CN103351179A - Novel printing glaze material and production method thereof - Google Patents
Novel printing glaze material and production method thereof Download PDFInfo
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- CN103351179A CN103351179A CN2013102957107A CN201310295710A CN103351179A CN 103351179 A CN103351179 A CN 103351179A CN 2013102957107 A CN2013102957107 A CN 2013102957107A CN 201310295710 A CN201310295710 A CN 201310295710A CN 103351179 A CN103351179 A CN 103351179A
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Abstract
The invention provides a novel printing glaze material and a production method thereof. The novel printing glaze material consistent with standards is produced by putting the following components into a ball mill for grinding, wherein the components are as follows in percentage by weight: 36% to 42% of albite, 8% to 10% of nepheline orthoclase, 6% to 8% of wollastonite, 4% to 8% of kaolin, 2% to 5% of ball clay, 4% to 7% of quartz, 3% to 5% of aluminium oxide, 5% to 8% of corundum, 8% to 10% of calcium carbonate, 1% to 2% of barium carbonate, 4% to 10% of clinker and 6% to 10% of fluxing agent. The produced novel printing glaze material solves the problems of needle hole, poor permeability, poor sewage suction performance, poor abrasive resistance and poor warping degree.
Description
Technical field
The present invention relates to a kind of novel printing glaze and production method thereof.
Background technology
Full throwing screen printing glaze is the main product on the present ceramic tile consumption market, and it is to utilize multiple pottery formulated according to a certain percentage with raw material.This ratio is to obtain through theoretical basis and lot of experiments, and requirement must be that performance is more stable and can improve some defectives that isomorphism type product on the market often produces when producing ceramic tile.
Its main component has feldspar, quartz, kaolin, alkaline earth metal oxide (oxide compound that comprises aluminium, calcium, magnesium, barium, zinc) and frit.Briefly: entirely throwing screen printing glaze is to execute one glaze that overlays on ceramic tile surface, and it must burn till through kiln just can obtain our desired characteristic and effect.
But, owing to produce the self-characteristic of the complete raw material of throwing screen printing glaze and the prescription of each raw material, cause in the market printing entirely throw glaze exist pin hole, increased devitrification resistance, soil pick-up poor, wear no resistance and five problems such as angularity is bad.
The pin hole that produces in the pin hole that the origin cause of formation that pin hole occurs produces when mainly being divided into the glazing line operation and the ceramic tile sintering process.
Formed pin hole is normally owing to complete not enough of ball clay constituents ratio of throwing in the screen printing glaze prescription composition causes during the glazing line operation, we find the preparation that general full throwing screen printing glaze product custom is filled a prescription with the relatively poor great soil group of plasticity-, such ceramic full-polished screen printing glaze is subject to easily the impact of idiosome excess Temperature and makes the glaze slip flowability excessively low when glazing, and then forms pin hole.
And the pin hole that produces in the ceramic tile sintering process, normally owing to ceramic tile institute of not mating owing to idiosome, glaze and firing condition in sintering process causes, we find general full throwing screen printing glaze product because the narrower problem excessively low with the beginning fusing point of firing range, often cause the impurity in the base substrate not volatile clean in sintering process, gas in the final base substrate will form pin hole at the brick face when burning till thermal zone effusion.
Increased devitrification resistance is very high for the importance of full throwing vitreous brick, and the ceramic tile of devitrification will make color and the figure of product become dim and fuzzy.The main cause that general full throwing screen printing glaze forms increased devitrification resistance is entirely to throw in the too high or prescription of screen printing glaze refractoriness to be rich in the opaque raw material.About this problem, main key is incorrect to the selection of raw material and the characteristic of raw material is unfamiliar with institute causes, these common full throwing screen printing glazes often cause the glaze layer not have complete melting because the calorific value that kiln gives is not enough in sintering process and form the devitrification state, and then so that the color of product and figure become dim and fuzzy.
Inhaling soil pick-up is an important pointer of quality inspection on the consumption market, ceramic tile city, substandard tile laying is when ground, always because its not anti-soil pick-up characteristic and so that ceramic tile loses the difficulty that the value of viewing and admiring has increased maintenance simultaneously, so anti-soil pick-up is the research and development of all kinds of ceramic tiles and the important topic of making always.
Ceramic tile in sintering process since idiosome, glaze and firing condition do not mate with regard to easy formation pin hole, soil pick-up is poor and the problem such as idiosome evil mind, we find general full throwing screen printing glaze product because the excessively low problem of beginning fusing point, often cause the impurity in the base substrate not volatile clean in sintering process, gas in the final base substrate is when burning till thermal zone effusion, will form very tiny pin hole at the brick face, these fine and closely woven little pin holes are exactly the main cause that causes the soil pick-up poor performance.
Wear resistance is the very important quality pointer, particularly paving of floor tile class ceramic tile floor tile in public places, and wearing coefficient is required to reach Mohs' hardness more than 4 grades usually.Full throwing screen printing glaze is the glaze layer that covers the ceramic tile surface the superiors, after burning till, it is through polished finish, appearance attractive in appearance but can not illustrate its hardness and wear resistance, so the relatively poor product paving of wear resistance will soon form many cuts at ceramic tile surface because of wearing away speed faster on ground.
General full throwing screen printing glaze is in order to reduce raw materials cost, custom is with the comparatively cheap allotment of filling a prescription, and ignored improving the key element of glaze layer hardness requirement, this major embodiment is excessively to select the lower raw material of the Mohs' hardness such as talcum, calcium carbonate as fusing assistant, full throwing screen printing glaze hardness after burning till of this class is lower, usually can only reach 3 grades of Mohs' hardness.
Angularity is to weigh one of the most direct standard of ceramic tile quality, if no matter the angularity unfairness of ceramic tile is to upwarp or lower curved, all will encounters difficulties in the paving of ceramic tile so even can't paving use, so the warpage planeness of ceramic tile is extremely important.
Ceramic tile may make the angularity deviation of ceramic tile except the kiln firing condition is bad in sintering procedure, main also is that the most direct influence factor is exactly that to come from the drop of coefficient of expansion value of base substrate and glaze layer excessive, usually the full coefficient of expansion of glaze ground brick product of throwing is between 215-230, the general full throwing screen printing glaze coefficient of expansion then drops on about 195-205, so after klining one-tenth is advanced in the idiosome glazing, even because kiln firing technology personnel are controlled at the angularity of ceramic tile within the desirable scope reluctantly, after the ceramic tile cooling, along with time lapse, base substrate forms pullling of stress with the complete coefficient of expansion of throwing the screen printing glaze layer because drop is excessive, cause the most at last the warpage planeness of ceramic tile bad.
In order to solve these technological deficiencies, be badly in need of a kind of brand-new printing glaze material of invention and production method thereof.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of novel printing glaze and production method thereof, the novel printing glaze of producing by the method can be good at solving some defectives and the deficiency that exists in the prior art.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of novel printing glaze, it comprises albite 36～42%, nepheline potash feldspar 8～10%, wollastonite 6～8%, kaolin 4～8%, ball clay 2～5%, quartz 4～7%, aluminum oxide 3～5%, corundum 5～8%, calcium carbonate 8～10%, barium carbonate 1～2%, frit 4～10%, fusing assistant 6～10%, and said components is all by the percentage calculation that accounts for separately whole novel printing glaze weight.
As a further improvement on the present invention, described fusing assistant comprises one or more in zinc oxide, talcum, the rhombspar.
As a further improvement on the present invention, each fusing assistant weight percent of accounting for whole frit is respectively: zinc oxide 2～5%, talcum 1～2%, rhombspar 3～5%.
A kind of ceramic tile comprises and executes the novel printing glaze as claimed in claim 1 that is overlying on ceramic tile surface.
As a further improvement on the present invention, the Mohs' hardness of described ceramic tile surface novel printing glaze is not less than 4 grades.
A kind of production method of novel printing glaze specifically comprises the steps
A, each raw material joined according to its weight percent get, albite 36～42%, nepheline potash feldspar 8～10%, wollastonite 6～8%, kaolin 4～8%, ball clay 2～5%, quartzy 4～7%, aluminum oxide 3～5%, corundum 5～8%, calcium carbonate 8～10%, barium carbonate 1～2%, frit 4～10%, fusing assistant 6～10%, zinc oxide 2～5%, talcum 1～2%, rhombspar 3～5%;
B, each raw material is dropped in the clean ball mill, and add clear water, lock ball grinding machine lid starts ball mill, the raw material in it is ground to the normal abrasive time that ball mill sets till;
C, to the detection of taking a sample of the residue of glaze slip in the ball mill, and burn till the contrast experiment, such as the fineness of residue less than 0.3g/325mesh/100cc, and it is qualified to burn till the contrast experiment, then unload slurry process, continue to grind otherwise namely start ball mill, until up to standard;
D, use flash baking kiln are dried glaze slip, the glaze after the oven dry is transported to powder beater beats the powder operation, and then to the operation that glaze powder sieves, so namely make described novel printing glaze.
As a further improvement on the present invention, among the step c residue of glaze slip in the ball mill taken a sample and detects concrete operations and comprise:
C11, after ball mill is fully static, open the ball mill cover, a glaze slurry samples of pulling 300-500g to get slurry spoon in ball mill out is poured in the clean beaker of previously prepd to be measured, measures the 100cc glaze slip with the standard specific gravity bottle, and it is poured in the standard sieve of 325mesh fully;
C12, with the glaze slip in the tap water flushing standard sieve, until glaze slip is cleaned totally only surplus residue in the sieve, then residue is all poured in the iron pan, and the clear water in the iron pan is clean;
C13, iron pan is put into baking oven together with the residue above it dry, set the temperature range of baking oven at 120 ℃～180 ℃, after 1 hour, treat residue complete drying in the iron pan, and after its cooling, residue brush in it is dropped down onto on the electronic balance, claim its weight.
As a further improvement on the present invention, the concrete operations of burning till the contrast experiment among the step c comprise:
C21, the accurate glaze slip of label taking (standard model) are got the glaze slip after ground again, the adjustment period proportion to 1.75, take out dried a slice, scrape one piece of enamal organ;
C22, dried is placed the glaze spraying cabinet, will inject clear water in the spray gun and thinly execute clear water in the embryo face and be moisture state until give birth to embryo surface, the livings embryo of surface wettability is moved on the worktable rapidly, and will scrape the glaze enamal organ and entirely be put in the embryo face, the preparation glazing;
C23, respectively standard glaze slip and sampling glaze slip are poured in the comparison groove of scraping enamal organ, uniformly both are scraped on green compact, then green compact are put into test roller-way electrical kiln and burnt till, its temperature is set at 1180 ℃;
C24, after 1 hour, the green compact that burnt till are moved to ventilation opening, behind its naturally cooling, observe contrast and experiment in the place of light source abundance, with gloss and the quality difference of visual method contrast sampling glaze slip and standard glaze slip.
We will have the strong ball clay of plasticity-humectant and make an addition in the prescription according to certain ratio among the present invention, so that the novel printing glaze forms certain fill up effect for the position that may produce pin hole because having better mobile ductility when glazing; Then we will throw the beginning melting temperature raising of screen printing glaze entirely, this is by increase molten matter (albite in prescription, the nepheline potash feldspar, wollastonite) with refractory raw material (kaolin, ball clay, quartzy, aluminum oxide, corundum) ratio, and moderately reduce calcium carbonate, the consumption of barium carbonate, novel printing glaze of the present invention has like this postponed the time of melting, help impurity in the idiosome and gas to have time enough to overflow and avoided producing in the ceramic tile sintering process possibility of pin hole, so just solve the problem of pin hole, thereby improved the anti-soil pick-up of ceramic tile surface novel printing glaze.
Among the present invention, we for the selection portion of alumina raw material divide select the transparency higher corundum substitute, select the lower albite of iron-holder for the selection of feldspar raw material, it is more reasonable like this prescription to be allocated as, make glaze slip molten moving property when molten state stronger and then produce and stronger melt effect altogether and so that the glaze layer is more aobvious transparent, so just solved the increased devitrification resistance problem.
Among the present invention, we increase the usage ratio of centering high temperature frit by reducing the ratio of talcum and calcium carbonate, reduce the ratio of aluminum oxide, the usage ratio of increase corundum, thereby so that the Mohs' hardness of novel printing glaze of the present invention reach more than 4 grades even 4 grades.
Among the present invention, we are by reducing kaolin and quartzy use, and the nepheline potash feldspar that adds part replaces albite, also are unlikely to excessive to the properties influence of glaze when guaranteeing to improve the coefficient of expansion of novel printing glaze.
The present invention compared with prior art has following beneficial effect:
Frit provided by the invention and production method thereof can so that printing glaze material when operation mobile better, reduced pin hole, and by in prescription, adding corundum, improved the increased devitrification resistance problem of the demand of printing glaze material product, in addition, the novel printing glaze that the present invention produces has solved the soil pick-up problem of ceramic tile surface, and hardness and the wear resistance of ceramic tile surface all are improved, and the brick type warpage planeness after ceramic tile burns till has simultaneously also obtained guarantee.
Embodiment
In order better to explain invention main points of the present invention, provide first component and the proportioning situation thereof of several groups of existing printing glaze materials
| The component title | Proportioning 1 | Proportioning 2 | Proportioning 3 | Proportioning 4 |
| Albite | 38 | 38 | 38 | 38 |
| The nepheline potash feldspar | 10 | 10 | 10 | 0 |
| Wollastonite | 8 | 8 | 8 | 8 |
| Kaolin | 8 | 5 | 5 | 5 |
| Ball clay | 0 | 3 | 3 | 3 |
| Quartzy | 4 | 4 | 4 | 4 |
| Aluminum oxide | 4 | 10 | 4 | 4 |
| Corundum | 6 | 0 | 6 | 6 |
| Zinc oxide | 3 | 3 | 3 | 3 |
| Calcium carbonate | 8 | 8 | 13 | 8 |
| Barium carbonate | 1 | 1 | 1 | 1 |
| Talcum | 1 | 1 | 1 | 1 |
| Rhombspar | 4 | 4 | 4 | 4 |
| Frit | 5 | 5 | 0 | 5 |
Various components are all calculated with the weight percentage that accounts for total quality in each proportioning of above table.
Each raw material in the proportioning 1 matched well to get then according to its percentage each raw material is dropped in the clean ball mill, and add clear water, lock ball grinding machine lid starts ball mill, the raw material in it is ground to the normal abrasive time that ball mill sets till;
Then, to the detection of taking a sample of the residue of glaze slip in the ball mill, and burn till the contrast experiment, less than 0.3g/325mesh/100cc, and it is qualified to burn till the contrast experiment, then unloads slurry process such as the fineness of residue, continue to grind otherwise namely start ball mill, until up to standard;
The residue sampling detecting step here is as follows:
(1) after ball mill is fully static, open the ball mill cover, a glaze slurry samples of pulling 300-500g to get slurry spoon in ball mill out is poured in the clean beaker of previously prepd to be measured, measures the 100cc glaze slip with the standard specific gravity bottle, and it is poured in the standard sieve of 325mesh fully;
(2) with the glaze slip in the tap water flushing standard sieve, until glaze slip is cleaned totally only surplus residue in the sieve, then residue is all poured in the iron pan, and the clear water in the iron pan is clean;
(3) iron pan is put into baking oven together with the residue above it and dry, set the temperature range of baking oven at 120 ℃～180 ℃, after 1 hour, treat residue complete drying in the iron pan, and after its cooling, residue brush in it is dropped down onto on the electronic balance, claim its weight.
The meaning of here " less than 0.3g/325mesh/100cc " is exactly: after every 100cc glaze slip screens in the standard sieve of 325mesh, weigh less than 0.3g in it after last residue oven dry.
The step of burning till the contrast experiment is as follows:
(1) the accurate glaze slip of label taking (standard model) is got the glaze slip after ground again, the adjustment period proportion to 1.75, take out dried a slice, scrape one piece of enamal organ;
(2) dried is placed the glaze spraying cabinet, will inject clear water in the spray gun and thinly execute clear water in the embryo face and be moisture state until give birth to embryo surface, the livings embryo of surface wettability is moved on the worktable rapidly, and will scrape the glaze enamal organ and entirely be put in the embryo face, the preparation glazing;
(3) respectively standard glaze slip and sampling glaze slip are poured in the comparison groove of scraping enamal organ, uniformly both are scraped on green compact, then green compact are put into test roller-way electrical kiln and burnt till, its temperature is set at 1180 ℃;
After (4) 1 hours, the green compact that burnt till are moved to ventilation opening, behind its naturally cooling, observe contrast and experiment in the place of light source abundance, with gloss and the quality difference of visual method contrast sampling glaze slip and standard glaze slip.
At last, use the flash baking kiln that glaze slip is dried, the glaze after the oven dry is transported to powder beater beats the powder operation, and then to the operation that glaze powder sieves, so namely make described novel printing glaze.
Each raw material in the proportioning 2 matched well according to its percentage get, and can find that hardness of glaze surface does not reach 4 grades after burning till according to the glaze that above-mentioned identical production method makes, and glaze layer increased devitrification resistance is relatively poor, in its prescription, we find not add corundum.
Each raw material in the proportioning 3 matched well according to its percentage get, and can find that the anti-soil pick-up of glaze is relatively poor after burning till according to the glaze that above-mentioned identical production method makes, in its prescription, we find that calcium carbonate content is higher.
Each raw material in the proportioning 4 matched well according to its percentage get, and can find after burning till according to the glaze that above-mentioned identical production method makes that the coefficient of expansion value of glaze layer is lower, it is also bad to fire the ceramic tile angularity that forms with it, and in its prescription, we find not add the nepheline potash feldspar.
The below provides component and the proportioning situation thereof of several groups of novel printing glaze of the present invention
| The component title | Proportioning 5 | Proportioning 6 | Proportioning 7 | Proportioning 8 | Proportioning 9 | Proportioning 10 | Proportioning 11 | Proportioning 12 |
| Albite | 38 | 37.8 | 36 | 39 | 41 | 37 | 42 | 40 |
| The nepheline potash feldspar | 10 | 9.9 | 8 | 8 | 8 | 8.5 | 8 | 8.1 |
| Wollastonite | 8 | 8 | 6 | 7 | 6 | 7.8 | 6 | 6.2 |
| Kaolin | 5 | 5.1 | 8 | 4 | 5 | 5.4 | 4 | 4 |
| Ball clay | 3 | 3.1 | 3 | 2 | 5 | 3.1 | 2 | 2 |
| Quartzy | 4 | 5 | 6 | 7 | 4 | 4 | 4 | 5 |
| Aluminum oxide | 4 | 3 | 3 | 3 | 3 | 5 | 3 | 3.3 |
| Corundum | 6 | 6.1 | 5 | 4 | 7 | 6.2 | 8 | 4 |
| Zinc oxide | 3 | 3 | 4 | 3 | 3 | 3 | 5 | 3 |
| Calcium carbonate | 8 | 9 | 8 | 8 | 8 | 10 | 8 | 8 |
| Barium carbonate | 1 | 1.6 | 2 | 1 | 1 | 1 | 1 | 1.4 |
| Talcum | 1 | 1.4 | 1 | 2 | 1 | 1 | 1 | 1 |
| Rhombspar | 4 | 5 | 4 | 4 | 4 | 4 | 4 | 4 |
| Frit | 5 | 4 | 6 | 7 | 4 | 4 | 4 | 10 |
Various components are all calculated with the weight percentage that accounts for total quality in each proportioning of above table.
And just in the proportioning 5～12 each raw material match well according to its percentage and get, and the every glaze parameter after burning till according to the glaze that above-mentioned identical production method makes can both reach beneficial effect of the present invention.
We will have the strong ball clay of plasticity-humectant and make an addition in the prescription according to certain ratio in the present invention, so that the novel printing glaze forms certain fill up effect for the position that may produce pin hole because having better mobile ductility when glazing; Then we will throw the beginning melting temperature raising of screen printing glaze entirely, this is by increase molten matter (albite in prescription, the nepheline potash feldspar, wollastonite) with refractory raw material (kaolin, ball clay, quartzy, aluminum oxide, corundum) ratio, and moderately reduce calcium carbonate, the consumption of barium carbonate, novel printing glaze of the present invention has like this postponed the time of melting, help impurity in the idiosome and gas to have time enough to overflow and avoided producing in the ceramic tile sintering process possibility of pin hole, so just solve the problem of pin hole, thereby improved the anti-soil pick-up of ceramic tile surface novel printing glaze.
Then we divide for the selection portion of alumina raw material and select the higher corundum of the transparency to substitute, select the lower albite of iron-holder for the selection of feldspar raw material, it is more reasonable like this prescription to be allocated as, make glaze slip molten moving property when molten state stronger and then produce and stronger melt effect altogether and so that the glaze layer is more aobvious transparent, so just solved the increased devitrification resistance problem.
Then we increase the usage ratio of centering high temperature frit by reducing the ratio of talcum and calcium carbonate, reduce the ratio of aluminum oxide, the usage ratio of increase corundum, thereby so that the Mohs' hardness of novel printing glaze of the present invention reach more than 4 grades even 4 grades.
Listed the Moh's scale number of several raw materials commonly used in the below's table
From above-mentioned table, can very clearly find out the change of the present invention on some proportioning raw materials, to reach the effect of wanting required for the present invention.
We are by reducing kaolin and quartzy use at last, and the nepheline potash feldspar that adds part replaces albite, also are unlikely to excessive to the properties influence of glaze when guaranteeing to improve the coefficient of expansion of novel printing glaze.
Listed the coefficient of expansion value of every raw material commonly used in the following form
We will have the strong ball clay of plasticity-humectant and make an addition in the prescription according to certain ratio among the present invention, so that the novel printing glaze forms certain fill up effect for the position that may produce pin hole because having better mobile ductility when glazing; Then we will throw the beginning melting temperature raising of screen printing glaze entirely, this is by increase molten matter (albite in prescription, the nepheline potash feldspar, wollastonite) with refractory raw material (kaolin, ball clay, quartzy, aluminum oxide, corundum) ratio, and moderately reduce calcium carbonate, the consumption of barium carbonate, novel printing glaze of the present invention has like this postponed the time of melting, help impurity in the idiosome and gas to have time enough to overflow and avoided producing in the ceramic tile sintering process possibility of pin hole, so just solve the problem of pin hole, thereby improved the anti-soil pick-up of ceramic tile surface novel printing glaze.
Above content is the further description of the present invention being done in conjunction with concrete embodiment; can not assert that the specific embodiment of the present invention is confined to these; for the those of ordinary skill in the technical field of the invention; without departing from the inventive concept of the premise; can also make some simple deduction or replace, all should be considered as belonging to protection scope of the present invention.
Claims (8)
1. novel printing glaze, it is characterized in that: it comprises albite 36～42%, nepheline potash feldspar 8～10%, wollastonite 6～8%, kaolin 4～8%, ball clay 2～5%, quartz 4～7%, aluminum oxide 3～5%, corundum 5～8%, calcium carbonate 8～10%, barium carbonate 1～2%, frit 4～10%, fusing assistant 6～10%, and said components is all by the percentage calculation that accounts for separately whole novel printing glaze weight.
2. novel printing glaze according to claim 1, it is characterized in that: described fusing assistant comprises one or more in zinc oxide, talcum, the rhombspar.
3. novel printing glaze according to claim 2, it is characterized in that: the weight percent that each fusing assistant accounts for whole frit is respectively: zinc oxide 2～5%, talcum 1～2%, rhombspar 3～5%.
4. a ceramic tile is characterized in that: comprise and execute the novel printing glaze as claimed in claim 1 that is overlying on ceramic tile surface.
5. ceramic tile according to claim 4, it is characterized in that: the Mohs' hardness of described ceramic tile surface novel printing glaze is not less than 4 grades.
6. the production method of a novel printing glaze is characterized in that: specifically comprise the steps
A, each raw material joined according to its weight percent get, albite 36～42%, nepheline potash feldspar 8～10%, wollastonite 6～8%, kaolin 4～8%, ball clay 2～5%, quartzy 4～7%, aluminum oxide 3～5%, corundum 5～8%, calcium carbonate 8～10%, barium carbonate 1～2%, frit 4～10%, fusing assistant 6～10%, zinc oxide 2～5%, talcum 1～2%, rhombspar 3～5%;
B, each raw material is dropped in the clean ball mill, and add clear water, lock ball grinding machine lid starts ball mill, the raw material in it is ground to the normal abrasive time that ball mill sets till;
C, to the detection of taking a sample of the residue of glaze slip in the ball mill, and burn till the contrast experiment, such as the fineness of residue less than 0.3g/325mesh/100cc, and it is qualified to burn till the contrast experiment, then unload slurry process, continue to grind otherwise namely start ball mill, until up to standard;
D, use flash baking kiln are dried glaze slip, the glaze after the oven dry is transported to powder beater beats the powder operation, and then to the operation that glaze powder sieves, so namely make described novel printing glaze.
7. the production method of novel printing glaze according to claim 6 is characterized in that: among the step c residue of glaze slip in the ball mill taken a sample and detect concrete operations and comprise:
C11, after ball mill is fully static, open the ball mill cover, a glaze slurry samples of pulling 300-500g to get slurry spoon in ball mill out is poured in the clean beaker of previously prepd to be measured, measures the 100cc glaze slip with the standard specific gravity bottle, and it is poured in the standard sieve of 325mesh fully;
C12, with the glaze slip in the tap water flushing standard sieve, until glaze slip is cleaned totally only surplus residue in the sieve, then residue is all poured in the iron pan, and the clear water in the iron pan is clean;
C13, iron pan is put into baking oven together with the residue above it dry, set the temperature range of baking oven at 120 ℃～180 ℃, after 1 hour, treat residue complete drying in the iron pan, and after its cooling, residue brush in it is dropped down onto on the electronic balance, claim its weight.
8. the production method of novel printing glaze according to claim 6, it is characterized in that: the concrete operations of burning till the contrast experiment among the step c comprise:
C21, the accurate glaze slip of label taking (standard model) are got the glaze slip after ground again, the adjustment period proportion to 1.75, take out dried a slice, scrape one piece of enamal organ;
C22, dried is placed the glaze spraying cabinet, will inject clear water in the spray gun and thinly execute clear water in the embryo face and be moisture state until give birth to embryo surface, the livings embryo of surface wettability is moved on the worktable rapidly, and will scrape the glaze enamal organ and entirely be put in the embryo face, the preparation glazing;
C23, respectively standard glaze slip and sampling glaze slip are poured in the comparison groove of scraping enamal organ, uniformly both are scraped on green compact, then green compact are put into test roller-way electrical kiln and burnt till, its temperature is set at 1180 ℃;
C24, after 1 hour, the green compact that burnt till are moved to ventilation opening, behind its naturally cooling, observe contrast and experiment in the place of light source abundance, with gloss and the quality difference of visual method contrast sampling glaze slip and standard glaze slip.
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| CN105000865A (en) * | 2015-07-08 | 2015-10-28 | 福建省晋江市丹豪陶瓷有限公司 | Preparation method for large-sized ceramic tile |
| CN106495493A (en) * | 2016-10-11 | 2017-03-15 | 常州市鼎日环保科技有限公司 | A kind of preparation method of crystallite stone ceramic tile |
| CN107200554A (en) * | 2017-07-20 | 2017-09-26 | 淄博新博陶瓷有限公司 | A kind of preparation technology of antifouling sheen Dali stone ceramic tile |
| CN107324655A (en) * | 2017-07-20 | 2017-11-07 | 淄博新博陶瓷有限公司 | A kind of cover-coat enamel glaze of antifouling sheen Dali stone ceramic tile |
| CN108996908A (en) * | 2018-10-23 | 2018-12-14 | 佛山市陶莹新型材料有限公司 | A kind of printing polishing glaze and preparation method thereof and the application method in tile product |
| CN109293398A (en) * | 2018-10-23 | 2019-02-01 | 佛山市陶莹新型材料有限公司 | A kind of anti-skidding glaze and its processing method and the application method in fired brick |
| CN112661494A (en) * | 2020-12-26 | 2021-04-16 | 江西金泰源陶瓷有限公司 | Composite antibacterial ceramic tile and preparation process thereof |
| CN113582542A (en) * | 2021-07-13 | 2021-11-02 | 广东兴辉陶瓷集团有限公司 | Glaze material imitating velvet feeling of cloth grain or wallpaper |
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| CN102531706A (en) * | 2012-01-18 | 2012-07-04 | 卡罗比亚釉料（昆山）有限公司 | Special printing glaze material for ceramic full-polished glaze |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103804027A (en) * | 2014-02-28 | 2014-05-21 | 湖南泰鑫瓷业有限公司 | Glazed with natural drape texture and manufacturing method thereof |
| CN105000865A (en) * | 2015-07-08 | 2015-10-28 | 福建省晋江市丹豪陶瓷有限公司 | Preparation method for large-sized ceramic tile |
| CN106495493A (en) * | 2016-10-11 | 2017-03-15 | 常州市鼎日环保科技有限公司 | A kind of preparation method of crystallite stone ceramic tile |
| CN106495493B (en) * | 2016-10-11 | 2019-01-18 | 邯郸市永年区金缔陶瓷有限公司 | A kind of preparation method of crystallite stone ceramic tile |
| CN107200554A (en) * | 2017-07-20 | 2017-09-26 | 淄博新博陶瓷有限公司 | A kind of preparation technology of antifouling sheen Dali stone ceramic tile |
| CN107324655A (en) * | 2017-07-20 | 2017-11-07 | 淄博新博陶瓷有限公司 | A kind of cover-coat enamel glaze of antifouling sheen Dali stone ceramic tile |
| CN108996908A (en) * | 2018-10-23 | 2018-12-14 | 佛山市陶莹新型材料有限公司 | A kind of printing polishing glaze and preparation method thereof and the application method in tile product |
| CN109293398A (en) * | 2018-10-23 | 2019-02-01 | 佛山市陶莹新型材料有限公司 | A kind of anti-skidding glaze and its processing method and the application method in fired brick |
| CN112661494A (en) * | 2020-12-26 | 2021-04-16 | 江西金泰源陶瓷有限公司 | Composite antibacterial ceramic tile and preparation process thereof |
| CN113582542A (en) * | 2021-07-13 | 2021-11-02 | 广东兴辉陶瓷集团有限公司 | Glaze material imitating velvet feeling of cloth grain or wallpaper |
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