CN103351179B - Printing glaze material and production method thereof - Google Patents
Printing glaze material and production method thereof Download PDFInfo
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- CN103351179B CN103351179B CN201310295710.7A CN201310295710A CN103351179B CN 103351179 B CN103351179 B CN 103351179B CN 201310295710 A CN201310295710 A CN 201310295710A CN 103351179 B CN103351179 B CN 103351179B
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Abstract
The invention provides a kind of novel printing glaze and production method thereof, by albite 36 ~ 42%, nepheline syenite 8 ~ 10%, wollastonite 6 ~ 8%, kaolin 4 ~ 8%, ball clay 2 ~ 5%, quartz 4 ~ 7%, aluminum oxide 3 ~ 5%, corundum 5 ~ 8%, calcium carbonate 8 ~ 10%, barium carbonate 1 ~ 2%, frit 4 ~ 10%, fusing assistant 6 ~ 10% being added the novel printing glaze meeting standard of the present invention of the operations such as ball mill grinding.Novel printing glaze customer service that the present invention produces pin hole, increased devitrification resistance, soil pick-up be poor, wear no resistance five problems such as bad with angularity.
Description
Technical field
The present invention relates to a kind of printing glaze material and production method thereof.
Background technology
Full throwing screen printing glaze is the main product on current ceramic tile consumption market, and it utilizes multiple pottery raw material formulated according to a certain percentage.This ratio is through that theoretical basis and lot of experiments obtain, and requirement must be some defects that Performance comparision stablizes and can improve that on market, isomorphism type product often produces in time producing ceramic tile.
Its main component has feldspar, quartz, kaolin, alkaline earth metal oxide (comprising the oxide compound of aluminium, calcium, magnesium, barium, zinc) and frit.Briefly: complete to throw screen printing glaze be execute one glaze overlaying on ceramic tile surface, it has to pass through kiln and burns till and just can obtain our desired characteristic and effect.
But, owing to producing the complete self-characteristic of raw material and the formula of each raw material of throwing screen printing glaze, cause printing in the market entirely to throw glaze and have that pin hole, increased devitrification resistance, soil pick-up are poor, wear no resistance five problems such as bad with angularity.
The pin hole produced in the pin hole of the origin cause of formation that pin hole occurs generation when being mainly divided into glazing line operate and ceramic tile sintering process.
The pin hole formed during glazing line operation is normally because the ball clay constituents ratio deficiency of entirely throwing in screen printing glaze formula composition caused, we find that general full throwing screen printing glaze product custom carries out the preparation of filling a prescription with the great soil group that plasticity-is poor, such ceramic full-polished screen printing glaze is easily subject to the too high impact of idiosome temperature and makes glaze slip mobility too low when glazing, and then forms pin hole.
And the pin hole produced in ceramic tile sintering process, normally due to ceramic tile in sintering process because idiosome, glaze caused with not mating of firing condition, we find that general full throwing screen printing glaze product is due to the narrower problem too low with beginning fusing point of firing range, often cause the impurity in base substrate totally not volatile in sintering process, gas in final base substrate, when burning till thermal zone effusion, will form pin hole in brick face.
Increased devitrification resistance is very high for the importance of full throwing vitreous brick, and the color and figure that make product are become dim and fuzzy by the ceramic tile of devitrification.The main cause that general full throwing screen printing glaze forms increased devitrification resistance entirely throws in the too high or formula of screen printing glaze refractoriness to be rich in opaque raw material.About this problem, main key is caused with being unfamiliar with the characteristic of raw material the selection of raw material is incorrect, these common full throwing screen printing glazes often cause glaze layer do not have complete melting and form devitrification state because the calorific value that gives of kiln is not enough in sintering process, and then make the color of product and figure become dim and fuzzy.
Inhale an important pointer of quality inspection on consumption market, soil pick-up Xing Shi ceramic tile city, substandard tile laying is when ground, the value always ceramic tile being lost view and admire because of the characteristic of its not resistance to soil pick-up adds the difficulty of maintenance simultaneously, so anti-soil pick-up is the research and development of all kinds of ceramic tile and the important topic manufactured always.
Ceramic tile in sintering process because idiosome, not mating of glaze and firing condition, just easily form the problem such as pin hole, soil pick-up difference and idiosome evil mind, we find that general full throwing screen printing glaze product is due to the too low problem of beginning fusing point, often cause the impurity in base substrate totally not volatile in sintering process, gas in final base substrate is when burning till thermal zone effusion, will form very tiny pin hole in brick face, these fine and closely woven little pin holes are exactly the main cause causing soil pick-up poor performance.
Wear resistance is the very important CQI, particularly paving of floor tile class ceramic tile floor tile in public places, and wearing coefficient is required to reach Mohs' hardness more than 4 grades usually.Full throwing screen printing glaze is the glaze layer covering the ceramic tile surface the superiors, after burning till, it is through polished finish, appearance attractive in appearance but can not illustrate its hardness and wear resistance, so the poor product paving of wear resistance will soon form many cuts because of wearing away speed faster at ceramic tile surface on ground.
General full throwing screen printing glaze is in order to reduce raw materials cost, be accustomed to the allotment of comparatively cheap carrying out formula, and the key element that have ignored improving glaze layer hardness requirement, this major embodiment is excessively to select raw material that the Mohs' hardness such as talcum, calcium carbonate is lower as fusing assistant, this kind of full throwing screen printing glaze hardness after burning till is lower, usually can only reach Mohs' hardness 3 grades.
Angularity weighs one of ceramic tile quality the most direct standard, if the angularity unfairness of ceramic tile, is no matter to upwarp or lower curved, and so all will encounter difficulties in the paving of ceramic tile even cannot paving use, so the warpage planeness of ceramic tile is extremely important.
Except the angularity deviation that ceramic tile may make ceramic tile except kiln firing condition is bad in sintering procedure, the drop of main to be also the most direct influence factor the be exactly expansion coefficient value coming from base substrate and glaze layer is excessive, usually the coefficient of expansion of complete with throwing glaze brick product is between 215-230, the general full throwing screen printing glaze coefficient of expansion then drops on about 195-205, so after klining one-tenth is entered in idiosome glazing, even if because the angularity of ceramic tile controls within desirable scope by kiln firing technology personnel reluctantly, when after ceramic tile cooling, along with time lapse, base substrate forms pullling of stress with the coefficient of expansion entirely throwing screen printing glaze layer because drop is excessive, cause the warpage planeness of ceramic tile bad the most at last.
In order to solve these technological deficiencies, be badly in need of a kind of brand-new printing glaze material of invention and production method thereof.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of printing glaze material and production method thereof, the printing glaze material produced by the method can be good at solving in prior art some defects and deficiency of existing.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of printing glaze material, it comprises albite 36 ~ 42%, nepheline syenite 8 ~ 10%, wollastonite 6 ~ 8%, kaolin 4 ~ 8%, ball clay 2 ~ 5%, quartz 4 ~ 7%, aluminum oxide 3 ~ 5%, corundum 5 ~ 8%, calcium carbonate 8 ~ 10%, barium carbonate 1 ~ 2%, frit 4 ~ 10%, fusing assistant 6 ~ 10%, and said components is all by the percentage calculation accounting for overall printing glaze weight separately.
As a further improvement on the present invention, described fusing assistant comprises one or more in zinc oxide, talcum, rhombspar.
As a further improvement on the present invention, the weight percent that zinc oxide in fusing assistant, talcum, each component of rhombspar account for overall glaze is respectively: zinc oxide 2 ~ 5%, talcum 1 ~ 2%, rhombspar 3 ~ 5%.
A kind of ceramic tile, comprises the printing glaze material as claimed in claim 1 executed and be overlying on ceramic tile surface.
As a further improvement on the present invention, the Mohs' hardness of described ceramic tile surface printing glaze material is not less than 4 grades.
A production method for printing glaze material, specifically comprises the steps
A, each raw material is carried out joining getting according to its weight percent, albite 36 ~ 42%, nepheline syenite 8 ~ 10%, wollastonite 6 ~ 8%, kaolin 4 ~ 8%, ball clay 2 ~ 5%, quartz 4 ~ 7%, aluminum oxide 3 ~ 5%, corundum 5 ~ 8%, calcium carbonate 8 ~ 10%, barium carbonate 1 ~ 2%, frit 4 ~ 10%, fusing assistant 6 ~ 10%, zinc oxide 2 ~ 5%, talcum 1 ~ 2%, rhombspar 3 ~ 5%;
B, each raw material to be dropped in clean ball mill, and add clear water, lock ball grinding machine lid, start ball mill, till the raw material in it being ground to the normal abrasive time of ball mill setting;
C, the residue of glaze slip in ball mill carried out to sampling and detect, and carry out burning till contrast experiment, the fineness as residue is less than 0.3g/325 order/100cc, and it is qualified to burn till contrast experiment, then carry out unloading slurry process, otherwise namely starts ball mill and continue grinding, until up to standard;
D, use flash baking kiln are dried glaze slip, the glaze after oven dry are transported to powder beater and carry out beating powder operation, and then to the operation that glaze powder sieves, so namely obtained described printing glaze material.
As a further improvement on the present invention, carry out sampling detection concrete operations to the residue of glaze slip in ball mill in step c to comprise:
C11, after ball mill is completely static, open ball mill cover, the glaze slurry samples pulling 300-500g out to get slurry spoon in ball mill is poured in the clean beaker of previously prepd to be measured, measures 100cc glaze slip, and it poured in 325 object standard sieves completely with standard specific gravity bottle;
C12, with the glaze slip in tap water standard sieve, until glaze slip is cleaned up only surplus residue in sieve, then residue all to be poured in iron pan, and by clean for the clear water in iron pan;
C13, iron pan is put into baking oven together with the residue above it dry, the temperature range of setting baking oven, at 120 DEG C ~ 180 DEG C, after 1 hour, treats residue complete drying in iron pan, and after its cooling, drops down onto on electronic balance, claim its weight by residue brush in it.
As a further improvement on the present invention, the concrete operations of burning till contrast experiment in step c comprise:
The accurate glaze slip of c21, label taking as standard model, then get ground after glaze slip, adjustment period proportion to 1.75, take out dried a slice, scrape enamal organ one piece;
C22, dried is placed in glaze spraying cabinet, injected clear water in spray gun is thinly executed clear water in embryo face until raw embryo surface be moisture state, the raw embryo of surface wettability is moved on worktable rapidly, and enamal organ will be scraped entirely be put in embryo face, preparation glazing;
C23, respectively standard glaze slip and sampling glaze slip are poured into and scraped in the comparison groove of enamal organ, uniformly both are scraped on green compact, then green compact are put into test roller-way electrical kiln and burn till, its temperature is set at 1180 DEG C;
C24, after 1 hour, the green compact burnt till are moved to ventilation opening, after its naturally cooling, observe contrast and experiment in the place of light source abundance, with the gloss of visual method contrast sampling glaze slip and standard glaze slip and quality difference.
In the present invention, we make an addition in formula by having the strong ball clay of plasticity-humectant according to certain ratio, preferably flow ductility to make printing glaze material and form certain effect of filling up when glazing for the position that may produce pin hole because have, then the beginning melting temperature entirely throwing screen printing glaze improves by we, this is by increasing molten matter (albite in formula, nepheline syenite, wollastonite) and refractory raw material (kaolin, ball clay, quartz, aluminum oxide, corundum) ratio, and moderately reduce calcium carbonate, the consumption of barium carbonate, printing glaze material of the present invention is like this delayed the time of melting, contribute to impurity in idiosome and gas has time enough overflow and avoid the possibility producing pin hole in ceramic tile sintering process, this addresses the problem the problem of pin hole, thus improve the anti-soil pick-up of ceramic tile surface printing glaze material.
In the present invention, we divide for the selection portion of alumina raw material and select the higher corundum of the transparency to substitute, the albite that selection for feldspar raw material selects iron-holder lower, it is more reasonable to be allocated as by formula like this, make glaze slip melting property when molten state stronger and then produce stronger melting effect altogether and make glaze layer more aobvious transparent, this addresses the problem increased devitrification resistance problem.
In the present invention, we, by reducing the ratio of talcum and calcium carbonate, increase the usage ratio of centering high temperature frit, reduce the ratio of aluminum oxide, increase the usage ratio of corundum, thus make the Mohs' hardness of printing glaze material of the present invention reach 4 grades even more than 4 grades.
In the present invention, we by reduce kaolin and quartz use, and add part nepheline syenite replace albite, with guarantee improve printing glaze material the coefficient of expansion while be also unlikely to excessive to the properties influence of glaze.
The present invention compared with prior art has following beneficial effect:
When frit provided by the invention and production method thereof can make printing glaze material operate, mobility is better, decrease pin hole, and by adding corundum in formula, improve the increased devitrification resistance problem of the most demand of printing glaze material product, in addition, the printing glaze material that the present invention produces solves the soil pick-up sex chromosome mosaicism of ceramic tile surface, and hardness and the wear resistance of ceramic tile surface are obtained for raising, simultaneously ceramic tile burn till after brick warpage planeness have also been obtained guarantee.
Embodiment
In order to better explain invention main points of the present invention, first provide component and the proportioning situation thereof of several groups of existing printing glaze materials
| Ingredient names | Proportioning 1 | Proportioning 2 | Proportioning 3 | Proportioning 4 |
| Albite | 38 | 38 | 38 | 38 |
| Nepheline syenite | 10 | 10 | 10 | 0 |
| Wollastonite | 8 | 8 | 8 | 8 |
| Kaolin | 8 | 5 | 5 | 5 |
| Ball clay | 0 | 3 | 3 | 3 |
| Quartz | 4 | 4 | 4 | 4 |
| Aluminum oxide | 4 | 10 | 4 | 4 |
| Corundum | 6 | 0 | 6 | 6 |
| Zinc oxide | 3 | 3 | 3 | 3 |
| Calcium carbonate | 8 | 8 | 13 | 8 |
| Barium carbonate | 1 | 1 | 1 | 1 |
| Talcum | 1 | 1 | 1 | 1 |
| Rhombspar | 4 | 4 | 4 | 4 |
| Frit | 5 | 5 | 0 | 5 |
In each proportioning of above table, various component all calculates with the weight percentage accounting for total quality.
Each raw material in proportioning 1 is matched well to get according to its percentage and then each raw material is dropped in clean ball mill, and add clear water, lock ball grinding machine lid, start ball mill, till the raw material in it being ground to the normal abrasive time of ball mill setting;
Then, sampling is carried out to the residue of glaze slip in ball mill and detects, and carry out burning till contrast experiment, fineness as residue is less than 0.3g/325 order/100cc, and it is qualified to burn till contrast experiment, then carry out unloading slurry process, otherwise namely start ball mill and continue grinding, until up to standard;
Here residue sampling detecting step is as follows:
(1) after ball mill is completely static, open ball mill cover, the glaze slurry samples pulling 300-500g out to get slurry spoon in ball mill is poured in the clean beaker of previously prepd to be measured, measures 100cc glaze slip, and it poured in 325 object standard sieves completely with standard specific gravity bottle;
(2) with the glaze slip in tap water standard sieve, until glaze slip is cleaned up only surplus residue in sieve, then residue is all poured in iron pan, and by clean for the clear water in iron pan;
(3) iron pan is put into baking oven together with the residue above it to dry, set the temperature range of baking oven at 120 DEG C ~ 180 DEG C, after 1 hour, treat residue complete drying in iron pan, and after its cooling, residue brush in it is dropped down onto on electronic balance, claims its weight.
The meaning of " being less than 0.3g/325 order/100cc " is here exactly: after every 100cc glaze slip screens in 325 object standard sieves, residue remaining in it dry after weigh less than 0.3g.
The step of burning till contrast experiment is as follows:
(1) the accurate glaze slip of label taking (standard model), then get ground after glaze slip, adjustment period proportion to 1.75, take out dried a slice, scrape enamal organ one piece;
(2) dried is placed in glaze spraying cabinet, injected clear water in spray gun is thinly executed clear water in embryo face until raw embryo surface be moisture state, the raw embryo of surface wettability is moved on worktable rapidly, and enamal organ will be scraped entirely be put in embryo face, preparation glazing;
(3) respectively standard glaze slip and sampling glaze slip are poured into and scraped in the comparison groove of enamal organ, uniformly both are scraped on green compact, then green compact are put into test roller-way electrical kiln and burn till, its temperature is set at 1180 DEG C;
After (4) 1 hours, the green compact burnt till are moved to ventilation opening, after its naturally cooling, observe contrast and experiment in the place of light source abundance, sample gloss and the quality difference of glaze slip and standard glaze slip with visual method contrast.
Finally, use flash baking kiln to dry glaze slip, the glaze after oven dry is transported to powder beater and carries out beating powder operation, and then to the operation that glaze powder sieves, so namely obtained described printing glaze material.
Matched well according to its percentage by raw material each in proportioning 2 and get, and can find that hardness of glaze surface does not reach 4 grades after burning till according to the glaze that above-mentioned identical production method is obtained, and glaze layer increased devitrification resistance is poor, in its formula, we find not add corundum.
Matched well according to its percentage by raw material each in proportioning 3 and get, and can find that the anti-soil pick-up of glaze paint is poor after burning till according to the glaze that above-mentioned identical production method is obtained, in its formula, we find that calcium carbonate content is higher.
Raw material each in proportioning 4 is matched well according to its percentage and gets, and can find that the expansion coefficient value of glaze layer is lower after burning till according to the glaze that above-mentioned identical production method obtains, the ceramic tile angularity fired with it is also bad, and in its formula, we find not add nepheline syenite.
Component and the proportioning situation thereof of several groups of printing glaze materials of the present invention are provided below
| Ingredient names | Proportioning 5 | Proportioning 6 | Proportioning 7 | Proportioning 8 | Proportioning 9 | Proportioning 10 | Proportioning 11 | Proportioning 12 |
| Albite | 38 | 37.8 | 36 | 39 | 41 | 37 | 42 | 40 |
| Nepheline syenite | 10 | 9.9 | 8 | 8 | 8 | 8.5 | 8 | 8.1 |
| Wollastonite | 8 | 8 | 6 | 7 | 6 | 7.8 | 6 | 6.2 |
| Kaolin | 5 | 5.1 | 8 | 4 | 5 | 5.4 | 4 | 4 |
| Ball clay | 3 | 3.1 | 3 | 2 | 5 | 3.1 | 2 | 2 |
| Quartz | 4 | 5 | 6 | 7 | 4 | 4 | 4 | 5 |
| Aluminum oxide | 4 | 3 | 3 | 3 | 3 | 5 | 3 | 3.3 |
| Corundum | 6 | 6.1 | 5 | 4 | 7 | 6.2 | 8 | 4 |
| Zinc oxide | 3 | 3 | 4 | 3 | 3 | 3 | 5 | 3 |
| Calcium carbonate | 8 | 9 | 8 | 8 | 8 | 10 | 8 | 8 |
| Barium carbonate | 1 | 1.6 | 2 | 1 | 1 | 1 | 1 | 1.4 |
| Talcum | 1 | 1.4 | 1 | 2 | 1 | 1 | 1 | 1 |
| Rhombspar | 4 | 5 | 4 | 4 | 4 | 4 | 4 | 4 |
| Frit | 5 | 4 | 6 | 7 | 4 | 4 | 4 | 10 |
In each proportioning of above table, various component all calculates with the weight percentage accounting for total quality.
And just in proportioning 5 ~ 12 each raw material match well according to its percentage and get, and beneficial effect of the present invention can be reached according to the every glaze paint parameter after the glaze that above-mentioned identical production method obtains burns till.
We make an addition in formula by having the strong ball clay of plasticity-humectant according to certain ratio in the present invention, preferably flow ductility to make printing glaze material and form certain effect of filling up when glazing for the position that may produce pin hole because have, then the beginning melting temperature entirely throwing screen printing glaze improves by we, this is by increasing molten matter (albite in formula, nepheline syenite, wollastonite) and refractory raw material (kaolin, ball clay, quartz, aluminum oxide, corundum) ratio, and moderately reduce calcium carbonate, the consumption of barium carbonate, printing glaze material of the present invention is like this delayed the time of melting, contribute to impurity in idiosome and gas has time enough overflow and avoid the possibility producing pin hole in ceramic tile sintering process, this addresses the problem the problem of pin hole, thus improve the anti-soil pick-up of ceramic tile surface printing glaze material.
Then we divide for the selection portion of alumina raw material and select the higher corundum of the transparency to substitute, the albite that selection for feldspar raw material selects iron-holder lower, it is more reasonable to be allocated as by formula like this, make glaze slip melting property when molten state stronger and then produce stronger melting effect altogether and make glaze layer more aobvious transparent, this addresses the problem increased devitrification resistance problem.
Then we are by reducing the ratio of talcum and calcium carbonate, increase the usage ratio of centering high temperature frit, reduce the ratio of aluminum oxide, increase the usage ratio of corundum, thus make the Mohs' hardness of printing glaze material of the present invention reach 4 grades even more than 4 grades.
The Moh's scale number of conventional several raw materials is listed below in table
The change of the present invention in some proportioning raw materials very clearly can be found out, to reach the effect wanted required for the present invention from above-mentioned table.
Finally we by reduce kaolin and quartz use, and add part nepheline syenite replace albite, with guarantee improve printing glaze material the coefficient of expansion while be also unlikely to excessive to the properties influence of glaze.
The expansion coefficient value of conventional every raw material is listed below in form
In the present invention, we make an addition in formula by having the strong ball clay of plasticity-humectant according to certain ratio, preferably flow ductility to make printing glaze material and form certain effect of filling up when glazing for the position that may produce pin hole because have, then the beginning melting temperature entirely throwing screen printing glaze improves by we, this is by increasing molten matter (albite in formula, nepheline syenite, wollastonite) and refractory raw material (kaolin, ball clay, quartz, aluminum oxide, corundum) ratio, and moderately reduce calcium carbonate, the consumption of barium carbonate, printing glaze material of the present invention is like this delayed the time of melting, contribute to impurity in idiosome and gas has time enough overflow and avoid the possibility producing pin hole in ceramic tile sintering process, this addresses the problem the problem of pin hole, thus improve the anti-soil pick-up of ceramic tile surface printing glaze material.
Above content is in conjunction with concrete embodiment further description made for the present invention; can not assert that the specific embodiment of the present invention is confined to these; for the those of ordinary skill in the technical field of the invention; without departing from the inventive concept of the premise; some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.
Claims (8)
1. a printing glaze material, it is characterized in that: it comprises albite 36 ~ 42%, nepheline syenite 8 ~ 10%, wollastonite 6 ~ 8%, kaolin 4 ~ 8%, ball clay 2 ~ 5%, quartz 4 ~ 7%, aluminum oxide 3 ~ 5%, corundum 5 ~ 8%, calcium carbonate 8 ~ 10%, barium carbonate 1 ~ 2%, frit 4 ~ 10%, fusing assistant 6 ~ 10%, and said components is all by the percentage calculation accounting for overall printing glaze weight separately.
2. printing glaze material according to claim 1, is characterized in that: described fusing assistant comprises one or more in zinc oxide, talcum, rhombspar.
3. printing glaze material according to claim 2, is characterized in that: the weight percent that zinc oxide in fusing assistant, talcum, each component of rhombspar account for overall glaze is respectively: zinc oxide 2 ~ 5%, talcum 1 ~ 2%, rhombspar 3 ~ 5%.
4. a ceramic tile, is characterized in that: comprise the printing glaze material as claimed in claim 1 executed and be overlying on ceramic tile surface.
5. ceramic tile according to claim 4, is characterized in that: the Mohs' hardness of described ceramic tile surface printing glaze material is not less than 4 grades.
6. a production method for printing glaze material, is characterized in that: specifically comprise the steps
A, each raw material is carried out joining getting according to its weight percent, albite 36 ~ 42%, nepheline syenite 8 ~ 10%, wollastonite 6 ~ 8%, kaolin 4 ~ 8%, ball clay 2 ~ 5%, quartz 4 ~ 7%, aluminum oxide 3 ~ 5%, corundum 5 ~ 8%, calcium carbonate 8 ~ 10%, barium carbonate 1 ~ 2%, frit 4 ~ 10%, fusing assistant 6 ~ 10%, zinc oxide 2 ~ 5%, talcum 1 ~ 2%, rhombspar 3 ~ 5%;
B, each raw material to be dropped in clean ball mill, and add clear water, lock ball grinding machine lid, start ball mill, till the raw material in it being ground to the normal abrasive time of ball mill setting;
C, the residue of glaze slip in ball mill carried out to sampling and detect, and carry out burning till contrast experiment, the fineness as residue is less than 0.3g/325 order/100cc, and it is qualified to burn till contrast experiment, then carry out unloading slurry process, otherwise namely starts ball mill and continue grinding, until up to standard;
D, use flash baking kiln are dried glaze slip, the glaze after oven dry are transported to powder beater and carry out beating powder operation, and then to the operation that glaze powder sieves, so namely obtained described printing glaze material.
7. the production method of printing glaze material according to claim 6, is characterized in that: carry out sampling detection concrete operations to the residue of glaze slip in ball mill in step c and comprise:
C11, after ball mill is completely static, open ball mill cover, the glaze slurry samples pulling 300-500g out to get slurry spoon in ball mill is poured in the clean beaker of previously prepd to be measured, measures 100cc glaze slip, and it poured in 325 object standard sieves completely with standard specific gravity bottle;
C12, with the glaze slip in tap water standard sieve, until glaze slip is cleaned up only surplus residue in sieve, then residue all to be poured in iron pan, and by clean for the clear water in iron pan;
C13, iron pan is put into baking oven together with the residue above it dry, the temperature range of setting baking oven, at 120 DEG C ~ 180 DEG C, after 1 hour, treats residue complete drying in iron pan, and after its cooling, drops down onto on electronic balance, claim its weight by residue brush in it.
8. the production method of printing glaze material according to claim 6, is characterized in that: the concrete operations of burning till contrast experiment in step c comprise:
The accurate glaze slip of c21, label taking as standard model, then get ground after glaze slip, adjust its proportion to 1.75, take out dried a slice, scrape enamal organ one piece;
C22, dried is placed in glaze spraying cabinet, injected clear water in spray gun is thinly executed clear water in embryo face until raw embryo surface be moisture state, the raw embryo of surface wettability is moved on worktable rapidly, and enamal organ will be scraped entirely be put in embryo face, preparation glazing;
C23, respectively standard glaze slip and sampling glaze slip are poured into and scraped in the comparison groove of enamal organ, uniformly both are scraped on green compact, then green compact are put into test roller-way electrical kiln and burn till, its temperature is set at 1180 DEG C;
C24, after 1 hour, the green compact burnt till are moved to ventilation opening, after its naturally cooling, observe contrast and experiment in the place of light source abundance, with the gloss of visual method contrast sampling glaze slip and standard glaze slip and quality difference.
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| CN1887812A (en) * | 2006-07-18 | 2007-01-03 | 广东三水大鸿制釉有限公司 | Decoration glaze for inner wall tile and its prepn and detection method |
| CN102531706A (en) * | 2012-01-18 | 2012-07-04 | 卡罗比亚釉料（昆山）有限公司 | Special printing glaze material for ceramic full-polished glaze |
| CN102531707A (en) * | 2012-01-18 | 2012-07-04 | 卡罗比亚釉料（昆山）有限公司 | Special printing glaze material for glaze polishing of ceramic metal |
| CN102731150A (en) * | 2012-06-14 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze with good oil rub resistance |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1887812A (en) * | 2006-07-18 | 2007-01-03 | 广东三水大鸿制釉有限公司 | Decoration glaze for inner wall tile and its prepn and detection method |
| CN102531706A (en) * | 2012-01-18 | 2012-07-04 | 卡罗比亚釉料（昆山）有限公司 | Special printing glaze material for ceramic full-polished glaze |
| CN102531707A (en) * | 2012-01-18 | 2012-07-04 | 卡罗比亚釉料（昆山）有限公司 | Special printing glaze material for glaze polishing of ceramic metal |
| CN102731150A (en) * | 2012-06-14 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze with good oil rub resistance |
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