CN110128016A - A kind of no zirconium ultrawhite overglaze and preparation method thereof - Google Patents
A kind of no zirconium ultrawhite overglaze and preparation method thereof Download PDFInfo
- Publication number
- CN110128016A CN110128016A CN201910338057.5A CN201910338057A CN110128016A CN 110128016 A CN110128016 A CN 110128016A CN 201910338057 A CN201910338057 A CN 201910338057A CN 110128016 A CN110128016 A CN 110128016A
- Authority
- CN
- China
- Prior art keywords
- parts
- zirconium
- ultrawhite
- overglaze
- glaze slip
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
Abstract
The invention discloses a kind of no zirconium ultrawhite overglazes, it is related to ceramic tile technical field, it solves the problems, such as ultrawhite overglaze higher cost in the prior art, is characterized in that: including below according to the raw material of mass parts: 20-45 parts of quartz, 0-10 parts of burning talcums, 4-10 parts of water-washed kaolines, 5-15 parts of calcined kaolins, 0-25 parts of potassium feldspars, 10-25 parts of albites, 5-35 parts of lithium porcelain stones, 5-20 parts of nephelines, 0-3 parts of dolomites, 0-20 parts of aluminium oxide, 0-5 parts of titanium white frits and 0-2 parts of zinc oxide；The present invention adds other raw materials by removing the compound of zirconium in glaze, ensure that the whiteness of overglaze, and relative to traditional glaze, cost of the present invention is lower, radiates smaller.
Description
Technical field
The present invention relates to ceramic tile technical fields more particularly to a kind of no zirconium ultrawhite overglaze and preparation method thereof.
Background technique
Glaze is a kind of silicate, and the glaze applied on ware is generally using quartz, feldspar, clay as raw material, ground plus water
After modulation, be coated on billet surface, the roasting through certain temperature and melt, when the temperature drops, formed ceramic surface the nature of glass
Thin layer.It increases ware by mechanical strength, thermal stability, dielectric strength and the erosion for preventing liquid, gas, and there are also increase for glaze
Porcelain is beautiful and convenient for washing the effects of wiping, not being sticky with by dust.
Zirconium oxide or zirconium silicate are typically contained in ultrawhite overglaze, to improve the performance of overglaze and improve the whiteness of overglaze,
But the higher cost of zirconium oxide or zirconium silicate, so that ultrawhite overglaze higher cost, so that the cost of ceramic tile has been driven, because
This, we have proposed a kind of no zirconium ultrawhite overglazes and preparation method thereof.
Summary of the invention
The technical problem to be solved by the present invention is in view of the foregoing drawbacks, provide a kind of no zirconium ultrawhite overglaze, full throwing glaze and nothing
Zirconium ultrawhite overglaze and the full preparation method for throwing glaze, to solve the problems, such as ultrawhite overglaze higher cost in the prior art.
To achieve the above object, the invention provides the following technical scheme:
A kind of no zirconium ultrawhite overglaze, including below according to the raw material of mass parts: 20-45 parts of quartz, 0-10 parts of burning talcums, 1-10 parts
Water-washed kaoline, 5-15 part calcined kaolin, 0-25 parts of potassium feldspars, 10-25 parts of albites, 5-35 parts of lithium porcelain stones, 5-20 parts of rosy clouds
Stone, 0-3 part dolomite, 0-20 parts of aluminium oxide, 0-5 parts of titanium white frits and 0-2 parts of zinc oxide.
As a further solution of the present invention, including below according to the raw material of mass parts: 25-35 parts of quartz, 2-8 parts of burnings are slided
Stone, 4-8 part water-washed kaoline, 8-12 parts of calcined kaolins, 5-15 parts of potassium feldspars, 12-20 parts of albites, 10-25 parts of lithium porcelain stones,
5-20 parts of nephelines, 0.5-2.5 parts of dolomites, 5-15 parts of aluminium oxide, 1-3 parts of titanium white frits and 0.5-1.5 parts of zinc oxide.
As a further solution of the present invention, including below according to the raw material of mass parts: 30 parts of quartz, 5 parts of burnings talcums, 5
Part water-washed kaoline, 10 parts of calcined kaolins, 10 parts of potassium feldspars, 15 parts of albites, 15 parts of lithium porcelain stones, 12 parts of nephelines, 2 parts of white clouds
Stone, 9 parts of aluminium oxide, 2 parts of titanium white frits and 1 part of zinc oxide.
A kind of preparation method based on above-mentioned no zirconium ultrawhite overglaze, comprising the following steps:
S1, ingredient: raw material for standby is weighed according to recipe ratio；
S2, ball milling: putting the raw materials into ball mill, and water is added to grind, and grinds 4-5h, obtains A glaze slip, and the fineness of A glaze slip is 0.6-
1.0, glaze slip specific gravity is 1.85-1.90, and glaze slip flow velocity is 50-70s；
S3, it crosses and screens out iron: the glaze slip of milled being crossed into the filtering of 160 mesh double deck screens, after removing metal trough, it is aging that glaze slip is extracted into stock tank,
Obtain no zirconium ultrawhite overglaze.
In conclusion compared with the prior art, the invention has the following beneficial effects:
The present invention adds other raw materials by removing the compound of zirconium in glaze, ensure that the whiteness of overglaze, relative to tradition
Glaze, cost of the present invention is lower, radiate it is smaller, and the full throwing glaze made based on the present invention and leaching glaze reduce into
This.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments, based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of no zirconium ultrawhite overglaze, including below according to the raw material of mass parts: 20 parts of quartz, 1 part of water-washed kaoline, 5 parts of calcinings
Kaolin, 10 parts of albites, 5 parts of lithium porcelain stones and 5 parts of nephelines.
A kind of preparation method based on above-mentioned no zirconium ultrawhite overglaze, comprising the following steps:
S1, ingredient: raw material for standby is weighed according to recipe ratio；
S2, ball milling: putting the raw materials into ball mill, and water is added to grind, and grinds 4h, obtains A glaze slip, and the fineness of A glaze slip is 0.6, glaze
Starching specific gravity is 1.85, and glaze slip flow velocity is 50s；
S3, it crosses and screens out iron: the glaze slip of milled being crossed into the filtering of 160 mesh double deck screens, after removing metal trough, it is aging that glaze slip is extracted into stock tank,
Obtain no zirconium ultrawhite overglaze.
Embodiment 2
A kind of no zirconium ultrawhite overglaze, including below according to the raw material of mass parts: 45 parts of quartz, 10 parts of burning talcums, 10 parts of washings are high
Ridge soil, 15 parts of calcined kaolins, 25 parts of potassium feldspars, 25 parts of albites, 35 parts of lithium porcelain stones, 20 parts of nephelines, 3 parts of dolomites, 20 parts
Aluminium oxide, 5 parts of titanium white frits and 2 parts of zinc oxide.
A kind of preparation method based on above-mentioned no zirconium ultrawhite overglaze, comprising the following steps:
S1, ingredient: raw material for standby is weighed according to recipe ratio；
S2, ball milling: putting the raw materials into ball mill, and water is added to grind, and grinds 5h, obtains A glaze slip, and the fineness of A glaze slip is 1.0, glaze
Starching specific gravity is 1.90, and glaze slip flow velocity is 70s；
S3, it crosses and screens out iron: the glaze slip of milled being crossed into the filtering of 160 mesh double deck screens, after removing metal trough, it is aging that glaze slip is extracted into stock tank,
Obtain no zirconium ultrawhite overglaze.
Embodiment 3
A kind of no zirconium ultrawhite overglaze, including below according to the raw material of mass parts: 35 parts of quartz, 8 parts of burning talcums, 8 parts of washing kaolinites
Soil, 12 parts of calcined kaolins, 15 parts of potassium feldspars, 20 parts of albites, 25 parts of lithium porcelain stones, 20 parts of nephelines, 2.5 parts of dolomites, 15 parts
Aluminium oxide, 3 parts of titanium white frits and 1.5 parts of zinc oxide.
A kind of preparation method based on above-mentioned no zirconium ultrawhite overglaze, comprising the following steps:
S1, ingredient: raw material for standby is weighed according to recipe ratio；
S2, ball milling: putting the raw materials into ball mill, and water is added to grind, and grinds 4.5h, obtains A glaze slip, and the fineness of A glaze slip is 0.8,
Glaze slip specific gravity is 1.86, and glaze slip flow velocity is 60s；
S3, it crosses and screens out iron: the glaze slip of milled being crossed into the filtering of 160 mesh double deck screens, after removing metal trough, it is aging that glaze slip is extracted into stock tank,
Obtain no zirconium ultrawhite overglaze.
Embodiment 4
A kind of no zirconium ultrawhite overglaze, including below according to the raw material of mass parts: 25 parts of quartz, 2 parts of burning talcums, 4 parts of washing kaolinites
Soil, 8 parts of calcined kaolins, 5 parts of potassium feldspars, 12 parts of albites, 10 parts of lithium porcelain stones, 5 parts of nephelines, 0.5 part of dolomite, 5 parts of oxidations
Aluminium, 1 part of titanium white frit and 0.5 part of zinc oxide.
A kind of preparation method based on above-mentioned no zirconium ultrawhite overglaze, comprising the following steps:
S1, ingredient: raw material for standby is weighed according to recipe ratio；
S2, ball milling: putting the raw materials into ball mill, and water is added to grind, and grinds 5h, obtains A glaze slip, and the fineness of A glaze slip is 0.6, glaze
Starching specific gravity is 1.85, and glaze slip flow velocity is 65s；
S3, it crosses and screens out iron: the glaze slip of milled being crossed into the filtering of 160 mesh double deck screens, after removing metal trough, it is aging that glaze slip is extracted into stock tank,
Obtain no zirconium ultrawhite overglaze.
Embodiment 5
A kind of no zirconium ultrawhite overglaze, including below according to the raw material of mass parts: 30 parts of quartz, 5 parts of burning talcums, 5 parts of washing kaolinites
Soil, 10 parts of calcined kaolins, 10 parts of potassium feldspars, 15 parts of albites, 15 parts of lithium porcelain stones, 12 parts of nephelines, 2 parts of dolomites, 9 parts of oxidations
Aluminium, 2 parts of titanium white frits and 1 part of zinc oxide.
A kind of preparation method based on above-mentioned no zirconium ultrawhite overglaze, comprising the following steps:
S1, ingredient: raw material for standby is weighed according to recipe ratio；
S2, ball milling: putting the raw materials into ball mill, and water is added to grind, and grinds 5h, obtains A glaze slip, and the fineness of A glaze slip is 0.6, glaze
Starching specific gravity is 1.85, and glaze slip flow velocity is 65s；
S3, it crosses and screens out iron: the glaze slip of milled being crossed into the filtering of 160 mesh double deck screens, after removing metal trough, it is aging that glaze slip is extracted into stock tank,
Obtain no zirconium ultrawhite overglaze.
Performance verification
Overglaze is made according to above-described embodiment, ceramic tile is processed using made overglaze, measures ceramic tile surface whiteness, measurement result
Show that the whiteness of ceramic tile is more than or equal to 75.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of no zirconium ultrawhite overglaze, which is characterized in that including below according to the raw material of mass parts: 20-45 parts of quartz, 0-10 parts
Burn talcum, 1-10 parts of water-washed kaolines, 5-15 parts of calcined kaolins, 0-25 parts of potassium feldspars, 10-25 parts of albites, 5-35 parts of lithiums
Porcelain stone, 5-20 part nepheline, 0-3 parts of dolomites, 0-20 parts of aluminium oxide, 0-5 parts of titanium white frits and 0-2 parts of zinc oxide.
2. no zirconium ultrawhite overglaze according to claim 1, which is characterized in that including below according to the raw material of mass parts: 25-
35 parts of quartz, 2-8 parts of burning talcums, 4-8 parts of water-washed kaolines, 8-12 parts of calcined kaolins, 5-15 parts of potassium feldspars, 12-20 parts of sodium
Feldspar, 10-25 parts of lithium porcelain stones, 5-20 parts of nephelines, 0.5-2.5 parts of dolomites, 5-15 parts of aluminium oxide, 1-3 parts of titanium white frits and
0.5-1.5 parts of zinc oxide.
3. no zirconium ultrawhite overglaze according to claim 1, which is characterized in that including below according to the raw material of mass parts: 30
Part quartz, 5 parts of burning talcums, 5 parts of water-washed kaolines, 10 parts of calcined kaolins, 10 parts of potassium feldspars, 15 parts of albites, 15 parts of lithium porcelain
Stone, 12 parts of nephelines, 2 parts of dolomites, 9 parts of aluminium oxide, 2 parts of titanium white frits and 1 part of zinc oxide.
4. a kind of preparation method based on any no zirconium ultrawhite overglaze of claim 1-3, which is characterized in that including following step
It is rapid:
S1, ingredient: raw material for standby is weighed according to recipe ratio；
S2, ball milling: putting the raw materials into ball mill, and water is added to grind, and obtains A glaze slip；
S3, it crosses and screens out iron: the glaze slip double deck screen of milled is filtered, after removing metal trough, it is aging that glaze slip is extracted into stock tank, obtains no zirconium
Ultrawhite overglaze.
5. the preparation method of no zirconium ultrawhite overglaze according to claim 4, which is characterized in that in S2, the fineness of glaze slip is
0.6-1.0, glaze slip specific gravity are 1.85-1.90, and glaze slip flow velocity is 50-70s.
6. the preparation method of no zirconium ultrawhite overglaze according to claim 4, which is characterized in that in S2, milling time 4-
5h。
7. the preparation method of no zirconium ultrawhite overglaze according to claim 5 or 6, which is characterized in that in S3, the double-deck grit number
For 160 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201910338057.5A CN110128016A (en) | 2019-04-26 | 2019-04-26 | A kind of no zirconium ultrawhite overglaze and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910338057.5A CN110128016A (en) | 2019-04-26 | 2019-04-26 | A kind of no zirconium ultrawhite overglaze and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110526744A (en) * | 2019-09-03 | 2019-12-03 | 广东新润成陶瓷有限公司 | A kind of spot Antique Imitation Tiles and preparation method thereof |
| CN110644705A (en) * | 2019-11-27 | 2020-01-03 | 佛山市南海区金之岚装饰材料有限公司 | Polycrystalline mosaic plate and preparation method thereof |
| CN111792948A (en) * | 2020-07-08 | 2020-10-20 | 佛山市东鹏陶瓷有限公司 | Preparation method of ceramic high-whiteness glazed tile and prepared ceramic high-whiteness glazed tile |
| CN113185125A (en) * | 2021-04-13 | 2021-07-30 | 佛山市陶莹新型材料有限公司 | Composite whitening environment-friendly glaze, ceramic tile and preparation method thereof |
| CN113651534A (en) * | 2021-08-17 | 2021-11-16 | 广东省新岩素智能家居科技有限公司 | Zirconium white glaze for dynamic forming process and application thereof |
| CN114315426A (en) * | 2022-03-17 | 2022-04-12 | 佛山市陶莹新型材料有限公司 | Preparation method of anti-skid bright-surface ceramic tile |
| CN115466054A (en) * | 2022-09-26 | 2022-12-13 | 佛山市东鹏陶瓷有限公司 | Flash and pit-free decorative material and preparation method and application of decorative surface |
| CN115521070A (en) * | 2022-11-29 | 2022-12-27 | 广东大角鹿新材料有限公司 | Nano ultra-white overglaze, ceramic tile and preparation method thereof |
| CN116023028A (en) * | 2022-12-30 | 2023-04-28 | 广东中印陶瓷科技有限公司 | Glaze material with antibacterial property of ultra-white band and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110526744A (en) * | 2019-09-03 | 2019-12-03 | 广东新润成陶瓷有限公司 | A kind of spot Antique Imitation Tiles and preparation method thereof |
| CN110526744B (en) * | 2019-09-03 | 2021-03-30 | 广东新润成陶瓷有限公司 | Spot archaized brick and manufacturing method thereof |
| CN110644705A (en) * | 2019-11-27 | 2020-01-03 | 佛山市南海区金之岚装饰材料有限公司 | Polycrystalline mosaic plate and preparation method thereof |
| CN111792948A (en) * | 2020-07-08 | 2020-10-20 | 佛山市东鹏陶瓷有限公司 | Preparation method of ceramic high-whiteness glazed tile and prepared ceramic high-whiteness glazed tile |
| CN113185125A (en) * | 2021-04-13 | 2021-07-30 | 佛山市陶莹新型材料有限公司 | Composite whitening environment-friendly glaze, ceramic tile and preparation method thereof |
| CN113651534A (en) * | 2021-08-17 | 2021-11-16 | 广东省新岩素智能家居科技有限公司 | Zirconium white glaze for dynamic forming process and application thereof |
| CN114315426A (en) * | 2022-03-17 | 2022-04-12 | 佛山市陶莹新型材料有限公司 | Preparation method of anti-skid bright-surface ceramic tile |
| CN115466054A (en) * | 2022-09-26 | 2022-12-13 | 佛山市东鹏陶瓷有限公司 | Flash and pit-free decorative material and preparation method and application of decorative surface |
| CN115466054B (en) * | 2022-09-26 | 2024-02-23 | 佛山市东鹏陶瓷有限公司 | Preparation method and application of flashing pit-free decorative material and decorative surface |
| CN115521070A (en) * | 2022-11-29 | 2022-12-27 | 广东大角鹿新材料有限公司 | Nano ultra-white overglaze, ceramic tile and preparation method thereof |
| CN116023028A (en) * | 2022-12-30 | 2023-04-28 | 广东中印陶瓷科技有限公司 | Glaze material with antibacterial property of ultra-white band and preparation method thereof |
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