CN105906377B - A kind of method that high rigidity matt enamel is prepared using Yijun's sand tailing - Google Patents

A kind of method that high rigidity matt enamel is prepared using Yijun's sand tailing Download PDF

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CN105906377B
CN105906377B CN201610255245.8A CN201610255245A CN105906377B CN 105906377 B CN105906377 B CN 105906377B CN 201610255245 A CN201610255245 A CN 201610255245A CN 105906377 B CN105906377 B CN 105906377B
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loess
yijun
sand
glaze
temperature
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CN105906377A (en
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王毅
施佩
范晶
王伟伟
杨晓燕
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Shaanxi University of Science and Technology
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Shaanxi University of Science and Technology
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

A kind of method that high rigidity matt enamel is prepared using Yijun's sand tailing, raw loess coarse fodder is ground uniformly in mortar, loads crucible, 600 DEG C are fired in high temperature furnace, natural cooling after sixty minutes is kept the temperature, carries out ball milling after cooling, 80 mesh sieves are crossed, fine calcined loess material is made；By Yijun's sand, raw loess, calcined loess, feldspar, calcium phosphate, sodium tripolyphosphate, CMC mixing, is finely ground to 250 mesh, modulation glaze slip proportion is 1.7g/cm3；Glaze slip is equably applied and is applied on base, is warming up to 1,150 1210 DEG C, keeps the temperature 20 35 minutes, then natural cooling；Since Yijun's sand in glaze slip contains substantial amounts of quartzy and a small amount of high calcium oxide, the hardness of glaze surface after burning till is high and wearability is good；Discarded Making Use of Tailings is recycled using Yijun's sand tailing, solid waste discharge is reduced, ceramic raw ore dosage is reduced, saves mineral resources, resulting ceramic product can reach the effect that cost is low, hardness is high, wearability is good, have economize on resources, the multiple advantage such as the cost declining that lowers consumption.

Description

A kind of method that high rigidity matt enamel is prepared using Yijun's sand tailing
Technical field
The invention belongs to technical field of ceramic production, and in particular to one kind prepares high rigidity matt porcelain using Yijun's sand tailing The method of glaze.
Background technology
Sub-shine glaze is also commonly referred to as mat glaze, it refers to a kind of smooth hidden glossiness novel building ceramics glaze of glaze paint, The glaze shows medium gloss on the weak side in itself, closer to no light effect.Compared with high glaze Transparent frlt, have a distinctive style.It is logical Often, since glaze layer separates out crystal during melt supersaturation cooling in melting process in glaze, under incident light irradiation, glaze paint occurs multiple The optical phenomenas such as miscellaneous specular scattering, form special effect.General Sub-shine glaze can be divided into calcium matt, barium matt, zinc matt, These four types of magnesium matt, different types of Sub-shine glaze, but this are obtained during preparation by adding different crystallizing agents These crystallizing agent raw materials that kind is added in formula are typically more expensive, and production cost also improves therewith.
Some scholars are made the compound Sub-shine glaze of low temperature fast firing (Li Yanping, Hong Chen, Shen Huarong low temperature fast firings are compound in recent years The development ceramics journals of Sub-shine glaze, 2010,31 (1)), mainly using zinc oxide as main crystallizing agent, by increasing fluxing agent Content, makes glaze Flashmelt, so as to reduce firing temperature, controls production cost to a certain extent.But such a preparation Method is to introduce to burn talcum, calcite and substantial amounts of zinc oxide in formula material, and the cost of material used is still expensive, And since the maturing temperature of glaze is low, the Sub-shine glaze prepared is general poor in terms of hardness of glaze surface and wearability.
The content of the invention
Cheap it is an object of the invention to provide being prepared using one kind, hardness is high, and wearability is good, the profit that performance is stablized The method that high rigidity matt enamel is prepared with Yijun's sand tailing.
To reach above-mentioned purpose, the technical solution adopted by the present invention is：
1) by mass percentage by Yijun's sand of 20-80%, the life loess of 20-30%, the ripe loess and 0- of 0-25% 30% feldspar powder is uniformly mixed to obtain mixture, and the tripolyphosphate of mixture quality 0.3-0.5% is then added into mixture The CMC of sodium and 1-2% are uniformly mixed, and are finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3；
2) glaze slip is equably applied and applied on base substrate, be warming up to 1150-1230 DEG C, 20-40 minutes natural coolings of insulation are Obtain high rigidity matt enamel.
The preparation of the ripe loess：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines simultaneously for 600 DEG C 60 minutes are kept the temperature, ball milling crosses 80 mesh sieves after cooling, obtains ripe loess.
The ball milling uses the ball mill of 900r/h, ball milling 30 minutes.
The present invention utilizes and is rich in a large amount of SiO2Yijun's sand (Shaanxi Province Tongchuan City Yijun County) of component, Yijun's sand and Loess Yuan Material is rich in iron oxide coloring components, can be spontaneous cream-coloured to reddish brown serial color glaze with the difference of introduction volume.Pass through extra-fine grinding height Yijun's sand (250 mesh) is measured, makes its easy melt crystallization during glaze is burnt till, produces the wear-resisting glaze paint of high rigidity.Similar quartz Glass, since the key of ≡ Si-Si ≡ is high by force, so high mechanical strength.Hardness of glaze surface prepared by the present invention is high, wearability is good, glaze Face is smooth and uniform, and according to dosage and the difference of firing temperature glaze paint can be made to form various luster, the glaze paint of different hardness. And such a tailing low in raw material price, hardness is high, and wearability is good, performance is stablized, and can be widely applied to all kinds of ceramic products.From And produce a kind of low cost, the ceramic product of high-strength abrasion-proof.
The another aspect present invention is by introducing ripe loess, raw loess carries out formula modulation, on the one hand reduces raw loess glaze It is dry to shrink the problem of excessive, it on the other hand can increase the amount ranges of loess, beneficial to the increase of glaze firing range.
Brief description of the drawings
Fig. 1 is the XRD diagram that the present invention implements Yijun's sand.
Fig. 2 is inventive samples glaze paint surface sweeping electronic microscope photos figure.
Embodiment
The present invention is described in further detail with reference to embodiment.
Embodiment 1：
1) by mass percentage by 80% Yijun's sand, 20% life loess is uniformly mixed to obtain mixture, then to mixing The sodium tripolyphosphate of mixture quality 0.4% is added in thing and 1% CMC is uniformly mixed, is finely ground to 250 mesh, modulates glaze slip ratio Weight is 1.7g/cm3；
2) glaze slip is equably applied and applied on base substrate, be warming up to 1210 DEG C, kept the temperature 35 minutes natural coolings and obtain height firmly Spend matt enamel.
Table one is the test result parameter of the chemical composition table of Yijun's sandy plain material；
Yijun's sand and loess contain chromophore component iron and therefore being capable of spontaneous colors as can be seen from Table 1 in forming.
Used Yijun's sand contains the mineral matters such as quartz, albite, calcium carbonate, potassium feldspar as seen from Figure 1.
As in the high rigidity Sub-shine glaze prepared by the sample glaze paint scanning electron microscope analysis figure of Fig. 2 can be seen that the present invention, depositing In substantial amounts of liquate crystal.
Embodiment 2：
1) by mass percentage by 70% Yijun's sand, 30% life loess is uniformly mixed to obtain mixture, then to mixing The sodium tripolyphosphate of mixture quality 0.3% is added in thing and 1% CMC is uniformly mixed, is finely ground to 250 mesh, modulates glaze slip ratio Weight is 1.7g/cm3；
2) glaze slip is equably applied and applied on base substrate, be warming up to 1230 DEG C, kept the temperature 20 minutes natural coolings and obtain height firmly Spend matt enamel.
Embodiment 3：
1) preparation of ripe loess：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines and keep the temperature for 600 DEG C 60 minutes, cross 80 mesh sieves using the ball mill of 900r/h, ball milling after cooling within 30 minutes, obtain ripe loess；
2) 50% Yijun's sand, 25% life loess, 25% ripe loess are uniformly mixed and must mixed by mass percentage Thing, then adds the sodium tripolyphosphate of mixture quality 0.4% into mixture and 2% CMC is uniformly mixed, be finely ground to 250 Mesh, modulation glaze slip proportion is 1.6g/cm3；
3) glaze slip is equably applied and applied on base substrate, be warming up to 1220 DEG C, kept the temperature 40 minutes natural coolings and obtain height firmly Spend matt enamel.
Embodiment 4：
1) preparation of ripe loess：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines and keep the temperature for 600 DEG C 60 minutes, cross 80 mesh sieves using the ball mill of 900r/h, ball milling after cooling within 30 minutes, obtain ripe loess；
2) by mass percentage by 30% Yijun's sand, 25% life loess, 25% ripe loess and 20% feldspar powder Mixture is uniformly mixed to obtain, sodium tripolyphosphate and the 1% CMC mixing of mixture quality 0.5% are then added into mixture Uniformly, 250 mesh are finely ground to, modulation glaze slip proportion is 1.6g/cm3；
3) glaze slip is equably applied and applied on base substrate, be warming up to 1200 DEG C, kept the temperature 30 minutes natural coolings and obtain height firmly Spend matt enamel.
Embodiment 5：
1) preparation of ripe loess：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines and keep the temperature for 600 DEG C 60 minutes, cross 80 mesh sieves using the ball mill of 900r/h, ball milling after cooling within 30 minutes, obtain ripe loess；
2) by mass percentage by 20% Yijun's sand, 25% life loess, 25% ripe loess and 30% feldspar powder Mixture is uniformly mixed to obtain, sodium tripolyphosphate and the 2% CMC mixing of mixture quality 0.5% are then added into mixture Uniformly, 250 mesh are finely ground to, modulation glaze slip proportion is 1.7g/cm3；
3) glaze slip is equably applied and applied on base substrate, be warming up to 1150 DEG C, kept the temperature 40 minutes natural coolings and obtain height firmly Spend matt enamel.
Embodiment 6：
1) preparation of ripe loess：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines and keep the temperature for 600 DEG C 60 minutes, cross 80 mesh sieves using the ball mill of 900r/h, ball milling after cooling within 30 minutes, obtain ripe loess；
2) by mass percentage by 42% Yijun's sand, 23% life loess, 10% ripe loess and 25% feldspar powder Mixture is uniformly mixed to obtain, then the sodium tripolyphosphate of mixture quality 0.3% is added into mixture and 1.5% CMC is mixed Close uniformly, be finely ground to 250 mesh, modulation glaze slip proportion is 1.6g/cm3；
3) glaze slip is equably applied and applied on base substrate, be warming up to 1180 DEG C, kept the temperature 35 minutes natural coolings and obtain height firmly Spend matt enamel.
Embodiment 7：
1) preparation of ripe loess：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines and keep the temperature for 600 DEG C 60 minutes, cross 80 mesh sieves using the ball mill of 900r/h, ball milling after cooling within 30 minutes, obtain ripe loess；
2) 57% Yijun's sand, 28% life loess, 5% ripe loess and 10% feldspar powder are mixed by mass percentage Close uniform that mixture, the sodium tripolyphosphate and 1.3% CMC that mixture quality 0.5% is then added into mixture mix Uniformly, 250 mesh are finely ground to, modulation glaze slip proportion is 1.7g/cm3；
3) glaze slip is equably applied and applied on base substrate, be warming up to 1190 DEG C, kept the temperature 30 minutes natural coolings and obtain height firmly Spend matt enamel.
Embodiment 8：
1) preparation of ripe loess：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines and keep the temperature for 600 DEG C 60 minutes, cross 80 mesh sieves using the ball mill of 900r/h, ball milling after cooling within 30 minutes, obtain ripe loess；
2) by mass percentage by 39% Yijun's sand, 26% life loess, 20% ripe loess and 15% feldspar powder Mixture is uniformly mixed to obtain, then the sodium tripolyphosphate of mixture quality 0.4% is added into mixture and 1.8% CMC is mixed Close uniformly, be finely ground to 250 mesh, modulation glaze slip proportion is 1.6g/cm3；
3) glaze slip is equably applied and applied on base substrate, be warming up to 1160 DEG C, kept the temperature 28 minutes natural coolings and obtain height firmly Spend matt enamel.

Claims (3)

  1. A kind of 1. method that high rigidity matt enamel is prepared using Yijun's sand tailing, it is characterised in that：
    1) by mass percentage by Yijun's sand tailing of 20-80%, the life loess of 20-30%, the ripe loess and 0- of 0-25% 30% feldspar powder is uniformly mixed to obtain mixture, and the tripolyphosphate of mixture quality 0.3-0.5% is then added into mixture The CMC of sodium and 1-2% are uniformly mixed, and are finely ground to 250 mesh, modulation glaze slip proportion is 1.6-1.7g/cm3；
    2) glaze slip is equably applied and applied on base substrate, be warming up to 1150-1230 DEG C, kept the temperature 20-40 minutes natural coolings and obtain High rigidity matt enamel.
  2. 2. the method according to claim 1 that high rigidity matt enamel is prepared using Yijun's sand tailing, it is characterised in that：Institute The preparation for the ripe loess stated：After raw loess is ground uniformly in mortar, it is placed in high temperature furnace and calcines and keep the temperature 60 points for 600 DEG C Clock, after cooling ball milling cross 80 mesh sieves, obtain ripe loess.
  3. 3. the method according to claim 2 that high rigidity matt enamel is prepared using Yijun's sand tailing, it is characterised in that：Institute The ball milling stated uses the ball mill of 900r/h, ball milling 30 minutes.
CN201610255245.8A 2016-04-22 2016-04-22 A kind of method that high rigidity matt enamel is prepared using Yijun's sand tailing Active CN105906377B (en)

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CN106242283A (en) * 2016-09-20 2016-12-21 陕西科技大学 A kind of matt porcelain glaze based on Yijun's sand and preparation method thereof
CN106517785A (en) * 2016-09-20 2017-03-22 陕西科技大学 Microcrystal green glaze based on yijun sand and preparing method of microcrystal green glaze
CN106746658B (en) * 2016-12-20 2019-02-26 云南省红河哈尼族彝族自治州民族师范学校 Using the method for building the water purple pottery natural ore soil preparation black glaze of matt
CN108101583A (en) * 2017-12-27 2018-06-01 陕西科技大学 A kind of method that the red glaze of crystallite is prepared using arenosols

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