CN103757056A - Method for producing biogas co-production organic fertilizer through peat gasket material - Google Patents

Method for producing biogas co-production organic fertilizer through peat gasket material Download PDF

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Publication number
CN103757056A
CN103757056A CN201410033034.0A CN201410033034A CN103757056A CN 103757056 A CN103757056 A CN 103757056A CN 201410033034 A CN201410033034 A CN 201410033034A CN 103757056 A CN103757056 A CN 103757056A
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CN
China
Prior art keywords
peat
biogas
gasket materials
gasket material
organic fertilizer
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Pending
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CN201410033034.0A
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Chinese (zh)
Inventor
李珺
马力通
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Inner Mongolia University of Science and Technology
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Inner Mongolia University of Science and Technology
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Priority to CN201410033034.0A priority Critical patent/CN103757056A/en
Publication of CN103757056A publication Critical patent/CN103757056A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Fertilizers (AREA)

Abstract

The invention discloses a method for producing a biogas co-production organic fertilizer through a peat gasket material. Livestock urine is added into the peat gasket material to regulate a carbon nitrogen ratio to be (25-30):1; the pH value is regulated to be 6.5-7.5, anaerobic activated sludge which accounts for 30-60 percent of the total mass of the material is added, a solid-to-liquid ratio is regulated to be 1:(1-20) g/ml, and the biogas is prepared through anaerobic fermentation within 7-40 days at the temperature of 28-50 DEG C. The production method comprises the following steps: performing anaerobic fermentation on residues through the peat gasket material, adding auxiliary materials to regulate the moisture content to be 50-70 percent, performing compost fermentation at the temperature of 50-60 DEG C for 10-40 days, granulating and drying to obtain the organic fertilizer. The problems that the peat only serves as a gasket material and is single in utilization mode, the peat gasket material is used for directly composting, pathogenic bacteria cannot be effectively killed, and the product is single and low in economic value are solved, the purposes of the peat are finally enlarged, the additional value of the peat is increased, and the economic benefits of peat mining and utilization are improved.

Description

A kind of peat gasket materials is produced the method for biogas coproduction fertilizer
 
Technical field
The present invention relates to a kind of peat gasket materials and produce the method for biogas coproduction fertilizer, belong to coal resources Application Areas.
Background technology
Coal is that China's distribution is the widest, and the Energy resources that reserves are more account for main status in the energy consumption structure of China.Coal, according to the difference of degree of coalification, can be divided into peat, brown coal, bituminous coal and hard coal.Peat (Peat) claim again the peat composed of rotten mosses or mud coal, it is the coal that degree of coalification is minimum, by the residual body of marsh plant, under the lower condition of excess moisture, poor aeration, temperature, failed fully to decompose, a kind of difficult decomposition forming through long-term accumulation is, the organism of the tiering of stable in properties.
Packing ring is showed dry ground, broken grass, peat etc. on the circle place mat of livestock.Peat has better water holding and absorption property, and therefore, available peat is done various gasket materials.Utilize peat to do the gasket materials of the domestic animals such as various horses, ox, sheep, pig, there is multiple benefit:
The first, anticorrosion, germ resistance is strong.It can suppress the corruption of ight soil and decompose, and effectively suppresses existence and the breeding of the multiple pathogenic bacteria of domestic animal.
The second, improve animal house miniclimate, for good sanitary condition is created in livestock life.Because peat water absorbability and adsorbed gas ability are strong, use peat packing ring, the gas (as ammonia, hydrogen sulfide, carbonic acid gas) that can absorb animal residue and decomposition generation thereof makes animal house keep clean, and corral inner drying is comfortable.
The 3rd, obtain high-quality barnyard manure.Utilize peat packing ring can more reasonably utilize barnyard manure.Stalk barnyard manure is in corral, and through diel nitrogen loss 10%, peat barnyard manure only loses 0. 7%.With 1t peat packing ring, can produce 4 ~ 5t high-quality organic fertilizer.
The 4th, utilize the alternative a large amount of stalks of peat packing ring, can be processed into feed or fodder additives, increase the feed resource of livestock industry.
The 5th, improve the throughput of domestic animal.Under same raising condition, livestock is raised on peat bedding and padding, and with comparing of raising on stalk or sawdust, milk amount improves 7% ~ 15%, and livestock increases weight 10% ~ 18% childhood, and birds, beasts and eggs output improves 5% ~ 12%.The 6th, peat can be made animal feed, fodder additives, fodder yeast, vitamin(e)-producing yeast etc., edible for livestock, poultry and fish.With peat forage feed domestic animal, poultry, not only expanded the source of feed, and because of the raising of nutritive value, also can promote it to grow.
Peat is applied to livestock industry as gasket materials, only utilized its good water holding and absorption property, ignore peat and be rich in organic and soil ulmin and multiple nutrients material, that causes peat utilizes mode single, the economic worth of peat resource does not fully demonstrate, and has limited comprehensive utilization and the higher value application of peat.
Summary of the invention
The technical issues that need to address of the present invention are just to overcome the defect of prior art, provide a kind of peat gasket materials to produce the method for biogas coproduction fertilizer, it utilizes peat gasket materials to mix the material feature of peat and livestock and poultry fecaluria, producing methane through anaerobic fermentation, natural pond slag is prepared fertilizer, solve peat and only done gasket materials and utilize problem and the direct compost of peat gasket materials that mode is single, can not effectively kill pathogenic bacteria, product one-sided economy is worth not high problem.The final purposes that expands peat, the added value of increase peat, improves the economic benefit of peat harvest and utilization.
For addressing the above problem, the present invention adopts following technical scheme:
The invention provides a kind of peat gasket materials and produce the method for biogas coproduction fertilizer, described method comprises the following steps:
(1) peat gasket materials interpolation livestock urine adjusting carbon-nitrogen ratio is (25-30): 1, regulating pH value is 6.5-7.5, add the anaerobic activated sludge that accounts for material total mass 30%-60%, adjusting solid-to-liquid ratio is 1:(1-20) g/ml, at 28-50 ℃, anaerobically fermenting 7-40 days prepares biogas;
(2) peat gasket materials anaerobically fermenting resistates, adding auxiliary material adjusting water content is 50%-70%, the 50-60 ℃ of rotten fermentation of heap 10-40 days, granulation post-drying obtains organic fertilizer.
Auxiliary material in step of the present invention (2) is the excrement of animals that is equivalent to residue total mass mark 30-80%, water content 50-75%.
Livestock described in the present invention is horse, ox, sheep or pig.
The present invention utilizes peat gasket materials to mix the material feature of peat and livestock and poultry fecaluria, producing methane through anaerobic fermentation, natural pond slag is prepared fertilizer, solve peat and only done gasket materials and utilize problem and the direct compost of peat gasket materials that mode is single, can not effectively kill pathogenic bacteria, product one-sided economy is worth not high problem.The final purposes that expands peat, the added value of increase peat, improves the economic benefit of peat harvest and utilization.
Thereby beneficial effect of the present invention is:
(1) the present invention fully utilizes peat gasket materials, peat and livestock fecaluria are by means of anaerobically fermenting, realize the coproduction of biogas and fertilizer, by low-carbon (LC) biomass energies such as the organic matter transformation in peat livestock fecaluria are biogas, both improved environment, realize the unification of environment benefits and economic gains, meet again national industry policy and Energy policy.
(2) the present invention fully utilizes peat gasket materials, peat gasket materials anaerobically fermenting coproduction biogas and fertilizer, the utilization of peat physical adsorption performance and chemical composition is excavated to greatest extent, by means of anaerobically fermenting, kill the pathogenic bacterium in livestock fecaluria, be conducive to improve the quality of follow-up fertilizer.
Embodiment
embodiment 1
Getting 200g peat gasket materials interpolation livestock urine adjusting carbon-nitrogen ratio is 25:1, regulating pH is 7.5, add the anaerobic activated sludge that accounts for material total mass 60%, adding water adjusting solid-to-liquid ratio is 1:10 g/ml, at 28 ℃, anaerobically fermenting is prepared biogas for 27 days, in fermenting process, stir, vibrate 4 times every day to fermentation unit, and draining water gathering of gas law is collected biogas 22853ml, the methane content average out to 56% in gas Chromatographic Determination biogas.
Peat gasket materials anaerobically fermenting resistates, adds the cow dung urine be equivalent to residue total mass mark 40%, water content 50%, and regulating water content is 55%, 50 ℃ of stacking fermentation 10 days of becoming thoroughly decomposed, and granulation post-drying obtains organic fertilizer.
Organic fertilizer is containing humic acids 26%, organic (butt) 45%, total nutrient (butt) 5.8%, moisture 23%, pH8.0, As, Cd, Pb, Cr, Hg content's index meet in NY 525-2012 4.3 regulation, detect 82/g of excrement colibacillus group number, induced worm egg death rate > 96%.
embodiment 2
Getting 300g peat gasket materials interpolation livestock urine adjusting carbon-nitrogen ratio is 28:1, regulating pH is 7.0, add and account for material total mass 50% anaerobic activated sludge, adding water adjusting solid-to-liquid ratio is 1:20g/ml, at 30 ℃, anaerobically fermenting is prepared biogas for 30 days, in fermenting process, stir, vibrate 4 times every day to fermentation unit, and draining water gathering of gas law is collected biogas 28974ml, the methane content average out to 58% in gas Chromatographic Determination biogas.
Peat gasket materials anaerobically fermenting resistates, adds and to be equivalent to residue massfraction 50%, the sheep excrement of water content 55%, and regulating water content is 50%, 50 ℃ of stacking fermentation 20 days of becoming thoroughly decomposed, granulation post-drying obtains organic fertilizer.
Organic fertilizer is containing humic acids 28%, organic (butt) 42%, total nutrient (butt) 5.6%, moisture 21%, pH6.0, As, Cd, Pb, Cr, Hg content's index meet in NY 525-2012 4.3 regulation, detect 76/g of excrement colibacillus group number, induced worm egg death rate > 97%.
embodiment 3
Getting 100g peat gasket materials interpolation livestock urine adjusting carbon-nitrogen ratio is 25:1, regulating pH is 6.5, add and account for material total mass 40% anaerobic activated sludge, adding water adjusting solid-to-liquid ratio is 1:1g/ml, at 50 ℃, anaerobically fermenting is prepared biogas for 7 days, in fermenting process, stir, vibrate 4 times every day to fermentation unit, and draining water gathering of gas law is collected biogas 14532ml, the methane content average out to 60% in gas Chromatographic Determination biogas.
Peat gasket materials anaerobically fermenting resistates, adds and to be equivalent to residue massfraction 30%, and it is 70%, 60 ℃ of stacking fermentation 30 days of becoming thoroughly decomposed that the pig manure of water content 50% regulates water content, and granulation post-drying obtains organic fertilizer.
Organic fertilizer is containing humic acids 26%, organic (butt) 42%, total nutrient (butt) 5.3%, moisture 24%, pH6.4, As, Cd, Pb, Cr, Hg content's index meet in NY 525-2012 4.3 regulation, detect 59/g of excrement colibacillus group number, induced worm egg death rate > 98%.
embodiment 4
Getting 200g peat gasket materials interpolation livestock urine adjusting carbon-nitrogen ratio is 30:1, regulating pH is 7.5, add and account for material total mass 30% anaerobic activated sludge, adding water adjusting solid-to-liquid ratio is 1:10 g/ml, at 35 ℃, anaerobically fermenting is prepared biogas for 22 days, in fermenting process, stir, vibrate 4 times every day to fermentation unit, and draining water gathering of gas law is collected biogas 21221ml, the methane content average out to 62% in gas Chromatographic Determination biogas.
Peat gasket materials anaerobically fermenting resistates, adds and to be equivalent to residue massfraction 40%, the cow dung of water content 52%, and regulating anaerobically fermenting resistates water content is 55%, 50 ℃ of stacking fermentation 12 days of becoming thoroughly decomposed, granulation post-drying obtains organic fertilizer.
Organic fertilizer is containing humic acids 24%, organic (butt) 41%, total nutrient (butt) 5.5%, moisture 21%, pH7.4, As, Cd, Pb, Cr, Hg content's index meet in NY 525-2012 4.3 regulation, detect 58/g of excrement colibacillus group number, induced worm egg death rate > 97%.
embodiment 5
Getting 150g peat gasket materials interpolation livestock urine adjusting carbon-nitrogen ratio is 28:1, regulating pH is 7.5, add and account for material total mass 60% anaerobic activated sludge, adding water adjusting solid-to-liquid ratio is 1:7 g/ml, at 50 ℃, anaerobically fermenting is prepared biogas for 40 days, in fermenting process, stir, vibrate 4 times every day to fermentation unit, and draining water gathering of gas law is collected biogas 16710ml, the methane content average out to 58% in gas Chromatographic Determination biogas.
Peat gasket materials anaerobically fermenting resistates, adds and to be equivalent to residue massfraction 40%, the horsehit of water content 60%, and regulating fermentation resistates water content is 60%, 50 ℃ of stacking fermentation 40 days of becoming thoroughly decomposed, granulation post-drying obtains organic fertilizer.
Organic fertilizer is containing humic acids 28%, organic (butt) 46%, total nutrient (butt) 5.7%, moisture 24%, pH8.1, As, Cd, Pb, Cr, Hg content's index meet in NY 525-2012 4.3 regulation, detect 41/g of excrement colibacillus group number, induced worm egg death rate > 96%.
Finally it should be noted that: obviously, above-described embodiment is only for example of the present invention is clearly described, and the not restriction to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without also giving all embodiments.And the apparent variation of being amplified out thus or change are still among protection scope of the present invention.

Claims (3)

1. peat gasket materials is produced a method for biogas coproduction fertilizer, it is characterized in that, described method comprises the following steps:
(1) peat gasket materials interpolation livestock urine adjusting carbon-nitrogen ratio is (25-30): 1, regulating pH value is 6.5-7.5, add the anaerobic activated sludge that accounts for material total mass 30%-60%, adjusting solid-to-liquid ratio is 1:(1-20) g/ml, at 28-50 ℃, anaerobically fermenting 7-40 days prepares biogas;
(2) peat gasket materials anaerobically fermenting resistates, adding auxiliary material adjusting water content is 50%-70%, the 50-60 ℃ of rotten fermentation of heap 10-40 days, granulation post-drying obtains organic fertilizer.
2. peat gasket materials as claimed in claim 1 is produced the method for biogas coproduction fertilizer, it is characterized in that, the auxiliary material in step (2) is the excrement of animals that is equivalent to residue total mass mark 30-80%, water content 50-75%.
3. peat gasket materials as claimed in claim 1 or 2 is produced the method for biogas coproduction fertilizer, it is characterized in that, described livestock is horse, ox, sheep or pig.
CN201410033034.0A 2014-01-24 2014-01-24 Method for producing biogas co-production organic fertilizer through peat gasket material Pending CN103757056A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009034545A2 (en) * 2007-09-14 2009-03-19 Willem Abraham Van Rooijen Granular fertilizer
CN103275745A (en) * 2012-12-31 2013-09-04 内蒙古科技大学 Method for preparation of biogas and combined production of organic fertilizer through processing peat by dilute acid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009034545A2 (en) * 2007-09-14 2009-03-19 Willem Abraham Van Rooijen Granular fertilizer
CN103275745A (en) * 2012-12-31 2013-09-04 内蒙古科技大学 Method for preparation of biogas and combined production of organic fertilizer through processing peat by dilute acid

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
谢大伟: "黑龙江省的泥炭资源及利用评价", 《腐植酸》 *

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