CN103649027B - 制备环庚烯的方法 - Google Patents

制备环庚烯的方法 Download PDF

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Publication number
CN103649027B
CN103649027B CN201280034094.3A CN201280034094A CN103649027B CN 103649027 B CN103649027 B CN 103649027B CN 201280034094 A CN201280034094 A CN 201280034094A CN 103649027 B CN103649027 B CN 103649027B
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Prior art keywords
reaction
diene
formula
closing metathesis
cycloheptene
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CN201280034094.3A
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Chinese (zh)
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CN103649027A (zh
Inventor
J·H·特莱斯
M·林巴赫
R·德恩
S·多伊尔莱因
M·丹兹
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/2078—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)-O- moiety is eliminated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C07C209/26—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/58—Preparation of carboxylic acid halides
    • C07C51/60—Preparation of carboxylic acid halides by conversion of carboxylic acids or their anhydrides or esters, lactones, salts into halides with the same carboxylic acid part
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280034094.3A 2011-07-12 2012-07-03 制备环庚烯的方法 Expired - Fee Related CN103649027B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11173656 2011-07-12
EP11173656.7 2011-07-12
PCT/EP2012/062944 WO2013007561A1 (de) 2011-07-12 2012-07-03 Verfahren zur herstellung von cyclohepten

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CN103649027A CN103649027A (zh) 2014-03-19
CN103649027B true CN103649027B (zh) 2016-04-20

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EP (1) EP2731923B1 (enExample)
JP (1) JP5916855B2 (enExample)
KR (1) KR20140054030A (enExample)
CN (1) CN103649027B (enExample)
IN (1) IN2014CN00746A (enExample)
WO (1) WO2013007561A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX356142B (es) 2012-06-13 2018-05-16 Basf Se Metodo para producir cetonas macrociclicas.
GB201604110D0 (en) * 2016-03-10 2016-04-20 Givaudan Sa Preparation of macrocyclic lactones

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101084184A (zh) * 2004-12-20 2007-12-05 霍夫曼-拉罗奇有限公司 环烷基胺衍生物

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3109040A (en) 1960-05-23 1963-10-29 Armour & Co Preparation of terminally unsaturated olefins from aliphatic carboxylic acids
US5077447A (en) 1990-09-28 1991-12-31 Henkel Research Corporation Process for making olefins
WO1996004289A1 (en) 1992-04-03 1996-02-15 California Institute Of Technology High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof
DE4321692A1 (de) 1993-06-30 1995-01-12 Basf Ag Verfahren zur Herstellung von cyclischen Ketonen
US5831108A (en) 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
KR100569619B1 (ko) 1997-06-25 2006-04-11 시바 스페셜티 케미칼스 홀딩 인크. 루테늄 및 오스뮴 카르벤 촉매
DE19815275B4 (de) 1998-04-06 2009-06-25 Evonik Degussa Gmbh Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
FR2796639A1 (fr) 1999-07-21 2001-01-26 Rhodia Chimie Sa Procede de preparation d'un acide carboxylique
DE60140455D1 (de) 2000-08-10 2009-12-24 Trustees Boston College Wiederverwendbare methathese-katalysatoren
US6759537B2 (en) 2001-03-23 2004-07-06 California Institute Of Technology Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
ATE348835T1 (de) 2002-01-22 2007-01-15 Univ Gent Metallkomplexe für die metathese
EP1394190B1 (de) * 2002-07-31 2007-01-03 Saltigo GmbH Metathesekatalysatoren
JP5406525B2 (ja) 2005-07-04 2014-02-05 ツァナン・サイテック・カンパニー・リミテッド ルテニウム錯体配位子、ルテニウム錯体、固定化ルテニウム錯体触媒及びその調製方法と用途
JP5612304B2 (ja) * 2006-04-11 2014-10-22 エージェンシー フォー サイエンス， テクノロジー アンド リサーチ 閉環メタセシスのための触媒
FR2909382B1 (fr) 2006-11-30 2009-01-23 Enscr Complexes catalytiques a base de ruthenium et utilisation de tels complexes pour la metathese d'olefines
DE102008008299B3 (de) 2008-02-08 2009-08-13 Leibniz-Institut für Oberflächenmodifizierung e.V. Latente photoaktivierbare Präkatalysatoren für die Metathesepolymerisation
US8044043B2 (en) * 2008-04-11 2011-10-25 Bristol-Myers Squibb Company CGRP receptor antagonists
US9410205B2 (en) 2010-02-18 2016-08-09 New York University Methods for predicting survival in metastatic melanoma patients

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101084184A (zh) * 2004-12-20 2007-12-05 霍夫曼-拉罗奇有限公司 环烷基胺衍生物

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
A Highly Catalytic and Selective Conversion of Carboxylic Acids to 1-Alkenes of One Less Carbon Atom;Joseph A. Miller;《J. Org. Chem.》;19931231;第58卷;18-20 *
New efficient catalytic system for hydroxycarbonylation without CO gas;Jean-Pierre Simonato;《Journal of Molecular Catalysis A: Chemical》;20031231;第197卷;61-64 *
On the relationship between structure and reaction rate in olefin ring-closing metathesis;Ian W. Ashworth et al;《Chem. Commun.》;20100906;第46卷;7145–7147 *
Organocatalyzed Conjugate Addition of Carbonyl Compounds to Nitrodienes/Nitroenynes and Synthetic Applications;Sébastien Belot et al;《Adv. Synth. Catal.》;20100219;第352卷;667-695 *
OXIDATION OF ORGANOBORANES WITH PYRIDINIUM CHLOROCHROMATE: A FACILE SYNTHESIS OF KETONES FROM ALKENES;V.V. RAMANA RAO et al;《Journal of Organomefallic Chemistry》;19781231;第162卷;C9-C10 *
Tandem Metal and Organocatalysis in Sequential Hydroformylation and Enantioselective Mannich Reactions;Serghei Chercheja et al;《Adv. Synth. Catal.》;20090206;第351卷;339-344 *

Also Published As

Publication number Publication date
WO2013007561A1 (de) 2013-01-17
JP5916855B2 (ja) 2016-05-11
CN103649027A (zh) 2014-03-19
EP2731923B1 (de) 2015-09-09
IN2014CN00746A (enExample) 2015-04-03
EP2731923A1 (de) 2014-05-21
JP2014524915A (ja) 2014-09-25
KR20140054030A (ko) 2014-05-08

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