CN103370345B - 高度氟化的亚磺酸的低聚物和共低聚物及其盐 - Google Patents
高度氟化的亚磺酸的低聚物和共低聚物及其盐 Download PDFInfo
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- CN103370345B CN103370345B CN201180067219.8A CN201180067219A CN103370345B CN 103370345 B CN103370345 B CN 103370345B CN 201180067219 A CN201180067219 A CN 201180067219A CN 103370345 B CN103370345 B CN 103370345B
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- PDAVOLCVHOKLEO-UHFFFAOYSA-N acetyl benzenecarboperoxoate Chemical compound CC(=O)OOC(=O)C1=CC=CC=C1 PDAVOLCVHOKLEO-UHFFFAOYSA-N 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- AQLMHYSWFMLWBS-UHFFFAOYSA-N arsenite(1-) Chemical compound O[As](O)[O-] AQLMHYSWFMLWBS-UHFFFAOYSA-N 0.000 description 1
- 150000004792 aryl magnesium halides Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- MWOBKFYERIDQSZ-UHFFFAOYSA-N benzene;sodium Chemical compound [Na].C1=CC=CC=C1 MWOBKFYERIDQSZ-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- IWTBWSGPDGPTIB-UHFFFAOYSA-N butanoyl butaneperoxoate Chemical compound CCCC(=O)OOC(=O)CCC IWTBWSGPDGPTIB-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- 125000000532 dioxanyl group Chemical group 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229940046149 ferrous bromide Drugs 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- AQYSYJUIMQTRMV-UHFFFAOYSA-N hypofluorous acid Chemical group FO AQYSYJUIMQTRMV-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 229910000103 lithium hydride Inorganic materials 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 238000003808 methanol extraction Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- URXNVXOMQQCBHS-UHFFFAOYSA-N naphthalene;sodium Chemical compound [Na].C1=CC=CC2=CC=CC=C21 URXNVXOMQQCBHS-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- RCIVOBGSMSSVTR-UHFFFAOYSA-L stannous sulfate Chemical compound [SnH2+2].[O-]S([O-])(=O)=O RCIVOBGSMSSVTR-UHFFFAOYSA-L 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000002730 succinyl group Chemical group C(CCC(=O)*)(=O)* 0.000 description 1
- 238000006351 sulfination reaction Methods 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical compound FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- DZXKSFDSPBRJPS-UHFFFAOYSA-N tin(2+);sulfide Chemical compound [S-2].[Sn+2] DZXKSFDSPBRJPS-UHFFFAOYSA-N 0.000 description 1
- 229910000375 tin(II) sulfate Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C313/02—Sulfinic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/184—Monomers containing fluorine with fluorinated vinyl ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061424153P | 2010-12-17 | 2010-12-17 | |
| US61/424,153 | 2010-12-17 | ||
| PCT/US2011/063383 WO2012082454A1 (en) | 2010-12-17 | 2011-12-06 | Oligomers and co-oligomers of highly fluorinated sulfinic acid and salts thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103370345A CN103370345A (zh) | 2013-10-23 |
| CN103370345B true CN103370345B (zh) | 2016-06-29 |
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| US (1) | US9266999B2 (enExample) |
| EP (1) | EP2651988B1 (enExample) |
| JP (2) | JP6081922B2 (enExample) |
| CN (1) | CN103370345B (enExample) |
| WO (1) | WO2012082454A1 (enExample) |
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| CN103370305B (zh) * | 2010-12-17 | 2015-12-09 | 3M创新有限公司 | 高度氟化的亚磺酸的低聚物和共低聚物以及它们的盐的制备 |
| EP2652049A4 (en) | 2010-12-17 | 2016-01-13 | 3M Innovative Properties Co | FLUORINATED OLIGOMERS HAVING FRACTIONS CONTAINING PENDING BROMINE |
| JP5986102B2 (ja) * | 2010-12-17 | 2016-09-06 | スリーエム イノベイティブ プロパティズ カンパニー | マイクロエマルジョン及びマイクロエマルジョンを用いて作製されたフルオロポリマー |
| CN103347842B (zh) | 2010-12-17 | 2016-09-28 | 3M创新有限公司 | 部分氟化的亚磺酸单体和它们的盐 |
| CN103261242B (zh) | 2010-12-17 | 2016-05-04 | 3M创新有限公司 | 包含含有亚磺酸根的分子的含氟聚合物 |
| CN103347853B (zh) * | 2010-12-17 | 2015-01-07 | 3M创新有限公司 | 全氟乙烯基醚亚磺酸及其盐的制备 |
| JP5997264B2 (ja) | 2011-06-03 | 2016-09-28 | スリーエム イノベイティブ プロパティズ カンパニー | アリルエーテル末端フルオロアルキルスルフィン酸及びその塩 |
| EP2788318A2 (en) * | 2011-12-06 | 2014-10-15 | 3M Innovative Properties Company | Fluorinated oligomers having pendant functional groups |
| US9187630B2 (en) | 2011-12-16 | 2015-11-17 | 3M Innovative Properties Company | Processing aid composition derived from a sulfinate-containing molecule |
| CN116622018A (zh) | 2018-03-01 | 2023-08-22 | 大金工业株式会社 | 含氟聚合物的制造方法 |
| US12195617B2 (en) | 2018-11-19 | 2025-01-14 | Daikin Industries, Ltd. | Composition and stretched body |
| CN113039213B (zh) | 2018-11-19 | 2023-07-28 | 大金工业株式会社 | 改性聚四氟乙烯的制造方法和组合物 |
| EP3960713A4 (en) | 2019-04-26 | 2023-01-18 | Daikin Industries, Ltd. | Water treatment method and composition |
| CN113728014B (zh) | 2019-04-26 | 2024-07-26 | 大金工业株式会社 | 含氟聚合物水性分散液的制造方法、排水的处理方法和含氟聚合物水性分散液 |
| WO2021045227A1 (ja) | 2019-09-05 | 2021-03-11 | ダイキン工業株式会社 | 組成物およびその製造方法 |
| JP7368759B2 (ja) | 2019-09-05 | 2023-10-25 | ダイキン工業株式会社 | パーフルオロエラストマーの製造方法および組成物 |
| JP7352110B2 (ja) | 2019-11-19 | 2023-09-28 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物 |
| JP7709062B2 (ja) | 2020-11-19 | 2025-07-16 | ダイキン工業株式会社 | 含フッ素エラストマー水性分散液の製造方法および組成物 |
| WO2022107894A1 (ja) | 2020-11-19 | 2022-05-27 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物 |
| EP4249525A4 (en) | 2020-11-19 | 2024-10-16 | Daikin Industries, Ltd. | METHOD FOR PREPARING AN AQUEOUS PERFLUOROLASTOMER DISPERSION, COMPOSITION, CROSS-LINKABLE COMPOSITION AND CROSS-LINKED PRODUCT |
| JP7727213B2 (ja) | 2021-03-10 | 2025-08-21 | ダイキン工業株式会社 | 塗料組成物、塗布膜、積層体および塗装物品 |
| JPWO2022244784A1 (enExample) | 2021-05-19 | 2022-11-24 | ||
| EP4342917A4 (en) | 2021-05-19 | 2025-06-04 | Daikin Industries, Ltd. | Fluoropolymer, aqueous solution and coating composition |
| CN117529511A (zh) | 2021-06-11 | 2024-02-06 | 大金工业株式会社 | 含氟弹性体水性分散液的制造方法、组合物和水性分散液 |
| EP4365211A4 (en) | 2021-06-30 | 2025-07-16 | Daikin Ind Ltd | METHOD FOR PRODUCING A COMPOSITION CONTAINING A HIGH-PURITY FLUOROPOLYMER, AND COMPOSITION CONTAINING A HIGH-PURITY FLUOROPOLYMER |
| JP7747987B2 (ja) | 2021-06-30 | 2025-10-02 | ダイキン工業株式会社 | フルオロポリマー組成物の製造方法およびフルオロポリマー組成物 |
| EP4497762A1 (en) | 2022-03-23 | 2025-01-29 | Daikin Industries, Ltd. | Method for producing fluoropolymer, and composition |
| WO2023210820A1 (ja) | 2022-04-28 | 2023-11-02 | ダイキン工業株式会社 | フッ素樹脂を含有する組成物の製造方法およびフッ素樹脂を含有する組成物 |
| WO2023210818A1 (ja) | 2022-04-28 | 2023-11-02 | ダイキン工業株式会社 | フッ素ゴムを含有する組成物 |
| EP4516819A1 (en) | 2022-04-28 | 2025-03-05 | Daikin Industries, Ltd. | Method for producing fluoropolymer |
| CN120548621A (zh) | 2023-01-18 | 2025-08-26 | 大金工业株式会社 | 电化学器件用合剂、电化学器件用合剂片、电极和电化学器件 |
| WO2024154773A1 (ja) | 2023-01-18 | 2024-07-25 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
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| US4544458A (en) * | 1978-11-13 | 1985-10-01 | E. I. Du Pont De Nemours And Company | Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof |
| CN1582304A (zh) * | 2001-09-01 | 2005-02-16 | 斯图加特大学化工研究所 | 含亚磺酸根基团的低聚物和聚合物及其生产方法 |
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|---|---|---|---|---|
| US2713593A (en) | 1953-12-21 | 1955-07-19 | Minnesota Mining & Mfg | Fluorocarbon acids and derivatives |
| US3420877A (en) | 1965-10-23 | 1969-01-07 | Minnesota Mining & Mfg | Process for the preparation of fluorocarbon sulfinates and derivatives thereof |
| US4151053A (en) * | 1975-07-09 | 1979-04-24 | Asahi Kasei Kogyo Kabushiki Kaisha | Cation exchange membrane preparation and use thereof |
| JPS5224176A (en) * | 1975-07-09 | 1977-02-23 | Asahi Chem Ind Co Ltd | Cathion exchange membrane |
| JPS5224177A (en) * | 1975-07-09 | 1977-02-23 | Asahi Chem Ind Co Ltd | Manufacturing method of fluorocarbon cathion exchange membrane |
| FR2388013B1 (fr) * | 1977-04-20 | 1985-08-02 | Du Pont | Polymeres fluores echangeurs d'ions contenant des groupes carboxyliques, leur preparation et leur utilisation dans des cellules d'electrolyse chlore-alcali |
| JPS5657832A (en) * | 1979-10-15 | 1981-05-20 | Kanegafuchi Chem Ind Co Ltd | Preparation of membrane structure for producing ion exchange membrane |
| JPS61185507A (ja) * | 1985-02-14 | 1986-08-19 | Tokuyama Soda Co Ltd | 陰イオン交換体の製造方法 |
| US4940525A (en) * | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| US5285002A (en) * | 1993-03-23 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Fluorine-containing polymers and preparation and use thereof |
| CN101721922B (zh) * | 2008-07-22 | 2011-12-28 | 山东华夏神舟新材料有限公司 | 一种微孔膜增强的多层含氟交联掺杂离子膜及其制备方法 |
| CN101693751B (zh) | 2009-10-26 | 2011-03-09 | 山东东岳神舟新材料有限公司 | 功能性氟树脂及其应用 |
| CN102008905B (zh) * | 2010-06-18 | 2013-09-25 | 山东华夏神舟新材料有限公司 | 一种质子交换膜及其制备方法和应用 |
| CN103347842B (zh) * | 2010-12-17 | 2016-09-28 | 3M创新有限公司 | 部分氟化的亚磺酸单体和它们的盐 |
| JP5986102B2 (ja) * | 2010-12-17 | 2016-09-06 | スリーエム イノベイティブ プロパティズ カンパニー | マイクロエマルジョン及びマイクロエマルジョンを用いて作製されたフルオロポリマー |
| CN103370305B (zh) * | 2010-12-17 | 2015-12-09 | 3M创新有限公司 | 高度氟化的亚磺酸的低聚物和共低聚物以及它们的盐的制备 |
| WO2012082546A1 (en) * | 2010-12-17 | 2012-06-21 | 3M Innovative Properties Company | Partially fluorinated polysulfinic acids and their salts |
| CN103261242B (zh) * | 2010-12-17 | 2016-05-04 | 3M创新有限公司 | 包含含有亚磺酸根的分子的含氟聚合物 |
-
2011
- 2011-12-06 WO PCT/US2011/063383 patent/WO2012082454A1/en not_active Ceased
- 2011-12-06 EP EP11802230.0A patent/EP2651988B1/en active Active
- 2011-12-06 JP JP2013544551A patent/JP6081922B2/ja active Active
- 2011-12-06 US US13/995,037 patent/US9266999B2/en active Active
- 2011-12-06 CN CN201180067219.8A patent/CN103370345B/zh active Active
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| US4544458A (en) * | 1978-11-13 | 1985-10-01 | E. I. Du Pont De Nemours And Company | Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof |
| CN1582304A (zh) * | 2001-09-01 | 2005-02-16 | 斯图加特大学化工研究所 | 含亚磺酸根基团的低聚物和聚合物及其生产方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20130267658A1 (en) | 2013-10-10 |
| US9266999B2 (en) | 2016-02-23 |
| WO2012082454A1 (en) | 2012-06-21 |
| EP2651988A1 (en) | 2013-10-23 |
| JP6081922B2 (ja) | 2017-02-15 |
| CN103370345A (zh) | 2013-10-23 |
| EP2651988B1 (en) | 2014-10-22 |
| JP2017061470A (ja) | 2017-03-30 |
| JP6279688B2 (ja) | 2018-02-14 |
| JP2014504293A (ja) | 2014-02-20 |
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