CN103951780A - 一种大孔弱酸性阳离子交换树脂的制备方法 - Google Patents
一种大孔弱酸性阳离子交换树脂的制备方法 Download PDFInfo
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- CN103951780A CN103951780A CN201410199853.2A CN201410199853A CN103951780A CN 103951780 A CN103951780 A CN 103951780A CN 201410199853 A CN201410199853 A CN 201410199853A CN 103951780 A CN103951780 A CN 103951780A
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- exchange resin
- cation exchange
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- macroporous weak
- monomer
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- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000003729 cation exchange resin Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000002253 acid Substances 0.000 claims abstract description 29
- 238000005406 washing Methods 0.000 claims abstract description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 18
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000001110 calcium chloride Substances 0.000 claims abstract description 16
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 16
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 35
- 239000000178 monomer Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 11
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 11
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 11
- 239000003999 initiator Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 239000001913 cellulose Substances 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 239000006210 lotion Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 10
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 9
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 9
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 9
- 239000003643 water by type Substances 0.000 claims description 7
- 239000011324 bead Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 6
- 238000003811 acetone extraction Methods 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 238000002242 deionisation method Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 239000003456 ion exchange resin Substances 0.000 claims description 5
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 5
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 9
- 230000007062 hydrolysis Effects 0.000 abstract description 8
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 8
- 238000006116 polymerization reaction Methods 0.000 abstract description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- 239000004088 foaming agent Substances 0.000 abstract 2
- 125000003158 alcohol group Chemical group 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 241001566735 Archon Species 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000234435 Lilium Species 0.000 description 1
- -1 acrylic acid resin cation Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
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Abstract
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106699974A (zh) * | 2016-12-16 | 2017-05-24 | 东至绿洲环保化工有限公司 | 用于除去废水中碱性盐的大孔弱酸性阳离子交换树脂 |
CN108707247A (zh) * | 2018-03-22 | 2018-10-26 | 安徽皖东树脂科技有限公司 | 用于抗菌素提纯的树脂的制备方法 |
CN109485786A (zh) * | 2018-10-30 | 2019-03-19 | 扬州金珠树脂有限公司 | 一种复合引发剂在制备离子交换树脂中的应用 |
CN109575186A (zh) * | 2018-12-20 | 2019-04-05 | 安徽三星树脂科技有限公司 | 一种大孔弱碱性阴离子交换树脂及其制备方法 |
CN110317297A (zh) * | 2019-07-17 | 2019-10-11 | 河北利江生物科技有限公司 | 乙烯基吡啶两性树脂的制备方法 |
CN110563130A (zh) * | 2019-07-25 | 2019-12-13 | 广东卓信环境科技股份有限公司 | 一种膜生物反应器的复合填料及其制备方法 |
CN111170401A (zh) * | 2020-01-18 | 2020-05-19 | 中国人民解放军火箭军工程大学 | 偏二甲肼吸收剂及制备方法和应用 |
EP4029604A1 (de) | 2021-01-13 | 2022-07-20 | LANXESS Deutschland GmbH | Kationenaustauscher auf acrylnitrilbasis |
CN115785515A (zh) * | 2021-09-09 | 2023-03-14 | 佛山市云米电器科技有限公司 | 一种弱酸性树脂及其制备方法 |
CN115888852A (zh) * | 2023-01-06 | 2023-04-04 | 山东德川化工科技有限责任公司 | 丙烯酸酯系弱酸阳离子交换树脂的制备工艺 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1320647A (zh) * | 2001-01-05 | 2001-11-07 | 南京大学 | 大孔丙烯酸系弱酸性阳离子交换树脂生产工艺 |
US20070027222A1 (en) * | 2005-07-29 | 2007-02-01 | Lanxess Deutschland Gmbh | Monodisperse cation exchangers |
CN101310860A (zh) * | 2007-02-24 | 2008-11-26 | 朗盛德国有限责任公司 | 单分散弱酸性阳离子交换剂 |
CN102190753A (zh) * | 2010-03-19 | 2011-09-21 | 周家付 | 一种大孔弱酸性阳离子交换树脂的制备方法 |
-
2014
- 2014-05-13 CN CN201410199853.2A patent/CN103951780B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1320647A (zh) * | 2001-01-05 | 2001-11-07 | 南京大学 | 大孔丙烯酸系弱酸性阳离子交换树脂生产工艺 |
US20070027222A1 (en) * | 2005-07-29 | 2007-02-01 | Lanxess Deutschland Gmbh | Monodisperse cation exchangers |
CN101310860A (zh) * | 2007-02-24 | 2008-11-26 | 朗盛德国有限责任公司 | 单分散弱酸性阳离子交换剂 |
CN102190753A (zh) * | 2010-03-19 | 2011-09-21 | 周家付 | 一种大孔弱酸性阳离子交换树脂的制备方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106699974A (zh) * | 2016-12-16 | 2017-05-24 | 东至绿洲环保化工有限公司 | 用于除去废水中碱性盐的大孔弱酸性阳离子交换树脂 |
CN108707247A (zh) * | 2018-03-22 | 2018-10-26 | 安徽皖东树脂科技有限公司 | 用于抗菌素提纯的树脂的制备方法 |
CN109485786A (zh) * | 2018-10-30 | 2019-03-19 | 扬州金珠树脂有限公司 | 一种复合引发剂在制备离子交换树脂中的应用 |
CN109575186A (zh) * | 2018-12-20 | 2019-04-05 | 安徽三星树脂科技有限公司 | 一种大孔弱碱性阴离子交换树脂及其制备方法 |
CN110317297A (zh) * | 2019-07-17 | 2019-10-11 | 河北利江生物科技有限公司 | 乙烯基吡啶两性树脂的制备方法 |
CN110563130A (zh) * | 2019-07-25 | 2019-12-13 | 广东卓信环境科技股份有限公司 | 一种膜生物反应器的复合填料及其制备方法 |
CN111170401A (zh) * | 2020-01-18 | 2020-05-19 | 中国人民解放军火箭军工程大学 | 偏二甲肼吸收剂及制备方法和应用 |
EP4029604A1 (de) | 2021-01-13 | 2022-07-20 | LANXESS Deutschland GmbH | Kationenaustauscher auf acrylnitrilbasis |
CN115785515A (zh) * | 2021-09-09 | 2023-03-14 | 佛山市云米电器科技有限公司 | 一种弱酸性树脂及其制备方法 |
CN115785515B (zh) * | 2021-09-09 | 2024-01-26 | 佛山市云米电器科技有限公司 | 一种弱酸性树脂及其制备方法 |
CN115888852A (zh) * | 2023-01-06 | 2023-04-04 | 山东德川化工科技有限责任公司 | 丙烯酸酯系弱酸阳离子交换树脂的制备工艺 |
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