CN1030985C - 制备吡唑化合物的方法 - Google Patents
制备吡唑化合物的方法 Download PDFInfo
- Publication number
- CN1030985C CN1030985C CN92111258A CN92111258A CN1030985C CN 1030985 C CN1030985 C CN 1030985C CN 92111258 A CN92111258 A CN 92111258A CN 92111258 A CN92111258 A CN 92111258A CN 1030985 C CN1030985 C CN 1030985C
- Authority
- CN
- China
- Prior art keywords
- compound
- formula
- group
- amino
- pentafluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/38—Nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9120641.7 | 1991-09-27 | ||
GB919120641A GB9120641D0 (en) | 1991-09-27 | 1991-09-27 | Heterocyclic compounds |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN95114805A Division CN1115205A (zh) | 1991-09-27 | 1995-03-14 | 杀虫剂或杀螨剂组合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1071163A CN1071163A (zh) | 1993-04-21 |
CN1030985C true CN1030985C (zh) | 1996-02-14 |
Family
ID=10702123
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN92111258A Expired - Fee Related CN1030985C (zh) | 1991-09-27 | 1992-09-26 | 制备吡唑化合物的方法 |
CN95114805A Pending CN1115205A (zh) | 1991-09-27 | 1995-03-14 | 杀虫剂或杀螨剂组合物 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN95114805A Pending CN1115205A (zh) | 1991-09-27 | 1995-03-14 | 杀虫剂或杀螨剂组合物 |
Country Status (20)
Country | Link |
---|---|
US (1) | US5451598A (cs) |
EP (1) | EP0605469B1 (cs) |
JP (1) | JPH07500319A (cs) |
CN (2) | CN1030985C (cs) |
AT (1) | ATE163180T1 (cs) |
AU (2) | AU664199B2 (cs) |
BR (1) | BR9206552A (cs) |
CA (1) | CA2119385A1 (cs) |
CZ (1) | CZ71294A3 (cs) |
DE (1) | DE69224437T2 (cs) |
DK (1) | DK0605469T3 (cs) |
ES (1) | ES2112913T3 (cs) |
GB (2) | GB9120641D0 (cs) |
GR (1) | GR3026099T3 (cs) |
HU (1) | HU213636B (cs) |
IL (1) | IL103083A (cs) |
NZ (1) | NZ244265A (cs) |
TW (1) | TW221290B (cs) |
WO (1) | WO1993006089A1 (cs) |
ZA (1) | ZA926785B (cs) |
Families Citing this family (103)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2716453B1 (fr) * | 1994-02-22 | 1996-03-29 | Rhone Poulenc Agrochimie | Procédé de sulfinylation de composés hétérocycliques. |
GB9306184D0 (en) * | 1993-03-25 | 1993-05-19 | Zeneca Ltd | Heteroaromatic compounds |
US5747519A (en) * | 1994-02-27 | 1998-05-05 | Rhone-Poulenc Agrochimie | Synergistic termiticidal composition of pyrethroid and N-phenyl-pyrazole |
KR100385254B1 (ko) * | 1994-11-21 | 2003-08-21 | 세이코 엡슨 가부시키가이샤 | 액정구동장치,액정표시장치,아날로그버퍼및액정구동방법 |
IL116148A (en) * | 1994-11-30 | 2001-03-19 | Rhone Poulenc Agrochimie | Complexible composition for insect control |
IL116147A (en) | 1994-11-30 | 2002-05-23 | Aventis Cropscience Sa | Complexible composition for insect control |
CN1066717C (zh) * | 1995-02-17 | 2001-06-06 | 罗纳-普朗克农业化学公司 | 1-芳基吡唑类杀虫剂 |
US5637607A (en) * | 1995-02-17 | 1997-06-10 | Rhone-Poulenc Inc. | Pesticidal 1-arylpyrazoles |
US5801189A (en) * | 1995-04-05 | 1998-09-01 | Rhone-Poulenc Agriculture Limited | Method for combating insects |
US5629335A (en) * | 1995-04-07 | 1997-05-13 | Rhone-Poulenc Inc. | Pesticidal 1-arylpyrazole-3-carboximidothioic acid esters |
US5614182A (en) * | 1995-04-10 | 1997-03-25 | Rhone-Poulenc Inc. | Methods of attracting and combatting insects |
FR2733120B1 (fr) * | 1995-04-19 | 2002-09-13 | Rhone Poulenc Agrochimie | Protection des cultures contre les oiseaux a l'aide d'un compose de type phenylpyrazole |
US5585329A (en) * | 1995-04-28 | 1996-12-17 | Rhone-Poulenc Inc. | Plant growth promotion using 3-cyano-1-phenylpyrazoles such as fipronil |
US5707934A (en) * | 1995-04-28 | 1998-01-13 | Rhone-Poulenc Inc. | Plant growth regulation using 3-cyano-1-phenylpyrazoles such as fipronil |
US5696144A (en) * | 1995-05-01 | 1997-12-09 | Rhone-Poulenc Inc. | Protection of corn |
AUPN328395A0 (en) * | 1995-05-31 | 1995-06-22 | Rhone-Poulenc Rural Australia Pty Ltd | Insecticide |
US6060495A (en) * | 1995-06-05 | 2000-05-09 | Rhone-Poulenc Agrochimie | Pesticidal sulfur compounds |
US6060502A (en) * | 1995-06-05 | 2000-05-09 | Rhone-Poulenc Agrochimie | Pesticidal sulfur compounds |
US6136983A (en) * | 1995-06-05 | 2000-10-24 | Rhone-Poulenc Agrochimie | Pesticidal sulfur compounds |
US6261996B1 (en) | 1995-06-08 | 2001-07-17 | Rhone-Poulenc Inc. | Pregerminated rice seed |
FR2735951A1 (fr) * | 1995-06-29 | 1997-01-03 | Rhone Poulenc Agrochimie | Procede de controle d'une population de fourmis ou de guepes |
FR2735950B1 (fr) * | 1995-06-29 | 1997-08-01 | Rhone Poulenc Agrochimie | Compositions insecticides a base d'un derive de phenylpyrazole pour lutter notamment contre les fourmis |
FR2735952B1 (fr) * | 1995-06-29 | 1997-08-01 | Rhone Poulenc Agrochimie | Procede de controle d'une population d'insectes sociaux |
FR2739255B1 (fr) | 1995-09-29 | 1998-09-04 | Rhone Merieux | Composition antiparasitaire pour le traitement et la protection des animaux de compagnie |
FR2739254B1 (fr) * | 1995-09-29 | 1997-12-19 | Rhone Merieux | Composition antiparasitaire pour le traitement et la protection des animaux de compagnie |
US5814652A (en) * | 1995-12-20 | 1998-09-29 | Rhone-Poulenc Inc. | Pesticidal 5-amino-4-ethylsulfinyl-1-arylpyrazoles |
AU1555797A (en) | 1996-01-30 | 1997-08-22 | Takeda Chemical Industries Ltd. | Arylpyrazole insecticides |
FR2745469B1 (fr) * | 1996-03-04 | 1998-09-18 | Rhone Poulenc Agrochimie | Pyrazoles fongicides |
GB9604691D0 (en) * | 1996-03-05 | 1996-05-01 | Rhone Poulenc Agriculture | New processes for preparing pesticidal intermediates |
GR1002899B (el) * | 1996-03-29 | 1998-05-11 | Rhone Merieux | Περιλαιμιο κατα ψυλλων και κροτωνων για σκυλους και γατες, με βαση ν-φαινυλπυραζολη |
IE970215A1 (en) * | 1996-03-29 | 1997-10-08 | Rhone Merieux | Direct pour-on skin solution for antiparasitic use in cattle¹and sheep |
IE80657B1 (en) | 1996-03-29 | 1998-11-04 | Merial Sas | Insecticidal combination to control mammal fleas in particular fleas on cats and dogs |
AU727980B2 (en) | 1996-04-09 | 2001-01-04 | Rhone-Poulenc Agro | Wood glue incorporating an insecticide |
FR2747068B1 (fr) * | 1996-04-09 | 1998-04-30 | Rhone Poulenc Agrochimie | Materiaux a base de bois de type agglomere traites a l'aide d'un insecticide pyrazole |
FR2748503B1 (fr) | 1996-05-10 | 2001-03-02 | Rhone Poulenc Agrochimie | Utilisation de 1-phenyl pyrazole pour la protection de materiau composite contre les termites |
AU724487B2 (en) * | 1996-06-07 | 2000-09-21 | Rhone-Poulenc Rural Australia Pty Ltd | Method of treatment of sugar plant to improve the sugar content |
KR100577885B1 (ko) | 1996-07-23 | 2006-05-09 | 바이엘 크롭사이언스 소시에떼아노님 | 동물 주변 환경의 구충 처리를 위한 방법 및 조성물 |
US6524603B1 (en) | 1996-07-23 | 2003-02-25 | Rhone-Poulenc Agro | Process and composition for the antiparasitic treatment of the surroundings of animals |
ES2215231T3 (es) * | 1996-07-25 | 2004-10-01 | Pfizer Inc. | Pirazoles antiparasitarios. |
FR2753377B1 (fr) * | 1996-09-19 | 1999-09-24 | Rhone Merieux | Nouvelle association parasiticide a base de 1-n-phenylpyra- zoles et de lactones macrocycliques endectocides |
FR2753602B1 (fr) * | 1996-09-26 | 1998-10-30 | Composition agrochimique comprenant un 1-arylpyrazole et un polyethylene imine pour traitement des semences de riz | |
EP0839809A1 (en) * | 1996-11-01 | 1998-05-06 | Rhone-Poulenc Agrochimie | Pesticidal 1-arylpyrazole-5-sulfinilimine derivatives |
DE69715769T2 (de) | 1996-11-04 | 2003-05-28 | Bayer Cropscience S.A., Lyon | 1-Polyarylpyrazole als Pestizide |
EP0843962A1 (en) | 1996-11-22 | 1998-05-27 | Rhone-Poulenc Agrochimie | Flexible web containing 1-arylpyrazole pesticide |
EP0845211B1 (en) | 1996-11-29 | 2003-10-01 | Bayer CropScience S.A. | Protection of buildings against termites by 1-Arylpyrazoles |
DE19650197A1 (de) | 1996-12-04 | 1998-06-10 | Bayer Ag | 3-Thiocarbamoylpyrazol-Derivate |
TW524667B (en) | 1996-12-05 | 2003-03-21 | Pfizer | Parasiticidal pyrazoles |
US5929121A (en) * | 1996-12-13 | 1999-07-27 | Rhone-Poulenc Agro | Protection of trees |
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ZA9711534B (en) | 1996-12-24 | 1998-06-24 | Rhone Poulenc Agrochimie | Pesticidal 1-arylpyrazoles. |
JP2001506665A (ja) * | 1996-12-24 | 2001-05-22 | ローヌ−プーラン・アグロ | 農薬としての1−アリールおよびピリジルピラゾール誘導体 |
US6350771B1 (en) * | 1996-12-24 | 2002-02-26 | Rhone-Poulenc, Inc. | Pesticidal 1-arylpyrazoles |
ID22679A (id) * | 1997-03-03 | 1999-12-09 | Rhone Poulenc Agrochimie | Pengolahan untuk membuat bahan-bahan perantara untuk pestisida |
ZA981934B (en) * | 1997-03-10 | 1999-09-06 | Rhone Poulenc Agrochimie | Pesticidal 1-aryl-3-iminopyrazoles. |
ZA981776B (en) | 1997-03-10 | 1998-09-03 | Rhone Poulenc Agrochimie | Pesticidal 1-arylpyrazoles |
US5907041A (en) * | 1997-03-12 | 1999-05-25 | Rhone-Poulenc Inc. | Process for preparing pyrazole derivatives |
US6057355A (en) * | 1997-08-05 | 2000-05-02 | Rhone-Poulenc Inc. | Pesticidal combination |
EP0898885A1 (en) | 1997-08-29 | 1999-03-03 | Rhone-Poulenc Agrochimie | Protection system against subterranean termites |
EP0898888A1 (en) | 1997-08-29 | 1999-03-03 | Rhone-Poulenc Agrochimie | Device for the control of crawling social and/or congregating insects |
US6107314A (en) | 1997-10-07 | 2000-08-22 | Rhone-Poulenc Inc. | Pesticides |
US5981565A (en) | 1997-10-07 | 1999-11-09 | Rhone-Poulenc Inc. | Pyrazole pesticides |
BR9705278A (pt) * | 1997-10-15 | 1999-05-25 | Rhone Poulenc Agrochimie | Composição método para controlar formigas cortadas de folha e produto comercial |
BR9900235A (pt) * | 1998-02-20 | 2000-04-25 | Rhone Poulenc Agrochimie | Método de sugação quìmica de uma árvore e método de proteção de duas ou mais árvoes. |
DE69925255T2 (de) * | 1998-03-19 | 2006-02-23 | Merck & Co., Inc. | Schwefelpentafluorophenylpyrazole zur kontrolle von ektoparasitenbefall |
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DE19824487A1 (de) | 1998-06-02 | 1999-12-09 | Bayer Ag | Substituierte 3-Thiocarbamoylpyrazole |
EP0963695A1 (en) * | 1998-06-08 | 1999-12-15 | Rhone Poulenc Agro | Insecticidal method |
US6559175B1 (en) | 1998-09-18 | 2003-05-06 | Bayer Cropscience Inc. | Method of insect control |
US6149913A (en) * | 1998-11-16 | 2000-11-21 | Rhone-Poulenc Ag Company, Inc. | Compositions and methods for controlling insects |
AR021608A1 (es) * | 1998-12-11 | 2002-07-31 | Merial Ltd | Represion de artropodos en animales |
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US6156703A (en) * | 1999-05-21 | 2000-12-05 | Ijo Products, Llc | Method of inhibiting fruit set on fruit producing plants using an aqueous emulsion of eicosenyl eicosenoate and docosenyl eicosenoate |
US6409988B1 (en) | 1999-07-01 | 2002-06-25 | 3-Dimensional Pharmaceuticals, Inc. | Radiolabeled 1-aryl pyrazoles, the synthesis thereof and the use thereof as pest GABA receptor ligands |
US6506784B1 (en) | 1999-07-01 | 2003-01-14 | 3-Dimensional Pharmaceuticals, Inc. | Use of 1,3-substituted pyrazol-5-yl sulfonates as pesticides |
WO2001007413A1 (en) | 1999-07-22 | 2001-02-01 | 3-Dimensional Pharmaceuticals, Inc. | 1-aryl-3-thioalkyl pyrazoles, the synthesis thereof and the use thereof as insecticides |
FR2798042B1 (fr) * | 1999-09-07 | 2003-04-25 | Aventis Cropscience Sa | Compositions insecticides dont la matiere active est de type phenyl-pyrazole et procede de lutte contre les insectes du sol |
US6545033B1 (en) | 1999-10-06 | 2003-04-08 | 3-Dimensional Pharmaceuticals, Inc. | Fused 1-(2,6-dichloro-4-trifluoromethylphenyl)-pyrazoles, the synthesis thereof and the use thereof as pesticides |
EP1264823A1 (en) * | 2001-06-08 | 2002-12-11 | Novartis AG | Process for the preparation of 2,3-dicyanopropionates |
IL163790A0 (en) | 2002-03-05 | 2005-12-18 | Bayer Cropscience Sa | 5-Substituted-alkylaminopyrazole derivatives as pesticides |
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KR101033717B1 (ko) | 2002-12-03 | 2011-05-09 | 메리얼 리미티드 | 살충성 설포닐아미노피라졸 |
AU2002953128A0 (en) * | 2002-12-05 | 2002-12-19 | Osmose (Australia) Pty Ltd | Surface treatment for wood and wood products |
US7262214B2 (en) | 2003-02-26 | 2007-08-28 | Merial Limited | 1-N-arylpyrazole derivatives in prevention of arthropod-borne and mosquito-borne diseases |
WO2005023773A1 (en) * | 2003-09-04 | 2005-03-17 | Pfizer Limited | Process for the preparation of substituted aryl pyrazoles |
DE10353205A1 (de) * | 2003-11-13 | 2005-06-16 | Aventis Pharma Deutschland Gmbh | Ortho-substituierte Pentafluorsulfuranyl-Benzole, Verfahren zu ihrer Herstellung sowie ihre Verwendung als wertvolle Synthese-Zwischenstufen |
US7514464B2 (en) * | 2003-12-18 | 2009-04-07 | Pfizer Limited | Substituted arylpyrazoles |
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ATE456557T1 (de) | 2005-06-15 | 2010-02-15 | Pfizer Ltd | Substituierte arylpyrazole zur verwendung gegen parasiten |
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CN100391936C (zh) * | 2005-11-07 | 2008-06-04 | 栾忠岳 | 一种合成2、3-二氰基丙酸乙酯的工艺 |
CA2630849C (en) | 2005-12-14 | 2013-05-14 | Makhteshim Chemical Works Ltd. | Polymorphs and amorphous forms of 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1h-pyrazole-3-carbonitrile |
CA2656617C (en) | 2006-07-05 | 2014-10-14 | Aventis Agriculture | 1-aryl-5-alkyl pyrazole derivative compounds, processes of making and methods of using thereof |
WO2010106325A2 (en) | 2009-03-18 | 2010-09-23 | Omnipharm Limited | Parasiticidal formulation |
CN102250008A (zh) * | 2010-05-17 | 2011-11-23 | 温州大学 | 5-氨基-3-氰基-4-乙硫基-1-(2,6-二氯-4-三氟甲基苯基)吡唑的制备方法 |
WO2012147093A1 (en) | 2011-04-25 | 2012-11-01 | Keki Hormusji Gharda | A process for preparation of dicyanocarboxylate derivatives |
TWI579274B (zh) | 2012-04-20 | 2017-04-21 | 龍馬躍公司 | 製備1-芳基-5-烷基吡唑化合物的改良方法 |
GB201520724D0 (en) | 2015-11-24 | 2016-01-06 | Merial Inc | Veterinary formulations |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8531485D0 (en) * | 1985-12-20 | 1986-02-05 | May & Baker Ltd | Compositions of matter |
GB8713768D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
GB8920521D0 (en) * | 1989-09-11 | 1989-10-25 | May & Baker Ltd | New compositions of matter |
US5159105A (en) * | 1990-02-28 | 1992-10-27 | Minnesota Mining And Manufacturing Company | Higher pentafluorosulfanyl-fluoroaliphatic carbonyl and sulfonyl fluorides, and derivatives |
-
1991
- 1991-09-27 GB GB919120641A patent/GB9120641D0/en active Pending
-
1992
- 1992-09-02 GB GB929218552A patent/GB9218552D0/en active Pending
- 1992-09-07 IL IL10308392A patent/IL103083A/en not_active IP Right Cessation
- 1992-09-07 ZA ZA926785A patent/ZA926785B/xx unknown
- 1992-09-08 NZ NZ244265A patent/NZ244265A/en unknown
- 1992-09-08 WO PCT/GB1992/001636 patent/WO1993006089A1/en active IP Right Grant
- 1992-09-08 HU HU9400855A patent/HU213636B/hu not_active IP Right Cessation
- 1992-09-08 JP JP5505864A patent/JPH07500319A/ja active Pending
- 1992-09-08 US US08/211,232 patent/US5451598A/en not_active Expired - Fee Related
- 1992-09-08 ES ES92918815T patent/ES2112913T3/es not_active Expired - Lifetime
- 1992-09-08 DE DE69224437T patent/DE69224437T2/de not_active Expired - Fee Related
- 1992-09-08 BR BR9206552A patent/BR9206552A/pt not_active Application Discontinuation
- 1992-09-08 CA CA002119385A patent/CA2119385A1/en not_active Abandoned
- 1992-09-08 CZ CS94712A patent/CZ71294A3/cs unknown
- 1992-09-08 EP EP92918815A patent/EP0605469B1/en not_active Expired - Lifetime
- 1992-09-08 TW TW081107097A patent/TW221290B/zh active
- 1992-09-08 AT AT92918815T patent/ATE163180T1/de active
- 1992-09-08 AU AU25413/92A patent/AU664199B2/en not_active Ceased
- 1992-09-08 DK DK92918815T patent/DK0605469T3/da active
- 1992-09-26 CN CN92111258A patent/CN1030985C/zh not_active Expired - Fee Related
-
1995
- 1995-03-14 CN CN95114805A patent/CN1115205A/zh active Pending
- 1995-09-08 AU AU30512/95A patent/AU692902B2/en not_active Ceased
-
1998
- 1998-02-12 GR GR980400084T patent/GR3026099T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
CN1115205A (zh) | 1996-01-24 |
HU213636B (en) | 1997-08-28 |
ZA926785B (en) | 1993-06-09 |
DE69224437D1 (de) | 1998-03-19 |
TW221290B (cs) | 1994-02-21 |
GB9218552D0 (en) | 1992-10-14 |
ATE163180T1 (de) | 1998-02-15 |
WO1993006089A1 (en) | 1993-04-01 |
AU692902B2 (en) | 1998-06-18 |
NZ244265A (en) | 1995-03-28 |
DK0605469T3 (da) | 1998-09-23 |
GB9120641D0 (en) | 1991-11-06 |
CZ71294A3 (en) | 1994-07-13 |
EP0605469A1 (en) | 1994-07-13 |
GR3026099T3 (en) | 1998-05-29 |
IL103083A0 (en) | 1993-02-21 |
EP0605469B1 (en) | 1998-02-11 |
CA2119385A1 (en) | 1993-04-01 |
AU3051295A (en) | 1995-11-23 |
HUT66735A (en) | 1994-12-28 |
IL103083A (en) | 1999-03-12 |
HU9400855D0 (en) | 1994-06-28 |
ES2112913T3 (es) | 1998-04-16 |
US5451598A (en) | 1995-09-19 |
CN1071163A (zh) | 1993-04-21 |
JPH07500319A (ja) | 1995-01-12 |
AU2541392A (en) | 1993-04-27 |
DE69224437T2 (de) | 1998-06-04 |
AU664199B2 (en) | 1995-11-09 |
BR9206552A (pt) | 1995-10-17 |
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