CN103268936B - 锂离子二次电池 - Google Patents
锂离子二次电池 Download PDFInfo
- Publication number
- CN103268936B CN103268936B CN201310117193.4A CN201310117193A CN103268936B CN 103268936 B CN103268936 B CN 103268936B CN 201310117193 A CN201310117193 A CN 201310117193A CN 103268936 B CN103268936 B CN 103268936B
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- Prior art keywords
- lithium
- battery
- active cathode
- equal
- cathode material
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- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 264
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 258
- 150000001875 compounds Chemical class 0.000 claims abstract description 95
- 239000002253 acid Substances 0.000 claims abstract description 86
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 81
- 239000011029 spinel Substances 0.000 claims abstract description 81
- 239000006182 cathode active material Substances 0.000 claims abstract description 78
- LBSANEJBGMCTBH-UHFFFAOYSA-N manganate Chemical compound [O-][Mn]([O-])(=O)=O LBSANEJBGMCTBH-UHFFFAOYSA-N 0.000 claims abstract description 78
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 74
- 239000010941 cobalt Substances 0.000 claims abstract description 74
- 229910052609 olivine Inorganic materials 0.000 claims abstract description 74
- 239000010450 olivine Substances 0.000 claims abstract description 74
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 229910004493 Li(Ni1/3Co1/3Mn1/3)O2 Inorganic materials 0.000 claims abstract description 36
- 229910015818 MPO4 Inorganic materials 0.000 claims abstract description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 157
- 239000011572 manganese Substances 0.000 claims description 73
- 239000004411 aluminium Substances 0.000 claims description 50
- 229910052782 aluminium Inorganic materials 0.000 claims description 50
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 50
- 229910032387 LiCoO2 Inorganic materials 0.000 claims description 49
- 239000011777 magnesium Substances 0.000 claims description 43
- 229910052759 nickel Inorganic materials 0.000 claims description 40
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 35
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 27
- 229910052748 manganese Inorganic materials 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 21
- 229910052749 magnesium Inorganic materials 0.000 claims description 21
- 239000011575 calcium Substances 0.000 claims description 16
- 229910052742 iron Inorganic materials 0.000 claims description 16
- -1 niobium sodium Chemical compound 0.000 claims description 14
- 239000010936 titanium Substances 0.000 claims description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 229910052796 boron Inorganic materials 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
- 229910052712 strontium Inorganic materials 0.000 claims description 5
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 239000003607 modifier Substances 0.000 claims description 2
- 150000002641 lithium Chemical class 0.000 claims 4
- 150000001868 cobalt Chemical class 0.000 claims 3
- FQNGWRSKYZLJDK-UHFFFAOYSA-N [Ca].[Ba] Chemical compound [Ca].[Ba] FQNGWRSKYZLJDK-UHFFFAOYSA-N 0.000 claims 2
- NACUKFIFISCLOQ-UHFFFAOYSA-N [Mg].[Cr] Chemical compound [Mg].[Cr] NACUKFIFISCLOQ-UHFFFAOYSA-N 0.000 claims 1
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 45
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 42
- 239000003792 electrolyte Substances 0.000 abstract description 29
- 229910002995 LiNi0.8Co0.15Al0.05O2 Inorganic materials 0.000 abstract description 26
- 238000000034 method Methods 0.000 abstract description 13
- 229910012820 LiCoO Inorganic materials 0.000 abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 31
- 239000010949 copper Substances 0.000 description 31
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 30
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 15
- 239000010406 cathode material Substances 0.000 description 15
- 229910052802 copper Inorganic materials 0.000 description 15
- 230000005611 electricity Effects 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 13
- 229910002804 graphite Inorganic materials 0.000 description 13
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- 150000003839 salts Chemical class 0.000 description 9
- 239000011149 active material Substances 0.000 description 8
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- 230000001070 adhesive effect Effects 0.000 description 8
- 238000013461 design Methods 0.000 description 8
- 229910052493 LiFePO4 Inorganic materials 0.000 description 7
- 229910014078 LiMn1.9Al0.1O4 Inorganic materials 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 7
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- 238000004519 manufacturing process Methods 0.000 description 6
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- 229910000668 LiMnPO4 Inorganic materials 0.000 description 5
- 229910001290 LiPF6 Inorganic materials 0.000 description 5
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical class COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 5
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- 229910012851 LiCoO 2 Inorganic materials 0.000 description 3
- 229910015752 LiNi0.8Al0.05Co0.15O2 Inorganic materials 0.000 description 3
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- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 1
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- YHLVIDQQTOMBGN-UHFFFAOYSA-N methyl prop-2-enyl carbonate Chemical compound COC(=O)OCC=C YHLVIDQQTOMBGN-UHFFFAOYSA-N 0.000 description 1
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- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
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- YCCPTBSIWCOONA-UHFFFAOYSA-N prop-1-ene;sulfurous acid Chemical group CC=C.OS(O)=O YCCPTBSIWCOONA-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0436—Small-sized flat cells or batteries for portable equipment
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/425—Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
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- H—ELECTRICITY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
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- H—ELECTRICITY
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
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- H—ELECTRICITY
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/42—Grouping of primary cells into batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/103—Primary casings; Jackets or wrappings characterised by their shape or physical structure prismatic or rectangular
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Battery Mounting, Suspending (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60/680,271 | 2003-10-07 | ||
| US63927504P | 2004-12-28 | 2004-12-28 | |
| US60/639,275 | 2004-12-28 | ||
| US68027105P | 2005-05-12 | 2005-05-12 | |
| US69928505P | 2005-07-14 | 2005-07-14 | |
| US60/699,285 | 2005-07-14 | ||
| CN2005800450074A CN101288197B (zh) | 2004-12-28 | 2005-12-23 | 锂离子二次电池 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800450074A Division CN101288197B (zh) | 2004-12-28 | 2005-12-23 | 锂离子二次电池 |
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| CN103268936A CN103268936A (zh) | 2013-08-28 |
| CN103268936B true CN103268936B (zh) | 2016-08-31 |
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| CN201310117193.4A Expired - Fee Related CN103268936B (zh) | 2004-12-28 | 2005-12-23 | 锂离子二次电池 |
| CN2005800450074A Expired - Fee Related CN101288197B (zh) | 2004-12-28 | 2005-12-23 | 锂离子二次电池 |
| CN2010105932269A Pending CN102074701A (zh) | 2004-12-28 | 2005-12-23 | 锂离子二次电池 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2005800450074A Expired - Fee Related CN101288197B (zh) | 2004-12-28 | 2005-12-23 | 锂离子二次电池 |
| CN2010105932269A Pending CN102074701A (zh) | 2004-12-28 | 2005-12-23 | 锂离子二次电池 |
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| EP (3) | EP2325930B1 (enExample) |
| JP (2) | JP2008525973A (enExample) |
| KR (2) | KR101329669B1 (enExample) |
| CN (3) | CN103268936B (enExample) |
| AT (2) | ATE552618T1 (enExample) |
| DE (1) | DE602005018543D1 (enExample) |
| ES (1) | ES2339041T3 (enExample) |
| TW (2) | TW200635094A (enExample) |
| WO (1) | WO2006071972A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12009516B2 (en) | 2019-09-18 | 2024-06-11 | Industrial Technology Research Institute | Fast charging lithium-ion battery |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101329669B1 (ko) * | 2004-12-28 | 2013-11-15 | 보스톤-파워, 인크. | 리튬 이온 2차 배터리 |
| US7811707B2 (en) * | 2004-12-28 | 2010-10-12 | Boston-Power, Inc. | Lithium-ion secondary battery |
| US20080008933A1 (en) | 2005-12-23 | 2008-01-10 | Boston-Power, Inc. | Lithium-ion secondary battery |
| EP1907871A1 (en) | 2005-07-14 | 2008-04-09 | Boston-Power, Inc. | Control electronics for li-ion batteries |
| US8936873B2 (en) * | 2005-08-16 | 2015-01-20 | Lg Chem, Ltd. | Cathode active material and lithium secondary battery containing them |
| CN101228654A (zh) * | 2005-08-16 | 2008-07-23 | 株式会社Lg化学 | 阴极活性材料及包含该阴极活性材料的锂二次电池 |
| US8895187B2 (en) | 2005-08-16 | 2014-11-25 | Lg Chem, Ltd. | Cathode active material and lithium secondary battery containing the same |
| CN101223658A (zh) * | 2005-08-16 | 2008-07-16 | 株式会社Lg化学 | 阴极活性材料及包含该活性材料的锂二次电池 |
| JP5103857B2 (ja) * | 2005-11-10 | 2012-12-19 | 日産自動車株式会社 | 二次電池用電極、および、これを用いた二次電池 |
| KR100801637B1 (ko) | 2006-05-29 | 2008-02-11 | 주식회사 엘지화학 | 양극 활물질 및 그것을 포함하고 있는 리튬 이차전지 |
| US8003241B2 (en) | 2006-06-23 | 2011-08-23 | Boston-Power, Inc. | Lithium battery with external positive thermal coefficient layer |
| CN101479865A (zh) | 2006-06-27 | 2009-07-08 | 波士顿电力公司 | 用于锂离子电池的整合性电流中断装置 |
| TWI426678B (zh) | 2006-06-28 | 2014-02-11 | Boston Power Inc | 具有多重充電率之電子裝置、電池組、充電於電子裝置中的鋰離子電荷儲存電源供應器之方法及可攜式電腦 |
| EP1989983B1 (de) * | 2007-05-07 | 2014-04-30 | Wessel-Werk GmbH | Saugdüse mit Akkumulatoreinheit für einen Staubsauger |
| US7838143B2 (en) | 2007-06-22 | 2010-11-23 | Boston-Power, Inc. | CID retention device for Li-ion cell |
| JP4595987B2 (ja) * | 2007-10-25 | 2010-12-08 | トヨタ自動車株式会社 | 正極活物質 |
| US7983021B2 (en) * | 2007-10-31 | 2011-07-19 | Corning Incorporated | Oblong electrochemical double layer capacitor |
| JP5370937B2 (ja) * | 2008-01-28 | 2013-12-18 | シャープ株式会社 | 正極活物質、正極及び非水二次電池 |
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| JP2008525973A (ja) | 2008-07-17 |
| EP2325930B1 (en) | 2012-10-10 |
| ATE453225T1 (de) | 2010-01-15 |
| HK1103858A1 (en) | 2007-12-28 |
| TW201114095A (en) | 2011-04-16 |
| ATE552618T1 (de) | 2012-04-15 |
| CN103268936A (zh) | 2013-08-28 |
| EP2178137A1 (en) | 2010-04-21 |
| CN101288197B (zh) | 2013-04-17 |
| EP1831952A2 (en) | 2007-09-12 |
| TW200635094A (en) | 2006-10-01 |
| EP2325930A1 (en) | 2011-05-25 |
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| KR20110000697A (ko) | 2011-01-04 |
| CN101288197A (zh) | 2008-10-15 |
| EP2178137B1 (en) | 2012-04-04 |
| WO2006071972A2 (en) | 2006-07-06 |
| KR101455663B1 (ko) | 2014-11-03 |
| ES2339041T3 (es) | 2010-05-14 |
| JP2011091052A (ja) | 2011-05-06 |
| CN102074701A (zh) | 2011-05-25 |
| KR101329669B1 (ko) | 2013-11-15 |
| KR20070100957A (ko) | 2007-10-15 |
| DE602005018543D1 (de) | 2010-02-04 |
| EP1831952B1 (en) | 2009-12-23 |
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