CN103613763A - 一种高流动性聚亚苯基醚砜酮树脂及其工业化合成方法 - Google Patents
一种高流动性聚亚苯基醚砜酮树脂及其工业化合成方法 Download PDFInfo
- Publication number
- CN103613763A CN103613763A CN201310608711.2A CN201310608711A CN103613763A CN 103613763 A CN103613763 A CN 103613763A CN 201310608711 A CN201310608711 A CN 201310608711A CN 103613763 A CN103613763 A CN 103613763A
- Authority
- CN
- China
- Prior art keywords
- benzophenone
- polyphenylene ether
- ether sulfone
- ketone resin
- dihalo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011347 resin Substances 0.000 title claims abstract description 25
- 229920005989 resin Polymers 0.000 title claims abstract description 25
- 229920001955 polyphenylene ether Polymers 0.000 title claims abstract description 21
- -1 sulfone ketone Chemical class 0.000 title claims abstract description 21
- 238000001308 synthesis method Methods 0.000 title claims description 10
- 239000000178 monomer Substances 0.000 claims abstract description 29
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- 239000012965 benzophenone Substances 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 19
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 239000004305 biphenyl Substances 0.000 claims description 11
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 8
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 8
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- GPAPPPVRLPGFEQ-UHFFFAOYSA-N 4,4'-dichlorodiphenyl sulfone Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC=C(Cl)C=C1 GPAPPPVRLPGFEQ-UHFFFAOYSA-N 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 210000003097 mucus Anatomy 0.000 claims description 6
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical group O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims description 6
- AUHZEENZYGFFBQ-UHFFFAOYSA-N 1,3,5-trimethylbenzene Chemical compound CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004695 Polyether sulfone Substances 0.000 claims description 5
- 229920006393 polyether sulfone Polymers 0.000 claims description 5
- 150000003457 sulfones Chemical class 0.000 claims description 5
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
- 150000005323 carbonate salts Chemical class 0.000 claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- LSQARZALBDFYQZ-UHFFFAOYSA-N 4,4'-difluorobenzophenone Chemical group C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 LSQARZALBDFYQZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- YXMYPHLWXBXNFF-UHFFFAOYSA-N (2-chlorophenyl)-(4-chlorophenyl)methanone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=CC=C1Cl YXMYPHLWXBXNFF-UHFFFAOYSA-N 0.000 claims description 2
- QSWKFJLPMWWZJE-UHFFFAOYSA-N (4-chlorophenyl)-(2-fluorophenyl)methanone Chemical compound FC1=CC=CC=C1C(=O)C1=CC=C(Cl)C=C1 QSWKFJLPMWWZJE-UHFFFAOYSA-N 0.000 claims description 2
- QRFMXBKGNQEADL-UHFFFAOYSA-N 1,1'-biphenyl;phenol Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.C1=CC=CC=C1C1=CC=CC=C1 QRFMXBKGNQEADL-UHFFFAOYSA-N 0.000 claims description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000003495 polar organic solvent Substances 0.000 claims description 2
- 239000002798 polar solvent Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000003021 water soluble solvent Substances 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 10
- 229920000570 polyether Polymers 0.000 abstract description 10
- 125000001174 sulfone group Chemical group 0.000 abstract description 10
- 150000008365 aromatic ketones Chemical class 0.000 abstract description 7
- 239000002904 solvent Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 3
- 229920006260 polyaryletherketone Polymers 0.000 abstract description 3
- 229920005604 random copolymer Polymers 0.000 abstract description 2
- 238000007493 shaping process Methods 0.000 abstract description 2
- 229920000491 Polyphenylsulfone Polymers 0.000 abstract 1
- 125000000468 ketone group Chemical group 0.000 description 13
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 description 1
- 150000001492 aromatic hydrocarbon derivatives Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
- C08G65/4056—(I) or (II) containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
- C08G75/23—Polyethersulfones
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310608711.2A CN103613763B (zh) | 2013-11-27 | 2013-11-27 | 一种高流动性聚亚苯基醚砜酮树脂及其工业化合成方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310608711.2A CN103613763B (zh) | 2013-11-27 | 2013-11-27 | 一种高流动性聚亚苯基醚砜酮树脂及其工业化合成方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103613763A true CN103613763A (zh) | 2014-03-05 |
CN103613763B CN103613763B (zh) | 2015-08-26 |
Family
ID=50164485
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310608711.2A Active CN103613763B (zh) | 2013-11-27 | 2013-11-27 | 一种高流动性聚亚苯基醚砜酮树脂及其工业化合成方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103613763B (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104497300A (zh) * | 2014-12-17 | 2015-04-08 | 江门市优巨新材料有限公司 | 一种高流动性聚亚苯基醚砜酮树脂及其制备方法 |
CN105368037A (zh) * | 2015-11-30 | 2016-03-02 | 江门市优巨新材料有限公司 | 一种玻纤增强型扩链改性聚芳醚砜树脂及其制备方法 |
CN105968357A (zh) * | 2016-06-29 | 2016-09-28 | 江苏傲伦达科技实业股份有限公司 | 一种聚芳醚砜的制备方法 |
CN107141478A (zh) * | 2017-06-19 | 2017-09-08 | 佛山市珀力玛高新材料有限公司 | 一种改性聚醚砜的酮类树脂及其合成方法 |
WO2020200666A1 (en) | 2019-04-01 | 2020-10-08 | Basf Se | Amorphous polymer (p) comprising segments (s1), (s2) and (s3) |
CN112390952A (zh) * | 2020-11-17 | 2021-02-23 | 吉林大学 | 结晶型聚芳醚砜酮及制备方法和应用、聚亚苯基砜-聚芳醚砜酮二元合金材料及制备方法 |
CN113881045A (zh) * | 2021-12-07 | 2022-01-04 | 富海(东营)新材料科技有限公司 | 稳定提升聚醚砜冲击强度的合成方法 |
WO2022042814A1 (en) * | 2020-08-24 | 2022-03-03 | Basf Se | Polyphenylene sulfone |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20230356156A1 (en) * | 2020-08-24 | 2023-11-09 | Basf Se | Membrane comprising an amorphous polymer |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0265842A2 (de) * | 1986-10-28 | 1988-05-04 | BASF Aktiengesellschaft | Hochtemperaturbeständige Polyethersulfon/Polyetherketon-Blockcopolykondensate |
CN101544760A (zh) * | 2009-04-28 | 2009-09-30 | 吉林大学 | 含联苯结构聚醚醚砜和聚醚酮醚砜无规共聚物及其制备方法 |
CN101903468A (zh) * | 2007-12-18 | 2010-12-01 | 索维高级聚合物股份有限公司 | 聚苯砜酮共聚物 |
CN103642031A (zh) * | 2013-11-27 | 2014-03-19 | 江门市优巨新材料有限公司 | 一种高流动性聚亚苯基醚砜酮树脂及其工业化生产工艺 |
-
2013
- 2013-11-27 CN CN201310608711.2A patent/CN103613763B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0265842A2 (de) * | 1986-10-28 | 1988-05-04 | BASF Aktiengesellschaft | Hochtemperaturbeständige Polyethersulfon/Polyetherketon-Blockcopolykondensate |
CN101903468A (zh) * | 2007-12-18 | 2010-12-01 | 索维高级聚合物股份有限公司 | 聚苯砜酮共聚物 |
CN101544760A (zh) * | 2009-04-28 | 2009-09-30 | 吉林大学 | 含联苯结构聚醚醚砜和聚醚酮醚砜无规共聚物及其制备方法 |
CN103642031A (zh) * | 2013-11-27 | 2014-03-19 | 江门市优巨新材料有限公司 | 一种高流动性聚亚苯基醚砜酮树脂及其工业化生产工艺 |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104497300A (zh) * | 2014-12-17 | 2015-04-08 | 江门市优巨新材料有限公司 | 一种高流动性聚亚苯基醚砜酮树脂及其制备方法 |
CN105368037A (zh) * | 2015-11-30 | 2016-03-02 | 江门市优巨新材料有限公司 | 一种玻纤增强型扩链改性聚芳醚砜树脂及其制备方法 |
CN105368037B (zh) * | 2015-11-30 | 2018-06-01 | 江门市优巨新材料有限公司 | 一种玻纤增强型扩链改性聚芳醚砜树脂及其制备方法 |
CN105968357A (zh) * | 2016-06-29 | 2016-09-28 | 江苏傲伦达科技实业股份有限公司 | 一种聚芳醚砜的制备方法 |
CN107141478A (zh) * | 2017-06-19 | 2017-09-08 | 佛山市珀力玛高新材料有限公司 | 一种改性聚醚砜的酮类树脂及其合成方法 |
CN107141478B (zh) * | 2017-06-19 | 2019-11-15 | 佛山市珀力玛高新材料有限公司 | 一种改性聚醚砜的酮类树脂及其合成方法 |
WO2020200666A1 (en) | 2019-04-01 | 2020-10-08 | Basf Se | Amorphous polymer (p) comprising segments (s1), (s2) and (s3) |
CN113728035A (zh) * | 2019-04-01 | 2021-11-30 | 巴斯夫欧洲公司 | 包含链段(s1)、(s2)和(s3)的无定形聚合物(p) |
WO2022042814A1 (en) * | 2020-08-24 | 2022-03-03 | Basf Se | Polyphenylene sulfone |
CN112390952A (zh) * | 2020-11-17 | 2021-02-23 | 吉林大学 | 结晶型聚芳醚砜酮及制备方法和应用、聚亚苯基砜-聚芳醚砜酮二元合金材料及制备方法 |
CN112390952B (zh) * | 2020-11-17 | 2021-10-19 | 吉林大学 | 结晶型聚芳醚砜酮及制备方法和应用、聚亚苯基砜-聚芳醚砜酮二元合金材料及制备方法 |
CN113881045A (zh) * | 2021-12-07 | 2022-01-04 | 富海(东营)新材料科技有限公司 | 稳定提升聚醚砜冲击强度的合成方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103613763B (zh) | 2015-08-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103613763B (zh) | 一种高流动性聚亚苯基醚砜酮树脂及其工业化合成方法 | |
CN103626992B (zh) | 一种高热稳定性封端聚芳醚砜树脂的工业化合成方法 | |
CN104530419A (zh) | 一种高热稳定性封端聚砜树脂的工业化合成方法 | |
KR101466241B1 (ko) | 세그먼트 i과 세그먼트 ii를 함유한 터폴리머의 제조방법 | |
CN100374483C (zh) | 聚醚醚砜和聚醚醚酮三元共聚物的制备方法 | |
CN103642029B (zh) | 一种高流动性聚醚砜酮树脂及其工业化合成方法 | |
CN103626999A (zh) | 一种聚芳醚砜树脂的工业化合成方法 | |
CN104497239A (zh) | 一种低色度、高热稳定性封端的聚醚醚酮树脂的工业化合成方法 | |
CN103642030A (zh) | 一种高固含量聚芳醚砜树脂的工业化合成方法 | |
CN103642031B (zh) | 一种高流动性聚亚苯基醚砜酮树脂及其工业化生产工艺 | |
CN104530418A (zh) | 一种高热稳定性封端聚芳醚酮树脂的工业化合成方法 | |
CN104497300A (zh) | 一种高流动性聚亚苯基醚砜酮树脂及其制备方法 | |
CN105348531A (zh) | 一种四元共缩聚技术制备聚芳醚酮砜无规共聚物的方法 | |
CN103626991B (zh) | 一种高流动性聚醚砜酮树脂及其工业化生产工艺 | |
WO2017114163A1 (zh) | 一种砜聚合物的组合物及其制备方法与应用 | |
CN104592515A (zh) | 一种聚芳醚砜树脂的工业化合成方法 | |
CN104479089A (zh) | 一种高热稳定性封端含联苯结构聚芳醚酮树脂的工业化合成方法 | |
CN105348511A (zh) | 一种高热稳定性封端聚芳醚酮砜树脂的工业化合成方法 | |
CN100389139C (zh) | 环丁砜为溶剂合成含联苯聚醚醚酮和聚醚醚酮三元共聚物的方法 | |
CN105348532A (zh) | 一种高热稳定性封端树形聚芳醚砜树脂的工业化合成方法 | |
CN105330838A (zh) | 一种高透明聚芳醚砜树脂的工业化合成方法 | |
CN104497302B (zh) | 高流动性聚砜酮树脂及其生产工艺 | |
WO2011075942A1 (zh) | 聚联苯醚砜与聚联苯醚联苯砜三元共聚物的制备方法 | |
CN102532517A (zh) | 可溶解可紫外交联固化聚芳醚酮及其制备方法 | |
CN105330841A (zh) | 一种封端改性聚芳醚酮树脂的工业化合成方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-fluidity polyphenylene ether sulfone ketone resin and industrial synthesis method thereof Effective date of registration: 20160902 Granted publication date: 20150826 Pledgee: Bank of China Limited by Share Ltd Jiangmen branch Pledgor: JIANGMEN YOUJU NEW MATERIALS CO., LTD. Registration number: 2016990000767 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 529040 Guangdong province Jiangmen City Road No. 291 dragon Jianghai District 1 buildings, 3 buildings Patentee after: Guangdong Youju advanced new material Co., Ltd Address before: 529080, No. 25, hi tech Zone, Jiangmen, Guangdong (Factory No. two) Patentee before: JIANGMEN YOUJU NEW MATERIALS Co.,Ltd. |
|
PM01 | Change of the registration of the contract for pledge of patent right | ||
PM01 | Change of the registration of the contract for pledge of patent right |
Change date: 20201125 Registration number: 2016990000767 Pledgor after: Guangdong Youju advanced new material Co., Ltd Pledgor before: JIANGMEN YOUJU NEW MATERIALS Co.,Ltd. |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220217 Granted publication date: 20150826 Pledgee: Bank of China Limited by Share Ltd. Jiangmen branch Pledgor: Guangdong Youju advanced new material Co.,Ltd. Registration number: 2016990000767 |