CN115466054A - Flash and pit-free decorative material and preparation method and application of decorative surface - Google Patents
Flash and pit-free decorative material and preparation method and application of decorative surface Download PDFInfo
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- CN115466054A CN115466054A CN202211175949.6A CN202211175949A CN115466054A CN 115466054 A CN115466054 A CN 115466054A CN 202211175949 A CN202211175949 A CN 202211175949A CN 115466054 A CN115466054 A CN 115466054A
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- 239000000463 material Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 98
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 50
- 238000002425 crystallisation Methods 0.000 claims abstract description 50
- 230000008025 crystallization Effects 0.000 claims abstract description 50
- 239000003292 glue Substances 0.000 claims abstract description 43
- 230000001681 protective effect Effects 0.000 claims abstract description 40
- 239000011787 zinc oxide Substances 0.000 claims abstract description 25
- 239000013078 crystal Substances 0.000 claims abstract description 23
- 239000010453 quartz Substances 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000005498 polishing Methods 0.000 claims abstract description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052656 albite Inorganic materials 0.000 claims abstract description 16
- 239000010456 wollastonite Substances 0.000 claims abstract description 16
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 16
- 239000000454 talc Substances 0.000 claims abstract description 15
- 229910052623 talc Inorganic materials 0.000 claims abstract description 15
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008187 granular material Substances 0.000 claims description 38
- 239000002994 raw material Substances 0.000 claims description 35
- 239000011449 brick Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 18
- 239000005995 Aluminium silicate Substances 0.000 claims description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims description 11
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 11
- 239000004744 fabric Substances 0.000 claims description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 11
- 238000003892 spreading Methods 0.000 claims description 11
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- 239000000395 magnesium oxide Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- 239000000919 ceramic Substances 0.000 claims description 7
- 238000005034 decoration Methods 0.000 claims description 7
- 238000007641 inkjet printing Methods 0.000 claims description 6
- 229910021532 Calcite Inorganic materials 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052637 diopside Inorganic materials 0.000 claims description 5
- 239000010459 dolomite Substances 0.000 claims description 5
- 229910000514 dolomite Inorganic materials 0.000 claims description 5
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000010434 nepheline Substances 0.000 claims description 5
- 229910052664 nepheline Inorganic materials 0.000 claims description 5
- 229910052573 porcelain Inorganic materials 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims description 5
- 239000004575 stone Substances 0.000 claims description 5
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 41
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 6
- 239000010433 feldspar Substances 0.000 abstract description 6
- 229940072033 potash Drugs 0.000 abstract description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 6
- 235000015320 potassium carbonate Nutrition 0.000 abstract description 6
- 238000010304 firing Methods 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 22
- 238000001035 drying Methods 0.000 description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 7
- 230000005484 gravity Effects 0.000 description 6
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
A preparation method and application of flashing and pitless decorative material and decorative surface, the preparation method, its step (1) is to spread the glue on the overglaze of the adobe; (2) distributing and applying positioning crystallization dry particles on the overglaze; (3) applying protective glaze; (4) After ordinary dry particles are coated, protective glaze is coated, dried and then sintered; (5) And firing the blank, and polishing the fired blank to be flat to obtain a decorative surface. The decorative material is prepared by the preparation method; the scheme provides a preparation method of a flashing and non-pit decorative surface, wherein positioned crystallized dry particles formed by combining clinker crystals with potash feldspar, albite, wollastonite, calcined talc, quartz, zinc oxide, calcined alumina and titanium oxide and zircon are matched with common dry particles and protective glaze to prepare the flashing and non-pit decorative surface, the decorative surface can present a continuous flashing effect, and the problem that flashing effects formed by the positioned crystallized dry particles of the decorative surface in the prior art are relatively convex to form pits is effectively solved.
Description
Technical Field
The invention relates to the technical field of glaze materials, in particular to a flashing and pit-free decorative material, a preparation method and application of a decorative surface.
Background
In the prior art, the crystallized dry grains are distributed on the whole surface of the brick surface, and the positioned crystallized dry grains are in local positions, so that the surface of the brick surface presents different flashing effects after being fired, the flashing effects are discontinuous and incoherent, the integral impression of the brick surface is obviously influenced, and the visual fatigue is easily generated during long-term use; meanwhile, in the prior art, the lamp tube in the place where the crystals are thrown out of the positioned crystal dry particles obviously protrudes, so that pits are formed relative to other parts, which is not favorable for touch feeling and visual feeling, as shown in fig. 7.
Disclosure of Invention
The invention aims to provide a preparation method of a flash decorative surface without pits, which combines frit crystals with potash feldspar, albite, wollastonite, calcined talc, quartz, zinc oxide, calcined alumina and titanium oxide with zircon to form positioned crystal dry particles, and the positioned crystal dry particles are matched with common dry particles and protective glaze to prepare the flash decorative surface without pits, wherein the decorative surface can present a continuous flash effect.
The invention also provides a flash decorative material without pits, and the decorative surface arranged on the blank body of the flash decorative material is prepared by the preparation method of the flash decorative surface without pits.
The invention also provides the application of the decorative surface in the preparation of the glittering non-pit ceramic product.
In order to achieve the purpose, the invention adopts the following technical scheme:
a method for preparing a glittering and non-pit decorative surface comprises the following steps:
step (1): spreading glue on the overglaze of the green brick;
step (2): laying positioning crystallization dry particles on the overglaze;
the positioning crystallization dry particle comprises the following raw materials in parts by weight: 90-110 parts of frit crystals, 5-20 parts of zircon and 0-10 parts of coloring agent; the frit crystallization raw material comprises the following components in parts by mass: 10-20 parts of potassium feldspar, 30-40 parts of albite, 9-15 parts of wollastonite, 0-2 parts of calcined talc, 16-20 parts of quartz, 0-2 parts of zinc oxide, 15-25 parts of calcined alumina and 0-2 parts of titanium oxide;
and (3): spreading protective glaze;
and (4): after ordinary dry particles are distributed, protective glaze is distributed, dried and then sintered;
and (5): and firing the blank, and polishing the fired blank to be flat to obtain a decorative surface.
Preferably, in the step (2), the localized crystalline dry particles and the ordinary dry particles are applied on the overglaze.
Preferably, in the step (1), before the glue is applied, the temperature of the glue is controlled to be 40-45 ℃; the glue application amount is 80-100g/m 2 ；
In the step (1), the overglaze comprises the following raw materials in parts by weight: 10-15 parts of lithium porcelain stone, 20-25 parts of albite, 15-20 parts of nepheline, 6-10 parts of water-washed kaolin, 18-22 parts of quartz, 8-12 parts of calcined alumina, 4-7 parts of talc and 2-4 parts of dolomite.
Preferably, the raw materials of the protective glaze comprise low-temperature polishing glaze and glue;
the low-temperature glaze polishing raw materials comprise, by mass: 15-20 parts of potassium feldspar, 6-10 parts of water-washed kaolin, 6-10 parts of wollastonite, 3-5 parts of diopside, 5-10 parts of calcite, 4-8 parts of quartz, 1-3 parts of zinc oxide, 3-5 parts of barium sulfate, 3-5 parts of strontium carbonate and 35-40 parts of low-temperature frit;
the low-temperature frit comprises the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% of CaO, 0-5% of MgO and 3-8% of K 2 O, 0-5% of Na 2 O, baO 0-5%, srO 1-7% and ZnO 5-13%.
Preferably, the common dry granules comprise the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% of CaO, 0-5% of MgO and 3-8% of K 2 O, 0-5% of Na 2 O, baO 0-5%, srO 1-7% and ZnO 5-13%.
Further optimally, the mesh number proportion of the common dry granules comprises the following components in percentage by mass: 40-60 meshes: 8 to 18 percent; 60-100 meshes: 28-38%:100-160 meshes: 45 to 55 percent; 160-180 meshes: 3 to 8 percent.
Preferably, in the step (4), the cloth application amount of the common dry granules is 500-700g/m 2 。
Optimally, in the step (1), after the overglaze is applied to the green brick cloth, the inkjet printing is firstly carried out, and then the glue is applied.
A flashing, non-dimpled trim material comprising: a blank body;
the blank body is provided with a decorative surface; the decorative surface is prepared by the preparation method of the flashing pitless decorative surface.
The use of a decorative cover for the production of a sparkling, crater-free ceramic product, which decorative cover is produced by a method as described above for the production of a sparkling, crater-free decorative cover.
The technical scheme provided by the invention can have the following beneficial effects:
the scheme provides a preparation method of a flashing and non-pit decorative surface, wherein positioned crystallized dry particles formed by combining clinker crystals with potash feldspar, albite, wollastonite, calcined talc, quartz, zinc oxide, calcined alumina and titanium oxide and zircon are matched with common dry particles and protective glaze to prepare the flashing and non-pit decorative surface, the decorative surface can present a continuous flashing effect, and the problem that flashing effects formed by the positioned crystallized dry particles of the decorative surface in the prior art are relatively convex to form pits is effectively solved.
Drawings
FIG. 1 is a standard schematic illustration of a preferred embodiment decorative face;
FIG. 2 is a standard schematic view of a decorative face of one embodiment;
FIG. 3 is a standard schematic view of a decorative face of one embodiment;
FIG. 4 is a standard schematic view of a decorative cover according to one embodiment;
FIG. 5 is a standard schematic view of a decorative cover with insufficient sparkling effect;
FIG. 6 is a standard schematic of a decorative face with a dimpled embodiment.
Fig. 7 shows the whole face of the brick surface covered with the glittering effect in the prior art.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
The technical scheme of the scheme is further explained by the specific implementation mode in combination with the attached drawings.
A method for preparing a flashing non-pit decorative surface comprises the following steps:
step (1): spreading glue on the overglaze of the green brick;
after the glue is applied to the overglaze, the glue can be used for adhering and positioning crystallized dry particles; attaching the positioning crystallization dry particles and the common dry particles to the overglaze;
step (2): laying positioning crystallized dry particles on the overglaze;
the positioning crystallization dry particle comprises the following raw materials in parts by mass: 90-110 parts of frit crystals, 5-20 parts of zircon and 0-10 parts of coloring agent; the frit crystallization raw material comprises the following components in parts by mass: 10-20 parts of potassium feldspar, 30-40 parts of albite, 9-15 parts of wollastonite, 0-2 parts of calcined talc, 16-20 parts of quartz, 0-2 parts of zinc oxide, 15-25 parts of calcined alumina and 0-2 parts of titanium oxide;
the frit crystallized raw material can be processed according to the known processing steps, for example, the raw material is crushed, mixed evenly, melted at the temperature of not less than 1600 ℃, and kept warm for at least 15min, and then cooled, crystallized and crushed to obtain the frit crystallized raw material;
in the scheme, positioning crystallization dry particles and/or common dry particles are/is distributed on the overglaze; the method comprises the steps of putting positioning crystallization dry particles and/or common dry particles in overglaze, wherein for a glue area of the overglaze, the positioning crystallization dry particles and/or the common dry particles can be attached to the glue area; for the non-glue area of the overglaze, the positioning crystallization dry particles and/or the common dry particles can be naturally separated or sucked away by vacuum; after the positioning crystallization dry particles and/or the common dry particles are applied, proper drying can be carried out according to the known means;
and (3): spreading protective glaze;
and (4): after ordinary dry particles are distributed, protective glaze is distributed, dried and then sintered;
in the scheme, the step (3) and the step (4) are carried out twice application of the protective glaze; the protective glaze can be replaced by the protective glaze on the market; the protective glaze in the scheme has a protective effect, and can wet the glaze surface, so that common dry particles are better combined with the glaze surface, and glaze shrinkage at the positions where the crystalline dry particles are distributed and positioned can be prevented; the common dry particles can be matched with the positioning crystallization dry particles for use, so that the problem of reduced flashing effect caused by whitening when the positioning crystallization dry particles are easy to agglomerate is prevented;
and (5): and sintering the blank, and polishing the sintered blank to be flat to obtain the decorative surface.
Positioning the crystallized dry particles and polishing to generate a flashing effect; polishing the decorative surface, and removing the raised parts of the partially positioned crystallized dry particles to ensure that the water ripples of the glaze surface of the decorative surface are smooth and finally have no pits;
the scheme provides a preparation method of a flashing and non-pit decorative surface, wherein positioned crystallized dry particles formed by combining clinker crystals with potash feldspar, albite, wollastonite, calcined talc, quartz, zinc oxide, calcined alumina and titanium oxide and zircon are matched with common dry particles and protective glaze to prepare the flashing and non-pit decorative surface, the decorative surface can present a continuous flashing effect, and the problem that flashing effects formed by the positioned crystallized dry particles of the decorative surface in the prior art are relatively convex to form pits is effectively solved.
Preferably, in the step (2), the localized crystalline dry particles and the ordinary dry particles are applied on the overglaze.
Preferably, in the step (1), before the glue is applied, the temperature of the glue is controlled to be 40-45 ℃; the glue application amount is 80-100g/m 2 ；
In the step (1), the overglaze comprises the following raw materials in parts by weight: 10-15 parts of lithium porcelain stone, 20-25 parts of albite, 15-20 parts of nepheline, 6-10 parts of water-washed kaolin, 18-22 parts of quartz, 8-12 parts of calcined alumina, 4-7 parts of talc and 2-4 parts of dolomite.
In the scheme, the overglaze can be replaced by the known overglaze; in the scheme, the overglaze is used, the glue is applied at 40-45 ℃, and the application amount is 80-100g/m 2 When the surface drying time of the glue is moderate, the viscosity is high, the adhesive force of the positioning crystallization dry particles on the overglaze is moderate, the positioning crystallization dry particles are not easy to fall off, and the positioning crystallization dry particles are easy to be absorbed away by a vacuum source.
Preferably, the raw materials of the protective glaze comprise low-temperature polishing glaze and glue;
the low-temperature glaze polishing raw materials comprise, by mass: 15-20 parts of potassium feldspar, 6-10 parts of water-washed kaolin, 6-10 parts of wollastonite, 3-5 parts of diopside, 5-10 parts of calcite, 4-8 parts of quartz, 1-3 parts of zinc oxide, 3-5 parts of barium sulfate, 3-5 parts of strontium carbonate and 35-40 parts of low-temperature frit;
the low-temperature frit comprises the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% of CaO, 0-5% of MgO and 3-8% of K 2 O, 0-5% of Na 2 O, baO 0-5%, srO 1-7% and ZnO 5-13%.
The protective glaze can be replaced by known protective glazes; in the scheme, when the protective glaze with the formula is used, the chemical components of the low-temperature frits in the protective glaze are basically the same as those of the common dry particles and are only in the mesh number ratio of the common dry particles, so that the compatibility of the protective glaze and the common dry particles is improved, and the flashing effect is best.
Wherein, the amount of the glue is determined according to the common dry granules, and the optimal addition amount can be obtained through a limited number of experiments.
Preferably, the common dry granules comprise the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% of CaO, 0-5% of MgO and 3-8% of K 2 O, 0-5% of Na 2 O, baO 0-5%, srO 1-7% and ZnO 5-13%.
The common dry granules used in the step (2) and/or the step (3) can be replaced by the known dry granules; in the scheme, dry particles with the same formula as the low-temperature frit are preferably used as common dry particles, so that the compatibility of the common dry particles and the protective glaze is improved, and the flashing effect can be further improved; in some embodiments, the step (2) is added with common dry particles, the positioning crystallization dry particles can be matched with the protective glaze more effectively, the combination of the common dry particles, the positioning crystallization dry particles and the protective glaze is good, and the flashing effect is optimal.
Preferably, the mesh number proportion of the common dry granules comprises the following components in percentage by mass: 40-60 meshes: 8 to 18 percent; 60-100 meshes: 28-38%:100-160 meshes: 45 to 55 percent; 160-180 meshes: 3 to 8 percent.
In the step (4), the mesh number of the common dry granules can be determined according to the actual situation; when the mesh number of the common dry granules is matched, the common dry granules comprise the following components in percentage by mass: 40-60 meshes: 8 to 18 percent; 60-100 meshes: 28-38%:100-160 meshes: 45 to 55 percent; 160-180 meshes: when the content is 3-8%, the common dry granules can more easily fill the positioning crystallization dry granules obtained in the step (2); for example, when the distribution speed of the distributing machine is not well adjusted by small gram, common dry particles can be supplemented in the positioning crystallization dry particles to replace the positioning crystallization dry particles, and the gram of the positioning crystallization dry particles is supplemented in proportion, so that the flashing effect is improved.
Further optimally, in the step (4), the cloth application amount of the common dry granules is 500-700g/m 2 。
When the common dry granules are the formula of the low-temperature frit and the mesh number proportion is used, the common dry granules are 500-700g/m 2 The raised part of the positioning crystallized dry particles of the final decorative surface can be reduced, so that the concave-convex condition at the later stage of the decorative surface can be accurately controlled. In the most preferred embodiment, the application amount of the common dry granules is 570-650g/m 2 。
Wherein, the cloth application amount of the positioning crystallization dry granules is preferably 140-200g/m 2 。
The distribution amount of the positioning crystallization dry particles can be distributed according to the actual amount, and when the positioning crystallization dry particles are distributed, the distribution amount of the positioning crystallization dry particles is increased within a certain range, so that the glittering effect of the decorative surface can be improved; the application amount of the positioning crystallization dry granules is 140-200g/m 2 The flashing effect of the decorative surface is optimal; in some embodiments, for example, the distribution of the crystallized dry granules is 130g/m 2 、135g/m 2 、210g/m 2 、215g/m 2 And also has better flash effect.
Preferably, in the step (1), after the overglaze is applied to the green brick cloth, the inkjet printing is firstly performed, and then the glue is applied.
The ink-jet printing can be used for printing color ink according to the corresponding decoration requirement and printing the carved ink so as to improve the appearance and the touch of the decoration surface and further improve the decoration effect of the decoration surface.
A flashing dimpled-free trim material comprising: a blank body;
the blank is provided with a decorative surface; the decorative surface is prepared by the preparation method of the flashing non-pit decorative surface.
The blank body can be a base blank of a known decorative material, and the base blank can be originally provided with a decorative effect or not, such as a blank body of a ceramic product, a bottom plate of a decorative plate, a blank body of a bathroom and the like. Preferably applied to ceramic articles, especially ceramic tiles.
Use of a decorative cover for the manufacture of a sparkling non-pitted ceramic article, said decorative cover being made by a method of manufacturing a sparkling non-pitted decorative cover as described above.
And (4) performance testing:
flashing effect: and (3) shining the brick body by using strip-shaped light, and observing the flashing effect on the surface of the brick body, wherein the flashing effect is continuous and qualified.
Appearance evaluation: and (3) shining the brick body by using strip-shaped light, observing the flashing effect on the surface of the brick body, and touching and observing whether pits exist at the flashing part or not, wherein the pits are unqualified.
The green body of the scheme can be a bottom blank of a known decorative material, and a brick blank is taken as an example here; the preparation of the green brick, which is known as the green body forming step, is carried out as follows in the examples or before the comparative examples: (1) firstly, preparing or purchasing raw materials; (2) preparing green bricks (specifically comprising green brick forming and green brick surface cleaning); (3) drying and sintering green bricks; (4) and sweeping the green bricks.
Example A:
step (1): spreading glue on the overglaze of the green brick; before the glue is distributed and applied, the temperature of the glue is controlled to be 40 ℃; the glue spreading amount is 90g/m 2 ；
The overglaze comprises the following raw materials in parts by weight: 13 parts of lithium porcelain stone, 22 parts of albite, 16 parts of nepheline, 7 parts of water-washed kaolin, 20 parts of quartz, 10 parts of calcined alumina, 5 parts of talc and 3 parts of dolomite; the specific gravity of the overglaze is 1.86g/ml, the flow rate is 32s, and the pouring is 500g/m 2 (ii) a Controlling the glossiness to be 6 degrees;
step (2): after the positioning crystallization dry particles are coated on the overglaze, small drying is carried out; the application amount of the positioning crystallization dry granules is 160g/m 2 (ii) a The temperature of the small drying is controlled to be 100 ℃,drying time 120s;
positioning the crystallized dry particles in the step (2);
the positioning crystallization dry particle comprises the following raw materials in parts by weight: 100 parts of frit crystals and 10 parts of zircon; the frit crystallization raw material comprises the following components in parts by mass: 15 parts of potassium feldspar, 35 parts of albite, 10 parts of wollastonite, 1 part of calcined talc, 18 parts of quartz, 1 part of zinc oxide, 20 parts of calcined alumina and 1 part of titanium oxide; the preparation method of the frit crystal comprises the steps of crushing and uniformly mixing the raw materials, melting at 1600 ℃, keeping the temperature for 15min, and then cooling, crystallizing and crushing to obtain the frit crystal; the dry grain ratio of the crystal in the embodiment is 60-80 meshes: 20 percent; 80-100 meshes: 40 percent; 100-160 meshes: 35 percent; 160 meshes below: 5 percent.
And (3): the specific gravity of the protective glaze is 1.16g/ml, and the gram number is 225g/m 2 ；
The protective glaze comprises, by mass, 100 parts of low-temperature glaze polishing, 200 parts of glue, 0.13 part of ink discharging agent and 0.13 part of defoaming agent;
the low-temperature glaze polishing raw materials comprise the following components in parts by weight: 20 parts of potash feldspar, 10 parts of water-washed kaolin, 6 parts of wollastonite, 5 parts of diopside, 5 parts of calcite, 8 parts of quartz, 1 part of zinc oxide, 5 parts of barium sulfate, 3 parts of strontium carbonate and 40 parts of low-temperature frit;
and (4): after ordinary dry particles are distributed, protective glaze is distributed, dried and then sintered; the cloth application amount of the common dry granules is 600g/m 2 ；
The common dry granules comprise the following chemical components in percentage by mass: 56% SiO 2 8% of Al 2 O 3 11% of CaO, 3% of MgO and 8% of K 2 O, 3% of Na 2 O, 4% BaO, 2% SrO and 5% ZnO;
the mesh number proportion of the common dry granules comprises the following components in percentage by mass: 40-60 meshes: 12 percent; 60-100 meshes: 32%:100-160 meshes: 50 percent; 160-180 meshes: 6 percent.
And (5): and sintering the blank, and polishing the sintered blank to be flat to obtain the decorative surface.
Example B:
step (1): spreading surface glaze on the green brick, and then spreading glue; before the glue is applied, the temperature of the glue is controlled to be 45 ℃; the glue application amount is 100g/m 2 ；
The overglaze is purchased from the market, and the raw materials thereof comprise the following components in parts by weight: 25% of potassium feldspar, 15% of albite, 9% of kaolin, 20% of quartz, 3% of alumina, 4% of zinc oxide, 4% of magnesium oxide, 15% of limestone and 5% of zirconium silicate; the specific gravity of the overglaze is 1.84g/ml, the flow rate is 36s, and the sprinkling rate is 450g/m 2 (ii) a Controlling the glossiness to be 5 degrees;
step (2): after the positioning crystallization dry particles are distributed on the overglaze, small drying is carried out; the application amount of the positioning crystallization dry granules is 140g/m 2 (ii) a Controlling the small drying temperature at 120 ℃, and drying for 120s;
positioning the crystallized dry particles in the step (2);
the positioning crystallization dry particle comprises the following raw materials in parts by weight: 90 parts of frit crystals and 5 parts of zircon; the frit crystallization raw material comprises the following components in parts by mass: 10 parts of potassium feldspar, 40 parts of albite, 9 parts of wollastonite, 2 parts of calcined talc, 20 parts of quartz, 15 parts of calcined alumina and 2 parts of titanium oxide; the preparation method of the frit crystal comprises the steps of crushing and uniformly mixing the raw materials, melting at 1650 ℃, preserving heat for 20min, and then cooling, crystallizing and crushing to obtain the frit crystal; the dry grain proportion of the crystal of the embodiment is 60-80 meshes: 25 percent; 80-100 meshes: 45 percent; 100 meshes below: 30 percent.
And (3): the specific gravity of the protective glaze is 1.15g/ml, and the gram number is 245g/m 2 ；
And (4): after ordinary dry particles are distributed, protective glaze is distributed, dried and then sintered; the cloth application amount of the common dry granules is 500g/m 2 ；
The common dry granules comprise the following chemical components in percentage by mass: 50% SiO 2 15% of Al 2 O 3 6% of CaO and 3% of K 2 O, 5% of Na 2 O, 5% BaO, 4% SrO and 12% ZnO;
the mesh number proportion of the common dry granules comprises the following components in percentage by mass: 40-60 meshes: 8 percent; 60-100 meshes: 38%:100-160 meshes: 46 percent; 160-180 meshes: 8 percent.
In this embodiment, the protective glaze is randomly purchased from the market, and the raw materials thereof include, by mass: 22 parts of quartz, 17 parts of potassium feldspar, 10 parts of wollastonite, 5 parts of talc, 4 parts of zinc oxide, 9 parts of calcined alumina, 3 parts of barium oxide and 30 parts of frit; glue accounting for 200 percent of the total mass, 0.13 percent of ink discharging agent and 0.13 percent of defoaming agent are additionally added;
and (5): and firing the blank, and polishing the fired blank to be flat to obtain a decorative surface.
Example C:
step (1): spreading glue on the overglaze of the green brick; before the glue is applied, the temperature of the glue is controlled to be 40 ℃; the glue application amount is 80g/m 2 ；
The overglaze comprises the following raw materials in parts by weight: 15 parts of lithium porcelain stone, 20 parts of albite, 20 parts of nepheline, 6 parts of water-washed kaolin, 22 parts of quartz, 8 parts of calcined alumina, 7 parts of talc and 2 parts of dolomite; the specific gravity of the overglaze is 1.89g/ml, the flow rate is 30s,530g/m 2 (ii) a Controlling the glossiness to be 8 degrees;
step (2): after the positioning crystallization dry particles are coated on the overglaze, small drying is carried out; the application amount of the positioning crystallization dry granules is 180g/m 2 Then, 20g/m of the powder is supplemented externally 2 Common dry granules, keeping the cloth application amount of the total dry granules at 200g/m 2 (ii) a Controlling the small drying temperature at 120 ℃, and drying for 120s;
positioning the crystallized dry particles in the step (2);
the positioning crystallization dry particle comprises the following raw materials in parts by weight: 110 parts of frit crystals, 20 parts of zircon and 10 parts of a colorant; the frit crystallization raw materials comprise the following components in parts by mass: 20 parts of potassium feldspar, 30 parts of albite, 15 parts of wollastonite, 16 parts of quartz, 2 parts of zinc oxide and 25 parts of calcined alumina; the preparation method of the frit crystal comprises the steps of crushing and uniformly mixing the raw materials, melting at 1600 ℃, preserving heat for 15min, and then cooling, crystallizing and crushing to obtain the frit crystal; the dry grain proportion of the crystal of the embodiment is 60-80 meshes: 20 percent; 80-100 meshes: 40 percent; 100-160 meshes: 35 percent; 160 meshes below: 5 percent.
And (3):the specific gravity of the protective glaze is 1.18g/ml, and the gram number is 205g/m 2 ；
The glaze protecting material comprises, by mass, 100 parts of low-temperature polishing glaze, 200 parts of glue, 0.13 part of ink discharging agent and 0.13 part of defoaming agent;
the low-temperature glaze polishing raw materials comprise, by mass: 20 parts of potash feldspar, 10 parts of water-washed kaolin, 6 parts of wollastonite, 5 parts of diopside, 5 parts of calcite, 8 parts of quartz, 1 part of zinc oxide, 5 parts of barium sulfate, 3 parts of strontium carbonate and 40 parts of low-temperature frit;
and (4): after ordinary dry particles are coated, protective glaze is coated, dried and then sintered; the cloth application amount of the common dry granules is 700g/m 2 ；
In this example, the ordinary dry granules were randomly purchased from the market, and the raw materials thereof in parts by mass included: 15% of CaO and 50% of SiO 2 6% of ZnO, 3% of MgO, 1% of BaO and 20% of Al 2 O 3 2% of K 2 O, 2% of Na 2 O and 1% i.l.
The mesh number proportion of the common dry granules comprises the following components in percentage by mass: 40-60 meshes: 20 percent; 60-100 meshes: 25%:100-160 meshes: 50 percent; 160-180 meshes: 5 percent.
And (5): and firing the blank, and polishing the fired blank to be flat to obtain a decorative surface.
Example D:
the procedure of example D is substantially the same as example a, except that in example D, after the overglaze is applied to the tile blank, the inkjet printing is performed first, and then the glue is applied; in the ink jet printing, printing of color ink and printing of finishing impression ink are performed in sequence. The ink-jet channels can be arranged in sequence according to blue, brown, yellow, black and carved ink. The refined carving ink is Dolisi CZN ink.
Comparative example E1: comparative example E1 was substantially the same procedure as example a, except that comparative example E1 applied the normal dry pellets in step (2) instead of the localized crystalline dry pellets of example a.
Comparative example E2: comparative example E2 was substantially the same in procedure as example A, except that in comparative example E2, after the step (3) was carried out, it was dried directly and then fired.
Comparative example E3: comparative example E3 was substantially the same in procedure as example a, except that comparative example E3 did not perform step (5).
The examples A-D, and comparative examples E1-E3 were compared for performance and the results are shown in Table 1.
TABLE 1 comparison of the Properties of examples A-D and comparative examples E1-E3
Remarking: as in fig. 1-5, the white stripes on the surface of the brick body are glittering effects.
Description of the drawings:
1. comparing example A with comparative example E1, comparative example E1 applies the common dry granules in step (2) instead of the localized crystalline dry granules of example A, and comparative example E1 does not use the localized crystalline dry granules; in the scheme, the positioning crystallization dry particles can effectively improve the flashing effect, and can be realized after being combined with the common dry particles and the protective glaze, so that the continuous flashing effect can be realized on the brick body; thus, the surface of comparative example No. E1 had no pits, but the glittering effect of the surface was insufficient, as shown in FIG. 5. The embodiment A uses the positioning crystallization dry grains, the flashing effect of different positions of the brick body is continuous, and no pit exists; the formula of the positioning crystallization dry particles of the scheme is used, so that the flash effect of the blank can be effectively improved.
2. As can be seen from the comparison between example A and comparative example E2, in comparative example E2, after the step (3), the mixture is directly dried and then sintered, and the ordinary dry particles and the protective glaze are not applied again. In the scheme, the common dry particles can be matched with the positioning crystallization dry particles for use, so that the problem of reduced flash effect caused by whitening when the positioning crystallization dry particles are easy to agglomerate is prevented; therefore, the glittering effect of comparative example E2 is insufficient, as shown in fig. 5; in the embodiment a, after the step (3) is executed, the step (4) is continued to present the flash effect, as shown in fig. 1; it shows that after the protective glaze is applied in the step (3), the step (4) is required to be performed to continue applying the common dry particles and the protective glaze, and the flash effect can be generated.
3. As can be seen from the comparison of example A with comparative example E3, comparative example E3 does not carry out step (5), i.e., the green brick is not polished after firing; in the scheme, the positioning crystallization dry particles need to be polished to generate a flashing effect; polishing the decorative surface, and removing the raised parts of the partially positioned crystallized dry particles to smooth the water ripples of the glaze surface of the decorative surface and finally eliminate pits; thus comparative example E3 had no sparkling effect, as in fig. 6. The green brick of example A was polished to smooth the decorative surface, so that the flashing effect was obtained at different positions of the green brick, and the flashing positions were continuous and no pits existed, as shown in FIG. 1.
In conclusion, the decoration surface of the scheme needs to arrange the protection glaze twice, the protection glaze is distributed on the positioning crystallization dry particles for the first time, the protection glaze is distributed on the second common dry particles for the second time, and the continuous flashing effect of the brick body can be formed by drying, sintering and polishing, so that the problem that the flashing effect formed by the positioning crystallization dry particles of the decoration surface in the prior art is relatively convex to form the existing pits is effectively solved.
The technical principles of the present solution have been described above with reference to specific embodiments. These descriptions are made for the purpose of illustrating the principles of the present solution and are not to be construed in any way as limiting the scope of the present solution. Based on the explanations provided herein, a person skilled in the art will be able to conceive of other embodiments of the present solution without inventive effort, which shall fall within the scope of protection of the present solution.
Claims (10)
1. A method for preparing a flashing non-pit decorative surface is characterized by comprising the following steps:
step (1): spreading glue on the overglaze of the green brick;
step (2): laying positioning crystallized dry particles on the overglaze;
the positioning crystallization dry particle comprises the following raw materials in parts by weight: 90-110 parts of frit crystals, 5-20 parts of zircon and 0-10 parts of coloring agents; the frit crystallization raw material comprises the following components in parts by mass: 10-20 parts of potassium feldspar, 30-40 parts of albite, 9-15 parts of wollastonite, 0-2 parts of calcined talc, 16-20 parts of quartz, 0-2 parts of zinc oxide, 15-25 parts of calcined alumina and 0-2 parts of titanium oxide;
and (3): spreading protective glaze;
and (4): after ordinary dry particles are distributed, protective glaze is distributed, dried and then sintered;
and (5): and sintering the blank, and polishing the sintered blank to be flat to obtain the decorative surface.
2. The method for preparing a glittering pitless decorative surface according to claim 1, wherein in the step (2), the localized crystalline dry particles and the ordinary dry particles are applied on the overglaze.
3. The method for preparing a glittering pitless decorative surface according to claim 1, wherein in the step (1), before the glue is applied, the temperature of the glue is controlled to be 40-45 ℃; the glue application amount is 80-100g/m 2 ；
In the step (1), the overglaze comprises the following raw materials in parts by weight: 10-15 parts of lithium porcelain stone, 20-25 parts of albite, 15-20 parts of nepheline, 6-10 parts of water-washed kaolin, 18-22 parts of quartz, 8-12 parts of calcined alumina, 4-7 parts of talc and 2-4 parts of dolomite.
4. The method for preparing a glittering pitless decorative surface according to claim 1, wherein the protective glaze comprises raw materials of low-temperature polishing glaze and glue;
the low-temperature glaze polishing raw materials comprise, by mass: 15-20 parts of potassium feldspar, 6-10 parts of water-washed kaolin, 6-10 parts of wollastonite, 3-5 parts of diopside, 5-10 parts of calcite, 4-8 parts of quartz, 1-3 parts of zinc oxide, 3-5 parts of barium sulfate, 3-5 parts of strontium carbonate and 35-40 parts of low-temperature frit;
the low-temperature frit comprises the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% of CaO, 0-5% of MgO and 3-8% of K 2 O, 0-5% of Na 2 O, baO 0-5%, srO 1-7% and ZnO 5-13%.
5. The method for preparing a glittering and non-pit decoration surface according to any one of claim 4, wherein the general dry granules comprise the following chemical components in percentage by mass: 50-65% SiO 2 6-15% of Al 2 O 3 6-15% of CaO, 0-5% of MgO and 3-8% of K 2 O, 0-5% of Na 2 O, baO 0-5%, srO 1-7% and ZnO 5-13%.
6. The method for preparing a glittering pitless decorative surface according to claim 5, wherein the mesh number proportion of the common dry particles comprises, by mass percent: 40-60 meshes: 8 to 18 percent; 60-100 meshes: 28-38%:100-160 meshes: 45 to 55 percent; 160-180 meshes: 3 to 8 percent.
7. The method for preparing a sparkling dimpled decorative surface according to claim 6, wherein in the step (4), the amount of the cloth applied of the ordinary dry particles is 500 to 700g/m 2 。
8. The method for preparing a glittering pitless decorative surface according to any one of claims 1 to 7, wherein in the step (1), after the surface glaze is applied to the raw brick cloth, the ink-jet printing is performed, and then the glue is applied.
9. A flashing, non-dimpled trim material, comprising: a green body;
the blank is provided with a decorative surface; the decorative surface is prepared by the method for preparing the glittering non-pit decorative surface of any one of claims 1 to 8.
10. Use of a decorative surface for the manufacture of a sparkling craterless ceramic article, wherein the decorative surface is produced by the method of producing a sparkling craterless decorative surface according to any one of claims 1 to 8.
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