CN107162566A - A kind of ecological permeable Ceramic Tiles and its production method - Google Patents

A kind of ecological permeable Ceramic Tiles and its production method Download PDF

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Publication number
CN107162566A
CN107162566A CN201610126755.5A CN201610126755A CN107162566A CN 107162566 A CN107162566 A CN 107162566A CN 201610126755 A CN201610126755 A CN 201610126755A CN 107162566 A CN107162566 A CN 107162566A
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China
Prior art keywords
parts
weight
mud
ceramic tiles
permeable ceramic
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Pending
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CN201610126755.5A
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Chinese (zh)
Inventor
兰其成
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Shanghai Mingcheng Yongmei Environmental Technology Co Ltd
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Shanghai Mingcheng Yongmei Environmental Technology Co Ltd
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Priority to CN201610126755.5A priority Critical patent/CN107162566A/en
Publication of CN107162566A publication Critical patent/CN107162566A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/1305Organic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses a kind of ecological permeable Ceramic Tiles and its production method.Its composition included is:The parts by weight of mud 15~20, the parts by weight of shraff 70~80, the parts by weight of pore former 1.5~3, the parts by weight of adhesive 1.5~2.Its production method is:1st, get the raw materials ready;2nd, mud is dried and grinds uniform, water, adhesive, poly- light ball are mixed and made into slurry;3rd, it is thickness solid particle to be carried out crushing and sieving with jaw crusher by shraff;4th, slurry and thickness solid particle are well mixed respectively, it is compressing with 800~1200 tons of pressure on briquetting press;5th, it is put into roller kilns or tunnel cave and dries 1~2 hour;6th, calcined 3~5 hours under 1180~1200 degree of high temperature, taken out after furnace temperature is down to room temperature and produce product.Beneficial effects of the present invention are:The permeable Ceramic Tiles good water permeability of the present invention, intensity is high, and moisturizing, resistance to compression, anti-skidding, cold-resistant, weather resistance, excellent noise reduction effect are environmentally friendly, reusable.

Description

A kind of ecological permeable Ceramic Tiles and its production method
Technical field
The present invention relates to water-permeable brick technical field, more particularly to a kind of environmental protection, intensity height, the ecology of water penetration by force are thoroughly Ceramic water brick and its production method.
Background technology
Base water-permeable brick is built originating from Holland, during Dutchman encloses Hai Zaocheng, discovery arranges the ground meeting after seawater Because Long Term Contact causes continual surface subsidence less than moisture.Once the dykes and dams on coastline are rushed to open, seawater meeting The city more much lower than sea level is flushed to rapidly all to flood whole city of bordering on the sea.In order that ground no longer sinks, Dutchman A kind of 200 millimeters of small-sized pavior bricks 50 or 60 millimeters high of 100 mm wide of length have been manufactured to be laid on surface of the street, and make brick with 2 millimeters of gap has been reserved between brick.Permeated the ground in the gap that rainwater can be between brick when so raining.Later, water-permeable brick Be widely used in building in bottom surface waterproof it is permeable in.
Ceramic water-permeable brick is one kind of water-permeable brick, and ceramic water-permeable brick refers to utilize the screened sorting of ceramic raw material, and tissue is closed Manage after grain composition, addition bonding agent, through the permeable building materials of high-quality formed by shaping, drying, high temperature sintering.It has higher Intensity, good water permeability, freezing and thawing performance are good, non-skid property is good, and its surface particles is thicker, and rain penetration is fast, after rain and after snow not Ponding, do not form ice sheet;And good ecological, environmental protective performance, material is repeatable to be utilized;And urban micro-climate, retardance city can be improved The formation of city's flood.
Ceramic water-permeable brick is widely used with its excellent characteristic.It is main that ceramic water-permeable brick, which has using clay, in the market The ceramic water-permeable brick of raw material production, the ceramic water-permeable brick also produced with shraff and waste ceramic.Using clay as primary raw material The ceramic water-permeable brick of production(It is commonly called as fired brick), it has the disadvantage:Permeability rate is relatively low, and usual coefficient of permeability is 0.3-1*10-2cm/ s;And clay shortage of resources, clay destruction ecological environment is excavated, influence area geologic structure easily causes landslide, mud-rock flow etc. certainly Right disaster, destruction is easily caused to natural, ecological.In addition, the ceramic water-permeable brick produced with shraff and waste ceramic, waste ceramic Material has some limitations, it is impossible to extensive use.
As fully visible, it is now desired to a kind of ceramic water-permeable brick of new environmentally friendly paving product, to meet people to permeable Brick high intensity, high permeability rate, the demand of environmental protection, and meet the widespread demand in market.
The content of the invention
In order to solve the problems of the prior art, it is an object of the invention to provide a kind of ecological permeable Ceramic Tiles and its production Method, the ecological permeable Ceramic Tiles environmental protection, intensity height, water penetration are strong, can meet the widespread demand in market.
To achieve these goals, the technical solution adopted by the present invention is:
A kind of parts by weight shared by ecological permeable Ceramic Tiles, its raw material included and each raw material are:
The parts by weight of mud 15~20;
The parts by weight of shraff 70~80;
The parts by weight of pore former 1.5~3;
The parts by weight of adhesive 1.5~2.
Wherein, the mud is the Taihu Lake mud of harmless treatment;The pore former is the poly- light ball of organic material;It is described Adhesive is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
Present invention also offers a kind of production method of ecological permeable Ceramic Tiles, it comprises the following steps:
S1, by required parts by weight weigh following raw material:Mud, shraff, pore former and adhesive;
S2, mud dried, and the mud after drying is ground uniform with ball mill;
S3, pore former and adhesive with water be mixed and made into slurry;
S4, shraff crushed with jaw crusher, and will it is broken after particle screening be thick solid particle and thin solid Body particle;
S5, thick solid particle and fine solid particles be well mixed with the slurry obtained by step S3 respectively, obtain the mixing of coarse grain footpath Material and fine grain compound;
S6, lower floor's addition coarse grain footpath compound in harder mould, fine grain compound is added on the upper strata of harder mould, And it is compressing under 800~1200 tons of pressure, obtain semi-finished product;
S7, the water-permeable brick idiosome after shaping is put into roller kilns or tunnel cave, 1~2 is dried at a temperature of 100~120 DEG C Hour;
S8, dried water-permeable brick idiosome is put into 1180~1200 DEG C at a temperature of calcine 3~5 hours, treat that furnace temperature is down to room Taken out after temperature, that is, obtain the permeable Ceramic Tiles of microporous cellular.
It is preferred that scheme, the parts by weight described in step S1 shared by each raw material are respectively:The parts by weight of mud 15~20, waste ceramic Expect 70~80 parts by weight, the parts by weight of pore former 1.5~3, the parts by weight of adhesive 1.5~2.
Further preferred scheme, the mud is the Taihu Lake mud through harmless treatment, and the pore former is organic The poly- light ball of material, the adhesive is made up of cellulose, polyvinyl alcohol, waterglass and auxiliary agent.
Scheme still further preferably, the particle diameter of thick solid particle described in step S4 is 2~5mm, the grain of fine solid particles Footpath is 0.5~2mm.
Scheme still more preferably, the upper strata fine grain mixing of half product after briquetting press described in step S6 is compressing The thickness ratio of material and the coarse grain footpath compound of lower floor is 1:4.
When making ecological permeable Ceramic Tiles of the present invention, it can be added in the fine grain compound on harder mould upper strata suitable The pigment of different colours is measured, the permeable Ceramic Tiles of different colours are configured to.
By using above technical scheme, a kind of ecological permeable Ceramic Tiles and its production method of the invention and prior art phase Than its advantage is:
(1)The environment friendly pervious Ceramic Tiles water permeability of the present invention is good, with very high porosity, particularly there is more intercommunicating pore, Permeability rate is more than twice of same kind of products at abroad standard, can deal with 50mm/h rainfall in more than 2.0*10-2cm/s.I.e. Make to rain in torrents, rainwater can also permeate the ground rapidly through earth's surface, both reduce the generation of urban flooding, keep the fresh water money of preciousness here again Source, significantly improves the ecology and living environment in city.
(2)The environment friendly pervious Ceramic Tiles of the present invention can absorb the noise produced by vehicle, create quiet comfortable traffic environment, Pavement reflecting can be prevented in the rainy day, improves vehicle traveling and the security and comfortableness of pedestrian.
(3)The environment friendly pervious ceramic brick surface of the present invention is coarse, with good skid resistance and wearability, sleet sky road surface without Ponding, it is to avoid pedestrian Yin Lu is slided and fallen down, and the temperature and humidity of earth's surface can be adjusted, eliminate " heat island phenomenon ", safeguard ground Table is balanced.
(4)The environment friendly pervious Ceramic Tiles of the present invention are the ceramic materials produced using high temperature sintering, and technical performance index is than it His ground surface material is high.Its intensity is up to more than 50MPa, and anti-folding hardness is more than 7MPa, and surface Mohs' hardness is up to more than 8 grades.
(5)The environment friendly pervious Ceramic Tiles good permeability of the present invention, freezing and thawing performance is strong, and its service life is considerably beyond other classes The ground surface material of type.
(6)The environment friendly pervious Ceramic Tiles of the present invention make full use of the solid industrial waste residue such as mud, waste ceramic, cullet, reduce Pollution of the industrial residue to environment, has saved mineral resources.
(7)The environment friendly pervious Ceramic Tiles of the present invention can be fired into multicolour, lay out the urban landscape of elegant style.
(8)The environment friendly pervious ceramic brick laying method of the present invention is easy, and its integrated cost is low, with good economical and practical Property.
In a word, permeable Ceramic Tiles of the invention be with keep the water penetration on ground, moisture retention, resistance to compression, anti-skidding, high intensity, Cold-resistant, weather resistance, noise reduction, it is reusable the features such as environmental protection product.
Embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, with reference to instantiation, to the present invention It is further described.It should be understood that these descriptions are merely illustrative, and it is not intended to limit the scope of the present invention.In addition, In illustrating below, the description to known features and technology is eliminated, to avoid unnecessarily obscuring idea of the invention.
In the national Ecological Civilization Construction of promotion energetically, adhere to Green Development, build the national overall background in ecological sponge city Under, applicant is that primary raw material produces a kind of high intensity, height by prolonged research and utilization mud and shraff, waste residue The novel environment friendly paving product of permeability rate:Ecological permeable Ceramic Tiles.Parts by weight shared by its raw material included and each raw material are: The parts by weight of mud 15~20, the parts by weight of shraff 70~80, the parts by weight of pore former 1.5~3, the parts by weight of adhesive 1.5~2. Wherein, the mud is the Taihu Lake mud of harmless treatment;The pore former is the poly- light ball of organic material;The adhesive by Cellulose, polyvinyl alcohol, waterglass and auxiliary agent composition.
It is the specific embodiment of its preparation method below:
Embodiment 1
Mud 15KG, shraff 75KG, poly- light ball 2.5KG, adhesive 2KG are weighed as raw material;Mud is dried, and will be dried in the air Mud after dry grinds uniform with ball mill, and water, adhesive, poly- light ball are mixed into slurry;Shraff is first broken with jaw Broken machine is crushed, and by particle screening be thickness solid particle, fine grained particle diameter be 0.5 ~ 2mm, coarse granule particle diameter be 2 ~ 5mm;Slurry and thickness solid particle are well mixed respectively, coarse grain footpath compound is added in the lower floor of harder grinding tool, in mould The upper strata of tool adds fine grain compound and adds appropriate red pigment, and upper strata fine grain compound is mixed with the coarse grain footpath of lower floor The thickness ratio of material is 1:4, it is compressing under 800~1200 tons of pressure;It is finally putting into kiln (roller kilns or tunnel cave), First dried 1~2 hour under conditions of 100~120 DEG C, place under 1180~1200 degree of high temperature and calcine 3~5 hours;Treat stove Taken out after temperature drop to room temperature, you can the permeable Ceramic Tiles of red microporous cellular are made.
Embodiment 2
Mud 18KG, shraff 70KG, poly- light ball 1.5KG, adhesive 1.7KG are weighed as raw material;Mud is dried, and will Mud after drying grinds uniform with ball mill, and water, adhesive, poly- light ball are mixed into slurry;Shraff is first used into jaw Disintegrating machine is crushed, and by particle screening be thickness solid particle, fine grained particle diameter be 0.5 ~ 2mm, coarse granule particle diameter be 2 ~ 5mm;Slurry and thickness solid particle are well mixed respectively, coarse grain footpath compound is added in the lower floor of harder grinding tool, in mould The upper strata of tool adds fine grain compound and adds appropriate green pigment, and upper strata fine grain compound is mixed with the coarse grain footpath of lower floor The thickness ratio of material is 1:4, it is compressing under 800~1200 tons of pressure;It is finally putting into kiln (roller kilns or tunnel cave), First dried 1~2 hour under conditions of 100~120 DEG C, place under 1180~1200 degree of high temperature and calcine 3~5 hours;Treat stove Taken out after temperature drop to room temperature, you can the permeable Ceramic Tiles of cyan microporous cellular are made.
Embodiment 3
Mud 20KG, shraff 80KG, poly- light ball 3KG, adhesive 1.5KG are weighed as raw material;Mud is dried, and will be dried in the air Mud after dry grinds uniform with ball mill, and water, adhesive, poly- light ball are mixed into slurry;Shraff is first broken with jaw Broken machine is crushed, and by particle screening be thickness solid particle, fine grained particle diameter be 0.5 ~ 2mm, coarse granule particle diameter be 2 ~ 5mm;Slurry and thickness solid particle are well mixed respectively, coarse grain footpath compound is added in the lower floor of harder grinding tool, in mould The upper strata of tool adds fine grain compound and adds appropriate yellow uitramarine, and upper strata fine grain compound is mixed with the coarse grain footpath of lower floor The thickness ratio of material is 1:4, it is compressing under 800~1200 tons of pressure;It is finally putting into kiln (roller kilns or tunnel cave), First dried 1~2 hour under conditions of 100~120 DEG C, place under 1180~1200 degree of high temperature and calcine 3~5 hours;Treat stove Taken out after temperature drop to room temperature, you can the permeable Ceramic Tiles of yellow microporous cellular are made.
Above-mentioned embodiment is exemplary, be in order to preferably make skilled artisans appreciate that this Patent, it is impossible to be not understood as including this patent the limitation of scope;As long as times made of spirit according to disclosed in this patent How with change or modification, the scope that this patent includes is each fallen within.

Claims (10)

1. a kind of ecological permeable Ceramic Tiles, it is characterised in that the parts by weight shared by its raw material included and each raw material are:
The parts by weight of mud 15~20;
The parts by weight of shraff 70~80;
The parts by weight of pore former 1.5~3;
The parts by weight of adhesive 1.5~2.
2. a kind of ecological permeable Ceramic Tiles according to claim 1, it is characterised in that the mud is Taihu Lake mud.
3. a kind of ecological permeable Ceramic Tiles according to claim 1, it is characterised in that the mud is through harmless treatment The mud crossed.
4. a kind of ecological permeable Ceramic Tiles according to claim 1, it is characterised in that the pore former is poly- for organic material Light ball.
5. a kind of ecological permeable Ceramic Tiles according to claim 1, it is characterised in that the adhesive is by cellulose, poly- Vinyl alcohol, waterglass and auxiliary agent composition.
6. the production method of a kind of ecological permeable Ceramic Tiles as described in claim 1 to 5 is any, it is characterised in that it includes Following steps:
S1, by required parts by weight weigh following raw material:Mud, shraff, pore former and adhesive;
S2, mud dried, and the mud after drying is ground uniform with ball mill;
S3, pore former and adhesive with water be mixed and made into slurry;
S4, shraff crushed with jaw crusher, and will it is broken after particle screening be thick solid particle and thin solid Body particle;
S5, thick solid particle and fine solid particles be well mixed with the slurry obtained by step S3 respectively, obtain the mixing of coarse grain footpath Material and fine grain compound;
S6, lower floor's addition coarse grain footpath compound in harder mould, fine grain compound is added on the upper strata of harder mould, And it is compressing under 800~1200 tons of pressure, obtain semi-finished product;
S7, the water-permeable brick idiosome after shaping is put into roller kilns or tunnel cave, 1~2 is dried at a temperature of 100~120 DEG C Hour;
S8, dried water-permeable brick idiosome is put into 1180~1200 DEG C at a temperature of calcine 3~5 hours, treat that furnace temperature is down to room Taken out after temperature, that is, obtain the permeable Ceramic Tiles of microporous cellular.
7. the production method of a kind of ecological permeable Ceramic Tiles according to claim 6, it is characterised in that described in step S1 Parts by weight shared by each raw material are respectively:The parts by weight of mud 15~20, the parts by weight of shraff 70~80, pore former 1.5~3 Parts by weight, the parts by weight of adhesive 1.5~2.
8. the production method of a kind of ecological permeable Ceramic Tiles according to claim 7, it is characterised in that the mud is warp The Taihu Lake mud of harmless treatment, the pore former is the poly- light ball of organic material, and the adhesive is by cellulose, polyethylene Alcohol, waterglass and auxiliary agent composition.
9. the production method of a kind of ecological permeable Ceramic Tiles according to claim 6, it is characterised in that thick described in step S4 The particle diameter of solid particle is 2~5mm, and the particle diameter of fine solid particles is 0.5~2mm.
10. the production method of a kind of ecological permeable Ceramic Tiles according to claim 6, it is characterised in that described in step S6 The thickness ratio of the upper strata fine grain compound of half product after briquetting press is compressing and the coarse grain footpath compound of lower floor is 1:4.
CN201610126755.5A 2016-03-07 2016-03-07 A kind of ecological permeable Ceramic Tiles and its production method Pending CN107162566A (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN108947486A (en) * 2018-08-28 2018-12-07 攀枝花市恒岩钛洁新材料科技有限公司 The method for preparing photocatalysis porous brick using high-titanium blast furnace slag
CN110683834A (en) * 2019-11-13 2020-01-14 武汉理工大学 Water permeable brick capable of removing various pollutants and preparation method thereof
CN111335108A (en) * 2020-03-17 2020-06-26 安庆仁创聚源生态环保科技有限公司 Ecological water-permeable pavement brick and production process thereof
CN113979725A (en) * 2021-11-17 2022-01-28 广州航海学院 Residual mud sintered porous brick prepared by sawdust balling method and preparation process thereof
CN115012268A (en) * 2022-07-05 2022-09-06 佛山生态海绵城市科技发展有限公司 Environment-friendly water permeable brick and preparation process thereof
CN115180922A (en) * 2022-06-30 2022-10-14 武汉理工大学 Sintered water permeable brick based on granite waste and coal slag and preparation method thereof

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947486A (en) * 2018-08-28 2018-12-07 攀枝花市恒岩钛洁新材料科技有限公司 The method for preparing photocatalysis porous brick using high-titanium blast furnace slag
CN110683834A (en) * 2019-11-13 2020-01-14 武汉理工大学 Water permeable brick capable of removing various pollutants and preparation method thereof
CN110683834B (en) * 2019-11-13 2022-07-08 武汉理工大学 Water permeable brick capable of removing various pollutants and preparation method thereof
CN111335108A (en) * 2020-03-17 2020-06-26 安庆仁创聚源生态环保科技有限公司 Ecological water-permeable pavement brick and production process thereof
CN111335108B (en) * 2020-03-17 2020-11-06 安庆仁创聚源生态环保科技有限公司 Ecological water-permeable pavement brick and production process thereof
CN113979725A (en) * 2021-11-17 2022-01-28 广州航海学院 Residual mud sintered porous brick prepared by sawdust balling method and preparation process thereof
CN115180922A (en) * 2022-06-30 2022-10-14 武汉理工大学 Sintered water permeable brick based on granite waste and coal slag and preparation method thereof
CN115012268A (en) * 2022-07-05 2022-09-06 佛山生态海绵城市科技发展有限公司 Environment-friendly water permeable brick and preparation process thereof

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Application publication date: 20170915