CN115466054B - Preparation method and application of flashing pit-free decorative material and decorative surface - Google Patents
Preparation method and application of flashing pit-free decorative material and decorative surface Download PDFInfo
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- CN115466054B CN115466054B CN202211175949.6A CN202211175949A CN115466054B CN 115466054 B CN115466054 B CN 115466054B CN 202211175949 A CN202211175949 A CN 202211175949A CN 115466054 B CN115466054 B CN 115466054B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000000463 material Substances 0.000 title claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 72
- 239000013078 crystal Substances 0.000 claims abstract description 51
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000003292 glue Substances 0.000 claims abstract description 45
- 230000001681 protective effect Effects 0.000 claims abstract description 41
- 239000011449 brick Substances 0.000 claims abstract description 33
- 239000011787 zinc oxide Substances 0.000 claims abstract description 24
- 238000005498 polishing Methods 0.000 claims abstract description 22
- 239000010453 quartz Substances 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 17
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010456 wollastonite Substances 0.000 claims abstract description 16
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 16
- 239000000454 talc Substances 0.000 claims abstract description 15
- 235000012222 talc Nutrition 0.000 claims abstract description 15
- 229910052623 talc Inorganic materials 0.000 claims abstract description 15
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 12
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005245 sintering Methods 0.000 claims abstract description 8
- 238000003892 spreading Methods 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims description 36
- 238000002425 crystallisation Methods 0.000 claims description 24
- 230000008025 crystallization Effects 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 15
- 229910052656 albite Inorganic materials 0.000 claims description 13
- 239000005995 Aluminium silicate Substances 0.000 claims description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 11
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- 239000000395 magnesium oxide Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- 239000000919 ceramic Substances 0.000 claims description 7
- 229910052845 zircon Inorganic materials 0.000 claims description 6
- 229910021532 Calcite Inorganic materials 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052637 diopside Inorganic materials 0.000 claims description 5
- 239000010459 dolomite Substances 0.000 claims description 5
- 229910000514 dolomite Inorganic materials 0.000 claims description 5
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 239000010434 nepheline Substances 0.000 claims description 5
- 229910052664 nepheline Inorganic materials 0.000 claims description 5
- 229910052573 porcelain Inorganic materials 0.000 claims description 5
- 239000004575 stone Substances 0.000 claims description 5
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims 6
- 230000000694 effects Effects 0.000 abstract description 42
- 239000011734 sodium Substances 0.000 abstract description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 3
- 239000010433 feldspar Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 22
- 238000009826 distribution Methods 0.000 description 11
- 238000001035 drying Methods 0.000 description 11
- 239000004744 fabric Substances 0.000 description 11
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 9
- 239000008187 granular material Substances 0.000 description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 7
- 238000005034 decoration Methods 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 238000007641 inkjet printing Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001599 direct drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
A flashing non-pit decorative material and a preparation method and application of a decorative surface, the preparation method comprises the steps of (1) spreading glue on the surface glaze of a green brick; (2) coating Shi Dingwei with dry crystalline particles; (3) applying protective glaze; (4) After common dry grains are distributed, protective glaze is distributed, and the materials are dried and sintered; (5) And (3) polishing the blank after sintering to be flat, and obtaining the decorative surface. The decorative material is prepared by the preparation method; the scheme provides a preparation method of a flashing non-pit decorative surface, which combines frit crystals with potassium feldspar, sodium feldspar, wollastonite, calcined talcum, quartz, zinc oxide, calcined alumina and titanium oxide with zirconite to form positioning crystal dry particles, and the positioning crystal dry particles are matched with common dry particles and protective glaze to prepare the flashing non-pit decorative surface, wherein the decorative surface can have a continuous flashing effect, and the problem that the flashing effect formed by the positioning crystal dry particles of the decorative surface in the prior art is relatively convex to form a current pit is effectively solved.
Description
Technical Field
The invention relates to the technical field of glazes, in particular to a flashing pit-free decorative material, a preparation method and application of a decorative surface.
Background
In the prior art, the crystal dry grains are distributed on the whole surface of the brick surface, and the crystal dry grains are positioned at local positions, so that different flashing effects are presented on the surface of the brick surface after the brick surface is baked, the flashing effects are discontinuous and incoherent, the overall appearance of the brick surface is obviously influenced, and visual fatigue is easy to generate when the brick surface is used for a long time; meanwhile, in the prior art, the lamp tube at the crystallization place where the positioning crystallization dry particles are thrown out is obviously protruded, so that pits are formed opposite to other parts, and the touch feeling and the look and feel are not facilitated, as shown in fig. 7.
Disclosure of Invention
The invention aims to provide a preparation method of a flashing non-pit decorative surface, which combines frit crystals with potassium feldspar, albite, wollastonite, calcined talcum, quartz, zinc oxide, calcined alumina and titanium oxide with zirconite to form positioning crystal dry particles, and the positioning crystal dry particles are matched with common dry particles and protective glaze to prepare the flashing non-pit decorative surface, wherein the decorative surface can have a continuous flashing effect.
The invention also provides a flashing decorative material without pits, and the decorative surface arranged on the blank is prepared by the preparation method of the flashing decorative surface without pits.
The invention also provides an application of the decorative surface in preparing the flashing ceramic product without pits.
To achieve the purpose, the invention adopts the following technical scheme:
a preparation method of a flashing decorative surface without pits comprises the following steps:
step (1): spreading glue on the surface glaze of the green bricks;
step (2): coating Shi Dingwei on the overglaze to form crystal dry grains;
positioning crystalline dry particles, which are prepared from the following raw materials in parts by weight: 90-110 parts of frit crystals, 5-20 parts of zircon and 0-10 parts of coloring agent; the raw materials for frit crystallization comprise the following components in parts by weight: 10-20 parts of potassium feldspar, 30-40 parts of albite, 9-15 parts of wollastonite, 0-2 parts of calcined talcum, 16-20 parts of quartz, 0-2 parts of zinc oxide, 15-25 parts of calcined alumina and 0-2 parts of titanium oxide;
step (3): applying protective glaze;
step (4): after common dry grains are distributed, protective glaze is distributed, and the materials are dried and sintered;
step (5): and (3) polishing the blank after sintering to be flat, and obtaining the decorative surface.
Preferably, in the step (2), the dry grains and the ordinary dry grains are crystallized on the overglaze cloth Shi Dingwei.
Preferably, in the step (1), the temperature of the glue is controlled to be 40-45 ℃ before the glue is applied; the application amount of the glue is 80-100g/m 2 ；
In the step (1), the raw materials of the overglaze comprise the following components in parts by mass: 10-15 parts of lithium porcelain stone, 20-25 parts of albite, 15-20 parts of nepheline, 6-10 parts of water-washed kaolin, 18-22 parts of quartz, 8-12 parts of calcined alumina, 4-7 parts of talcum and 2-4 parts of dolomite.
Preferably, the raw materials of the protective glaze comprise low-temperature glaze polishing and glue;
the low-temperature glaze polishing comprises the following raw materials in parts by mass: 15-20 parts of potassium feldspar, 6-10 parts of water-washed kaolin, 6-10 parts of wollastonite, 3-5 parts of diopside, 5-10 parts of calcite, 4-8 parts of quartz, 1-3 parts of zinc oxide, 3-5 parts of barium sulfate, 3-5 parts of strontium carbonate and 35-40 parts of low-temperature frit;
the low-temperature frit comprises the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% CaO, 0-5% MgO, 3-8% K 2 O, 0-5% Na 2 O, 0-5% BaO, 1-7% SrO and 5-13% ZnO.
More preferably, the common dry particles comprise the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% CaO, 0-5% MgO, 3-8% K 2 O, 0-5% Na 2 O, 0-5% BaO, 1-7% SrO and 5-13% ZnO.
Further optimally, the mesh ratio of the common dry particles comprises the following components in percentage by mass: 40-60 mesh: 8-18%;60-100 mesh: 28-38%:100-160 mesh: 45-55%;160-180 mesh: 3-8%.
Preferably, in the step (4), the common dry particles are applied in an amount of 500-700g/m 2 。
Preferably, in the step (1), after the surface glaze is applied to the green brick, ink-jet printing is performed first, and then glue is applied.
A sparkling non-pitted decorative material comprising: a blank body;
the green body is provided with a decorative surface; the decorative surface is prepared by the preparation method of the flashing decorative surface without pits.
The use of a decorative surface in the preparation of a sparkling and pit-free ceramic product, wherein the decorative surface is prepared by the preparation method of the sparkling and pit-free decorative surface.
The technical scheme provided by the invention can comprise the following beneficial effects:
the scheme provides a preparation method of a flashing non-pit decorative surface, which combines frit crystals with potassium feldspar, sodium feldspar, wollastonite, calcined talcum, quartz, zinc oxide, calcined alumina and titanium oxide with zirconite to form positioning crystal dry particles, and the positioning crystal dry particles are matched with common dry particles and protective glaze to prepare the flashing non-pit decorative surface, wherein the decorative surface can have a continuous flashing effect, and the problem that the flashing effect formed by the positioning crystal dry particles of the decorative surface in the prior art is relatively convex to form a current pit is effectively solved.
Drawings
FIG. 1 is a standard schematic view of a trim face of a preferred embodiment;
FIG. 2 is a standard schematic illustration of a trim face of one embodiment;
FIG. 3 is a standard schematic view of a trim face of one embodiment;
FIG. 4 is a standard schematic illustration of a trim face of one embodiment;
FIG. 5 is a standard schematic illustration of a decorative surface with insufficient sparkle effect;
fig. 6 is a standard schematic of a decorative surface with a dimple embodiment.
Fig. 7 shows the entire surface of a brick with a flashing effect according to the prior art.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and fully with reference to the accompanying drawings, in which it is evident that the embodiments described are some, but not all embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The technical scheme of the scheme is further described through the specific embodiments with reference to the accompanying drawings.
A preparation method of a flashing decorative surface without pits comprises the following steps:
step (1): spreading glue on the surface glaze of the green bricks;
after the glue is applied to the overglaze, the glue can be used for adhering and positioning crystal dry grains; attaching the oriented crystalline dry particles and the ordinary dry particles to the overglaze;
step (2): coating Shi Dingwei on the overglaze to form crystal dry grains;
positioning crystalline dry particles, which are prepared from the following raw materials in parts by weight: 90-110 parts of frit crystals, 5-20 parts of zircon and 0-10 parts of coloring agent; the raw materials for frit crystallization comprise the following components in parts by weight: 10-20 parts of potassium feldspar, 30-40 parts of albite, 9-15 parts of wollastonite, 0-2 parts of calcined talcum, 16-20 parts of quartz, 0-2 parts of zinc oxide, 15-25 parts of calcined alumina and 0-2 parts of titanium oxide;
the raw materials of the frit crystallization can be processed according to the known processing steps, for example, the raw materials are crushed, uniformly mixed, melted at the temperature of not lower than 1600 ℃ and kept at the temperature for at least 15min, and then cooled, crystallized and crushed to obtain the frit;
in this scheme, the overglaze is coated with Shi Dingwei crystalline dry grains and/or common dry grains; positioning crystal dry grains and/or common dry grains are/is arranged on overglaze, and the positioning crystal dry grains and/or common dry grains are/is attached to a glue area for the glue area carried by the overglaze; for non-glue areas of the overglaze, the positioned crystallization dry grains and/or the common dry grains can be naturally separated or sucked away by vacuum; after the cloth Shi Dingwei is crystallized and dried and/or ordinary dried, the cloth may be properly dried by a known means;
step (3): applying protective glaze;
step (4): after common dry grains are distributed, protective glaze is distributed, and the materials are dried and sintered;
in the scheme, the step (3) and the step (4) are performed with the protective glaze distributed twice; the protective glaze can be replaced by protective glaze on the market; the protective glaze in the scheme not only plays a protective role, but also wets the glaze surface so that the common dry grains are better combined with the glaze surface, and the shrinkage glaze at the position where the cloth is applied with the crystallized dry grains can be prevented; the common dry particles can be matched with the positioning crystal dry particles to prevent the problem of reduced flashing effect caused by whitening when the positioning crystal dry particles are easy to agglomerate;
step (5): and (3) polishing the blank after sintering to be flat, and obtaining the decorative surface.
The crystal dry grains are positioned to be polished to generate a flashing effect; polishing the decorative surface, namely polishing the protruding part of the crystalline dry grain with the partial positioning, so that the water ripple on the glaze surface of the decorative surface is smooth, and finally, no pit exists;
the scheme provides a preparation method of a flashing non-pit decorative surface, which combines frit crystals with potassium feldspar, sodium feldspar, wollastonite, calcined talcum, quartz, zinc oxide, calcined alumina and titanium oxide with zirconite to form positioning crystal dry particles, and the positioning crystal dry particles are matched with common dry particles and protective glaze to prepare the flashing non-pit decorative surface, wherein the decorative surface can have a continuous flashing effect, and the problem that the flashing effect formed by the positioning crystal dry particles of the decorative surface in the prior art is relatively convex to form a current pit is effectively solved.
Preferably, in the step (2), the dry grains and the ordinary dry grains are crystallized on the overglaze cloth Shi Dingwei.
Preferably, in the step (1), the temperature of the glue is controlled to be 40-45 ℃ before the glue is applied; the application amount of the glue is 80-100g/m 2 ；
In the step (1), the raw materials of the overglaze comprise the following components in parts by mass: 10-15 parts of lithium porcelain stone, 20-25 parts of albite, 15-20 parts of nepheline, 6-10 parts of water-washed kaolin, 18-22 parts of quartz, 8-12 parts of calcined alumina, 4-7 parts of talcum and 2-4 parts of dolomite.
In this solution, the overglaze may be replaced by a known overglaze; in the scheme, the overglaze is used, the glue is applied at the temperature of 40-45 ℃ and the distribution amount is 80-100g/m 2 When the surface of the glue is dry, the adhesive force of the positioning crystal dry particles on the overglaze is moderate, the glue is not easy to fall off, and the glue is easy to be sucked away by a vacuum source.
Preferably, the raw materials of the protective glaze comprise low-temperature glaze polishing and glue;
the low-temperature glaze polishing comprises the following raw materials in parts by mass: 15-20 parts of potassium feldspar, 6-10 parts of water-washed kaolin, 6-10 parts of wollastonite, 3-5 parts of diopside, 5-10 parts of calcite, 4-8 parts of quartz, 1-3 parts of zinc oxide, 3-5 parts of barium sulfate, 3-5 parts of strontium carbonate and 35-40 parts of low-temperature frit;
the low-temperature frit comprises the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% CaO, 0-5% MgO, 3-8% K 2 O, 0-5% Na 2 O, 0-5% BaO, 1-7% SrO and 5-13% ZnO.
The protective glaze may be replaced by a known protective glaze; in the scheme, when the protective glaze of the formula is used, the chemical components of the low-temperature frit in the protective glaze are basically the same as those of the common dry grains, and only the mesh ratio of the common dry grains is adopted, so that the compatibility of the protective glaze and the common dry grains is improved, and the flashing effect is best.
Wherein, the glue amount is determined according to the common dry particles, and the optimal addition amount can be obtained through a limited number of experiments.
Preferably, the common dry particles comprise the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% CaO, 0-5% MgO, 3-8% K 2 O, 0-5% Na 2 O, 0-5% BaO, 1-7% SrO and 5-13% ZnO.
The usual dry granules used in step (2) and/or step (3) may be replaced by known dry granules; in the scheme, the dry granules with the same formula as the low-temperature frit are preferably used as common dry granules, so that the compatibility of the common dry granules and the protective glaze is improved, and the flashing effect can be further improved; especially in some embodiments, the common dry particles are added in the step (2), the positioning crystallization dry particles can be more effectively matched with the protective glaze, the common dry particles, the positioning crystallization dry particles and the protective glaze are well combined, and the flashing effect is optimal.
More preferably, the mesh proportion of the common dry particles comprises the following components in percentage by mass: 40-60 mesh: 8-18%;60-100 mesh: 28-38%:100-160 mesh: 45-55%;160-180 mesh: 3-8%.
In the step (4), the mesh number of the common dry grains can be determined according to actual conditions; when the mesh ratio of the common dry particles is calculated, the dry particles comprise the following components in percentage by mass: 40-60 mesh: 8-18%;60-100 mesh: 28-38%:100-160 mesh: 45-55%;160-180 mesh: when the content is 3-8%, the common dry grains can more easily supplement the positioning crystal dry grains in the step (2); for example, when the cloth speed of the cloth machine is not good to adjust the small gram number, common dry grains can be added into the positioning crystal dry grains to replace the positioning crystal dry grains, so that the gram number of the positioning crystal dry grains is supplemented proportionally, and the flashing effect is improved.
Further preferably, in the step (4), the common dry particles are applied in an amount of 500-700g/m 2 。
When the common dry particles are the formula of the low-temperature frit and the mesh number ratio is used, the common dry particles are 500-700g/m 2 The protruding part of the final decorative surface for positioning crystallization dry particles can be reduced, so that the concave-convex condition of the later stage of the decorative surface can be accurately controlled. In a preferred embodiment, the cloth Shi Liang of the conventional dry grain is 570-650g/m 2 。
Wherein, the distribution amount of the positioning crystallization dry particles in the scheme is preferably 140-200g/m 2 。
The distribution amount of the positioning crystallization dry particles can be distributed according to the actual amount, and when the crystallization dry particles are distributed, the flash effect of the decorative surface can be improved by improving the distribution amount of the positioning crystallization dry particles in a certain range; and the distribution amount of the positioned crystal dry particles is 140-200g/m 2 When the decorative surface is used, the flashing effect of the decorative surface is optimal; in some examples, for example, the crystalline dry particles are positioned to be applied at 130g/m 2 、135g/m 2 、210g/m 2 、215g/m 2 The flash effect is better.
Preferably, in the step (1), after the surface glaze is applied to the green brick, ink-jet printing is performed first, and then glue is applied.
The ink-jet printing can print color ink according to the corresponding decoration requirement and print engraving ink so as to improve the look and feel of the decoration surface and further improve the decoration effect of the decoration surface.
A sparkling non-pitted decorative material comprising: a blank body;
the green body is provided with a decorative surface; the decorative surface is prepared by the preparation method of the flashing decorative surface without pits.
The blank can be a base blank of a known decorative material, and the base blank can have a decorative effect or have no decorative effect, such as a ceramic product blank, a decorative plate bottom plate, a bathroom blank and the like. Preferably applied to ceramic products, in particular ceramic tiles.
The use of a decorative surface in the preparation of a sparkling and pit-free ceramic product, wherein the decorative surface is prepared by the preparation method of the sparkling and pit-free decorative surface.
Performance test:
flash effect: the long strip-shaped light is used for shining the brick body, the flashing effect on the surface of the brick body is observed, and the flashing effect is continuously qualified.
Appearance evaluation: the long strip-shaped light is used for shining the brick body, the flashing effect on the surface of the brick body is observed, whether pits exist at the flashing position is touched and observed, and the pits are unqualified.
The green body of the scheme can be a bottom body of a known decorative material, and the green body is taken as an example for illustration; the green bricks were prepared in the following examples or comparative examples, and the green brick molding step is known: (1) firstly, preparing or purchasing raw materials; (2) the preparation of the green bricks (specifically comprising green brick molding and green brick surface cleaning); (3) drying and firing the green bricks; (4) and cleaning the green bricks.
Example a:
step (1): spreading glue on the surface glaze of the green bricks; before glue is applied, the temperature of the glue is controlled to be 40 ℃; the glue application amount is 90g/m 2 ；
The surface glaze comprises the following raw materials in parts by mass: 13 parts of lithium porcelain stone, 22 parts of albite, 16 parts of nepheline, 7 parts of water-washed kaolin, 20 parts of quartz, 10 parts of calcined alumina, 5 parts of talcum and 3 parts of dolomite; specific gravity of overglaze 1.86g/ml, flow rate 32s, showering 500g/m 2 The method comprises the steps of carrying out a first treatment on the surface of the Controlling the glossiness to be 6 degrees;
step (2): after the crystal dry grains are coated on the overglaze Shi Dingwei, small drying is carried out; the distribution of the positioned crystallization dry grain is 160g/m 2 The method comprises the steps of carrying out a first treatment on the surface of the The small drying temperature is controlled to be 100 ℃, and the drying time is 120s;
positioning the crystalline dry particles in the step (2);
positioning crystalline dry particles, which are prepared from the following raw materials in parts by weight: 100 parts of frit crystals and 10 parts of zircon; the raw materials for frit crystallization comprise the following components in parts by weight: 15 parts of potassium feldspar, 35 parts of albite, 10 parts of wollastonite, 1 part of calcined talc, 18 parts of quartz, 1 part of zinc oxide, 20 parts of calcined alumina and 1 part of titanium oxide; the preparation method of the frit crystal comprises the steps of crushing and uniformly mixing raw materials, melting at 1600 ℃ and preserving heat for 15min, and then cooling, crystallizing and crushing to obtain the frit crystal; the proportion of the crystalline dry particles in the embodiment is 60-80 meshes: 20% of a base; 80-100 mesh: 40%;100-160 mesh: 35%;160 mesh below: 5%.
Step (3): protective glaze is applied, the specific gravity is 1.16g/ml, and the gram number is 225g/m 2 ；
The protective glaze comprises the raw materials of, by mass, 100 parts of low-temperature glaze polishing, 200 parts of glue, 0.13 part of ink discharging agent and 0.13 part of defoaming agent;
the low-temperature glaze polishing comprises the following raw materials in parts by mass: 20 parts of potassium feldspar, 10 parts of water-washed kaolin, 6 parts of wollastonite, 5 parts of diopside, 5 parts of calcite, 8 parts of quartz, 1 part of zinc oxide, 5 parts of barium sulfate, 3 parts of strontium carbonate and 40 parts of low-temperature frit;
step (4): after common dry grains are distributed, protective glaze is distributed, and the materials are dried and sintered; the distribution of the common dry particles is 600g/m 2 ；
The common dry particle comprises the following chemical components in percentage by mass: 56% SiO 2 8% Al 2 O 3 11% CaO, 3% MgO, 8% K 2 O, 3% Na 2 O, 4% BaO, 2% SrO, and 5% ZnO;
the mesh number proportion of the common dry particles comprises the following components in percentage by mass: 40-60 mesh: 12%;60-100 mesh: 32%:100-160 mesh: 50%;160-180 mesh: 6%.
Step (5): and (3) polishing the blank after sintering to be flat, and obtaining the decorative surface.
Example B:
step (1): spreading glue after the surface glaze is applied to the green bricks; before glue is applied, the temperature of the glue is controlled to be 45 ℃; the glue application amount is 100g/m 2 ；
The overglaze is purchased from the market and comprises the following raw materials in parts by mass: 25% of potassium feldspar, 15% of albite, 9% of kaolin, 20% of quartz, 3% of alumina and 4% of oxidationZinc, 4% magnesium oxide, 15% limestone and 5% zirconium silicate; specific gravity of overglaze 1.84g/ml, flow rate 36s, showering 450g/m 2 The method comprises the steps of carrying out a first treatment on the surface of the Controlling the glossiness to 5 degrees;
step (2): after the crystal dry grains are coated on the overglaze Shi Dingwei, small drying is carried out; the distribution of the positioned crystallization dry grain is 140g/m 2 The method comprises the steps of carrying out a first treatment on the surface of the The small drying temperature is controlled to be 120 ℃, and the drying time is 120s;
positioning the crystalline dry particles in the step (2);
positioning crystalline dry particles, which are prepared from the following raw materials in parts by weight: 90 parts of frit crystals and 5 parts of zircon; the raw materials for frit crystallization comprise the following components in parts by weight: 10 parts of potassium feldspar, 40 parts of albite, 9 parts of wollastonite, 2 parts of calcined talc, 20 parts of quartz, 15 parts of calcined alumina and 2 parts of titanium oxide; the preparation method of the frit crystal comprises the steps of crushing and uniformly mixing the raw materials, melting at 1650 ℃ and preserving heat for 20min, and then cooling, crystallizing and crushing to obtain the frit crystal; the proportion of the crystalline dry particles in the embodiment is 60-80 meshes: 25%;80-100 mesh: 45%; the size of the powder is 100 meshes below: 30%.
Step (3): protective glaze is applied, the specific gravity is 1.15g/ml, and the gram number is 245g/m 2 ；
Step (4): after common dry grains are distributed, protective glaze is distributed, and the materials are dried and sintered; the distribution of the common dry particles is 500g/m 2 ；
The common dry particle comprises the following chemical components in percentage by mass: 50% SiO 2 15% Al 2 O 3 6% CaO, 3% K 2 O, 5% Na 2 O, 5% BaO, 4% SrO, and 12% ZnO;
the mesh number proportion of the common dry particles comprises the following components in percentage by mass: 40-60 mesh: 8%;60-100 mesh: 38%:100-160 mesh: 46%;160-180 mesh: 8%.
In this example, the protective glaze is randomly purchased from the market, and comprises the following raw materials in parts by mass: 22 parts of quartz, 17 parts of potassium feldspar, 10 parts of wollastonite, 5 parts of talcum, 4 parts of zinc oxide, 9 parts of calcined alumina, 3 parts of barium oxide and 30 parts of frit; adding glue accounting for 200 percent of the total mass, 0.13 percent of ink discharging agent and 0.13 percent of defoaming agent;
step (5): and (3) polishing the blank after sintering to be flat, and obtaining the decorative surface.
Example C:
step (1): spreading glue on the surface glaze of the green bricks; before glue is applied, the temperature of the glue is controlled to be 40 ℃; the glue application amount is 80g/m 2 ；
The surface glaze comprises the following raw materials in parts by mass: 15 parts of lithium porcelain stone, 20 parts of albite, 20 parts of nepheline, 6 parts of water-washed kaolin, 22 parts of quartz, 8 parts of calcined alumina, 7 parts of talcum and 2 parts of dolomite; specific gravity of the overglaze was 1.89g/ml, flow rate 30s,530g/m 2 The method comprises the steps of carrying out a first treatment on the surface of the Controlling the glossiness to 8 degrees;
step (2): after the crystal dry grains are coated on the overglaze Shi Dingwei, small drying is carried out; the distribution of the positioned crystallization dry grain is 180g/m 2 Then externally supplement 20g/m 2 Ordinary dry grain, cloth Shi Liang for keeping total dry grain at 200g/m 2 The method comprises the steps of carrying out a first treatment on the surface of the The small drying temperature is controlled to be 120 ℃, and the drying time is 120s;
positioning the crystalline dry particles in the step (2);
positioning crystalline dry particles, which are prepared from the following raw materials in parts by weight: 110 parts of frit crystals, 20 parts of zircon and 10 parts of colorant; the raw materials for frit crystallization comprise the following components in parts by weight: 20 parts of potassium feldspar, 30 parts of albite, 15 parts of wollastonite, 16 parts of quartz, 2 parts of zinc oxide and 25 parts of calcined alumina; the preparation method of the frit crystal comprises the steps of crushing and uniformly mixing raw materials, melting at 1600 ℃ and preserving heat for 15min, and then cooling, crystallizing and crushing to obtain the frit crystal; the proportion of the crystalline dry particles in the embodiment is 60-80 meshes: 20% of a base; 80-100 mesh: 40%;100-160 mesh: 35%;160 mesh below: 5%.
Step (3): protective glaze is applied, the specific gravity is 1.18g/ml, and the gram number is 205g/m 2 ；
The protective glaze comprises the raw materials of, by mass, 100 parts of low-temperature glaze polishing, 200 parts of glue, 0.13 part of ink discharging agent and 0.13 part of defoaming agent;
the low-temperature glaze polishing comprises the following raw materials in parts by mass: 20 parts of potassium feldspar, 10 parts of water-washed kaolin, 6 parts of wollastonite, 5 parts of diopside, 5 parts of calcite, 8 parts of quartz, 1 part of zinc oxide, 5 parts of barium sulfate, 3 parts of strontium carbonate and 40 parts of low-temperature frit;
step (4): after common dry grains are distributed, protective glaze is distributed, and the materials are dried and sintered; the distribution amount of the common dry particles is 700g/m 2 ；
In this example, the common dry particles are randomly purchased from the market, and the raw materials comprise the following components in parts by weight: 15% CaO, 50% SiO 2 6% ZnO, 3% MgO, 1% BaO, 20% Al 2 O 3 2% of K 2 O, 2% Na 2 O and 1% I.L.
The mesh number proportion of the common dry particles comprises the following components in percentage by mass: 40-60 mesh: 20% of a base; 60-100 mesh: 25%:100-160 mesh: 50%;160-180 mesh: 5%.
Step (5): and (3) polishing the blank after sintering to be flat, and obtaining the decorative surface.
Example D:
the procedure of example D was essentially the same as that of example a, except that example D was followed by inkjet printing and glue application after the green tile had been overglazed; the printing of the color ink and the printing of the engraving ink are sequentially performed in the inkjet printing. The ink jet channels may be sequentially arranged in blue, brown, yellow, black and cnc ink. The engraving ink is Tao Lixi CZN type ink.
Comparative example E1: the procedure of comparative example E1 was substantially the same as in example A, except that comparative example E1 was conducted by distributing ordinary dry grains in step (2) instead of the oriented crystalline dry grains of example A.
Comparative example E2: the procedure of comparative example E2 was substantially the same as in example A, except that in comparative example E2, the procedure of step (3) was followed by direct drying and firing.
Comparative example E3: the procedure of comparative example E3 was substantially the same as in example A, except that comparative example E3 did not perform step (5).
The performance of examples A-D, and comparative examples E1-E3 were compared and the results are shown in Table 1.
TABLE 1 comparison of the Properties of examples A-D and comparative examples E1-E3
Remarks: as shown in fig. 1-5, the white strips on the surface of the brick body are flashing effects.
Description:
1. as can be seen from the comparison of example A with comparative example E1, comparative example E1 was provided with conventional dry granules in step (2) instead of the oriented crystalline dry granules of example A, and comparative example E1 did not use oriented crystalline dry granules; in the scheme, the positioning crystallization dry grain can effectively improve the flashing effect, can be realized after being combined with the common dry grain and the protective glaze, and can realize continuous flashing effect on the brick body; thus, the surface of comparative example E1 had no pits, but the effect of the flash on the surface was insufficient, as shown in FIG. 5. In the embodiment A, the crystal dry grains are positioned, the flashing effect of different positions of the brick body is achieved, the flashing is continuous, and pits are not formed; the formula of the positioning crystallization dry particle with the scheme is illustrated, and the flashing effect of a blank body can be effectively improved.
2. As is evident from the comparison of example A and comparative example E2, comparative example E2 was directly dried and then fired after step (3), and no conventional dry granules and protective glaze were applied. In the scheme, the common dry particles can be matched with the positioning crystal dry particles to prevent the problem of reduced flashing effect caused by whitening when the positioning crystal dry particles are easy to agglomerate; therefore, the flash effect of comparative example E2 is insufficient as shown in fig. 5; in embodiment A, after executing step (3), proceed to step (4), which presents a flashing effect, as shown in FIG. 1; it is described that after the protective glaze is applied in the step (3), the step (4) is needed to continuously apply the common dry grains and the protective glaze, so that the flashing effect can be achieved.
3. As can be seen from the comparison of example A with comparative example E3, comparative example E3 did not perform step (5), i.e., the green brick was not polished after firing; in the scheme, the positioning crystal dry grains need to be polished to generate a flashing effect; polishing the decorative surface, namely polishing the protruding part of the crystalline dry grain with the partial positioning, so that the water ripple on the glaze surface of the decorative surface is smooth, and finally, no pit exists; thus comparative example E3 does not have a sparkling effect as shown in fig. 6. The green bricks of the embodiment A are polished to flatten the decorative surface, the flashing effect of different positions of the brick body is achieved, the flashing positions are continuous, and pits are not formed, as shown in fig. 1.
To sum up, the decoration surface of this scheme needs to arrange twice protection glaze, and first time protection glaze cloth is applied to location crystallization dry grain, and second time protection glaze cloth is applied to second ordinary dry grain, and after drying and sintering, polishing again can form the continuous flash effect of brick body, has effectively solved the flash effect that the decoration surface location crystallization dry grain formed and has relatively protruded problem of forming present pit in prior art.
The technical principle of the present solution is described above in connection with the specific embodiments. The description is only intended to explain the principles of the present solution and should not be construed in any way as limiting the scope of the present solution. Based on the explanations herein, other embodiments of the present solution will be apparent to those skilled in the art without undue burden, and such modifications will fall within the scope of the present solution.
Claims (9)
1. The preparation method of the flashing decorative surface without pits is characterized by comprising the following steps of:
step (1): spreading glue on the surface glaze of the green bricks;
step (2): coating Shi Dingwei on the overglaze to form crystal dry grains;
positioning crystalline dry particles, which are prepared from the following raw materials in parts by weight: 90-110 parts of frit crystals, 5-20 parts of zircon and 0-10 parts of coloring agent; the raw materials for frit crystallization comprise the following components in parts by weight: 10-20 parts of potassium feldspar, 30-40 parts of albite, 9-15 parts of wollastonite, 0-2 parts of calcined talcum, 16-20 parts of quartz, 0-2 parts of zinc oxide, 15-25 parts of calcined alumina and 0-2 parts of titanium oxide;
step (3): applying protective glaze;
step (4): after common dry grains are distributed, protective glaze is distributed, and the materials are dried and sintered;
the common dry particle comprises the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% CaO, 0-5% MgO, 3-8% K 2 O, 0-5% Na 2 O, 0-5% BaO, 1-7% SrO and 5-13% ZnO;
step (5): and (3) polishing the blank after sintering to be flat, and obtaining the decorative surface.
2. The method of producing a sparkling, dent-free decorative surface according to claim 1, wherein in the step (2), shi Dingwei crystalline dry grains and ordinary dry grains are spread on the overglaze.
3. The method for producing a flash non-pit decorative surface according to claim 1, wherein in the step (1), the glue temperature is controlled to 40-45 ℃ before the glue is applied; the application amount of the glue is 80-100g/m 2 ；
In the step (1), the raw materials of the overglaze comprise the following components in parts by mass: 10-15 parts of lithium porcelain stone, 20-25 parts of albite, 15-20 parts of nepheline, 6-10 parts of water-washed kaolin, 18-22 parts of quartz, 8-12 parts of calcined alumina, 4-7 parts of talcum and 2-4 parts of dolomite.
4. The method for manufacturing the flash pit-free decorative surface according to claim 1, wherein the raw materials of the protective glaze comprise low-temperature glaze polishing and glue;
the low-temperature glaze polishing comprises the following raw materials in parts by mass: 15-20 parts of potassium feldspar, 6-10 parts of water-washed kaolin, 6-10 parts of wollastonite, 3-5 parts of diopside, 5-10 parts of calcite, 4-8 parts of quartz, 1-3 parts of zinc oxide, 3-5 parts of barium sulfate, 3-5 parts of strontium carbonate and 35-40 parts of low-temperature frit;
the low-temperature frit comprises the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% of CaO,0-5% MgO, 3-8% K 2 O, 0-5% Na 2 O, 0-5% BaO, 1-7% SrO and 5-13% ZnO.
5. The method for manufacturing the flash pit-free decorative surface according to claim 1, wherein the mesh number proportion of the common dry particles comprises the following components in percentage by mass: 40-60 mesh: 8-18%;60-100 mesh: 28-38%:100-160 mesh: 45-55%;160-180 mesh: 3-8%.
6. The method for producing a sparkling and dimpled decorative surface according to claim 5, wherein in the step (4), the normal dry grain is applied in an amount of 500 to 700g/m 2 。
7. The method of any one of claims 1 to 6, wherein in step (1), after the green tile is coated with the overglaze, the green tile is first inkjet printed and then glue is applied.
8. A flashing, potless decorative material comprising: a blank body;
the green body is provided with a decorative surface; the decorative surface is prepared by the preparation method of the flashing decorative surface without pits according to any one of claims 1 to 7.
9. Use of a decorative surface in the manufacture of a sparkling, potless ceramic article, wherein the decorative surface is manufactured by a method of manufacturing a sparkling potless decorative surface according to any one of claims 1 to 7.
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