CN106186688A - A kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl - Google Patents
A kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl Download PDFInfo
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- CN106186688A CN106186688A CN201610572937.5A CN201610572937A CN106186688A CN 106186688 A CN106186688 A CN 106186688A CN 201610572937 A CN201610572937 A CN 201610572937A CN 106186688 A CN106186688 A CN 106186688A
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- Prior art keywords
- glaze
- wet base
- glazing
- applicable
- toilet bowl
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Detergent Compositions (AREA)
- Sanitary Device For Flush Toilet (AREA)
Abstract
The invention discloses a kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl, its raw material includes by weight: wherein 27 30 parts of quartz, potassium feldspar 25 28 parts, 14 16 parts of calcite, dolomite 45 parts, zinc oxide 34 parts, aluminium oxide 23 parts, Kaolin 34 parts, Zirconium orthosilicate. 14 16 parts.The present invention can directly on toilet wet base pipeline glazing to reach common glaze effect of glazing on dry body.
Description
Technical field
The present invention relates to a kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl.
Background technology
Pipeline is filled on semi-finished product dry body by the glazing mode of conventional sanitation ceramic toilet pipeline for setting up operation
Glaze, and if use tradition glaze slip spraying on wet base pipeline product glaze can be caused thin, whiteness is low, and glaze easily peels off simultaneously
Increase the defect that product glaze is convex.Traditional mode of production mode need to set up post and operate, and has dragged down production average personal efficiency；Simultaneously because increasing
Add the carrying number of times to dry body so that the product probability of defect such as collide with improves.
Summary of the invention
The invention provides a kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl, which overcome background technology
In be applicable to the deficiency existing for glaze of sanitary ceramics conduit of toilet bowl wet base glazing.
The present invention solves being the technical scheme is that of its technical problem
A kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl, it is characterised in that its raw material is by weight
Including: include quartz 27-30 part, potassium feldspar 25-28 part, calcite 14-16 part, dolomite 4-5 part, zinc oxide 3-4 part, oxidation
Aluminum 2-3 part, Kaolin 3-4 part, Zirconium orthosilicate. 14-16 part.
Aforesaid a kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl, it is characterised in that: its raw material is by weight
Amount part ratio includes: SiO2(silicon dioxide) 56.0-60.0 part, Al2O3(aluminium sesquioxide): 8-11 part, CaO (calcium oxide): 6-8
Part, MgO (magnesium oxide): 0.5-1.5 part, K2O (potassium oxide): 2-4 part, Na2O (sodium oxide): 1.0-2.0 part, Fe2O3(oxidation
Ferrum): 0 part-0.15 part, TiO2(titanium oxide): 0 part-0.15 part, ZnO (zinc oxide): 3.0-5.0 part, ZrO2(zirconium oxide): 9-11
Part；Water；The weight ratio of above compound gross weight and water is 1:0.3-0.5；Also include the sodium carboxymethyl cellulose added
And appropriate degumming agent, it adjusts glaze slip performance to proportion 1.75-1.80g/ml, viscosity V0 190s-210s/200ml.
More preferably, a kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl, its raw material includes by weight:
SiO2:56.0-60.0 part, Al2O3: 8-11 part, CaO:6-8 part, MgO:0.5-1.5 part, K2O:2-4 part, Na2O:1.0-2.0 part,
Fe2O3: 0.1 part-0.15 part, TiO2: 0.1 part-0.15 part, ZnO:3.0-5.0 part, ZrO2: 9-11 part；Water；Above chemical combination
The weight ratio of thing gross weight and water is 1:0.3-0.5；Also include sodium carboxymethyl cellulose and appropriate degumming agent, its adjustment added
Glaze slip performance is to proportion 1.75-1.80g/ml, viscosity V0 190s-210s/200ml.
Preferably, include by weight: SiO2: 56.52%, Al2O3: 9.02%, CaO:6.34%, MgO:0.82%,
K2O:2.92%, Na2O:1.13%, Fe2O3: 0.12%, TiO2: 0.11%, ZnO:3.62%, ZrO2: 9.6%.
Preferably, include by weight: SiO2: 57.12%, Al2O3: 9.23%, CaO:6.50%, MgO:0.96%,
K2O:2.36%, Na2O:1.34%, Fe2O3: 0.13%, TiO2: 0.08%, ZnO:3.48%, ZrO2: 10.0%.
The preparation method of a kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl, comprises the steps:
(1) carry out with raw materials such as quartz, potassium feldspar, calcite, dolomite, zinc oxide, aluminium oxide, Kaolin, Zirconium orthosilicate .s
Proportioning, wherein SiO2:56.0-60.0 part, Al2O3: 8-11 part, CaO:6-8 part, MgO:0.5-1.5 part, K2O:2-4 part, Na2O:
1.0-2.0 part, Fe2O3: 0 part-0.15 part, TiO2: 0 part-0.15 part, ZnO:3.0%-5.0%, ZrO2: 9%-11%, burns and loses:
8.0%-10.0%；
(2) by material: water puts into ball mill ball milling than 1:0.3-0.5, is milled to glaze slip 10 μm following particle accounting 65%-
180 mesh sieves, iron removal by magnetic separation is crossed after 68%；
(3) add sodium carboxymethyl cellulose and glaze slip performance is adjusted by appropriate degumming agent, adjust glaze slip performance extremely: ratio
Weight 1.75-1.80g/ml, viscosity V0 190s-210s/200ml；The wet base glazing of sanitary ceramics conduit of toilet bowl, has executed the half of glaze
Finished product burns till through kiln 1200-1220 DEG C.
In the present invention, described degumming agent, for glaze degumming agent, in the preferred embodiment, during for Beijing
The glaze degumming agent that Dai Yitao Science and Technology Ltd. provides.
In the present invention, the introducing of Zirconium orthosilicate. composition, after high temperature burns till, the generation of baddeleyite is promoted at product, thus
Incident light wave is formed scattering, reaches the effect that glaze whiteness promotes.
The glaze slip of the present invention can carry out pipeline glazing to toilet on wet base, and pipeline glazing operation is incorporated to molding work
Sequence, just can carry out pipeline glazing to it after the wet base demoulding.To reach to promote average personal efficiency, to reduce semi-finished product and collide with the effect of defect
Really.
The technical program is compared with background technology, and it has the advantage that
1) can directly on toilet wet base pipeline glazing to reach common glaze effect of glazing on dry body.
2) directly can use on wet base, just wet base pipeline can be carried out glazing in molding procedure, it is to avoid later process
Special hilllock is set base substrate pipeline is carried out glazing
3) both save cost of labor, decrease again the decline moving the semi-finished product qualification rate damaged and bring because of base substrate
3-1) reduce post setting, promote average personal efficiency；Tradition dry body pipeline fills glaze, can fill 200 the most for each person every day,
By the factory of a daily output 1600, then need 8 people；Carry out wet base glazing according to new glaze slip in molding procedure and then can save 8 people.
3-2) reduce semi-finished product to collide with defect, promote semi-finished product qualification rate.Dry body strength before pottery does not burns is relatively low, tradition
Dry body pipeline fills the relatively new method of glaze and adds the handling process of a dry body, easily causes product and collide with and broken in handling process
Broken.The use of new glaze slip can reduce dry body breakage rate 0.5%.
4) glaze slip viscosity is high, and adhesive force is strong, burns till rear whiteness height, covering power by force, and glaze surface evenness is good.
Detailed description of the invention
Embodiment 1
A kind of pipeline glaze being applicable to sanitary ceramics wet base glazing, specifically comprises the following steps that (1) uses quartz, potassium feldspar, Fang Xie
Stone, dolomite, zinc oxide, aluminium oxide, Kaolin, Zirconium orthosilicate. raw material carry out proportioning, and after proportioning, chemical composition is SiO2:
56.52%, Al2O3: 9.02%, CaO:6.34%, MgO:0.82%, K2O:2.92%, Na2O:1.13%, Fe2O3: 0.12%,
TiO2: 0.11%, ZnO:3.62%, ZrO2: 9.6%, burn and lose: 9.8%；(2) by material: water puts into ball mill ball milling than 1:0.4,
Ball milling records glaze slip 10 μm following particle accounting 66.2%, rear mistake 180 mesh sieve, iron removal by magnetic separation after 9 hours；(3) to sieving and removing
Glaze slip after ferrum adds 0.2% sodium carboxymethyl cellulose and appropriate degumming agent carries out adjusting performance, adjusts glaze slip performance and is: proportion
1.78g/ml, viscosity V0 202s/200ml.(4) glaze slip modulated is directly with spray gun glazing on the wet base pipeline of the firm demoulding.
(5) after kiln 1202 DEG C burns till, porcelain is become after body drying.
Embodiment 2
A kind of glaze being applicable to the wet base pipeline glazing of sanitary ceramics toilet, specifically comprises the following steps that (1) is long with quartz, potassium
Stone, calcite, dolomite, zinc oxide, aluminium oxide, Kaolin, Zirconium orthosilicate. raw material carry out proportioning, and after proportioning, chemical composition is
SiO2: 57.12%, Al2O3: 9.23%, CaO:6.50%, MgO:0.96%, K2O:2.36%, Na2O:1.34%, Fe2O3:
0.13%, TiO2: 0.08%, ZnO:3.48%, ZrO2: 10.0%, burn and lose: 8.8%；(2) by material: water puts into ball milling than 1:0.3
Machine ball milling, ball milling records glaze slip 10 μm following particle accounting 65.3%, rear mistake 180 mesh sieve, iron removal by magnetic separation after 8 hours；(3) to mistake
Glaze slip after sieving and removing ferrum adds 0.2% sodium carboxymethyl cellulose and appropriate degumming agent carries out adjusting performance, adjusts glaze slip performance
For: proportion 1.76g/ml, viscosity V0 196s/200ml.(4) glaze slip modulated directly uses spray gun at the wet base pipeline of the firm demoulding
Upper glazing.(5) after kiln 1202 DEG C burns till, porcelain is become after body drying.
In above-described embodiment, product after kiln high temperature burns till, its pipeline glaze whiteness and smoothness and tradition dry body
Glazing mode is suitable, and its product quality reaches requirement；Owing to being to carry out glazing on wet base after demoulding, which reduce rear operation
The specially setting on hilllock.
Claims (6)
1. the glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl, it is characterised in that its raw material wraps by weight
Include: include quartz 27-30 part, potassium feldspar 25-28 part, calcite 14-16 part, dolomite 4-5 part, zinc oxide 3-4 part, aluminium oxide
2-3 part, Kaolin 3-4 part, Zirconium orthosilicate. 14-16 part.
A kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl the most according to claim 1, it is characterised in that:
Its raw material includes by weight: SiO2: 56.0-60.0 part, Al2O3: 8-11 part, CaO:6-8 part, MgO:0.5-1.5 part,
K2O:2-4 part, Na2O:1.0-2.0 part, Fe2O3: 0 part-0.15 part, TiO2: 0 part-0.15 part, ZnO:3.0-5.0 part, ZrO2: 9-
11 parts；Water；The weight ratio of above compound gross weight and water is 1:0.3-0.5；Also include the carboxymethyl cellulose added
Sodium and appropriate degumming agent, it adjusts glaze slip performance to proportion 1.75-1.80g/ml, viscosity V0190s-210s/200ml.
A kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl the most according to claim 1, it is characterised in that:
Its raw material includes by weight: SiO2: 56.0-60.0 part, Al2O3: 8-11 part, CaO:6-8 part, MgO:0.5-1.5 part,
K2O:2-4 part, Na2O:1.0-2.0 part, Fe2O3: 0.1 part-0.15 part, TiO2: 0.1 part-0.15 part, ZnO:3.0-5.0 part,
ZrO2: 9-11 part；Water；The weight ratio of above compound gross weight and water is 1:0.3-0.5；Also include the carboxymethyl added
Sodium cellulosate and appropriate degumming agent, it adjusts glaze slip performance to proportion 1.75-1.80g/ml, viscosity V0190s-210s/200ml.
A kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl the most according to claim 1, it is characterised in that:
Include by weight: SiO2: 56.52%, Al2O3: 9.02%, CaO:6.34%, MgO:0.82%, K2O:2.92%, Na2O:
1.13%, Fe2O3: 0.12%, TiO2: 0.11%, ZnO:3.62%, ZrO2: 9.6%.
A kind of glaze being applicable to the wet base glazing of sanitary ceramics conduit of toilet bowl the most according to claim 1, it is characterised in that:
Include by weight: SiO2: 57.12%, Al2O3: 9.23%, CaO:6.50%, MgO:0.96%, K2O:2.36%, Na2O:
1.34%, Fe2O3: 0.13%, TiO2: 0.08%, ZnO:3.48%, ZrO2: 10.0%.
6. it is applicable to a preparation method for the glaze of sanitary ceramics conduit of toilet bowl wet base glazing, comprises the steps:
(1) proportioning is carried out with raw materials such as quartz, potassium feldspar, calcite, dolomite, zinc oxide, aluminium oxide, Kaolin, Zirconium orthosilicate .s,
Wherein SiO2: 56.0-60.0 part, Al2O3: 8-11 part, CaO:6-8 part, MgO:0.5-1.5 part, K2O:2-4 part, Na2O:1.0-
2.0 parts, Fe2O3: 0 part-0.15 part, TiO2: 0 part-0.15 part, ZnO:3.0%-5.0%, ZrO2: 9%-11%, burns and loses:
8.0%-10.0%；
(2) by material: water puts into ball mill ball milling than 1:0.3-0.5, after being milled to glaze slip 10 μm following particle accounting 65%-68%
Cross 180 mesh sieves, iron removal by magnetic separation；
(3) add sodium carboxymethyl cellulose and glaze slip performance is adjusted by appropriate degumming agent, adjust glaze slip performance extremely: proportion
1.75-1.80g/ml, viscosity V0 190s-210s/200ml；The wet base pipeline glaze that slurry modulates, uses watering can to carry out pipeline
Glazing, the semi-finished product having executed glaze burn till through kiln 1200-1220 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572937.5A CN106186688B (en) | 2016-07-20 | 2016-07-20 | A kind of glaze and preparation method thereof suitable for the wet base glazing of sanitary ceramics conduit of toilet bowl |
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|---|---|---|---|
| CN201610572937.5A CN106186688B (en) | 2016-07-20 | 2016-07-20 | A kind of glaze and preparation method thereof suitable for the wet base glazing of sanitary ceramics conduit of toilet bowl |
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| CN106186688A true CN106186688A (en) | 2016-12-07 |
| CN106186688B CN106186688B (en) | 2019-07-23 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106977103A (en) * | 2017-01-12 | 2017-07-25 | 九牧厨卫股份有限公司 | The preparation method of one planting sand light glaze sanitary ceramics |
| CN108147666A (en) * | 2017-12-29 | 2018-06-12 | 广东尚高科技有限公司 | A kind of glaze for being used for double-deck glazing, preparation method and application |
| CN109133624A (en) * | 2018-08-27 | 2019-01-04 | 佛山石湾鹰牌陶瓷有限公司 | High whiteness overglaze and application thereof and acidproof ultrawhite brick |
| CN110171927A (en) * | 2019-04-29 | 2019-08-27 | 福建良格厨卫有限公司 | A kind of self-cleaning glaze repairing glaze, preparation and its use for sanitary ceramics |
| CN111484321A (en) * | 2020-04-20 | 2020-08-04 | 福建省德化县鹏坤陶瓷有限公司 | Ultrahigh-strength domestic ceramic and preparation method thereof |
| CN113683394A (en) * | 2021-09-11 | 2021-11-23 | 景德镇陶瓷大学 | High-performance self-cleaning sanitary ceramic and preparation method thereof |
| CN113816721A (en) * | 2021-10-08 | 2021-12-21 | 广东金牌陶瓷有限公司 | High-whiteness ceramic large plate and preparation method thereof |
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| CN104692833A (en) * | 2015-02-27 | 2015-06-10 | 唐山中陶卫浴制造有限公司 | High-hardness wollastonite glaze slip and preparation method thereof |
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| CN102424608A (en) * | 2011-09-16 | 2012-04-25 | 唐山华丽陶瓷有限公司 | Glaze material with fluxing agent |
| CN104692833A (en) * | 2015-02-27 | 2015-06-10 | 唐山中陶卫浴制造有限公司 | High-hardness wollastonite glaze slip and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106977103A (en) * | 2017-01-12 | 2017-07-25 | 九牧厨卫股份有限公司 | The preparation method of one planting sand light glaze sanitary ceramics |
| CN106977103B (en) * | 2017-01-12 | 2020-03-17 | 九牧厨卫股份有限公司 | Preparation method of sand glaze sanitary ceramic |
| CN108147666A (en) * | 2017-12-29 | 2018-06-12 | 广东尚高科技有限公司 | A kind of glaze for being used for double-deck glazing, preparation method and application |
| CN108147666B (en) * | 2017-12-29 | 2021-01-05 | 广东尚高科技有限公司 | Glaze for double-layer glazing, preparation method and application |
| CN109133624A (en) * | 2018-08-27 | 2019-01-04 | 佛山石湾鹰牌陶瓷有限公司 | High whiteness overglaze and application thereof and acidproof ultrawhite brick |
| CN110171927A (en) * | 2019-04-29 | 2019-08-27 | 福建良格厨卫有限公司 | A kind of self-cleaning glaze repairing glaze, preparation and its use for sanitary ceramics |
| CN110171927B (en) * | 2019-04-29 | 2020-11-27 | 福建良瓷科技有限公司 | Self-cleaning glaze repair glaze for sanitary ceramics, preparation and application thereof |
| CN111484321A (en) * | 2020-04-20 | 2020-08-04 | 福建省德化县鹏坤陶瓷有限公司 | Ultrahigh-strength domestic ceramic and preparation method thereof |
| CN113683394A (en) * | 2021-09-11 | 2021-11-23 | 景德镇陶瓷大学 | High-performance self-cleaning sanitary ceramic and preparation method thereof |
| CN113816721A (en) * | 2021-10-08 | 2021-12-21 | 广东金牌陶瓷有限公司 | High-whiteness ceramic large plate and preparation method thereof |
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| CN106186688B (en) | 2019-07-23 |
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