CN107445642A - A kind of permeable granitic production technology of artificial ecological - Google Patents

A kind of permeable granitic production technology of artificial ecological Download PDF

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Publication number
CN107445642A
CN107445642A CN201610376958.XA CN201610376958A CN107445642A CN 107445642 A CN107445642 A CN 107445642A CN 201610376958 A CN201610376958 A CN 201610376958A CN 107445642 A CN107445642 A CN 107445642A
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permeable
granitic
production technology
artificial ecological
parts
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兰其成
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Shanghai Mingcheng Yongmei Environmental Technology Co Ltd
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Shanghai Mingcheng Yongmei Environmental Technology Co Ltd
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
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    • C04B33/00Clay-wares
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
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    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
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    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1328Waste materials; Refuse; Residues without additional clay
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    • C04B33/00Clay-wares
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • C04B35/634Polymers
    • C04B35/63404Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B35/63416Polyvinylalcohols [PVA]; Polyvinylacetates
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • C04B35/636Polysaccharides or derivatives thereof
    • C04B35/6365Cellulose or derivatives thereof
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    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
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  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
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  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention provides a kind of permeable granitic production technology of artificial ecological.The novel artificial ecological permeable granite produced using mud, shraff and industrial residue had both solved decorative effect attractive in appearance of paving the way, and solves the problems, such as ecological, environmental protective again, Green Development, benefits the nation and the people.

Description

A kind of permeable granitic production technology of artificial ecological
Technical field
The invention belongs to decorative building material technical field, is related to a kind of stonite, and in particular to a kind of artificial ecological is saturating The granitic production technology of water.
Background technology
High-end paveio(u)r is mostly that lithotome, stone material are mainly natural granite in the market, and Stone Strength is high, rule Lattice are random strong, can arbitrarily be cut according to customer requirement, surface natural figure, good decorating effect, and class is high, but following lack be present Fall into:
1st, natural stone resource is limited, the ore deposits of many stone material kinds without;
2nd, the deforestation that cuts into a mountain easily causes environmental destruction;
3rd, its fluid-tight characteristic of stone material is layered on urban road and can cause seeping phenomenon, urban waterlogging easily occur;
4th, urban surface pollutant is directly discharged into the pollution for causing Urban Water Environment in river by waterproof pavement rainwater;
5th, lithotome, which is paved the way, has completely cut off the aqueous vapor Natural Circulation of urban surface, and urban ecology is easily destroyed;
6th, lithotome all has extremely strong heat absorptivity due to its internal various mineral composition, can so aggravate urban heat island Effect, causes the surface temperature more and more higher in city, the walking comfort serious loss of summer people trip, serious threat To the living environment in city;
7th, lithotome construction integrated cost of paving the way is high, the dark line of effect and material in itself due to ground mental and physical efforts(Non- equalization is strong Degree)It is easily broken off, maintenance cost is high.
Therefore, from the point of view of ecological, environmental protective and Ecological Road permeable pavement, lithotome is unsuitable for for urban pavement Mat formation.Conservation culture and sponge urban construction are greatly developed in country's proposition, and its purpose seeks to keep blue mountains and green waters, builds nature Save, naturally osmotic, the ecological sponge city of self-purification, urban water-through paving be improve the maximally effective skill of urban ecology Art means.
The content of the invention
The present invention is in order to solve the technical problem of urban water-through paving, there is provided a kind of permeable granite of artificial ecological Production technology.The novel artificial ecological permeable granite produced using mud, shraff and industrial residue had both solved paving Road decorative effect attractive in appearance, solves the problems, such as ecological, environmental protective, Green Development, benefits the nation and the people again.
In order to realize foregoing invention purpose, the present invention adopts the following technical scheme that:
A kind of permeable granitic production technology of artificial ecological, step are as follows:
1)Raw material is prepared
Take the mud of 10-15 parts to dry, and grind uniformly, mud material is made;
Into 1.5-2 parts adhesive and the poly- light ball of 1.5-3 parts plus water mixes, and slurry is made;
60-70 parts shraff, 10-15 parts waste residue and 10-20 part glass wastes are broken into fine grained and coarse granule;
0.1-0.5 part ceramic pigments are added in fine grained material, and is well mixed and is used as fine aggregate, adds and becomes silted up in coarse granule material Pug, and be well mixed and be used as coarse aggregate;
Preferably, the fine grain particle diameter is 0.5 ~ 2mm.
Preferably, the coarse grained particle diameter is 2 ~ 5mm.
2)It is compressing
Slurry and fine aggregate are mixed, is stirred, is obtained A compounds, slurry is mixed with coarse aggregate, stir, obtain B Compound;
B compounds are added in the lower floor of harder grinding tool, A compounds are added in the lower floor of harder grinding tool, on upper layer material surface Preparing ceramic clinker 0.3-0.5 parts of different color are added, it is compressing;
Preferably, the compressing pressure is 1200-1800 tons.
Preferably, the thickness ratio of the upper layer material and lower layered material is 1:3-5.
It is further preferred that described upper layer material thickness 10mm, 30-50mm of lower layered material thickness.
3)Calcining
Compressing blank is put into kiln, 1-2 hours are dried at a temperature of 100 ~ 120 DEG C, place into 1180-1250 3-5 hours are calcined under DEG C high temperature, are taken out after furnace temperature is down to room temperature, you can the permeable granite of microporous cellular is made.
Automation electricity can be carried out according to computer formula in the raw material of upper strata according to the color and texture of lithotome during manufacture Brain cloth system, you can burn till high intensity, the permeable granite product of the artificial ecological of high water-permeability of different colours.
Shraff, glass waste refer to the substandard product of ceramics and glass, such as damaged ceramics, glass and waste ceramic, Cullet is recycled.
Present invention process as raw material, has certain plasticity using mud, beneficial to shaping, the porcelain after high-temperature calcination, It is big that mud high temperature burns till shrinkage ratio, is internally formed slight void, beneficial to water conservation with it is permeable;Ceramics are used as main aggregate, ceramics Intergranular sinters again at high temperature, forms high intensity;Glass melts as aggregate, increases intensity at high temperature;Adhesive has Certain adhesive effect, good forming effect;Preparing ceramic clinker is melted under different state of temperatures and semi-molten, surface is formed not The texture and color change of rule;For poly- light ball as pore former, high temperature forms its interiors of products structure after burning till uniform thin Small micropore shape, increase product water conservation water penetration.
Adhesive of the present invention is cellulose low temperature adhesive.
Preferably, described cellulose low temperature adhesive is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.Especially It is optimal suitable for the bonding of ceramics and glass, molding effect.
Waste residue of the present invention is broken natural stone grain.
The beneficial effects of the present invention are:
1st, the artificial granitic production technology of ecological permeable of the present invention is all using solid industrials such as mud, waste ceramic, cullet Waste residue, it is extremely important to industry pollution treatment and environmental protection, be advantageous to green economy development;The utilization of mud is advantageous to lake water ring The utilization of the industrial residue such as the improvement in border, waste ceramic, cullet reduces pollution of the industrial residue to environment, and product is recyclable to follow Ring recycles, and greatlys save mineral resources, meets country 13 and plans green development strategy;Product formula cost is cheap, pole Easy a wide range of popularization and application;Product can be recycled repeatedly, be advantageous to the development of recycling economy.
2nd, stonite's water permeability that technique obtains is good, has the screen system of molecular structural formula, and permeability rate exists More than 3mm/s, 50mm/h rainfall can be dealt with.Even if raining in torrents, rainwater can also permeate the ground rapidly through earth's surface, addedly Lower water, recharging groundwater, had both reduced the generation of urban flooding, kept the freshwater resources of preciousness here again, significantly improved city Ecology and living environment.
3rd, technique uses two layers of cloth, upper strata 10MM thickness fine grains material, 30-50MM of lower floor thickness coarse grain footpath material, by high temperature Distinctive upper-class elements' structural formula screen system is formed after calcining, is not easily blocked, easy to clean, road surface is all the time in clean cleaning State, substantially reduce the generation of PM2.5 and haze.
4th, the permeable granite of artificial ecological that technique obtains has various granitic colors and decorative pattern texture, attractive in appearance big Side, class are high, and product nature aberration is smaller, good decorating effect.
5th, the permeable granite walking comfort of artificial ecological that technique obtains is strong.Rainy day road surface not ponding, not long moss, Noise-reducing, noise caused by vehicle is absorbed, create quiet comfortable traffic environment, pavement reflecting can be prevented in the rainy day, improve Vehicle travels and the security and comfortableness of pedestrian.
6th, the artificial permeable surface of granite that technique obtains is coarse, has good skid resistance and wearability, sleet sky road Face is avoided pedestrian Yin Lu sliding and fallen down without ponding, and can adjust the temperature and humidity of earth's surface, is eliminated " heat island phenomenon ", is changed Kind urban surface aqueous vapor circulation, safeguard the natural equilibrium of ecology.
7th, the permeable granite good permeability of artificial ecological that technique obtains, freezing and thawing performance is strong, and its service life is much super Cross other kinds of ground surface material.
8th, the ecological permeable granite that technique obtains can be fired into multicolour, meet that the art of city different designs will Ask, lay out the urban landscape of elegant style.Will never fade, for a long time Chang Xin;The permeable granite laying method of artificial ecological is easy, Its integrated cost is low, and pavement preservation cost is low, has good economic and practical;The permeable granite of artificial ecological is radiationless, nothing Any radioactive element, it is adapted to the use of various Environment spaces, widely used, well permeable, water conservation, permeability can also be made Used for roof greening and vertical greening and extraordinary exterior wall dried hanging.
Embodiment
The essentiality content of the present invention is described in further detail with reference to embodiment.
Embodiment 1
A kind of permeable granitic production technology of artificial ecological, step are as follows:
1)Raw material is prepared
Take 10 parts of mud to dry, and grind uniformly, mud material is made;
Into 1.5 parts of adhesive and 1.5 parts of poly- light balls plus water mixes, and slurry is made;
60 parts of shrafves, 10 parts of waste residues and 10 parts of glass wastes are broken into fine grained and coarse granule, added in fine grained material Enter 0.1 part of ceramic pigment, and be well mixed and be used as fine aggregate, mud material is added in coarse granule material, and it is well mixed as thick Aggregate;
2)It is compressing
Slurry and fine aggregate are mixed, is stirred, is obtained A compounds, slurry is mixed with coarse aggregate, stir, obtain B Compound;B compounds are added in the lower floor of harder grinding tool, A compounds are added on the upper strata of harder grinding tool, in upper layer material table Face adds 0.3 part of the preparing ceramic clinker of different color, compressing;
3)Calcining
Compressing blank is put into kiln, is dried 2 hours at a temperature of 100 DEG C, is placed under 1180 DEG C of high temperature and forge Burn 5 hours, taken out after furnace temperature is down to room temperature, you can the permeable granite of microporous cellular is made.
Embodiment 2
A kind of permeable granitic production technology of artificial ecological, step are as follows:
1)Raw material is prepared
Take 15 parts of mud to dry, and grind uniformly, mud material is made;
Into 2 parts of adhesive and 3 parts of poly- light balls plus water mixes, and slurry is made;
70 parts of shrafves, 15 parts of waste residues and 20 parts of glass wastes are broken into fine grained and coarse granule, added in fine grained material Enter 0.5 part of ceramic pigment, and be well mixed and be used as fine aggregate, mud material is added in coarse granule material, and it is well mixed as thick Aggregate;
2)It is compressing
Slurry and fine aggregate are mixed, is stirred, is obtained A compounds, slurry is mixed with coarse aggregate, stir, obtain B Compound;B compounds are added in the lower floor of harder grinding tool, A compounds are added on the upper strata of harder grinding tool, in upper layer material table Face adds 0.5 part of the preparing ceramic clinker of different color, compressing;
3)Calcining
Compressing blank is put into kiln, is dried 1 hour at a temperature of 120 DEG C, is placed under 1250 DEG C of high temperature and forge Burn 3 hours, taken out after furnace temperature is down to room temperature, you can the permeable granite of microporous cellular is made.
Embodiment 3
A kind of permeable granitic production technology of artificial ecological, step are as follows:
1)Raw material is prepared
Take 12 parts of mud to dry, and grind uniformly, mud material is made;
Into 1.6 parts of adhesive and 2 parts of poly- light balls plus water mixes, and slurry is made;
65 parts of shrafves, 12 parts of waste residues and 15 parts of glass wastes are broken into fine grained and coarse granule, added in fine grained material Enter 0.2 part of ceramic pigment, and be well mixed and be used as fine aggregate, mud material is added in coarse granule material, and it is well mixed as thick Aggregate;
2)It is compressing
Slurry and fine aggregate are mixed, is stirred, is obtained A compounds, slurry is mixed with coarse aggregate, stir, obtain B Compound;B compounds are added in the lower floor of harder grinding tool, A compounds are added on the upper strata of harder grinding tool, in upper layer material table Face adds 0.4 part of the preparing ceramic clinker of different color, compressing;
3)Calcining
Compressing blank is put into kiln, dries 1.5 hours, is placed under 1200 DEG C of high temperature at a temperature of 110 DEG C Calcining 4 hours, takes out, you can the permeable granite of microporous cellular is made after furnace temperature is down to room temperature.
Embodiment 4
The present embodiment is on the basis of embodiment 1:
The fine grain particle diameter is 0.5mm.
Embodiment 5
The present embodiment is on the basis of embodiment 1:
The fine grain particle diameter is 2mm.
The coarse grained particle diameter is 3mm.
Embodiment 6
The present embodiment is on the basis of embodiment 2:
The fine grain particle diameter is 1mm.
The coarse grained particle diameter is 2mm.
Described adhesive is cellulose low temperature adhesive.
Embodiment 7
The present embodiment is on the basis of embodiment 2:
The fine grain particle diameter is 2mm.
The coarse grained particle diameter is 5mm.
Described adhesive is cellulose low temperature adhesive, is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
Embodiment 8
The present embodiment is on the basis of embodiment 3:
The fine grain particle diameter is 1.5mm.
The coarse grained particle diameter is 4mm.
Described adhesive is cellulose low temperature adhesive, is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
The compressing pressure is 1200 tons.
Embodiment 9
The present embodiment is on the basis of embodiment 3:
The fine grain particle diameter is 0.8mm.
The coarse grained particle diameter is 3mm.
Described adhesive is cellulose low temperature adhesive, is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
The compressing pressure is 1800 tons.
The upper layer material thickness 10mm, lower layered material thickness 30mm.
Described waste residue is broken natural stone grain.
Embodiment 10
The present embodiment is on the basis of embodiment 1:
The fine grain particle diameter is 1.5mm.
The coarse grained particle diameter is 3.5mm.
The compressing pressure is 1600 tons.
Described adhesive is cellulose low temperature adhesive, is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
The upper layer material thickness 10mm, lower layered material thickness 40mm.
Described waste residue is broken natural stone grain.
Embodiment 11
The present embodiment is on the basis of embodiment 2:
The fine grain particle diameter is 1.2mm.
The coarse grained particle diameter is 2.5mm.
Described adhesive is cellulose low temperature adhesive, is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
The compressing pressure is 1500 tons.
The upper layer material thickness 10mm, lower layered material thickness 50mm.
Described waste residue is broken natural stone grain.

Claims (9)

  1. A kind of 1. permeable granitic production technology of artificial ecological, it is characterised in that:Step is as follows:
    Raw material is prepared
    Take the mud of 10-15 parts to dry, and grind uniformly, mud material is made;
    Into 1.5-2 parts adhesive and the poly- light ball of 1.5-3 parts plus water mixes, and slurry is made;
    60-70 parts shraff, 10-15 parts waste residue and 10-20 part glass wastes are broken into fine grained and coarse granule, at thin 0.1-0.5 part ceramic pigments are added in pellet, and is well mixed and is used as fine aggregate, mud material are added in coarse granule material, and mix Conjunction is uniformly used as coarse aggregate;
    It is compressing
    Slurry and fine aggregate are mixed, is stirred, is obtained A compounds, slurry is mixed with coarse aggregate, stir, obtain B Compound;B compounds are added in the lower floor of harder grinding tool, A compounds are added on the upper strata of harder grinding tool, in upper layer material table Face adds preparing ceramic clinker 0.3-0.5 parts of different color, compressing;
    3)Calcining
    Compressing blank is put into kiln, 1-2 hours are dried at a temperature of 100 ~ 120 DEG C, place into 1180-1250 3-5 hours are calcined under DEG C high temperature, are taken out after furnace temperature is down to room temperature, you can the permeable granite of microporous cellular is made.
  2. 2. the permeable granitic production technology of artificial ecological according to claim 1, it is characterised in that:It is described fine grain Particle diameter is 0.5 ~ 2mm.
  3. 3. the permeable granitic production technology of artificial ecological according to claim 1, it is characterised in that:It is described coarse grained Particle diameter is 2 ~ 5mm.
  4. 4. the permeable granitic production technology of artificial ecological according to claim 1, it is characterised in that:Described adhesive For cellulose low temperature adhesive.
  5. 5. the permeable granitic production technology of artificial ecological according to claim 4, it is characterised in that:Described cellulose Low temperature adhesive is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
  6. 6. the permeable granitic production technology of artificial ecological according to claim 1, it is characterised in that:It is described compressing Pressure be 1200-1800 tons.
  7. 7. the permeable granitic production technology of artificial ecological according to claim 1, it is characterised in that:The upper layer material and The thickness ratio of lower layered material is 1:3-5.
  8. 8. the permeable granitic production technology of artificial ecological according to claim 7, it is characterised in that:Described upper layer material Thick 10mm, 30-50mm of lower layered material thickness.
  9. 9. the permeable granitic production technology of artificial ecological according to claim 1, it is characterised in that:Described waste residue is Broken natural stone grain.
CN201610376958.XA 2016-06-01 2016-06-01 A kind of permeable granitic production technology of artificial ecological Pending CN107445642A (en)

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CN112110720A (en) * 2020-11-18 2020-12-22 广东欧文莱陶瓷有限公司 Preparation method of imitated natural granite ceramic tile
CN115124289A (en) * 2022-07-22 2022-09-30 浙江创垚环保科技有限公司 Inorganic artificial stone using silt-like general inorganic solid waste as main material and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112110720A (en) * 2020-11-18 2020-12-22 广东欧文莱陶瓷有限公司 Preparation method of imitated natural granite ceramic tile
CN115124289A (en) * 2022-07-22 2022-09-30 浙江创垚环保科技有限公司 Inorganic artificial stone using silt-like general inorganic solid waste as main material and preparation method thereof

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