CN112010676A - Production process of ceramic tile with three-dimensional positioning dry particles and product thereof - Google Patents
Production process of ceramic tile with three-dimensional positioning dry particles and product thereof Download PDFInfo
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- CN112010676A CN112010676A CN202011151608.6A CN202011151608A CN112010676A CN 112010676 A CN112010676 A CN 112010676A CN 202011151608 A CN202011151608 A CN 202011151608A CN 112010676 A CN112010676 A CN 112010676A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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Abstract
The invention discloses a production process of a ceramic tile with three-dimensional positioning dry granules and a product thereof, and the production process comprises the following steps: A. spraying base glaze on the surface of the ceramic adobe; B. digitally printing overglaze; C. printing glue ink patterns on the surface of the ceramic green brick; D. positioning and applying dry particles at the position printed with the glue ink pattern; E. spraying suspension glaze slurry on the surface of the ceramic adobe; F. and sintering to obtain the ceramic tile with the three-dimensional positioning dry particles. According to the production process of the ceramic tile with the three-dimensional positioning dry particles, the suspended glaze slurry is sprayed after the dry particles are distributed in a positioning mode, drying treatment is not needed before the ceramic tile is fired in a kiln, the process is simple, the problem that the dry particles and the protective glaze are distributed only for a long time to dry or the tile body cracks is solved, the prepared ceramic tile is good in abrasive resistance, hardness and flatness, clear in pattern, strong in three-dimensional effect, attractive in appearance and practical, and the problem that the ceramic tile with the dry particles and the protective glaze distributed only is poor in service performance is solved.
Description
Technical Field
The invention relates to the technical field of architectural ceramics, in particular to a production process of a ceramic tile with three-dimensional positioning dry granules and a product thereof.
Background
The competition of the architectural ceramic products is increasingly intense, the requirements of consumers on the surface performance of the ceramic are increasingly high, particularly in the aspects of ceramic surface hardness, surface decoration means, surface antiskid and surface functionalization, one important competition direction is the competition of color and variety, the focus of the competition is the level of product design and decorative materials, and the ceramic products using dry particles as decoration are produced. At present, to using dry grain to decorate ceramic product, mainly adopt directly to spread and spill the combination of dry grain and applying the protection glaze, because the protection glaze does not have viscidity to dry grain, can not fix dry grain, lead to dry grain to drop easily, and the moisture in the frit infiltrates the adobe the inside very easily, need carry out the drying alone after just can burn till, otherwise if the moisture in the adobe is too much when going into the kiln, then will lead to the brick body fracture after going into the kiln and burn till, the rejection rate of the ceramic brick of making is high, performance is poor.
Disclosure of Invention
The invention aims to provide a production process of a ceramic tile with three-dimensional positioning dry particles, which aims to solve the problems that the ceramic tile with the three-dimensional positioning dry particles needs to be dried for a long time or a tile body cracks because the suspension glaze slurry is sprayed after the dry particles are distributed and applied in a positioning way, the drying treatment is not needed before the ceramic tile is fired in a kiln, the process is simple, and the problems that the dry particles are distributed and applied only and the protective glaze needs to be dried for a long time or the tile body cracks are solved.
The invention also aims to provide a ceramic tile prepared by the production process of the ceramic tile with the three-dimensional positioning dry particles, which has the advantages of good wear resistance, hardness and flatness, clear pattern, strong three-dimensional sense, attractive appearance and practicability, and solves the problem of poor service performance of the ceramic tile with the single dry particle application and the protective glaze.
In order to achieve the purpose, the invention adopts the following technical scheme:
a production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. digitally printing overglaze;
C. printing glue ink patterns on the surface of the ceramic green brick;
D. positioning and applying dry particles at the position printed with the glue ink pattern;
E. spraying suspension glaze slurry on the surface of the ceramic adobe;
F. and sintering to obtain the ceramic tile with the three-dimensional positioning dry particles.
Preferably, the suspension glaze slurry comprises a suspending agent and a transparent glaze, and the mass ratio of the suspending agent to the transparent glaze is 50-90: 50-10.
Preferably, the flow speed of the suspension glaze slip is 15-25 s, and the specific gravity is 1.25-1.3 g/cm3。
Preferably, the overglaze comprises the raw material components of 25-55 parts of glaze powder and 45-75 parts of organic solvent by mass;
the glaze powder comprises, by mass, 50-65 parts of silicon dioxide, 10-30 parts of aluminum oxide, 5-12 parts of calcium oxide, 1-2 parts of barium oxide, 0.1-2 parts of strontium oxide, 1-4 parts of zinc oxide, 4-8 parts of zirconium oxide and 0.1-1.5 parts of titanium oxide.
Preferably, the step F further comprises a quick drying treatment before firing, and the drying time of the quick drying treatment is 15-60 s.
Preferably, in the step D, the dry particle application amount of the positioning cloth application dry particles is 450-550 g/m2。
Preferably, theIn the step E, the spraying amount of the spraying suspension glaze slip is 250-350 g/m2。
Preferably, the firing temperature in the step F is 1210-1230 ℃, and the firing time is 60-90 min.
Preferably, step F further includes a polishing process after the firing.
A ceramic tile with three-dimensional positioning dry grains is prepared by using a production process of the ceramic tile with three-dimensional positioning dry grains.
Compared with the prior art, the invention has the following beneficial effects:
1. the dry particles are distributed and applied in a positioning way and then the suspended glaze slurry is sprayed, drying treatment is not needed before the ceramic tile is fired in a kiln, the process is simple, the dry particles and the suspended glaze slurry are fused with each other in the firing process, the leveling effect is good after the ceramic tile is fired, the wear resistance, hardness and flatness of the ceramic tile are effectively improved, the later-stage polishing amount is reduced, the dry particles distributed in a positioning way correspond to the patterns printed by the glue ink, the patterns of the ceramic tile are clear, and the three-dimensional effect is strong;
2. the flow rate and the specific gravity of the suspension glaze slurry are moderate, so that the spraying effect is good when the suspension glaze slurry is sprayed, the suspension glaze slurry can easily permeate into gaps among the dry particles to wrap the dry particles, the melting effect of the surface of a fired brick is good, and the wear resistance, the hardness and the flatness of the ceramic brick are good;
3. the overglaze is digitally printed, the glue ink is used for printing the pattern, then the dry particles are positioned and distributed at the position where the glue ink pattern is printed, and the overglaze is matched with the dry particles after being fired, so that the dry particles have bright color and texture and high saturation, the prepared ceramic tile is exposed in the air after long-term use, the surface of the ceramic tile is not bluing, the ceramic tile is not easy to oxidize, and the using effect of the ceramic tile is improved.
Detailed Description
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. digitally printing overglaze;
C. printing glue ink patterns on the surface of the ceramic green brick;
D. positioning and applying dry particles at the position printed with the glue ink pattern;
E. spraying suspension glaze slurry on the surface of the ceramic adobe;
F. and sintering to obtain the ceramic tile with the three-dimensional positioning dry particles.
The method comprises the steps of spraying a base glaze on the surface of a ceramic brick blank, then digitally printing a cover glaze, matching the cover glaze with dry grains, enabling the dry grains to have bright colors and texture after being fired, then printing patterns on the surface of the ceramic brick blank by using glue ink, positioning and applying the dry grains at the positions printed with the glue ink patterns, enabling the dry grains to be adhered to the surface of the ceramic brick blank under the action of the glue ink, and then spraying suspension glaze slurry on the whole surface of the ceramic brick blank, wherein the suspension glaze slurry can wrap liquid moisture on the surface of the ceramic brick blank and the dry grains, so that the dry grains are fixed on the surface of the dry grains, the dry grains are prevented from falling off in the subsequent firing process step, and the suspension glaze slurry can wrap the liquid moisture on the surface of the ceramic brick blank, and the moisture of the suspension glaze slurry is not easy to permeate into the ceramic brick blank, avoided only cloth to apply dry grain and protection glaze to lead to moisture to ooze inside the ceramic adobe easily, need alone through the kiln firing of long-time dry drainage moisture again, if only cloth apply dry grain after apply the protection glaze and do not pass through the drying, then because moisture is too big when ceramic adobe gets into the kiln firing, moisture is not totally arranged before getting into the kiln, leads to the brick fracture.
According to the invention, the dry particles are positioned and distributed and then the suspension glaze slurry is sprayed, drying treatment is not needed before the ceramic tile is fired in a kiln, the process is simple, and because the components of the dry particles and the suspension glaze slurry are fused with each other in the firing process, the leveling effect is good after the ceramic tile is fired, the wear resistance, hardness and flatness of the ceramic tile are effectively improved, the later-stage throwing amount is reduced, the positioned and distributed dry particles correspond to the patterns printed by the glue ink, the patterns of the ceramic tile are clear, and the stereoscopic impression is strong.
Preferably, the suspension glaze slurry comprises a suspending agent and a transparent glaze, and the mass ratio of the suspending agent to the transparent glaze is 50-90: 50-10.
The suspending agent is a conventional suspending agent.
The suspension glaze slip comprises a suspending agent and transparent glaze, wherein the suspending agent enables the suspension glaze slip to be sprayed on the surface of a ceramic brick blank, water is not easy to permeate into the ceramic brick blank, dry particles on the surface of the ceramic brick blank can be wrapped, the mass ratio of the suspending agent to the transparent glaze is 50-90: 50-10, if the amount of the suspending agent is too small, the wrapping effect of the suspension glaze slip on the liquid water and the dry particles on the surface of the ceramic brick blank is poor, the speed of water permeating into the ceramic brick blank is accelerated, the performance of a manufactured ceramic tile is easy to influence, and if the amount of the suspending agent is too large, the fusion effect of the dry particles and the transparent glaze of the suspension glaze slip in the firing process is poor, and the wear resistance and hardness of the ceramic tile are easy to influence.
Preferably, the flow speed of the suspension glaze slip is 15-25 s, and the specific gravity is 1.25-1.3 g/cm3。
Preferably, the preparation method of the suspension glaze slurry comprises the steps of uniformly mixing the suspending agent and the transparent glaze by adopting a high-speed stirring mode, then adding water to adjust the flow rate of the suspension glaze slurry to be 15-25 s and the specific gravity to be 1.25-1.3 g/cm3。
The flow rate and the specific gravity of the suspension glaze slurry are moderate, so that the spraying effect is good when the suspension glaze slurry is sprayed, the suspension glaze slurry can easily permeate into gaps among the dry particles to wrap the dry particles, the melting effect of the surface of a fired brick is good, and the wear resistance, the hardness and the flatness of the ceramic brick are good; if the specific gravity is too large and the flow rate is too large, the suspension glaze slip is not uniform during application and is easy to generate skinning, and if the specific gravity is too small and the flow rate is too small, the suspension glaze slip is easily influenced by the outside during application, so that glaze pouring is not smooth, the production efficiency is low, and the flatness of the brick surface is poor.
Preferably, the overglaze comprises the raw material components of 25-55 parts of glaze powder and 45-75 parts of organic solvent by mass;
the glaze powder comprises, by mass, 50-65 parts of silicon dioxide, 10-30 parts of aluminum oxide, 5-12 parts of calcium oxide, 1-2 parts of barium oxide, 0.1-2 parts of strontium oxide, 1-4 parts of zinc oxide, 4-8 parts of zirconium oxide and 0.1-1.5 parts of titanium oxide.
Preferably, the organic solvent is a conventional organic solvent for ceramic ink.
Preferably, the dry granules adopt colored dry granules.
The strontium oxide is added, so that the color development of the overglaze is good, the overglaze is digitally printed, the glue ink is used for printing the pattern, then the dry particles are distributed at the position where the glue ink pattern is printed, the overglaze is matched with the dry particles after being fired, so that the dry particles have bright color and texture and high saturation, the surface of the prepared ceramic tile is not bluish after being used for a long time and is not easy to oxidize, and the use effect of the ceramic tile is improved.
Preferably, the step F further comprises a quick drying treatment before firing, and the drying time of the quick drying treatment is 15-60 s.
Preferably, the drying time of the rapid drying treatment is 30 s.
The method comprises the steps of spraying the suspension glaze slurry on the surface of a ceramic brick blank, enabling the ceramic brick blank to enter a small glaze line drying kiln for quick drying, then firing, avoiding water from permeating into the ceramic brick blank, then firing, improving the firing effect of the ceramic brick blank, and greatly saving drying time due to the fact that the suspension glaze slurry is sprayed after dry particles are distributed in a positioning mode, enabling the water brought by the suspension glaze slurry to be wrapped on the surface of the dry particles and enabling the water of the suspension glaze slurry to not easily permeate into the interior of the ceramic brick blank, effectively improving production efficiency and reducing production cost under the condition of guaranteeing the service performance of the manufactured ceramic brick. If the protective glaze is applied after the dry particles are simply applied, and drying is not performed or drying is performed for a short time, the ceramic brick body is cracked because the moisture is too large when the ceramic brick blank is put into a kiln to be fired and the moisture is not completely discharged before the ceramic brick blank is put into the kiln, and the service performance of the prepared ceramic brick is directly influenced.
Preferably, in the step D, the dry particle application amount of the positioning cloth application dry particles is 450-550 g/m2。
Preferably, in the step D, the dry particles are distributed and applied at the position where the glue ink pattern is applied by using a screen printing or dry particle distributing machine.
The dry granules are positioned and distributed at the position where the glue ink pattern is distributed by adopting a screen printing or dry granule distributing machine, so that the direct large-area spreading of the dry granules is avoided, the dry granule distribution quantity of the positioned and distributed dry granules is limited in the range, if the dry granule distribution quantity is too large, the dry granules are sintered after the suspension glaze slurry is sprayed, air bubbles are difficult to discharge, pores are easily formed on the surface of the brick, and the using effect of the prepared ceramic brick is influenced.
Preferably, in the step E, the spraying amount of the spraying suspension glaze slip is 250-350 g/m2。
Preferably, in the step E, the suspended glaze slurry is atomized and sprayed onto the surface of the ceramic adobe by using a spray gun.
Through the spraying suspension glaze slip, because suspension glaze slip sprays after atomizing ceramic adobe surface, after the atomizing suspension glaze slip soaks and wraps up in the surface of dry grain for the gas between the dry grain of difference discharges easily, avoids adobe surface bubble to be difficult to get rid of and leads to adobe surface to produce the gas pocket defect, and if spraying suspension glaze slip's spraying volume undersize, then can't live with whole dry grain parcel, leads to levelling effect relatively poor, and the roughness of ceramic brick is relatively poor, if spraying suspension glaze slip's spraying volume is too big, makes the bubble discharge more difficult, and has increased the throwing of later stage and cut the volume.
Preferably, the firing temperature in the step F is 1210-1230 ℃, and the firing time is 60-90 min.
After the ceramic brick blank is sintered at high temperature, the dry particles and the components of the suspension glaze slip are fused with each other in the sintering process, and the ceramic brick prepared by sintering has good wear resistance, hardness and flatness and good service performance.
Preferably, step F further includes a polishing process after the firing.
The ceramic green brick is polished after being fired to obtain the glazed brick with the three-dimensional positioning dry grains, so that the flatness of the brick surface is effectively improved, the polished brick surface is high in attractiveness, and a high practical effect is achieved while the attractive effect is achieved.
A ceramic tile with three-dimensional positioning dry grains is prepared by using a production process of the ceramic tile with three-dimensional positioning dry grains.
The ceramic tile with the three-dimensional positioning dry grains prepared by the production process of the ceramic tile with the three-dimensional positioning dry grains has the advantages of abrasion resistance, hardness and flatness, clear pattern, strong three-dimensional effect, and attractive appearance and practicability.
The technical solution of the present invention is further explained by the following embodiments.
Example 1
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 50:50, the flow rate of the suspension glaze slip is 25s, and the specific gravity is 1.3g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 2
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 70:30, the flow rate of the suspension glaze slip is 20s, and the specific gravity is 1.27g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 3
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 90:10, the flow rate of the suspension glaze slip is 15s, and the specific gravity is 1.25g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 4
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 50:50, the flow rate of the suspension glaze slip is 25s, and the specific gravity is 1.3g/cm3；
F. And (3) carrying out rapid drying treatment on the ceramic adobe for 30s, and then putting the ceramic adobe into a kiln for firing at the firing temperature of 1220 ℃ for 70min to obtain the ceramic tile with three-dimensional positioning dry grains.
Example 5
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 40:60, the flow rate of the suspension glaze slip is 28s, and the specific gravity is 1.35g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 6
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 95:5, the flow rate of the suspension glaze slip is 10s, and the specific gravity is 1.2g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 7
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 70:30, the flow rate of the suspension glaze slip is 20s, and the specific gravity is 1.27g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 8
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 600g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic green brick by using a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 70:30, the flow rate of the suspension glaze slip is 20s, and the specific gravity is 1.27g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 9
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic adobe by a spray gun, wherein the spraying amount is 200g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 70:30, the flow rate of the suspension glaze slip is 20s, and the specific gravity is 1.27g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Example 10
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying suspended glaze slurry on the surface of a ceramic adobe by a spray gun, wherein the spraying amount is 400g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 70:30, the flow rate of the suspension glaze slip is 20s, and the specific gravity is 1.27g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Comparative example 1
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying a protective glaze (the conventional protective glaze is adopted as the protective glaze) on the surface of the ceramic adobe by a spray gun, wherein the spraying amount is 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 70:30, the flow rate of the suspension glaze slip is 20s, and the specific gravity is 1.27g/cm3；
F. And (3) firing the ceramic brick blank in a kiln at the firing temperature of 1220 ℃ for 70min to obtain the ceramic brick with the three-dimensional positioning dry grains.
Comparative example 2
A production process of a ceramic tile with three-dimensional positioning dry particles comprises the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. printing a surface glaze by using a digital glaze spraying machine (wherein the surface glaze consists of 50 parts of glaze powder and 50 parts of organic solvent;
the glaze powder comprises the following raw materials in parts by weight: 55 parts of silicon dioxide, 25 parts of aluminum oxide, 10 parts of calcium oxide, 1 part of barium oxide, 2 parts of strontium oxide, 3 parts of zinc oxide, 5 parts of zirconium oxide and 1 part of titanium oxide);
C. printing glue ink patterns on the surface of the ceramic green brick in an ink-jet manner;
D. positioning and applying color dry granules at the position printed with the glue ink pattern by using a dry granule distributing machine, wherein the application amount of the dry granules is 500g/m2；
E. Spraying protective glaze on the surface of the ceramic adobe by a spray gun (the protective glaze adopts the existing common glaze)Regular protective glaze) with the spraying amount of 300g/m2Wherein the suspension glaze slip consists of a suspending agent and a transparent glaze, the mass ratio of the suspending agent to the transparent glaze is 70:30, the flow rate of the suspension glaze slip is 20s, and the specific gravity is 1.27g/cm3；
F. Drying the ceramic adobe for 30s, then putting the ceramic adobe into a kiln for sintering at 1220 ℃ for 70min to obtain the ceramic brick with three-dimensional positioning dry grains.
And (3) performance testing:
1. mohs hardness determination: the sample was placed on a rigid support with the facing up. The surface of a sample is scribed by selecting standard ores with different Mohs values from small to large, the surface of the sample is scribed uniformly and vertically by applying force through a new ore cutting edge, the force application needs to be moderate, and the cutting edge of the standard ore cannot be broken by excessive force application to form double-line or multi-line scribing traces. The lowest hardness value which just produces obvious scratches is taken as the test result, and the lowest value of all the test values of the test sample is taken as the test result.
2. And (3) determining the wear resistance: GB/T3810.7-2016, part 7 of the ceramic tile testing method: the abrasion resistance of the glaze surface of the product is tested by the testing method in the determination of the abrasion resistance of the surface of the glazed brick, and the abrasion resistance of the ceramic brick is evaluated by placing a grinding medium on the brick surface and rotating to observe and compare a worn sample with an unworn sample.
3. Surface flatness measurement: according to GB-T3810.2-2016 ceramic tile test method section 2: the inspection of dimension and surface quality measures the flatness of the surface of the ceramic tile, and the comprehensive determinator for the flatness, right angle and corner degree of the ceramic tile is used for measuring the dimension and shape characteristics of the ceramic tile, wherein the measured parameters comprise the indexes of the straightness, right angle and flatness (central bending, side bending and warping) of the tile.
4. Surface defect (pore) determination: according to GB-T3810.2-2016 ceramic tile test method section 2: the inspection of size and surface quality "measures the surface flatness of a large ceramic plate, detects the illuminance at the central part and each corner of the surface of the tested ceramic tile under the uniform irradiation of the lamp light with the color temperature of 6000K-6500K and the illuminance of 300lx, and observes the visible defects on the surface of the tested ceramic tile by naked eyes at the vertical distance of 1 m.
From the embodiments 1 to 3, it can be seen that the dry particles are distributed in a positioning manner and then the suspended glaze slurry is sprayed, so that the ceramic tile does not need to be dried before being fired in a kiln, the prepared ceramic tile has good wear resistance, hardness and flatness, the surface is smooth and uniform, no obvious pores exist, the dry particles have bright color and texture, and the saturation is high;
in the embodiment 4, as the ceramic adobe is dried before being fired, the firing effect of the ceramic adobe is improved, and the prepared ceramic tile has high hardness and good service performance;
in example 5, if the amount of the suspending agent in the suspended glaze slip is too small, the wrapping effect of the suspended glaze slip on the liquid moisture and dry particles on the surface of the ceramic tile blank is deteriorated, the speed of water permeating into the ceramic tile blank is increased, the performance of the ceramic tile is easily affected, and the wear resistance of the ceramic tile is deteriorated; example 6 because the amount of the suspending agent in the suspended glaze slip is too large, the fusion effect of the dry particles and the transparent glaze of the suspended glaze slip is poor in the firing process, and the hardness and the wear resistance of the ceramic tile are poor; in the raw material components of the overglaze in the embodiment 7, the raw material components of the glaze powder do not contain strontium oxide, the color development of the overglaze is poor, and the prepared ceramic tile has poor dry particle color saturation and poor aesthetic degree when observed by naked eyes; in the embodiment 8, the distribution amount of the dry particles is too large, so that gas among the dry particles is difficult to discharge, and dispersed pores appear on the surface of the fired ceramic tile, thereby influencing the use effect of the prepared ceramic tile; example 9 is because the spraying amount of suspension glaze thick liquid is too little, can't wrap up whole dry grain, leads to the leveling effect to be poor, and the roughness of ceramic brick is relatively poor, and example 10 is because the spraying amount of suspension glaze thick liquid is too big, leads to the difficult discharge of bubble, and the brick face appears the dispersion pore after the fever.
Comparative example 1 is a method of spraying a protective glaze after independently applying dry particles, since moisture in the protective glaze is easily infiltrated into a green brick, under the condition of not drying, the green brick body cracks due to excessive moisture when the green brick is put into a kiln to be fired, the ceramic brick can not be normally used, the comparative example 2 is that after the dry particles are independently applied, the protective glaze is sprayed, even if the drying is carried out, because the drying time is too short, the moisture in the green brick is not fully discharged, the moisture of the green brick is still too large when the green brick is put into a kiln for firing, finally the brick body is cracked, the ceramic tile can not be normally used, in examples 1 to 3, the suspension glaze slip is used, so that the liquid water on the surface of the ceramic green brick can be wrapped by the suspension glaze slip, and the water of the suspension glaze slip is not easy to permeate into the ceramic green brick, drying treatment is not needed before the ceramic tiles are fired in a kiln, the process is simple, the production cost is low, and the service performance of the prepared ceramic tiles is good.
The technical principle of the present invention is described above in connection with specific embodiments. The description is made for the purpose of illustrating the principles of the invention and should not be construed in any way as limiting the scope of the invention. Based on the explanations herein, those skilled in the art will be able to conceive of other embodiments of the present invention without inventive effort, which would fall within the scope of the present invention.
Claims (9)
1. A production process of a ceramic tile with three-dimensional positioning dry particles is characterized by comprising the following steps:
A. spraying base glaze on the surface of the ceramic adobe;
B. digitally printing overglaze;
C. printing glue ink patterns on the surface of the ceramic green brick;
D. positioning and applying dry particles at the position printed with the glue ink pattern;
E. spraying suspension glaze slurry on the surface of the ceramic adobe;
F. and sintering to obtain the ceramic tile with the three-dimensional positioning dry particles.
2. The process for producing the ceramic tile with the stereotactic dry particles as claimed in claim 1, wherein said suspension glaze slip comprises a suspending agent and a transparent glaze, and the mass ratio of said suspending agent to said transparent glaze is 50-90: 50-10.
3. The process for producing ceramic tiles with stereotactic dry particles as claimed in claim 1, wherein said suspension glaze slip has a flow rate of 15-25 s and a specific gravity of 1.25-1.3 g/cm3。
4. The production process of the three-dimensional positioning dry-particle ceramic tile according to claim 1, wherein the raw material components of the overglaze comprise 25-55 parts of glaze powder and 45-75 parts of organic solvent by mass;
the glaze powder comprises, by mass, 50-65 parts of silicon dioxide, 10-30 parts of aluminum oxide, 5-12 parts of calcium oxide, 1-2 parts of barium oxide, 0.1-2 parts of strontium oxide, 1-4 parts of zinc oxide, 4-8 parts of zirconium oxide and 0.1-1.5 parts of titanium oxide.
5. The process for producing ceramic tile with stereotactic dry granules as claimed in claim 1, wherein in said step D, the dry granules distribution amount of said stereotactic dry granules is 450-550 g/m2。
6. The production process of the ceramic tile with the three-dimensional positioning dry granules as claimed in claim 1, wherein in the step E, the spraying amount of the spraying suspension glaze slip is 250-350 g/m2。
7. The production process of the ceramic tile with the three-dimensional positioning dry granules as claimed in claim 1, wherein the firing temperature in the step F is 1210-1230 ℃, and the firing time is 60-90 min.
8. The process for producing ceramic tiles with stereotactic dry particles as claimed in claim 1, wherein said firing of step F is followed by polishing.
9. A stereotactic dry-particled ceramic tile, which is prepared by using the production process of the stereotactic dry-particled ceramic tile according to any one of claims 1 to 8.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112707642A (en) * | 2020-12-28 | 2021-04-27 | 丰城市东鹏陶瓷有限公司 | Flash overglaze, preparation method thereof and preparation method of ceramic tile with flash effect |
| CN112876290A (en) * | 2020-12-16 | 2021-06-01 | 佛山石湾鹰牌陶瓷有限公司 | Preparation method of colored crystal glaze porcelain |
| CN113248285A (en) * | 2021-06-28 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Dry particle decorative ceramic tile and preparation method thereof |
| CN115057728A (en) * | 2022-08-19 | 2022-09-16 | 广东兴辉陶瓷集团有限公司 | Production process of positioning stripping dry grain ceramic tile and product thereof |
| CN115340411A (en) * | 2022-07-25 | 2022-11-15 | 广西蒙娜丽莎新材料有限公司 | Preparation method of natural jade-like porcelain tile |
| CN115466054A (en) * | 2022-09-26 | 2022-12-13 | 佛山市东鹏陶瓷有限公司 | Flash and pit-free decorative material and preparation method and application of decorative surface |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885256A (en) * | 2019-11-19 | 2020-03-17 | 蒙娜丽莎集团股份有限公司 | Digital dry particle inner wall brick with stereoscopic luminous effect and preparation method thereof |
| CN111391084A (en) * | 2020-06-03 | 2020-07-10 | 佛山市东鹏陶瓷发展有限公司 | Production system and process of ceramic tile with strong stereoscopic impression |
-
2020
- 2020-10-26 CN CN202011151608.6A patent/CN112010676A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885256A (en) * | 2019-11-19 | 2020-03-17 | 蒙娜丽莎集团股份有限公司 | Digital dry particle inner wall brick with stereoscopic luminous effect and preparation method thereof |
| CN111391084A (en) * | 2020-06-03 | 2020-07-10 | 佛山市东鹏陶瓷发展有限公司 | Production system and process of ceramic tile with strong stereoscopic impression |
Non-Patent Citations (3)
| Title |
|---|
| J.R.TAYLOR著，郭少明译: "《陶瓷釉技术》", 31 December 1990, 鹭江出版社 * |
| 周张键主编: "《无机非金属材料工艺学》", 31 January 2010, 中国轻工业出版社 * |
| 徐建华等: "《陶瓷花釉与装饰技术》", 30 April 2011, 中国轻工业出版社 * |
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|---|---|---|---|---|
| CN112876290A (en) * | 2020-12-16 | 2021-06-01 | 佛山石湾鹰牌陶瓷有限公司 | Preparation method of colored crystal glaze porcelain |
| CN112707642A (en) * | 2020-12-28 | 2021-04-27 | 丰城市东鹏陶瓷有限公司 | Flash overglaze, preparation method thereof and preparation method of ceramic tile with flash effect |
| CN112707642B (en) * | 2020-12-28 | 2022-09-02 | 丰城市东鹏陶瓷有限公司 | Flash overglaze, preparation method thereof and preparation method of ceramic tile with flash effect |
| CN113248285A (en) * | 2021-06-28 | 2021-08-13 | 佛山欧神诺陶瓷有限公司 | Dry particle decorative ceramic tile and preparation method thereof |
| CN113248285B (en) * | 2021-06-28 | 2022-03-22 | 佛山欧神诺陶瓷有限公司 | Dry particle decorative ceramic tile and preparation method thereof |
| CN115340411A (en) * | 2022-07-25 | 2022-11-15 | 广西蒙娜丽莎新材料有限公司 | Preparation method of natural jade-like porcelain tile |
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