CN1036924C - 铬催化剂组合物及其在共聚方法中的应用 - Google Patents

铬催化剂组合物及其在共聚方法中的应用 Download PDF

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Publication number
CN1036924C
CN1036924C CN93118646A CN93118646A CN1036924C CN 1036924 C CN1036924 C CN 1036924C CN 93118646 A CN93118646 A CN 93118646A CN 93118646 A CN93118646 A CN 93118646A CN 1036924 C CN1036924 C CN 1036924C
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CN
China
Prior art keywords
chromium
chromium catalyst
weight
catalyst composition
chrome catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN93118646A
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English (en)
Chinese (zh)
Other versions
CN1085566A (zh
Inventor
R·D·巴德雷
E·A·贝纳姆
M·P·麦克丹尼尔
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Phillips Petroleum Co
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Phillips Petroleum Co
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Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of CN1085566A publication Critical patent/CN1085566A/zh
Application granted granted Critical
Publication of CN1036924C publication Critical patent/CN1036924C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN93118646A 1992-10-08 1993-10-05 铬催化剂组合物及其在共聚方法中的应用 Expired - Fee Related CN1036924C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/958,668 US5486584A (en) 1992-10-08 1992-10-08 Chromium catalyst compositions
US958,668 1992-10-08

Related Child Applications (2)

Application Number Title Priority Date Filing Date
CN96111936A Division CN1100068C (zh) 1992-10-08 1996-08-26 铬催化剂组合物及其在共聚方法中的应用
CN96111935A Division CN1150954A (zh) 1992-10-08 1996-08-26 铬催化剂组合物及其在共聚方法中的应用

Publications (2)

Publication Number Publication Date
CN1085566A CN1085566A (zh) 1994-04-20
CN1036924C true CN1036924C (zh) 1998-01-07

Family

ID=25501177

Family Applications (3)

Application Number Title Priority Date Filing Date
CN93118646A Expired - Fee Related CN1036924C (zh) 1992-10-08 1993-10-05 铬催化剂组合物及其在共聚方法中的应用
CN96111935A Pending CN1150954A (zh) 1992-10-08 1996-08-26 铬催化剂组合物及其在共聚方法中的应用
CN96111936A Expired - Fee Related CN1100068C (zh) 1992-10-08 1996-08-26 铬催化剂组合物及其在共聚方法中的应用

Family Applications After (2)

Application Number Title Priority Date Filing Date
CN96111935A Pending CN1150954A (zh) 1992-10-08 1996-08-26 铬催化剂组合物及其在共聚方法中的应用
CN96111936A Expired - Fee Related CN1100068C (zh) 1992-10-08 1996-08-26 铬催化剂组合物及其在共聚方法中的应用

Country Status (18)

Country Link
US (2) US5486584A (OSRAM)
EP (1) EP0591968B1 (OSRAM)
JP (1) JP3198206B2 (OSRAM)
KR (1) KR100278751B1 (OSRAM)
CN (3) CN1036924C (OSRAM)
AT (1) ATE155146T1 (OSRAM)
AU (1) AU654445B2 (OSRAM)
CA (1) CA2100144C (OSRAM)
DE (1) DE69312005T2 (OSRAM)
DK (1) DK0591968T3 (OSRAM)
ES (1) ES2104017T3 (OSRAM)
HU (1) HU212809B (OSRAM)
MX (1) MX9306146A (OSRAM)
NO (1) NO301375B1 (OSRAM)
RU (1) RU2104288C1 (OSRAM)
SG (1) SG48772A1 (OSRAM)
TW (1) TW259796B (OSRAM)
YU (1) YU63593A (OSRAM)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5714424A (en) * 1995-01-09 1998-02-03 W. R. Grace & Co.-Conn. Multi-component polyolefin catalysts
EP0849293A1 (en) 1996-12-20 1998-06-24 Fina Research S.A. Production of polyethylene having a bimodal molecular weight distribution
AU5630198A (en) * 1997-03-07 1998-09-10 Phillips Petroleum Company A process for polymerizing olefins
EP1041089A1 (en) 1999-03-29 2000-10-04 Fina Research S.A. Production of polyethylene
US6569960B2 (en) 1999-07-27 2003-05-27 Phillips Petroleum Company Process to produce polymers
US6538077B1 (en) * 1999-11-04 2003-03-25 Phillips Petroleum Company Polymerization catalyst systems, methods of making and uses therefor
GB9928176D0 (en) 1999-11-29 2000-01-26 Borealis Polymers Oy Polymer
US6696388B2 (en) * 2000-01-24 2004-02-24 E. I. Du Pont De Nemours And Company Gel catalysts and process for preparing thereof
EP1138604A1 (en) 2000-03-30 2001-10-04 Fina Research S.A. Glossy plastic containers
ES2225586T3 (es) 2000-07-05 2005-03-16 Basell Polyolefine Gmbh Catalizador de cromo soportado, titanizado, y su empleo para la obtrencion de homopolimeros y copolimeros de etileno.
EP1300240A1 (en) * 2001-10-02 2003-04-09 Atofina Research S.A. High ESCR glossy plastic containers
JP4048043B2 (ja) * 2001-11-02 2008-02-13 日揮株式会社 硫化カルボニル及びシアン化水素の分解触媒及び分解方法
AU2003226163A1 (en) * 2003-03-31 2004-11-23 Exxonmobil Chemical Patents Inc. Catalyst activation method and activated catalyst
US6982304B2 (en) 2003-12-22 2006-01-03 Union Carbide Chemicals & Plastics Technology Corporation Blow molding resins with improved ESCR
MX2012000254A (es) * 2009-06-29 2012-01-25 Chevron Philips Chemical Company Lp El uso de catalizadores de depuracion de hidrogeno para controlar niveles de hidrogeno y peso molecular de polimero en un reactor de polimerizacion.
SG176975A1 (en) 2009-06-29 2012-02-28 Chevron Phillips Chemical Co Dual metallocene catalyst systems for decreasing melt index and increasing polymer production rates
BR112012011066B1 (pt) * 2009-11-10 2019-09-10 Ineos Commercial Services Uk processo para a polimerização, de preferência a polimerização em fase gasosa, de pelo menos uma alfa-olefina
US8399580B2 (en) 2010-08-11 2013-03-19 Chevron Philips Chemical Company Lp Additives to chromium catalyst mix tank
WO2012086780A1 (ja) * 2010-12-24 2012-06-28 日本ポリエチレン株式会社 改良された分岐度分布を有するポリエチレン
WO2012133713A1 (ja) 2011-03-30 2012-10-04 日本ポリエチレン株式会社 エチレン系重合体、エチレン系重合体の製造方法および重合用触媒の製造方法、並びにエチレン系重合体を含む中空プラスチック成形品とその用途
CN109160963B (zh) * 2018-08-28 2021-05-04 吉化集团吉林市天龙催化剂有限公司 一种乙烯聚合用镁改性铬系催化剂及其制备方法
US11186656B2 (en) 2019-05-24 2021-11-30 Chevron Phillips Chemical Company Lp Preparation of large pore silicas and uses thereof in chromium catalysts for olefin polymerization

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978002A (en) * 1972-12-04 1976-08-31 National Petro Chemicals Corporation Catalyst useful for olefin polymerization process
US4735931A (en) * 1986-06-16 1988-04-05 Phillips Petroleum Company In situ comonomer generation in olefin polymerization
EP0291824A2 (en) * 1987-05-20 1988-11-23 QUANTUM CHEMICAL CORPORATION (a Virginia corp.) Improved chromium catalyst compositions
EP0307907A2 (en) * 1987-09-18 1989-03-22 Phillips Petroleum Company Process for olefin polymerization
WO1992017511A1 (en) * 1991-03-26 1992-10-15 Quantum Chemical Corporation Mixed chromium catalysts and polymerizations utilizing same

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3135809A (en) * 1960-07-21 1964-06-02 Southern Res Inst Isomerization process
US3225023A (en) * 1962-11-30 1965-12-21 Phillips Petroleum Co Process for controlling melt index
US3624063A (en) * 1969-07-10 1971-11-30 Phillips Petroleum Co Ethylene polymerization using catalyst of controlled particle size
US3798202A (en) * 1971-10-12 1974-03-19 Phillips Petroleum Co Polyolefin production
US4025707A (en) * 1974-03-28 1977-05-24 Phillips Petroleum Company Mixed hydrocarbyloxide treated catalyst activated at different temperatures
USRE31443E (en) * 1977-12-05 1983-11-15 Phillips Petroleum Company Treatment of silica
US4248735A (en) * 1979-06-01 1981-02-03 Phillips Petroleum Company Treatment of silica
US4169926A (en) * 1978-01-16 1979-10-02 Phillips Petroleum Company Inorganic hydrogels and uses thereof
US4325839A (en) * 1979-12-21 1982-04-20 Phillips Petroleum Company Impregnated second valence chromium compound in supported catalyst
US4384086A (en) * 1980-02-06 1983-05-17 Phillips Petroleum Company Large pore volume olefin polymerization catalysts
US4806513A (en) * 1984-05-29 1989-02-21 Phillips Petroleum Company Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same
US4560733A (en) * 1984-10-01 1985-12-24 Phillips Petroleum Company Polymerization and catalyst
US4981927A (en) * 1987-05-20 1991-01-01 National Distillers And Chemical Corporation Chromium catalyst compositions and polymerization utilizing same
US4981831A (en) * 1988-07-25 1991-01-01 Phillips Petroleum Company Twice-aged porous inorganic oxides, catalysts, and polymerization processes
JPH02105806A (ja) * 1988-10-13 1990-04-18 Nippon Oil Co Ltd エチレン重合体の製造方法
US4967029A (en) * 1989-09-07 1990-10-30 Mobil Oil Corporation Liquid lubricants from alpha-olefin and styrene copolymers
US4988657A (en) * 1989-10-06 1991-01-29 Phillips Petroleum Company Process for olefin polymerization
US5034364A (en) * 1989-11-09 1991-07-23 Mobil Oil Corporation Multiple chromium compound-containing catalyst composition and olefin polymerization therewith

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978002A (en) * 1972-12-04 1976-08-31 National Petro Chemicals Corporation Catalyst useful for olefin polymerization process
US4735931A (en) * 1986-06-16 1988-04-05 Phillips Petroleum Company In situ comonomer generation in olefin polymerization
EP0291824A2 (en) * 1987-05-20 1988-11-23 QUANTUM CHEMICAL CORPORATION (a Virginia corp.) Improved chromium catalyst compositions
EP0307907A2 (en) * 1987-09-18 1989-03-22 Phillips Petroleum Company Process for olefin polymerization
WO1992017511A1 (en) * 1991-03-26 1992-10-15 Quantum Chemical Corporation Mixed chromium catalysts and polymerizations utilizing same

Also Published As

Publication number Publication date
RU2104288C1 (ru) 1998-02-10
CN1167121A (zh) 1997-12-10
DK0591968T3 (da) 1998-01-26
CA2100144A1 (en) 1994-04-09
EP0591968B1 (en) 1997-07-09
AU654445B2 (en) 1994-11-03
US5486584A (en) 1996-01-23
HU9302831D0 (en) 1994-01-28
KR940009215A (ko) 1994-05-20
ATE155146T1 (de) 1997-07-15
ES2104017T3 (es) 1997-10-01
JPH06199920A (ja) 1994-07-19
CA2100144C (en) 1998-12-29
NO933577D0 (no) 1993-10-06
EP0591968A3 (en) 1994-11-30
NO933577L (no) 1994-04-11
SG48772A1 (en) 1998-05-18
KR100278751B1 (ko) 2001-01-15
HUT69750A (en) 1995-09-28
CN1085566A (zh) 1994-04-20
DE69312005T2 (de) 1997-10-30
CN1100068C (zh) 2003-01-29
NO301375B1 (no) 1997-10-20
MX9306146A (es) 1994-04-29
HU212809B (en) 1996-11-28
YU63593A (sh) 1996-07-24
JP3198206B2 (ja) 2001-08-13
CN1150954A (zh) 1997-06-04
AU4628793A (en) 1994-04-21
TW259796B (OSRAM) 1995-10-11
EP0591968A2 (en) 1994-04-13
US5595953A (en) 1997-01-21
DE69312005D1 (de) 1997-08-14

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