CN104018182A - 用于氯碱工业的离子传导膜及其制备方法 - Google Patents
用于氯碱工业的离子传导膜及其制备方法 Download PDFInfo
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- CN104018182A CN104018182A CN201410251263.XA CN201410251263A CN104018182A CN 104018182 A CN104018182 A CN 104018182A CN 201410251263 A CN201410251263 A CN 201410251263A CN 104018182 A CN104018182 A CN 104018182A
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- Prior art keywords
- perfluorinated
- resin
- ion
- microparticle
- ion exchange
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- 239000012528 membrane Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000003513 alkali Substances 0.000 title abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 158
- 229920005989 resin Polymers 0.000 claims abstract description 158
- 239000011859 microparticle Substances 0.000 claims abstract description 88
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical class C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 238000000034 method Methods 0.000 claims abstract description 41
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 230000000694 effects Effects 0.000 claims abstract description 16
- 230000008569 process Effects 0.000 claims abstract description 13
- 229920006026 co-polymeric resin Polymers 0.000 claims abstract description 9
- 239000002344 surface layer Substances 0.000 claims abstract description 9
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract 8
- 239000003014 ion exchange membrane Substances 0.000 claims description 49
- 239000010410 layer Substances 0.000 claims description 44
- 210000004379 membrane Anatomy 0.000 claims description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 31
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 28
- 210000002469 basement membrane Anatomy 0.000 claims description 28
- 239000007864 aqueous solution Substances 0.000 claims description 23
- 239000002243 precursor Substances 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 21
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 20
- 239000000460 chlorine Substances 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 20
- 229910052801 chlorine Inorganic materials 0.000 claims description 19
- 239000004745 nonwoven fabric Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 238000005342 ion exchange Methods 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 238000000265 homogenisation Methods 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 8
- 238000010298 pulverizing process Methods 0.000 claims description 8
- 238000007766 curtain coating Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 7
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 5
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract description 3
- 150000003460 sulfonic acids Chemical class 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 1
- 238000007872 degassing Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000012779 reinforcing material Substances 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 48
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 32
- 239000011780 sodium chloride Substances 0.000 description 24
- 238000012360 testing method Methods 0.000 description 18
- 238000005868 electrolysis reaction Methods 0.000 description 16
- 238000002474 experimental method Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 12
- 238000007599 discharging Methods 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 239000012535 impurity Substances 0.000 description 8
- 230000001788 irregular Effects 0.000 description 8
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- 229960004756 ethanol Drugs 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 5
- 238000011056 performance test Methods 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 229910052809 inorganic oxide Inorganic materials 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000003254 anti-foaming effect Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000000051 modifying effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 108091006146 Channels Proteins 0.000 description 1
- 108090000862 Ion Channels Proteins 0.000 description 1
- 102000004310 Ion Channels Human genes 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000010220 ion permeability Effects 0.000 description 1
- 230000037427 ion transport Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/04—Diaphragms; Spacing elements characterised by the material
- C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0004—Organic membrane manufacture by agglomeration of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0004—Organic membrane manufacture by agglomeration of particles
- B01D67/00042—Organic membrane manufacture by agglomeration of particles by deposition of fibres, nanofibres or nanofibrils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
- B01D69/107—Organic support material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
- B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/02—Diaphragms; Spacing elements characterised by shape or form
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/06—Specific process operations in the permeate stream
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/46—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/14—Membrane materials having negatively charged functional groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/42—Ion-exchange membranes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Nanotechnology (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Dispersion Chemistry (AREA)
Abstract
Description
Claims (10)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410251263.XA CN104018182B (zh) | 2014-06-06 | 用于氯碱工业的离子传导膜及其制备方法 | |
PCT/CN2014/000653 WO2015184569A1 (zh) | 2014-06-06 | 2014-07-07 | 用于氯碱工业的离子传导膜及其制备方法 |
US15/314,927 US20170198404A1 (en) | 2014-06-06 | 2014-07-07 | Ion-conducting membrane used in chlor-alkali industry and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410251263.XA CN104018182B (zh) | 2014-06-06 | 用于氯碱工业的离子传导膜及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104018182A true CN104018182A (zh) | 2014-09-03 |
CN104018182B CN104018182B (zh) | 2016-11-30 |
Family
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111074295A (zh) * | 2019-12-31 | 2020-04-28 | 山东东岳未来氢能材料有限公司 | 氯碱工业用新型低阻离子传导膜及其制备方法 |
CN111188060A (zh) * | 2019-12-31 | 2020-05-22 | 山东东岳未来氢能材料有限公司 | 增强低阻氯碱电解槽隔膜及其制备方法 |
CN112159988A (zh) * | 2020-08-21 | 2021-01-01 | 广东臻鼎环境科技有限公司 | 一种聚四氟乙烯夹层保护离子交换膜及其制备方法和在电解领域的应用 |
CN113061251A (zh) * | 2021-03-22 | 2021-07-02 | 河北科技大学 | 一种改性聚酰亚胺及其制备方法和应用 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57158231A (en) * | 1981-03-24 | 1982-09-30 | Asahi Glass Co Ltd | Cation exchange membrane for electrolysis |
EP0061594A2 (en) * | 1981-03-20 | 1982-10-06 | Asahi Glass Company Ltd. | Ion exchange membrane and electrolytic cell using said membrane |
CN1145595A (zh) * | 1995-01-19 | 1997-03-19 | 旭硝子株式会社 | 多孔离子交换剂和生产去离子水的方法 |
CN1884352A (zh) * | 2005-06-24 | 2006-12-27 | 大连新源动力股份有限公司 | 用氯碱工业废弃离子交换膜制备全氟磺酸树脂溶液的方法 |
CN101768758A (zh) * | 2009-12-07 | 2010-07-07 | 山东东岳神舟新材料有限公司 | 一种电解用阳离子透过复合膜 |
CN101773791A (zh) * | 2009-12-07 | 2010-07-14 | 山东东岳高分子材料有限公司 | 一种具有高杂质耐受性的离子交换膜 |
CN102336043A (zh) * | 2011-05-27 | 2012-02-01 | 山东东岳高分子材料有限公司 | 具有高电流效率的离子交换膜及其制备方法和应用 |
CN102961979A (zh) * | 2012-11-26 | 2013-03-13 | 山东东岳高分子材料有限公司 | 一种无涂层零极距离子交换膜及其制备方法 |
CN102978654A (zh) * | 2012-12-14 | 2013-03-20 | 山东东岳高分子材料有限公司 | 氯碱工业用低电阻高强度离子交换膜及其制备方法 |
CN103014757A (zh) * | 2012-12-14 | 2013-04-03 | 山东东岳高分子材料有限公司 | 氯碱工业用含空穴的纤维增强离子交换膜及其制备方法 |
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0061594A2 (en) * | 1981-03-20 | 1982-10-06 | Asahi Glass Company Ltd. | Ion exchange membrane and electrolytic cell using said membrane |
JPS57158231A (en) * | 1981-03-24 | 1982-09-30 | Asahi Glass Co Ltd | Cation exchange membrane for electrolysis |
CN1145595A (zh) * | 1995-01-19 | 1997-03-19 | 旭硝子株式会社 | 多孔离子交换剂和生产去离子水的方法 |
CN1884352A (zh) * | 2005-06-24 | 2006-12-27 | 大连新源动力股份有限公司 | 用氯碱工业废弃离子交换膜制备全氟磺酸树脂溶液的方法 |
CN101768758A (zh) * | 2009-12-07 | 2010-07-07 | 山东东岳神舟新材料有限公司 | 一种电解用阳离子透过复合膜 |
CN101773791A (zh) * | 2009-12-07 | 2010-07-14 | 山东东岳高分子材料有限公司 | 一种具有高杂质耐受性的离子交换膜 |
CN102336043A (zh) * | 2011-05-27 | 2012-02-01 | 山东东岳高分子材料有限公司 | 具有高电流效率的离子交换膜及其制备方法和应用 |
CN102961979A (zh) * | 2012-11-26 | 2013-03-13 | 山东东岳高分子材料有限公司 | 一种无涂层零极距离子交换膜及其制备方法 |
CN102978654A (zh) * | 2012-12-14 | 2013-03-20 | 山东东岳高分子材料有限公司 | 氯碱工业用低电阻高强度离子交换膜及其制备方法 |
CN103014757A (zh) * | 2012-12-14 | 2013-04-03 | 山东东岳高分子材料有限公司 | 氯碱工业用含空穴的纤维增强离子交换膜及其制备方法 |
Non-Patent Citations (2)
Title |
---|
PEDRO ZAPATA,ET AL.: ""Composite Proton Exchange Membranes fromZirconium-Based Solid Acids and PVDF/AcrylicPolyelectrolyte Blends"", 《JOURNAL OF APPLIED POLYMER SCIENCE》, vol. 124, 20 February 2012 (2012-02-20), pages 241 - 250 * |
王凤霞: ""全氟磺酸树脂的熔融挤出加工性能及其离子交换膜的制备"", 《膜科学与技术》, vol. 27, no. 5, 24 December 2007 (2007-12-24), pages 74 - 77 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111074295A (zh) * | 2019-12-31 | 2020-04-28 | 山东东岳未来氢能材料有限公司 | 氯碱工业用新型低阻离子传导膜及其制备方法 |
CN111188060A (zh) * | 2019-12-31 | 2020-05-22 | 山东东岳未来氢能材料有限公司 | 增强低阻氯碱电解槽隔膜及其制备方法 |
CN111074295B (zh) * | 2019-12-31 | 2021-07-16 | 山东东岳高分子材料有限公司 | 氯碱工业用新型低阻离子传导膜及其制备方法 |
CN111188060B (zh) * | 2019-12-31 | 2021-08-10 | 山东东岳高分子材料有限公司 | 增强低阻氯碱电解槽隔膜及其制备方法 |
CN112159988A (zh) * | 2020-08-21 | 2021-01-01 | 广东臻鼎环境科技有限公司 | 一种聚四氟乙烯夹层保护离子交换膜及其制备方法和在电解领域的应用 |
CN113061251A (zh) * | 2021-03-22 | 2021-07-02 | 河北科技大学 | 一种改性聚酰亚胺及其制备方法和应用 |
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