CN104018180B - 零极距离子交换膜及其制备方法 - Google Patents
零极距离子交换膜及其制备方法 Download PDFInfo
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- CN104018180B CN104018180B CN201410249917.5A CN201410249917A CN104018180B CN 104018180 B CN104018180 B CN 104018180B CN 201410249917 A CN201410249917 A CN 201410249917A CN 104018180 B CN104018180 B CN 104018180B
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- amberplex
- resin
- pole span
- microparticle
- perfluorinated sulfonic
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
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- 229920005989 resin Polymers 0.000 claims abstract description 70
- 238000000034 method Methods 0.000 claims abstract description 48
- 239000011859 microparticle Substances 0.000 claims abstract description 38
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 239000006185 dispersion Substances 0.000 claims abstract description 32
- 229920006254 polymer film Polymers 0.000 claims abstract description 19
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 19
- 239000012779 reinforcing material Substances 0.000 claims abstract description 10
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical class C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003014 ion exchange membrane Substances 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 24
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 238000005342 ion exchange Methods 0.000 claims description 17
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- 239000007864 aqueous solution Substances 0.000 claims description 5
- -1 polytetrafluoroethylene Polymers 0.000 claims description 5
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
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- 238000005516 engineering process Methods 0.000 abstract description 4
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000460 chlorine Substances 0.000 abstract description 3
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 22
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- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 8
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
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- 230000001680 brushing effect Effects 0.000 description 2
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- 238000007598 dipping method Methods 0.000 description 2
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- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- 102000004310 Ion Channels Human genes 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
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- 239000003513 alkali Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 210000002469 basement membrane Anatomy 0.000 description 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical class OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
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- 239000003795 chemical substances by application Substances 0.000 description 1
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- 230000000052 comparative effect Effects 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
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- 239000003456 ion exchange resin Substances 0.000 description 1
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- 239000005416 organic matter Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
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- 230000001629 suppression Effects 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/04—Diaphragms; Spacing elements characterised by the material
- C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0013—Casting processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
- C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/02—Diaphragms; Spacing elements characterised by shape or form
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D2323/00—Details relating to membrane preparation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/42—Ion-exchange membranes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
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- H01—ELECTRIC ELEMENTS
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
Claims (10)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410249917.5A CN104018180B (zh) | 2014-06-06 | 2014-06-06 | 零极距离子交换膜及其制备方法 |
PCT/CN2014/000654 WO2015184570A1 (zh) | 2014-06-06 | 2014-07-07 | 零极距离子交换膜及其制备方法 |
US15/314,929 US20170198405A1 (en) | 2014-06-06 | 2014-07-07 | Zero polar distance ion exchange membrane and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410249917.5A CN104018180B (zh) | 2014-06-06 | 2014-06-06 | 零极距离子交换膜及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104018180A CN104018180A (zh) | 2014-09-03 |
CN104018180B true CN104018180B (zh) | 2016-10-05 |
Family
ID=51435164
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410249917.5A Active CN104018180B (zh) | 2014-06-06 | 2014-06-06 | 零极距离子交换膜及其制备方法 |
Country Status (3)
Country | Link |
---|---|
US (1) | US20170198405A1 (zh) |
CN (1) | CN104018180B (zh) |
WO (1) | WO2015184570A1 (zh) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112639169B (zh) * | 2018-09-21 | 2023-12-01 | 旭化成株式会社 | 层积体、层积体的保存方法、层积体的输送方法、保护层积体及其卷绕体 |
CN110492700A (zh) * | 2019-08-13 | 2019-11-22 | 宁国井田机电有限公司 | 一种压缩机电机定子的生产工艺 |
CN111188050B (zh) * | 2019-12-31 | 2021-07-09 | 山东东岳高分子材料有限公司 | 碱金属氯化物电解用超薄全氟磺酸离子交换膜及其制备方法 |
CN111074296B (zh) * | 2019-12-31 | 2021-07-09 | 山东东岳高分子材料有限公司 | 具有离子传导功能的疏气泡涂层及其制备方法 |
CN111074295B (zh) * | 2019-12-31 | 2021-07-16 | 山东东岳高分子材料有限公司 | 氯碱工业用新型低阻离子传导膜及其制备方法 |
CN111188065A (zh) * | 2019-12-31 | 2020-05-22 | 山东东岳未来氢能材料有限公司 | 用于氯化物电解的增强全氟磺酸离子交换膜及其制备方法 |
CN112430831B (zh) * | 2020-09-24 | 2022-04-29 | 山东东岳高分子材料有限公司 | 适用于零极距电解槽的离子交换膜及其制备方法 |
CN112323095B (zh) * | 2020-09-24 | 2021-12-07 | 山东东岳高分子材料有限公司 | 氯碱工业用高强度低槽压全氟离子交换膜及其制备方法 |
CN113061251B (zh) * | 2021-03-22 | 2022-11-29 | 河北科技大学 | 一种改性聚酰亚胺及其制备方法和应用 |
CN117543039A (zh) * | 2022-08-02 | 2024-02-09 | 北京清驰科技有限公司 | 一种质子交换膜用涂布液及其制备方法和应用 |
CN115364905A (zh) * | 2022-08-20 | 2022-11-22 | 西藏旭升矿业开发有限公司 | 一种可循环电极液离子交换膜及其制备方法 |
CN115347318B (zh) * | 2022-08-29 | 2023-08-04 | 中国华能集团清洁能源技术研究院有限公司 | 一种海水电解制氢复合隔膜及其制备方法、应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0061594A2 (en) * | 1981-03-20 | 1982-10-06 | Asahi Glass Company Ltd. | Ion exchange membrane and electrolytic cell using said membrane |
CN1062382A (zh) * | 1990-09-27 | 1992-07-01 | 旭硝子株式会社 | 含氟阳离子交换膜及其在电解中的应用 |
CN101768758A (zh) * | 2009-12-07 | 2010-07-07 | 山东东岳神舟新材料有限公司 | 一种电解用阳离子透过复合膜 |
CN101773791B (zh) * | 2009-12-07 | 2010-12-29 | 山东东岳高分子材料有限公司 | 一种具有高杂质耐受性的离子交换膜 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3075580B2 (ja) * | 1991-04-05 | 2000-08-14 | 旭硝子株式会社 | 電解用含フッ素陽イオン交換膜 |
JP5774514B2 (ja) * | 2012-02-13 | 2015-09-09 | 旭化成ケミカルズ株式会社 | 陽イオン交換膜、及びこれを用いた電解槽 |
CN102978654B (zh) * | 2012-12-14 | 2015-03-18 | 山东东岳高分子材料有限公司 | 氯碱工业用低电阻高强度离子交换膜及其制备方法 |
CN103540951B (zh) * | 2013-11-04 | 2016-08-17 | 山东东岳高分子材料有限公司 | 一种用于氧阴极电解的离子交换膜及其制备方法 |
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2014
- 2014-06-06 CN CN201410249917.5A patent/CN104018180B/zh active Active
- 2014-07-07 WO PCT/CN2014/000654 patent/WO2015184570A1/zh active Application Filing
- 2014-07-07 US US15/314,929 patent/US20170198405A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0061594A2 (en) * | 1981-03-20 | 1982-10-06 | Asahi Glass Company Ltd. | Ion exchange membrane and electrolytic cell using said membrane |
US4652356A (en) * | 1981-03-20 | 1987-03-24 | Asahi Glass Company, Ltd. | Ion exchange membrane and electrolytic cell using thereof |
CN1062382A (zh) * | 1990-09-27 | 1992-07-01 | 旭硝子株式会社 | 含氟阳离子交换膜及其在电解中的应用 |
CN101768758A (zh) * | 2009-12-07 | 2010-07-07 | 山东东岳神舟新材料有限公司 | 一种电解用阳离子透过复合膜 |
CN101773791B (zh) * | 2009-12-07 | 2010-12-29 | 山东东岳高分子材料有限公司 | 一种具有高杂质耐受性的离子交换膜 |
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