basis: GB6566-2001 " the radioactive material nucleic is limited the quantity of "
Owing to take technique scheme technology of the present invention to have following advantage and effect:
A) the sintering pervious environment protection brick of the ceramic waste residue production of a kind of usefulness of the present invention; Be to be the sintering pervious environment protection brick that raw material is processed, be the comprehensive utilization of resources of solid waste, adopt many particle diameters of thickness proportioning with ceramic waste residue waste material, cullet, the useless body refuse in basis, cinder and useless plant; Have certain water-permeable, ventilation property, water-retentivity; Can cooling, noise reduction, regulate the climate, eliminate urban heat land effect, improve Air quality, keep multinomial function such as surface water circulation.
b) Production process is simple, no waste emissions, in line with national energy conservation, low-carbon economy and circular economy policy and the State Council Document No. 66 "On vigorously develop energy, land, water, materials, waste utilization, heat , insulation and other new building materials "requirement spirit, and less investment, low cost, good benefits;
C) utilize ceramic waste residue, cullet, the useless body refuse in basis, cinder and the useless plant sintering pervious environment protection brick for raw material production, permeable speed can reach more than the 5mm/s, and its water retention property reaches 12L/m
2More than.It is beneath up to the face of land that rainwater can be penetrated into brick automatically when raining, and also has portion water to be retained in the adobe the inside.When it is fine, infiltrate under the brick or the water that is retained in the adobe the inside can be evaporated in the atmosphere at leisure, play and regulate atmospheric moisture, reduce free air temperature and eliminate the hot action of high temperature in sky, city.Also have absorption of noise and the function that alleviates city noise pollution; Be applicable to the laying on walkway, mall, park, square, have the function of beautifying and protecting environment.Be green, environmental protection, energy-saving building material, development prospect is widely arranged;
D) solved ceramic waste residue waste material, cullet, the useless body refuse in basis, cinder and useless plant need take a large amount of land resources and cause secondary pollution easily in the landfill process a difficult problem; Both protected environment; Practiced thrift the soil again, the comprehensive utilization of resources rate of ceramic waste residue, cullet, basis useless body refuse, cinder and useless plant is reached more than 98%.
Embodiment
Embodiment 1
With producing that abrasive dust, abrasive particle, brick that the waste material that produces in the ceramic process and ceramic produce belong to and the throw out that waste water obtains through WWT and the inorganic flocculating agent of interpolation in the deep processing polishing, remove scrap metal through sorting, fragmentation, magnetic separation after, again through drying, rolling abrasive dust, to process fineness after sieving be that the ceramic waste residue powder of 30 purposes is for use;
The cullet that produces in cullet fragment, cullet bottle, construction site and the house decoration process that will in handling the assorting room of domestic refuse, screen, the cullet powder of processing particle diameter through fragmentation, pulverizing, sorting, magnetic separation, drying, rolling abrasive dust, after sieving and be 1mm is for use;
The waste ceramic fragment that produces in the useless ceramic tile that the construction site is produced in fitment process, useless snitaryware, commercial location and the house decoration, processing fineness through fragmentation, pulverizing, sorting, magnetic separation, drying, rolling abrasive dust, after sieving is that 120 purpose powders are for use;
With the useless mud in municipal administration basis is the useless mud that in construction process, discharges of urban engineering project, the useless mud that the urban architecture engineering produces in the construction process that digs basis and underground parking, is that 120 purpose powders are for use through processing fineness after sorting, fragmentation, pulverizing, sorting, magnetic separation, drying, rolling abrasive dust, the screening;
With the furnace bottom waste residue of domestic refuse through discharging behind the burning electricity generation, remove scrap metal through sorting, pulverizing, magnetic separation after, behind drying, rolling abrasive dust sub-sieve, to process particle diameter again be that the cinder powder of 2mm is for use;
Waste wood, leaf, branch, the wood chip that will in handling the assorting room of domestic refuse, sort out are that the useless pure plant powder of 2mm is for use through processing particle diameter behind pulverizing, sorting, drying, rolling abrasive dust, the sub-sieve;
Ceramic waste residue powder 30kg, cullet powder 20kg, the useless mud powder 20kg in municipal administration basis, cinder powder 15kg, useless pure plant powder 5kg and the particle diameter of getting above-mentioned preparation are quicklime powder 10kg, calcium sulfate powder 5kg, talcum powder 4kg and the water 12kg of 0.2mm; Above-mentioned raw materials is added double-shaft mixing agitator to be stirred and to be that to use the mechanical vibration extrusion molding behind the moist shape be lower floor's brick of permeable brick; Waste ceramic fragment powder 20kg, wilkinite 5kg and the water 3kg that gets above-mentioned preparation again mixes the back and is uniformly distributed with one deck fine flour material with the secondary material distributing machine on the top of permeable brick lower floor brick; Under the pressure of 30Mpa, make the ceramic waste residue sintering pervious environment protection adobe of moulding then; Carry out seasoning; Send the ceramic waste residue sintering pervious environment protection adobe of moulding after seasoning to tunnel again and carry out roasting, temperature is controlled at and is fired into ceramic waste residue sintering pervious environment protection brick product in 1180 ℃ of scopes.Mean compressive strength is after testing: 35.3Mpa, rupture strength is: 22.5Mpa.Water retention is: 1.8g/cm
2, permeability rate is: 3.5x10
-2Cm/s, radioactivity: internal radiation 0.5, external radiation exposure 0.6 all reaches " the People's Republic of China's building material industry standard " requirement.Be specification product.
Embodiment 2
Ceramic waste residue powder 40kg, cullet powder 30kg, the useless mud powder 30kg in municipal administration basis, cinder powder 25kg, useless pure plant powder 8kg and the particle diameter of getting embodiment 1 are quicklime powder 15kg, calcium sulfate powder 8kg, talcum powder 6kg and the water 25kg of 0.2mm; Above-mentioned raw materials is added double-shaft mixing agitator to be stirred and to be that to use the mechanical vibration extrusion molding behind the moist shape be lower floor's brick of permeable brick; Waste ceramic fragment powder 30kg, wilkinite 8kg and the water 4kg that gets above-mentioned preparation again mixes the back and is uniformly distributed with one deck fine flour material with the secondary material distributing machine on the top of permeable brick lower floor brick; Under the pressure of 29Mpa, make the ceramic waste residue sintering pervious environment protection adobe of moulding then; Carry out seasoning; Send the ceramic waste residue sintering pervious environment protection adobe of moulding after seasoning to tunnel again and carry out roasting, temperature is controlled at and is fired into ceramic waste residue sintering pervious environment protection brick product in 1200 ℃ of scopes.The average compressive strength testing: 33.5Mpa, bending strength: 22Mpa, for qualified products.
Embodiment 3
Ceramic waste residue powder 33kg, cullet powder 22kg, the useless mud powder 22kg in municipal administration basis, cinder powder 18kg, useless pure plant powder 6kg and the particle diameter of getting embodiment 1 are quicklime powder 12kg, calcium sulfate powder 6kg, talcum powder 5kg and the water 16kg of 0.2mm; Above-mentioned raw materials is added double-shaft mixing agitator to be stirred and to be that to use the mechanical vibration extrusion molding behind the moist shape be lower floor's brick of permeable brick; Waste ceramic fragment powder 22kg, wilkinite 6kg and the water 4kg that gets above-mentioned preparation again mixes the back and is uniformly distributed with one deck fine flour material with the secondary material distributing machine on the top of permeable brick lower floor brick; Under the pressure of 28Mpa, make the ceramic waste residue sintering pervious environment protection adobe of moulding then; Carry out seasoning; Send the ceramic waste residue sintering pervious environment protection adobe of moulding after seasoning to tunnel again and carry out roasting, temperature is controlled at and is fired into ceramic waste residue sintering pervious environment protection brick product in 1160 ℃ of scopes.Through detecting mean compressive strength be: 36Mpa, folding strength is: 23Mpa is specification product.
Embodiment 4
Ceramic waste residue powder 35kg, cullet powder 25kg, the useless mud powder 25kg in municipal administration basis, cinder powder 20kg, useless pure plant powder 7kg and the particle diameter of getting embodiment 1 are quicklime powder 13kg, calcium sulfate powder 7kg, talcum powder 6kg and the water 20kg of 0.2mm; Above-mentioned raw materials is added double-shaft mixing agitator to be stirred and to be that to use the mechanical vibration extrusion molding behind the moist shape be lower floor's brick of permeable brick; Waste ceramic fragment powder 25kg, wilkinite 7kg and the water 4kg that gets above-mentioned preparation again mixes the back and is uniformly distributed with one deck fine flour material with the secondary material distributing machine on the top of permeable brick lower floor brick; Under the pressure of 26Mpa, make the ceramic waste residue sintering pervious environment protection adobe of moulding then; Carry out seasoning; Send the ceramic waste residue sintering pervious environment protection adobe of moulding after seasoning to tunnel again and carry out roasting, temperature is controlled at and is fired into ceramic waste residue sintering pervious environment protection brick product in 1150 ℃ of scopes.The average compressive strength testing: 35.8Mpa, bending strength: 23.5Mpa, for qualified products.
Embodiment 5
Ceramic waste residue powder 38kg, cullet powder 28kg, the useless mud powder 28kg in municipal administration basis, cinder powder 23kg, useless pure plant powder 8kg and the particle diameter of getting embodiment 1 are quicklime powder 14kg, calcium sulfate powder 8kg, talcum powder 6kg and the water 22kg of 0.2mm; Above-mentioned raw materials is added double-shaft mixing agitator to be stirred and to be that to use the mechanical vibration extrusion molding behind the moist shape be lower floor's brick of permeable brick; Waste ceramic fragment powder 28kg, wilkinite 8kg and the water 4kg that gets above-mentioned preparation again mixes the back and is uniformly distributed with one deck fine flour material with the secondary material distributing machine on the top of permeable brick lower floor brick; Under the pressure of 25Mpa, make the ceramic waste residue sintering pervious environment protection adobe of moulding then; Carry out seasoning; Send the ceramic waste residue sintering pervious environment protection adobe of moulding after seasoning to tunnel again and carry out roasting, temperature is controlled at and is fired into ceramic waste residue sintering pervious environment protection brick product in 1180 ℃ of scopes.The average compressive strength testing: 32Mpa, bending strength: 21Mpa, for qualified products.